TY - JOUR A1 - Lange, Dietrich A1 - Bedford, J. R. A1 - Moreno, M. A1 - Tilmann, F. A1 - Báez, Juan Carlos A1 - Bevis, M. A1 - Krüger, Frank T1 - Comparison of postseismic afterslip models with aftershock seismicity for three subduction-zone earthquakes: Nias 2005, Maule 2010 and Tohoku 2011 JF - Geophysical journal international N2 - We focus on the relation between seismic and total postseismic afterslip following the Maule M-w 8.8 earthquake on 2010 February 27 in central Chile. First, we calculate the cumulative slip released by aftershock seismicity. We do this by summing up the aftershock regions and slip estimated from scaling relations. Comparing the cumulative seismic slip with afterslip modelswe showthat seismic slip of individual aftershocks exceeds locally the inverted afterslip model from geodetic constraints. As the afterslip model implicitly contains the displacements from the aftershocks, this reflects the tendency of afterslip models to smear out the actual slip pattern. However, it also suggests that locally slip for a number of the larger aftershocks exceeds the aseismic slip in spite of the fact that the total equivalent moment of the afterslip exceeds the cumulative moment of aftershocks by a large factor. This effect, seen weakly for the Maule 2010 and also for the Tohoku 2011 earthquake, can be explained by taking into account the uncertainties of the seismicity and afterslip models. In spite of uncertainties, the hypocentral region of the Nias 2005 earthquake is suggested to release a large fraction of moment almost purely seismically. Therefore, these aftershocks are not driven solely by the afterslip but instead their slip areas have probably been stressed by interseismic loading and the mainshock rupture. In a second step, we divide the megathrust of the Maule 2010 rupture into discrete cells and count the number of aftershocks that occur within 50 km of the centre of each cell as a function of time. We then compare this number to a time-dependent afterslip model by defining the 'afterslip to aftershock ratio' (ASAR) for each cell as the slope of the best fitting line when the afterslip at time t is plotted against aftershock count. Although we find a linear relation between afterslip and aftershocks for most cells, there is significant variability in ASAR in both the downdip and along-strike directions of the megathrust. We compare the spatial distribution of ASAR with the spatial distribution of seismic coupling, coseismic slip and Bouguer gravity anomaly, and in each case we find no significant correlation. KW - Creep and deformation KW - Earthquake dynamics KW - Seismicity and tectonics KW - Continental margins: convergent Y1 - 2014 U6 - https://doi.org/10.1093/gji/ggu292 SN - 0956-540X SN - 1365-246X VL - 199 IS - 2 SP - 784 EP - 799 PB - Oxford Univ. Press CY - Oxford ER - TY - JOUR A1 - Douglas, John A1 - Akkar, Sinan A1 - Ameri, Gabriele A1 - Bard, Pierre-Yves A1 - Bindi, Dino A1 - Bommer, Julian J. A1 - Bora, Sanjay Singh A1 - Cotton, Fabrice A1 - Derras, Boumediene A1 - Hermkes, Marcel A1 - Kuehn, Nicolas Martin A1 - Luzi, Lucia A1 - Massa, Marco A1 - Pacor, Francesca A1 - Riggelsen, Carsten A1 - Sandikkaya, M. Abdullah A1 - Scherbaum, Frank A1 - Stafford, Peter J. A1 - Traversa, Paola T1 - Comparisons among the five ground-motion models developed using RESORCE for the prediction of response spectral accelerations due to earthquakes in Europe and the Middle East JF - Bulletin of earthquake engineering : official publication of the European Association for Earthquake Engineering N2 - This article presents comparisons among the five ground-motion models described in other articles within this special issue, in terms of data selection criteria, characteristics of the models and predicted peak ground and response spectral accelerations. Comparisons are also made with predictions from the Next Generation Attenuation (NGA) models to which the models presented here have similarities (e.g. a common master database has been used) but also differences (e.g. some models in this issue are nonparametric). As a result of the differing data selection criteria and derivation techniques the predicted median ground motions show considerable differences (up to a factor of two for certain scenarios), particularly for magnitudes and distances close to or beyond the range of the available observations. The predicted influence of style-of-faulting shows much variation among models whereas site amplification factors are more similar, with peak amplification at around 1s. These differences are greater than those among predictions from the NGA models. The models for aleatory variability (sigma), however, are similar and suggest that ground-motion variability from this region is slightly higher than that predicted by the NGA models, based primarily on data from California and Taiwan. KW - Strong-motion data KW - Ground-motion models KW - Ground-motion prediction equations KW - Style of faulting KW - Site amplification KW - Aleatory variability KW - Epistemic uncertainty KW - Europe KW - Middle East Y1 - 2014 U6 - https://doi.org/10.1007/s10518-013-9522-8 SN - 1570-761X SN - 1573-1456 VL - 12 IS - 1 SP - 341 EP - 358 PB - Springer CY - Dordrecht ER - TY - JOUR A1 - Spörer, Nadine A1 - Schuenemann, Nina T1 - competence: Analyzing effects on reading comprehension, reading strategy performance, and motivation for reading JF - Learning and instruction : the journal of the European Association for Research on Learning and Instruction N2 - In this study, reciprocal teaching (RT) was combined with specific self-regulation procedures to promote the reading comprehension of fifth grade students. Twenty four classes with N = 534 students were assigned to RT plus strategy implementation procedures (RT +SIP), RT plus outcome regulation procedures (RT + ORP), RT plus strategy implementation and outcome regulation procedures (RT+ SRL), or RT without explicit instruction in self-regulation. At maintenance students assigned to the three self-regulation conditions outperformed RT students according to a standardized measure of reading comprehension. RT+ SIP and RT + SRL students outperformed RI as well as RI + ORP students using a measure of reading strategy performance. However, reading comprehension was only mediated by strategy performance under the RT + SRL condition. Among students assigned to the RI + ORP condition, an improvement in reading motivation between pretest and posttest and between posttest and maintenance was observed. (C) 2014 Elsevier Ltd. All rights reserved. KW - Reading comprehension KW - Self-regulated learning KW - Reading strategies KW - Educational intervention research Y1 - 2014 U6 - https://doi.org/10.1016/j.learninstruc.2014.05.002 SN - 0959-4752 VL - 33 SP - 147 EP - 157 PB - Elsevier CY - Oxford ER - TY - JOUR A1 - Huber, Jasmina T1 - Competing Musical Traditions in the Holy Land in the 20th Century and How They Found Their Way into the Synagogue of Belgrade JF - PaRDeS : Zeitschrift der Vereinigung für Jüdische Studien e.V. N2 - The development of the current liturgical music used in the Belgrade synagogue is (in the last decades) heavily influenced by foreign traditions (mostly levantine) that are brought to Belgrade by modern communication systems. Therefore it is nearly impossible to speak of a status quo that might be possibly obsolete by tomorrow – at least with respect to the melodies. The great changes within the liturgical music occurred not due to acculturation into the Serbian majority but due to the personal preferences of the religious leaders of the Belgrade Jews. The alterations are a conscious process which is precisely the consequence of the musical taste of the local Rabbi and Cantor and not occurring autonomously. In order to understand the new nusah sepharadiyerushalmi that took the place of the forlorn nusah after the downfall of the Communist regime it is deemed necessary to look towards Israel where the rite developed. N2 - Die Analyse der Entwicklung der aktuellen liturgischen Musik in der Belgrader Synagoge zeigt, dass sie in den letzten Jahrzehnten mittels moderner Medien vielen Fremdeinflüssen, zumeist levantinischen, ausgesetzt war. Es ist daher fast unmöglich, von einem Status quo zu sprechen, da dieser alsbald zumindest in der Melodienwahl veraltet sein könnte. Der Wandel in den letzten zwanzig Jahren erfolgte nicht aufgrund von Akkulturation durch den Kontakt mit Serben, sondern auf Basis der individuellen musikalischen Präferenzen des Rabbiners und Kantors. Es ist kein Prozess, der automatisch als Anpassung abläuft, sondern bewusst gesteuerte Veränderung. Um den nach dem Fall des Kommunismus eingepflanzten neuen Ritus unter dem Namen nusah sepharadi-yerushalmi in seiner Entwicklung zu verstehen, muss man den regionalen Boden temporär verlassen und sich mit der ersten großen Aliah nach Israel begeben, um von dort aus seine Entstehung, Beschaffenheit und Verbreitung zurückzuverfolgen. Y1 - 2014 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus4-69234 SN - 1614-6492 SN - 1862-7684 VL - 20 SP - 87 EP - 98 PB - Universitätsverlag Potsdam CY - Potsdam ER - TY - THES A1 - Yeldesbay, Azamat T1 - Complex regimes of synchronization T1 - Komplexe Synchronisationszustände BT - modeling and analysis N2 - Synchronization is a fundamental phenomenon in nature. It can be considered as a general property of self-sustained oscillators to adjust their rhythm in the presence of an interaction. In this work we investigate complex regimes of synchronization phenomena by means of theoretical analysis, numerical modeling, as well as practical analysis of experimental data. As a subject of our investigation we consider chimera state, where due to spontaneous symmetry-breaking of an initially homogeneous oscillators lattice split the system into two parts with different dynamics. Chimera state as a new synchronization phenomenon was first found in non-locally coupled oscillators system, and has attracted a lot of attention in the last decade. However, the recent studies indicate that this state is also possible in globally coupled systems. In the first part of this work, we show under which conditions the chimera-like state appears in a system of globally coupled identical oscillators with intrinsic delayed feedback. The results of the research explain how initially monostable oscillators became effectivly bistable in the presence of the coupling and create a mean field that sustain the coexistence of synchronized and desynchronized states. Also we discuss other examples, where chimera-like state appears due to frequency dependence of the phase shift in the bistable system. In the second part, we make further investigation of this topic by modeling influence of an external periodic force to an oscillator with intrinsic delayed feedback. We made stability analysis of the synchronized state and constructed Arnold tongues. The results explain formation of the chimera-like state and hysteric behavior of the synchronization area. Also, we consider two sets of parameters of the oscillator with symmetric and asymmetric Arnold tongues, that correspond to mono- and bi-stable regimes of the oscillator. In the third part, we demonstrate the results of the work, which was done in collaboration with our colleagues from Psychology Department of University of Potsdam. The project aimed to study the effect of the cardiac rhythm on human perception of time using synchronization analysis. From our part, we made a statistical analysis of the data obtained from the conducted experiment on free time interval reproduction task. We examined how ones heartbeat influences the time perception and searched for possible phase synchronization between heartbeat cycles and time reproduction responses. The findings support the prediction that cardiac cycles can serve as input signals, and is used for reproduction of time intervals in the range of several seconds. N2 - Synchronisation ist ein fundamentales Naturphänomen. Es ist die grundlegende Eigenschaft sich selbsterhaltender Oszillatoren, in Gegenwart einer Wechselwirkung, danach zu streben, ihre Rhythmen anzupassen. In dieser Arbeit betrachten wir komplexe Synchronisationszustände sowohl mit Hilfe analytischer Methoden als auch durch numerische Simulation und in experimentellen Daten. Unser Untersuchungsobjekt sind die sogenannten Chimera Zustände, in welchen sich Ensemble von gekoppelten, identischen Oszillatoren auf Grund eines Symmetriebruches spontan in Gruppen mit unterschiedlicher Dynamik aufteilen. Die Entdeckung von Chimeras in zunächst nichtlokal gekoppelten Systemen hat in den letzten zehn Jahren ein großes Interesse an neuartigen Synchronisationsphänomenen geweckt. Neueste Forschungsergebnisse belegen, dass diese Zustände unter bestimmten Bedingungen auch in global gekoppelten Systemen existieren können. Solche Bedingungen werden im ersten Teil der Arbeit in Ensemblen global gekoppelter Oszillatoren mit zusätzlicher, zeitverzögerter Selbstkopplung untersucht. Wir zeigen, wie zunächst monostabile Oszillatoren in Gegenwart von dem Treiben der globalen Kopplung effektiv bistabil werden, und sich so in zwei Gruppen organisieren. Das mittlere Feld, welches durch diese Gruppen aufgebaut wird, ist quasiperiodisch wodurch der Chimera Zustand sich selbst stabilisiert. In einem anderen Beispiel zeigen wir, dass der Chimera Zustand auch durch einen frequenzabhängigen Phasenunterschied in der globalen Kopplung erreicht werden kann. Zur genaueren Untersuchung der Mechanismen, die zur effektiven Bistabilität führen, betrachten wir im zweiten Teil der Arbeit den Einfluss einer externen periodischen Kraft auf einzelne Oszillatoren mit zeitverzögerter Selbstkopplung. Wir führen die Stabilitätanalyse des synchronen Zustands durch, und stellen die Arnoldzunge dar. Im dritten Teil der Arbeit stellen wir die Ergebnisse einer Synchronisationsanalyse vor, welche in Kooperation mit Wissenschaftlern der Psychologischen Fakultät der Universität Potsdam durchgeführt wurde. In dem Projekt wurde die Auswirkung des Herzrhythmus auf die menschliche Zeitwahrnehmung erforscht. Unsere Aufgabe war es, die experimentellen Daten statistisch zu analysieren. Im Experiment sollten Probanden ein gegebenes Zeitintervall reproduzieren während gleichzeitig ihr Herzschlag aufgezeichnet wurde. Durch eine Phasenanalyse haben wir den Zusammenhang zwischen dem Herzschlag und der Start- bzw. Stoppzeit der zu reproduzierenden Zeitintervalle untersucht. Es stellt sich heraus, dass Herzschläge bei Zeitintervallen über einige Sekunden als Taktgeber dienen können. KW - synchronization KW - phase oscillators KW - chimera state KW - time perception KW - Synchronisation KW - Phasen Oszillatoren KW - chimera Zustände KW - zeitverzögerte Selbstkopplung KW - Synchronisationsanalyse KW - Zeitwahrnehmung Y1 - 2014 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus4-73348 ER - TY - JOUR A1 - Lorenz, Antje A1 - Heide, Judith A1 - Burchert, Frank T1 - Compound naming in aphasia: effects of complexity, part of speech, and semantic transparency JF - Language, cognition and neuroscience KW - compound production KW - morphology KW - decomposition KW - lemma KW - part of speech KW - semantic transparency KW - aphasia KW - word-finding difficulties Y1 - 2014 U6 - https://doi.org/10.1080/01690965.2013.766357 SN - 2327-3798 SN - 2327-3801 VL - 29 IS - 1 SP - 88 EP - 106 PB - Routledge, Taylor & Francis Group CY - Abingdon ER - TY - THES A1 - Brandt-Kobele, Oda-Christina T1 - Comprehension of verb inflection in German-speaking children T1 - Das Verständnis von Verbflexionsendungen bei deutschsprachigen Kindern N2 - Previous studies on the acquisition of verb inflection in normally developing children have revealed an astonishing pattern: children use correctly inflected verbs in their own speech but fail to make use of verb inflections when comprehending sentences uttered by others. Thus, a three-year old might well be able to say something like ‘The cat sleeps on the bed’, but fails to understand that the same sentence, when uttered by another person, refers to only one sleeping cat but not more than one. The previous studies that have examined children's comprehension of verb inflections have employed a variant of a picture selection task in which the child was asked to explicitly indicate (via pointing) what semantic meaning she had inferred from the test sentence. Recent research on other linguistic structures, such as pronouns or focus particles, has indicated that earlier comprehension abilities can be found when methods are used that do not require an explicit reaction, like preferential looking tasks. This dissertation aimed to examine whether children are truly not able to understand the connection the the verb form and the meaning of the sentence subject until the age of five years or whether earlier comprehension can be found when a different measure, preferential looking, is used. Additionally, children's processing of subject-verb agreement violations was examined. The three experiments of this thesis that examined children's comprehension of verb inflections revealed the following: German-speaking three- to four-year old children looked more to a picture showing one actor when hearing a sentence with a singular inflected verb but only when their eye gaze was tracked and they did not have to perform a picture selection task. When they were asked to point to the matching picture, they performed at chance-level. This pattern indicates asymmetries in children's language performance even within the receptive modality. The fourth experiment examined sensitivity to subject-verb agreement violations and did not reveal evidence for sensitivity toward agreement violations in three- and four-year old children, but only found that children's looking patterns were influenced by the grammatical violations at the age of five. The results from these experiments are discussed in relation to the existence of a production-comprehension asymmetry in the use of verb inflections and children's underlying grammatical knowledge. N2 - Experimentelle Studien zum Erwerb der Verbflexion bei sprachunauffälligen Kindern haben ein überraschendes Muster aufgezeigt. Kinder im Alter von drei und vier Jahren verwenden Verbflexionsendungen anscheinend korrekt in ihrer eigenen Sprachproduktion, aber sie scheinen unfähig zu sein, Verbflexionen in den Äußerungen anderer zu verstehen. Ein Kind ist also problemlos in der Lage “Sie schläft auf dem Bett.” zu sagen, wenn es die Position von z. B. einer Katze beschreiben möchte. Gleichzeitig scheint es nicht zu verstehen, dass sich ein Satz wie “Sie schläft auf dem Bett” auf nur eine schlafende Katze und nicht mehrere bezieht. Das Verständnis von Sätzen, in denen der einzige Hinweis auf die Anzahl der Handelnden (den Numerus des Subjekts) die Verbflexion ist, wurde bislang nur mit ‘Zeige-Experimenten’ untersucht. In solchen Sprachtests soll das Kind durch eine Zeigegeste auf eines von zwei vorgegebenen Bildern explizit anzeigen wie es den vorgegebenen Satz verstanden hat. Aktuelle Studien, die das Verständnis von sprachlichen Elementen wie Pronomen und Fokuspartikeln bei Kindern untersucht haben, lassen erkennen, dass die Testmethodik einen erheblichen Einfluss auf die kindlichen Sprachverständnisfähigkeiten zu haben scheint. Wenn man Methoden verwendet, die keine explizite Reaktion von Seiten der Kinder verlangen, findet man korrektes Verständnis schon bei jüngeren Kindern. Das Ziel dieser Dissertation war es zu untersuchen, ob drei- und vierjährige Kinder tatsächlich nicht in der Lage sind die Beziehung zwischen Verbform (Art der Verbflexion) und Subjektbedeutung (Numerus des Subjekts) zu verstehen oder ob man korrektes Sprachverständnis in jüngeren Populationen finden kann, wenn eine alternative Testmethode, die Messung der Augenbewegungen, verwendet wird. Zusätzlich wurde untersucht ob Kinder im gleichen Alter Verletzungen der Subjekt-Verb-Kongruenz in auditiv präsentierten Sätzen entdecken. Drei Experimente dieser Dissertation, die das kindliche Sprachverständnis in Bezug auf Verbflexion untersucht haben bringen folgendes Muster zum Vorschein: Deutsch-sprachige Kinder im Alter von drei bis vier Jahren schauten mehr zu einem Bild, auf dem nur ein Akteur zu sehen war, wenn sie einen Satz mit einem singular flektierten Verb hörten (Sie streichelt eine Katze). Andererseits schauten sie mehr zu einem Bild, auf dem zwei Akteure zu sehen waren, wenn sie einen Satz mit einem plural flektierten Verb hörten (Sie streicheln eine Katze). Wenn sie hingegen gebeten wurden, auf das korrekte Bild zu zeigen, reagierten sie nicht besser als es der Zufall erwartet hätte, d.h.~sie waren nicht in der Lage einen Satz einem entsprechenden Bild zuzuordnen. Dieses Ergebnismuster deutet auf die Existenz von (methoden-abhängigen) Asymmetrien innerhalb einer sprachlichen Modalität, dem Sprach\-verständnis, hin. Das vierte Experiment untersuchte die kindliche Sensitivität gegenüber der Verletzung von Subjekt-Verb-Kongruenz. Hier zeigte sich, dass das Blickverhalten von fünfjährigen Kindern von der Grammatikalität der Testsätze beeinflusst war, während keine Evidenz für das Erkennen von Grammatikalitätsverletzungen bei jüngeren Kindern gefunden werden konnte. Das asymmetrische Performanzmuster innerhalb der rezeptiven Modalität, das in dieser Arbeit gefunden wurde, erlaubt Rückschlüsse auf die Annahme einer Produktions-Verständnis-Aymmetrie und somit auch auf Theorien zur grammatischen Entwicklung bei Kindern. T3 - Spektrum Patholinguistik - Schriften - 6 KW - Spracherwerb KW - Verbflexion KW - Blickbewegungsmessung KW - Methoden KW - Sprachverständnis KW - Language acquisition KW - verb inflection KW - eye-tracking KW - methods KW - language comprehension Y1 - 2014 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus-62046 SN - 978-3-86956-216-2 SN - 1869-3822 SN - 1869-3830 PB - Universitätsverlag Potsdam CY - Potsdam ER - TY - JOUR A1 - Richter, Rico A1 - Döllner, Jürgen Roland Friedrich T1 - Concepts and techniques for integration, analysis and visualization of massive 3D point clouds JF - Computers, environment and urban systems N2 - Remote sensing methods, such as LiDAR and image-based photogrammetry, are established approaches for capturing the physical world. Professional and low-cost scanning devices are capable of generating dense 3D point clouds. Typically, these 3D point clouds are preprocessed by GIS and are then used as input data in a variety of applications such as urban planning, environmental monitoring, disaster management, and simulation. The availability of area-wide 3D point clouds will drastically increase in the future due to the availability of novel capturing methods (e.g., driver assistance systems) and low-cost scanning devices. Applications, systems, and workflows will therefore face large collections of redundant, up-to-date 3D point clouds and have to cope with massive amounts of data. Hence, approaches are required that will efficiently integrate, update, manage, analyze, and visualize 3D point clouds. In this paper, we define requirements for a system infrastructure that enables the integration of 3D point clouds from heterogeneous capturing devices and different timestamps. Change detection and update strategies for 3D point clouds are presented that reduce storage requirements and offer new insights for analysis purposes. We also present an approach that attributes 3D point clouds with semantic information (e.g., object class category information), which enables more effective data processing, analysis, and visualization. Out-of-core real-time rendering techniques then allow for an interactive exploration of the entire 3D point cloud and the corresponding analysis results. Web-based visualization services are utilized to make 3D point clouds available to a large community. The proposed concepts and techniques are designed to establish 3D point clouds as base datasets, as well as rendering primitives for analysis and visualization tasks, which allow operations to be performed directly on the point data. Finally, we evaluate the presented system, report on its applications, and discuss further research challenges. KW - 3D point clouds KW - System architecture KW - Classification KW - Out-of-core KW - Visualization Y1 - 2014 U6 - https://doi.org/10.1016/j.compenvurbsys.2013.07.004 SN - 0198-9715 SN - 1873-7587 VL - 45 SP - 114 EP - 124 PB - Elsevier CY - Oxford ER - TY - JOUR A1 - Plehn, Thomas A1 - Megow, Jörg A1 - May, Volkhard T1 - Concerted charge and energy transfer processes in a highly flexible fullerene-dye system: a mixed quantum-classical study JF - Physical chemistry, chemical physics : a journal of European Chemical Societies N2 - Photoinduced excitation energy transfer and accompanying charge separation are elucidated for a supramolecular system of a single fullerene covalently linked to six pyropheophorbide-a dye molecules. Molecular dynamics simulations are performed to gain an atomistic picture of the architecture and the surrounding solvent. Excitation energy transfer among the dye molecules and electron transfer from the excited dyes to the fullerene are described by a mixed quantum-classical version of the Forster rate and the semiclassical Marcus rate, respectively. The mean characteristic time of energy redistribution lies in the range of 10 ps, while electron transfer proceeds within 150 ps. In between, on a 20 to 50 ps time-scale, conformational changes take place in the system. This temporal hierarchy of processes guarantees efficient charge separation, if the structure is exposed to a solvent. The fast energy transfer can adopt the dye excitation to the actual conformation. In this sense, the probability to achieve charge separation is large enough since any dominance of unfavorable conformations that exhibit a large dye-fullerene distance is circumvented. And the slow electron transfer may realize an averaging with respect to different conformations. To confirm the reliability of our computations, ensemble measurements on the charge separation dynamics are simulated and a very good agreement with the experimental data is obtained. Y1 - 2014 U6 - https://doi.org/10.1039/c4cp01081g SN - 1463-9076 SN - 1463-9084 VL - 16 IS - 25 SP - 12949 EP - 12958 PB - Royal Society of Chemistry CY - Cambridge ER - TY - GEN A1 - Plehn, Thomas A1 - Megow, Jörg A1 - May, Volkhard T1 - Concerted charge and energy transfer processes in a highly flexible fullerene–dye system BT - a mixed quantum–classical study N2 - Photoinduced excitation energy transfer and accompanying charge separation are elucidated for a supramolecular system of a single fullerene covalently linked to six pyropheophorbide-a dye molecules. Molecular dynamics simulations are performed to gain an atomistic picture of the architecture and the surrounding solvent. Excitation energy transfer among the dye molecules and electron transfer from the excited dyes to the fullerene are described by a mixed quantum–classical version of the Förster rate and the semiclassical Marcus rate, respectively. The mean characteristic time of energy redistribution lies in the range of 10 ps, while electron transfer proceeds within 150 ps. In between, on a 20 to 50 ps time-scale, conformational changes take place in the system. This temporal hierarchy of processes guarantees efficient charge separation, if the structure is exposed to a solvent. The fast energy transfer can adopt the dye excitation to the actual conformation. In this sense, the probability to achieve charge separation is large enough since any dominance of unfavorable conformations that exhibit a large dye–fullerene distance is circumvented. And the slow electron transfer may realize an averaging with respect to different conformations. To confirm the reliability of our computations, ensemble measurements on the charge separation dynamics are simulated and a very good agreement with the experimental data is obtained. T3 - Zweitveröffentlichungen der Universität Potsdam : Mathematisch-Naturwissenschaftliche Reihe - 279 Y1 - 2014 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus4-98791 ER - TY - JOUR A1 - Rofes, Adria A1 - Bastiaanse, Roelien A1 - Martinez-Ferreiro, Silvia T1 - Conditional and future tense impairment in non-fluent aphasia JF - Aphasiology : an international, interdisciplinary journal N2 - Background: Morphological errors of tense and agreement are salient in agrammatic aphasia. The PADILIH predicts impairments in discourse linking that translate to greater difficulties in referring to a past event time than to a future or a present event time. In Catalan, the Periphrastic conditional tense (e.g., if the man had had time, he would have...) refers to the past and the Simple conditional tense refers to the future (e.g., if the man had time, he would...). These two tenses refer to an event that may happen (irrealis).Aims: We fill in the gap of the conditional tense and provide further data to study contrasts in verb inflection for time reference. We predict that verb forms that refer to an irrealis past event (Periphrastic conditional) are more impaired than forms that refer to an irrealis future event (Simple conditional and Future). We also predict that there are no differences between verb forms that refer to an irrealis future event (Simple conditional and Future). We also assessed whether problems in time reference extend to individuals with non-fluent aphasia that are not typical agrammatic Broca aphasia.Methods & Procedures: A sentence completion task that included 60 sentences (20 per type) of equal length in a Conditional structure (if-sentences) was designed. We tested three sentence types: Periphrastic conditional, Simple conditional and Future. The task was administered to nine participants with non-fluent aphasia and nine age-matched non-brain-damaged participants.Outcomes & Results: The Control group scored at ceiling on the three sentence types. Participants with non-fluent aphasia were most impaired in the production of the Periphrastic conditional as compared with the Simple conditional and the Future.Conclusions: When irrealis event times are compared, past events are more impaired than future events. These results can be explained by a deficit in time reference as predicted by the PADILIH. Our data reveal that the predictions of the PADILIH also hold for non-fluent speakers who have been diagnosed with Transcortical motor aphasia. KW - Time reference KW - Conditional tense KW - Future tense KW - Realis KW - Irrealis KW - Non-fluent aphasia KW - Catalan KW - PADILIH Y1 - 2014 U6 - https://doi.org/10.1080/02687038.2013.850650 SN - 0268-7038 SN - 1464-5041 VL - 28 IS - 1 SP - 99 EP - 115 PB - Routledge, Taylor & Francis Group CY - Abingdon ER - TY - JOUR A1 - Di Florio, G. A1 - Bruendermann, E. A1 - Yadavalli, Nataraja Sekhar A1 - Santer, Svetlana A1 - Havenith, Martina T1 - Confocal raman microscopy and AFM study of the interface between the photosensitive polymer layer and multilayer graphene JF - Soft materials N2 - In this paper we report on the interaction between photosensitive azobenzene-containing polymer films and on top adsorbed graphene multilayers. The photosensitive polymer film changes its topography under irradiation with light interference patterns according to their polarization distribution. The multilayer graphene follows the deformation of the polymer film and stretches accordingly. Using confocal Raman microspectroscopy we can detect the appearance of additional peaks in the Raman spectrum of the photosensitive polymer film upon irradiation indicating a molecular interaction at the interface between the graphene multilayer and the polymer matrix. Multi-component analysis of the specific Raman bands shows that the interaction involves the graphene rings and the aromatic rings of the azobenzenes causing the strong adhesion between the two materials. KW - Graphene KW - Multilayer graphene KW - Photosensitive polymer film KW - Confocal Raman microscopy KW - AFM KW - Surface Relief Grating KW - Interfacial molecular interaction Y1 - 2014 U6 - https://doi.org/10.1080/1539445X.2014.945040 SN - 1539-445X SN - 1539-4468 VL - 12 SP - S98 EP - S105 PB - Taylor & Francis Group CY - Philadelphia ER - TY - JOUR A1 - Heuveling, Johanna A1 - Frochaux, Violette A1 - Ziomkowska, Joanna A1 - Wawrzinek, Robert A1 - Wessig, Pablo A1 - Herrmann, Andreas A1 - Schneider, Erwin T1 - Conformational changes of the bacterial type I ATP-binding cassette importer HisQMP(2) at distinct steps of the catalytic cycle JF - Biochimica et biophysica acta : Biomembranes N2 - Prokaryotic solute binding protein-dependent ATP-binding cassette import systems are divided into type land type II and mechanistic differences in the transport process going along with this classification are under intensive investigation. Little is known about the conformational dynamics during the catalytic cycle especially concerning the transmembrane domains. The type I transporter for positively charged amino acids from Salmonella enterica serovar Typhimurium (1A0-Hi5QMP2) was studied by limited proteolysis in detergent solution in the absence and presence of co-factors including ATP, ADP, LAO/arginine, and Mg2+ ions. Stable peptide fragments could be obtained and differentially susceptible cleavage sites were determined by mass spectrometry as Lys-258 in the nucleotide-binding subunit, HisP, and Arg-217/Arg-218 in the transmembrane subunit, HisQ In contrast, transmembrane subunit HisM was gradually degraded but no stable fragment could be detected. HisP and HisQ were equally resistant under pre- and post-hydrolysis conditions in the presence of arginine-loaded solute-binding protein LAO and ATP/ADP. Some protection was also observed with LAO/arginine alone, thus reflecting binding to the transporter in the apo-state and transmembrane signaling. Comparable digestion patterns were obtained with the transporter reconstituted into proteoliposomes and nanodiscs. Fluorescence lifetime spectroscopy confirmed the change of HisQ(R218) to a more apolar microenvironment upon ATP binding and hydrolysis. Limited proteolysis was subsequently used as a tool to study the consequences of mutations on the transport cycle. Together, our data suggest similar conformational changes during the transport cycle as described for the maltose ABC transporter of Escherichia coli, despite distinct structural differences between both systems. KW - ABC transporter KW - Type I importer KW - Histidine transport KW - Limited proteolysis KW - Fluorescence lifetime KW - Altemate access model Y1 - 2014 U6 - https://doi.org/10.1016/j.bbamem.2013.08.024 SN - 0005-2736 SN - 0006-3002 VL - 1838 IS - 1 SP - 106 EP - 116 PB - Elsevier CY - Amsterdam ER - TY - JOUR A1 - Kang, Yu A1 - Barbirz, Stefanie A1 - Lipowsky, Reinhard A1 - Santer, Mark T1 - Conformational Diversity of O-Antigen Polysaccharides of the Gram-Negative Bacterium Shigella flexneri Serotype Y JF - The journal of physical chemistry : B, Condensed matter, materials, surfaces, interfaces & biophysical chemistry Y1 - 2014 U6 - https://doi.org/10.1021/jp4111713 SN - 1520-6106 VL - 118 IS - 9 SP - 2523 EP - 2534 PB - American Chemical Society CY - Washington ER - TY - JOUR A1 - Shainyan, Bagrat A. A1 - Moskalik, Mikhail Yu A1 - Heydenreich, Matthias A1 - Kleinpeter, Erich T1 - Conformational equilibrium and dynamic behavior of bis-N-triflyl substituted 3,8-diazabicyclo[3.2.1]octane JF - Magnetic resonance in chemistry N2 - Restricted rotation about the N-S partial double bonds in a bis-N-triflyl substituted 3,8-diazabicyclo[3.2.1]octane derivative 1 has been frozen at low temperature (Delta G* = 11.6 kcal mol(-1)), and the existence of all four rotamers about the two N-S bonds, 3-in, 8-in, 3-in, 8-out, 3-out, 8-in, and 3-out, 8-out, respectively, proved experimentally by NMR spectroscopy and theoretically by DFT and MP2 calculations. Copyright (C) 2014 John Wiley & Sons, Ltd. KW - NMR KW - H-1 KW - C-13 KW - F-19 KW - Dynamic NMR KW - Conformational equilibrium KW - restricted N-S rotation Y1 - 2014 U6 - https://doi.org/10.1002/mrc.4086 SN - 0749-1581 SN - 1097-458X VL - 52 IS - 8 SP - 448 EP - 452 PB - Wiley-Blackwell CY - Hoboken ER - TY - JOUR A1 - Shainyan, Bagrat A. A1 - Kleinpeter, Erich T1 - Conformational flexibility of 4,4-dimethyl-3,4-dihydro-2H-1,4-thiasiline and its monoheterocyclic analogs JF - Russian journal of general chemistry N2 - Conformational behavior of the first cyclic organosilicon vinylsulfide, 4,4-dimethyl-3,4-dihydro-2H-1,4-thiasiline as well as its monoheterocyclic analogs, 3,4-dihydro-2H-pyran, 3,4-dihydro-2H-thiopyran, and 1,1-dimethyl-1,2,3,4-tetrahydrosiline is studied in comparison with the carbocyclic analog, cyclohexene, using the methods of low-temperature NMR spectroscopy and theoretical calculations at the DFT and MP2 levels of theory. The barrier to the ring inversion with respect to that in cycloxene is increased in 3,4-dihydro-2H-pyran and 1,1-dimethyl-1,2,3,4-tetrahydrosiline, but, in contrast to the suggestions made in the literature, is decreased in 3,4-dihydro-2H-thiopyran. In 4,4-dimethyl-3,4-dihydro-2H-1,4-thiasiline the barrier is intermediate between those in the corresponding monoheterocycles, 1,1-dimethyl-1,2,3,4-tetrahydrosiline and 3,4-dihydro-2H-thiopyran. The observed variations are rationalized from the viewpoint of the interaction of the pi-electrons of the C=C double bond with the orbitals of heteroatoms in the ring. The structure of the transition state for the ring inversion is discussed. KW - 4,4-dimethyl-3,4-dihydro-2H-1,4-thiasiline KW - 1,1-dimethyl-1,2,3,4-tetrahydrosiline KW - 3,4-dihydro-2H-thiopyran KW - 3,4-dihydro-2H-pyran KW - onformational analysis Y1 - 2014 U6 - https://doi.org/10.1134/S1070363214070135 SN - 1070-3632 SN - 1608-3350 VL - 84 IS - 7 SP - 1325 EP - 1329 PB - Pleiades Publ. CY - New York ER - TY - JOUR A1 - Guo, Li A1 - Paycha, Sylvie A1 - Zhang, Bin T1 - Conical zeta values and their double subdivision relations JF - Advances in mathematics N2 - We introduce the concept of a conical zeta value as a geometric generalization of a multiple zeta value in the context of convex cones. The quasi-shuffle and shuffle relations of multiple zeta values are generalized to open cone subdivision and closed cone subdivision relations respectively for conical zeta values. In order to achieve the closed cone subdivision relation, we also interpret linear relations among fractions as subdivisions of decorated closed cones. As a generalization of the double shuffle relation of multiple zeta values, we give the double subdivision relation of conical zeta values and formulate the extended double subdivision relation conjecture for conical zeta values. KW - Convex cones KW - Conical zeta values KW - Smooth cones KW - Decorated cones KW - Subdivisions KW - Multiple zeta values KW - Shuffles KW - Quasi-shuffles KW - Fractions with linear poles KW - Shintani zeta values Y1 - 2014 U6 - https://doi.org/10.1016/j.aim.2013.10.022 SN - 0001-8708 SN - 1090-2082 VL - 252 SP - 343 EP - 381 PB - Elsevier CY - San Diego ER - TY - JOUR A1 - Zimmermann, Beate A1 - Zimmermann, Alexander A1 - Turner, Benjamin L. A1 - Francke, Till A1 - Elsenbeer, Helmut T1 - Connectivity of overland flow by drainage network expansion in a rain forest catchment JF - Water resources research N2 - Soils in various places of the Panama Canal Watershed feature a low saturated hydraulic conductivity (K-s) at shallow depth, which promotes overland-flow generation and associated flashy catchment responses. In undisturbed forests of these areas, overland flow is concentrated in flow lines that extend the channel network and provide hydrological connectivity between hillslopes and streams. To understand the dynamics of overland-flow connectivity, as well as the impact of connectivity on catchment response, we studied an undisturbed headwater catchment by monitoring overland-flow occurrence in all flow lines and discharge, suspended sediment, and total phosphorus at the catchment outlet. We find that connectivity is strongly influenced by seasonal variation in antecedent wetness and can develop even under light rainfall conditions. Connectivity increased rapidly as rainfall frequency increased, eventually leading to full connectivity and surficial drainage of entire hillslopes. Connectivity was nonlinearly related to catchment response. However, additional information on factors such as overland-flow volume would be required to constrain relationships between connectivity, stormflow, and the export of suspended sediment and phosphorus. The effort to monitor those factors would be substantial, so we advocate applying the established links between rain event characteristics, drainage network expansion by flow lines, and catchment response for predictive modeling and catchment classification in forests of the Panama Canal Watershed and in similar regions elsewhere. KW - connectivity KW - overland flow KW - stormflow KW - suspended sediment KW - phosphorus KW - drainage network expansion Y1 - 2014 U6 - https://doi.org/10.1002/2012WR012660 SN - 0043-1397 SN - 1944-7973 VL - 50 IS - 2 SP - 1457 EP - 1473 PB - American Geophysical Union CY - Washington ER - TY - JOUR A1 - Medeiros, Pedro Henrique Augusto A1 - de Araujo, Jose Carlos A1 - Mamede, George Leite A1 - Creutzfeldt, Benjamin A1 - Güntner, Andreas A1 - Bronstert, Axel T1 - Connectivity of sediment transport in a semiarid environment: a synthesis for the Upper Jaguaribe Basin, Brazil JF - Journal of soils and sediments : protection, risk assessment and remediation N2 - Hydrosedimentological studies conducted in the semiarid Upper Jaguaribe Basin, Brazil, enabled the identification of the key processes controlling sediment connectivity at different spatial scales (10(0)-10(4) km(2)). Water and sediment fluxes were assessed from discharge, sediment concentrations and reservoir siltation measurements. Additionally, mathematical modelling (WASA-SED model) was used to quantify water and sediment transfer within the watershed. Rainfall erosivity in the study area was moderate (4600 MJ mm ha(-1) h(-1) year(-1)), whereas runoff depths (16-60 mm year(-1)), and therefore the sediment transport capacity, were low. Consequently, similar to 60 % of the eroded sediment was deposited along the landscape, regardless of the spatial scale. The existing high-density reservoir network (contributing area of 6 km(2) per reservoir) also limits sediment propagation, retaining up to 47 % of the sediment at the large basin scale. The sediment delivery ratio (SDR) decreased with the spatial scale; on average, 41 % of the eroded sediment was yielded from the hillslopes, while for the whole 24,600-km(2) basin, the SDR was reduced to 1 % downstream of a large reservoir (1940-hm(3) capacity). Hydrological behaviour in the Upper Jaguaribe Basin represents a constraint on sediment propagation; low runoff depth is the main feature breaking sediment connectivity, which limits sediment transference from the hillslopes to the drainage system. Surface reservoirs are also important barriers, but their relative importance to sediment retention increases with scale, since larger contributing areas are more suitable for the construction of dams due to higher hydrological potential. KW - Brazil KW - Connectivity KW - Sediment redistribution KW - Semiarid KW - Spatial scale Y1 - 2014 U6 - https://doi.org/10.1007/s11368-014-0988-z SN - 1439-0108 SN - 1614-7480 VL - 14 IS - 12 SP - 1938 EP - 1948 PB - Springer CY - Heidelberg ER - TY - JOUR A1 - Kyriakos, Konstantinos A1 - Philipp, Martine A1 - Adelsberger, Joseph A1 - Jaksch, Sebastian A1 - Berezkin, Anatoly V. A1 - Lugo, Dersy M. A1 - Richtering, Walter A1 - Grillo, Isabelle A1 - Miasnikova, Anna A1 - Laschewsky, André A1 - Müller-Buschbaum, Peter A1 - Papadakis, Christine M. T1 - Cononsolvency of water/methanol mixtures for PNIPAM and PS-b-PNIPAM: pathway of aggregate formation investigated using time-resolved SANS JF - Macromolecules : a publication of the American Chemical Society N2 - We investigate the cononsolvency effect of poly(N-isopropylacrylamide) (PNIPAM) in mixtures of water and methanol. Two systems are studied: micellar solutions of polystyrene-b-poly(N-isopropylacrylamide) (PS-b-PNIPAM) diblock copolymers and, as a reference, solutions of PNIPAM homopolymers, both at a concentration of 20 mg/mL in DO. Using a stopped-flow instrument, fully deuterated methanol was rapidly added to these solutions at volume fractions between 10 and 20%. Time-resolved turbidimetry revealed aggregate formation within 10-100 s. The structural changes on mesoscopic length scales were followed by time-resolved small-angle neutron scattering (TR-SANS) with a time resolution of 0.1 s. In both systems, the pathway of the aggregation depends on the content of deuterated methanol; however, it is fundamentally different for homopolymer and diblock copolymer solutions: In the former, very large aggregates (>150 nm) are formed within the dead time of the setup, gradient appears at their surface in the late stages. In contrast, the growth of the aggregates in the latter system features different regimes, and the final aggregate size is 50 nm, thus much smaller than for the homopolymer. For the diblock copolymer, the time dependence of the aggregate radius can be described by two models: In the initial stage, the diffusion-limited coalescence model describes the data well; however, the resulting coalescence time is unreasonably high. In the late stage, a logarithmic coalescence model based on an energy barrier which is proportional to the aggregate radius is successfully applied. and a concentration Y1 - 2014 U6 - https://doi.org/10.1021/ma501434e SN - 0024-9297 SN - 1520-5835 VL - 47 IS - 19 SP - 6867 EP - 6879 PB - American Chemical Society CY - Washington ER - TY - JOUR A1 - Schroeder, Florian A1 - Lisso, Janina A1 - Obata, Toshihiro A1 - Erban, Alexander A1 - Maximova, Eugenia A1 - Giavalisco, Patrick A1 - Kopka, Joachim A1 - Fernie, Alisdair A1 - Willmitzer, Lothar A1 - Muessig, Carsten T1 - Consequences of induced brassinosteroid deficiency in Arabidopsis leaves JF - BMC plant biology N2 - Background: The identification of brassinosteroid (BR) deficient and BR insensitive mutants provided conclusive evidence that BR is a potent growth-promoting phytohormone. Arabidopsis mutants are characterized by a compact rosette structure, decreased plant height and reduced root system, delayed development, and reduced fertility. Cell expansion, cell division, and multiple developmental processes depend on BR. The molecular and physiological basis of BR action is diverse. The BR signalling pathway controls the activity of transcription factors, and numerous BR responsive genes have been identified. The analysis of dwarf mutants, however, may to some extent reveal phenotypic changes that are an effect of the altered morphology and physiology. This restriction holds particularly true for the analysis of established organs such as rosette leaves. Results: In this study, the mode of BR action was analysed in established leaves by means of two approaches. First, an inhibitor of BR biosynthesis (brassinazole) was applied to 21-day-old wild-type plants. Secondly, BR complementation of BR deficient plants, namely CPD (constitutive photomorphogenic dwarf)-antisense and cbb1 (cabbage1) mutant plants was stopped after 21 days. BR action in established leaves is associated with stimulated cell expansion, an increase in leaf index, starch accumulation, enhanced CO2 release by the tricarboxylic acid cycle, and increased biomass production. Cell number and protein content were barely affected. Conclusion: Previous analysis of BR promoted growth focused on genomic effects. However, the link between growth and changes in gene expression patterns barely provided clues to the physiological and metabolic basis of growth. Our study analysed comprehensive metabolic data sets of leaves with altered BR levels. The data suggest that BR promoted growth may depend on the increased provision and use of carbohydrates and energy. BR may stimulate both anabolic and catabolic pathways. KW - Brassinosteroids KW - Arabidopsis KW - Tricarboxylic acid cycle KW - Biomass KW - Cell expansion KW - Growth Y1 - 2014 U6 - https://doi.org/10.1186/s12870-014-0309-0 SN - 1471-2229 VL - 14 PB - BioMed Central CY - London ER - TY - CHAP A1 - Risch, Lucie A1 - Cassel, Michael A1 - Messerschmidt, Janin A1 - Intziegianni, Konstantina A1 - Mayer, Frank T1 - Consistency and reliability of examining intratendinous blood flow in Achilles tendinopathy patients using doppler ultrasonography T2 - Medicine and science in sports and exercise : official journal of the American College of Sports Medicine Y1 - 2014 SN - 0195-9131 SN - 1530-0315 VL - 46 IS - 5 SP - 46 EP - 46 PB - Lippincott Williams & Wilkins CY - Philadelphia ER - TY - JOUR A1 - Lukas, Marcus A1 - Wacker, Alexander T1 - Constraints by oxygen and food quality on carbon pathway regulation: a co-limitation study with an aquatic key herbivore JF - Ecology : a publication of the Ecological Society of America N2 - In food webs, herbivores are often constrained by low food quality in terms of mineral and biochemical limitations, which in aquatic ecosystems can co-occur with limited oxygen conditions. As low food quality implies that carbon (C) is available in excess, and therefore a regulation to get rid of excess C is crucial for the performance of consumers, we examined the C pathways (ingestion, feces release, excretion, and respiration) of a planktonic key herbivore (Daphnia magna). We tested whether consumer C pathways increase due to mineral (phosphorus, P) or biochemical (cholesterol and fatty acid) limitations and how these regulations vary when in addition oxygen is low. Under such conditions, at least the capability of the upregulation of respiration may be restricted. Furthermore, we discussed the potential role of the oxygen-transporting protein hemoglobin (Hb) in the regulation of C budgets. Different food quality constraints led to certain C regulation patterns to increase the removal of excess dietary C: P-limited D. magna increased excretion and respiration, while cholesterol-limited Daphnia in addition upregulated the release of feces. In contrast, the regulative effort was low and only feces release increased when D. magna was limited by a long-chain polyunsaturated fatty acid (eicosapentaenoic acid, EPA). Co-limiting oxygen did not always impact the discharge of excess C. We found the food-quality-induced upregulation of respiration was still present at low oxygen. In contrast, higher excretion of excess C was diminished at low oxygen supply. Besides the effect that the Hb concentration increased under low oxygen, our results indicate a low food-quality-induced increase in the Hb content of the animals. Overall, C budgeting is phenotypically plastic towards different (co-) limiting scenarios. These trigger specific regulation responses that could be the result of evolutionary adaptations. KW - carbon budget KW - carbon stoichiometry KW - cholesterol KW - co-limitation KW - Daphnia KW - EPA KW - hemoglobin KW - oxygen KW - phosphorus KW - polyunsaturated fatty acid KW - zooplankton Y1 - 2014 SN - 0012-9658 SN - 1939-9170 VL - 95 IS - 11 SP - 3068 EP - 3079 PB - Wiley CY - Washington ER - TY - JOUR A1 - Wendt, Martin T1 - Constraints on variations of m(p)/m(e) based on UVES observations of H-2 JF - Astronomische Nachrichten = Astronomical notes N2 - This article summarizes the latest results on the proton-to-electron mass ratio derived from H-2 observations at high redshift in the light of possible variations of fundamental physical constants. The focus lies on UVES observations of the past years as enormous progress was achieved since the first positive results on / were published. With the better understanding of systematics, dedicated observation runs, and numerous approaches to improve wavelength calibration accuracy, all current findings are in reasonable good agreement with no variation and provide an upper limit of / < 1 x 10(-5) for the redshift range of 2 < z < 3. (( KW - cosmology: observations KW - early Universe KW - quasars: absorption lines Y1 - 2014 U6 - https://doi.org/10.1002/asna.201312008 SN - 0004-6337 SN - 1521-3994 VL - 335 IS - 1 SP - 106 EP - 112 PB - Wiley-VCH CY - Weinheim ER - TY - JOUR A1 - Aliu, E. A1 - Aune, T. A1 - Barnacka, Anna A1 - Beilicke, M. A1 - Benbow, W. A1 - Berger, K. A1 - Biteau, Jonathan A1 - Buckley, J. H. A1 - Bugaev, V. A1 - Byrum, K. A1 - Cardenzana, J. V. A1 - Cerruti, M. A1 - Chen, Xuhui A1 - Ciupik, L. A1 - Connaughton, V. A1 - Cui, W. A1 - Dickinson, H. J. A1 - Eisch, J. D. A1 - Errando, M. A1 - Falcone, A. A1 - Federici, Simone A1 - Feng, Q. A1 - Finley, J. P. A1 - Fleischhack, H. A1 - Fortin, P. A1 - Fortson, L. A1 - Furniss, A. A1 - Galante, N. A1 - Gillanders, G. H. A1 - Griffin, S. A1 - Griffiths, S. T. A1 - Grube, J. A1 - Gyuk, G. A1 - Hakansson, Nils A1 - Hanna, D. A1 - Holder, J. A1 - Hughes, G. A1 - Humensky, T. B. A1 - Johnson, C. A. A1 - Kaaret, P. A1 - Kar, P. A1 - Kertzman, M. A1 - Khassen, Y. A1 - Kieda, D. A1 - Krawczynski, H. A1 - Krennrich, F. A1 - Lang, M. J. A1 - Madhavan, A. S. A1 - Maier, G. A1 - McArthur, S. A1 - McCann, A. A1 - Meagher, K. A1 - Millis, J. A1 - Moriarty, P. A1 - Mukherjee, R. A1 - Nieto, D. A1 - Ong, R. A. A1 - Otte, A. N. A1 - Park, N. A1 - Pohl, Martin A1 - Popkow, A. A1 - Prokoph, H. A1 - Pueschel, Elisa A1 - Quinn, J. A1 - Ragan, K. A1 - Rajotte, J. A1 - Reyes, L. C. A1 - Reynolds, P. T. A1 - Richards, G. T. A1 - Roache, E. A1 - Sembroski, G. H. A1 - Shahinyan, K. A1 - Smith, A. W. A1 - Staszak, D. A1 - Telezhinsky, Igor O. A1 - Tucci, J. V. A1 - Tyler, J. A1 - Varlotta, A. A1 - Vassiliev, V. V. A1 - Vincent, S. A1 - Wakely, S. P. A1 - Weiner, O. M. A1 - Weinstein, A. A1 - Welsing, R. A1 - Wilhelm, Alina A1 - Williams, D. A. A1 - Zitzer, B. A1 - McEnery, J. E. A1 - Perkins, J. S. A1 - Veres, P. A1 - Zhu, S. T1 - Constraints on very high energy emission from GRB 130427A JF - The astrophysical journal : an international review of spectroscopy and astronomical physics ; Part 2, Letters N2 - Prompt emission from the very fluent and nearby (z = 0.34) gamma-ray burst GRB130427A was detected by several orbiting telescopes and by ground-based, wide-field-of-view optical transient monitors. Apart from the intensity and proximity of this GRB, it is exceptional due to the extremely long-lived high-energy (100 MeV to 100 GeV) gamma-ray emission, which was detected by the Large Area Telescope on the Fermi Gamma-Ray Space Telescope for similar to 70 ks after the initial burst. The persistent, hard-spectrum, high-energy emission suggests that the highest-energy gamma rays may have been produced via synchrotron self-Compton processes though there is also evidence that the high-energy emission may instead be an extension of the synchrotron spectrum. VERITAS, a ground-based imaging atmospheric Cherenkov telescope array, began follow-up observations of GRB130427A similar to 71 ks (similar to 20 hr) after the onset of the burst. The GRB was not detected with VERITAS; however, the high elevation of the observations, coupled with the low redshift of the GRB, make VERITAS a very sensitive probe of the emission from GRB130427A for E > 100 GeV. The non-detection and consequent upper limit derived place constraints on the synchrotron self-Compton model of high-energy gamma-ray emission from this burst. KW - gamma-ray burst: individual (GRB 130427A) Y1 - 2014 U6 - https://doi.org/10.1088/2041-8205/795/1/L3 SN - 2041-8205 SN - 2041-8213 VL - 795 IS - 1 PB - IOP Publ. Ltd. CY - Bristol ER - TY - JOUR A1 - Lis, Monika ED - Lambrecht, Anna-Lena ED - Margaria, Tiziana T1 - Constructing a Phylogenetic Tree JF - Process Design for Natural Scientists: an agile model-driven approach N2 - In this project I constructed a workflow that takes a DNA sequence as input and provides a phylogenetic tree, consisting of the input sequence and other sequences which were found during a database search. In this phylogenetic tree the sequences are arranged depending on similarities. In bioinformatics, constructing phylogenetic trees is often used to explore the evolutionary relationships of genes or organisms and to understand the mechanisms of evolution itself. Y1 - 2014 SN - 978-3-662-45005-5 SN - 1865-0929 IS - 500 SP - 101 EP - 109 PB - Springer Verlag CY - Berlin ER - TY - THES A1 - Steinhaus, Sebastian Peter T1 - Constructing quantum spacetime T1 - Konstruktion der Quantenraumzeit BT - relation to classical gravity BT - Relation zur klassischen Gravitation N2 - Despite remarkable progress made in the past century, which has revolutionized our understanding of the universe, there are numerous open questions left in theoretical physics. Particularly important is the fact that the theories describing the fundamental interactions of nature are incompatible. Einstein's theory of general relative describes gravity as a dynamical spacetime, which is curved by matter and whose curvature determines the motion of matter. On the other hand we have quantum field theory, in form of the standard model of particle physics, where particles interact via the remaining interactions - electromagnetic, weak and strong interaction - on a flat, static spacetime without gravity. A theory of quantum gravity is hoped to cure this incompatibility by heuristically replacing classical spacetime by quantum spacetime'. Several approaches exist attempting to define such a theory with differing underlying premises and ideas, where it is not clear which is to be preferred. Yet a minimal requirement is the compatibility with the classical theory, they attempt to generalize. Interestingly many of these models rely on discrete structures in their definition or postulate discreteness of spacetime to be fundamental. Besides the direct advantages discretisations provide, e.g. permitting numerical simulations, they come with serious caveats requiring thorough investigation: In general discretisations break fundamental diffeomorphism symmetry of gravity and are generically not unique. Both complicates establishing the connection to the classical continuum theory. The main focus of this thesis lies in the investigation of this relation for spin foam models. This is done on different levels of the discretisation / triangulation, ranging from few simplices up to the continuum limit. In the regime of very few simplices we confirm and deepen the connection of spin foam models to discrete gravity. Moreover, we discuss dynamical, e.g. diffeomorphism invariance in the discrete, to fix the ambiguities of the models. In order to satisfy these conditions, the discrete models have to be improved in a renormalisation procedure, which also allows us to study their continuum dynamics. Applied to simplified spin foam models, we uncover a rich, non--trivial fixed point structure, which we summarize in a phase diagram. Inspired by these methods, we propose a method to consistently construct the continuum theory, which comes with a unique vacuum state. N2 - Trotz bemerkenswerter Fortschritte im vergangenen Jahrhundert, die unser Verständnis des Universums revolutioniert haben, gibt es noch zahlreiche ungeklärte Fragen in der theoretischen Physik. Besondere Bedeutung kommt der Tatsache zu, dass die Theorien, welche die fundamentalen Wechselwirkungen der Natur beschreiben, inkompatibel sind. Nach Einsteins allgemeiner Relativitätstheorie wird die Gravitation durch eine dynamische Raumzeit dargestellt, die von Materie gekrümmt wird und ihrerseits durch die Krümmung die Bewegung der Materie bestimmt. Dem gegenüber steht die Quantenfeldtheorie, die die verbliebenen Wechselwirkungen - elektromagnetische, schwache und starke Wechselwirkung - im Standardmodell der Teilchenphysik beschreibt, in dem Teilchen auf einer statischen Raumzeit -- ohne Gravitation -- miteinander interagieren. Die Hoffnung ist, dass eine Theorie der Quantengravitation diese Inkompatibilität beheben kann, indem, heuristisch, die klassische Raumzeit durch eine 'Quantenraumzeit' ersetzt wird. Es gibt zahlreiche Ansätze eine solche Theorie zu definieren, die auf unterschiedlichen Prämissen und Ideen beruhen, wobei a priori nicht klar ist, welche zu bevorzugen sind. Eine Minimalanforderung an diese Theorien ist Kompatibilität mit der klassischen Theorie, die sie verallgemeinern sollen. Interessanterweise basieren zahlreiche Modelle in ihrer Definition auf Diskretisierungen oder postulieren eine fundamentale Diskretheit der Raumzeit. Neben den unmittelbaren Vorteilen, die Diskretisierungen bieten, z.B. das Ermöglichen numerischer Simulationen, gibt es auch gravierende Nachteile, die einer ausführlichen Untersuchung bedürfen: Im Allgemeinen brechen Diskretisierungen die fundamentale Diffeomorphismensymmetrie der Gravitation und sind in der Regel nicht eindeutig definiert. Beides erschwert die Wiederherstellung der Verbindung zur klassischen, kontinuierlichen Theorie. Das Hauptaugenmerk dieser Doktorarbeit liegt darin diese Verbindung insbesondere für Spin-Schaum-Modelle (spin foam models) zu untersuchen. Dies geschieht auf sehr verschiedenen Ebenen der Diskretisierung / Triangulierung, angefangen bei wenigen Simplizes bis hin zum Kontinuumslimes. Im Regime weniger Simplizes wird die bekannte Verbindung von Spin--Schaum--Modellen zu diskreter Gravitation bestätigt und vertieft. Außerdem diskutieren wir dynamische Prinzipien, z.B. Diffeomorphismeninvarianz im Diskreten, um die Ambiguitäten der Modelle zu fixieren. Um diese Bedingungen zu erfüllen, müssen die diskreten Modelle durch Renormierungsverfahren verbessert werden, wodurch wir auch ihre Kontinuumsdynamik untersuchen können. Angewandt auf vereinfachte Spin-Schaum-Modelle finden wir eine reichhaltige, nicht-triviale Fixpunkt-Struktur, die wir in einem Phasendiagramm zusammenfassen. Inspiriert von diesen Methoden schlagen wir zu guter Letzt eine konsistente Konstruktionsmethode für die Kontinuumstheorie vor, die einen eindeutigen Vakuumszustand definiert. KW - Quantengravitation KW - Spin-Schaum-Modelle KW - Regge Kalkül KW - Renormierung KW - Verfeinerungslimes KW - quantum gravity KW - spin foams KW - regge calculus KW - renormalization and refinement limit Y1 - 2014 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus-72558 ER - TY - JOUR A1 - Burmester, Juliane A1 - Spalek, Katharina A1 - Wartenburger, Isabell T1 - Context updating during sentence comprehension: The effect of aboutness topic JF - Brain & language : a journal of the neurobiology of language KW - Information structure KW - Discourse context KW - Aboutness topic KW - Sentence processing KW - Word order variation KW - ERP KW - Late positivity KW - Syntax-Discourse Model Y1 - 2014 U6 - https://doi.org/10.1016/j.bandl.2014.08.001 SN - 0093-934X SN - 1090-2155 VL - 137 SP - 62 EP - 76 PB - Elsevier CY - San Diego ER - TY - JOUR A1 - Beim Graben, Peter T1 - Contextual emergence of intentionality JF - Journal of consciousness studies : controversies in science & the humanities ; an international multi-disciplinary journal N2 - By means of an intriguing physical example, magnetic surface swimmers, that can be described in terms of Dennett's intentional stance, I reconstruct a hierarchy of necessary and sufficient conditions for the applicability of the intentional strategy. It turns out that the different levels of the intentional hierarchy are contextually emergent from their respective subjacent levels by imposing stability constraints upon them. At the lowest level of the hierarchy, phenomenal physical laws emerge for the coarse-grained description of open, nonlinear, and dissipative non-equilibrium systems in critical states. One level higher, dynamic patterns, such as, for example, magnetic surface swimmers, are contextually emergent as they are invariant under certain symmetry operations. Again one level up, these patterns behave apparently rationally by selecting optimal pathways for the dissipation of energy that is delivered by external gradients. This is in accordance with the restated Second Law of thermodynamics as a stability criterion. At the highest level, true believers are intentional systems that are stable under exchanging their observation conditions. Y1 - 2014 SN - 1355-8250 VL - 21 IS - 5-6 SP - 75 EP - 96 PB - Imprint Academic CY - Exeter ER - TY - JOUR A1 - Glaeser, Stefanie P. A1 - Berghoff, Bork A. A1 - Stratmann, Verena A1 - Grossart, Hans-Peter A1 - Glaeser, Jens T1 - Contrasting effects of singlet oxygen and hydrogen peroxide on bacterial community composition in a humic lake JF - PLoS one N2 - Light excitation of humic matter generates reactive oxygen species (ROS) in surface waters of aquatic ecosystems. Abundant ROS generated in humic matter rich lakes include singlet oxygen (O-1(2)) and hydrogen peroxide (H2O2). Because these ROS differ in half-life time and toxicity, we compared their effects on microbial activity (C-14-Leucine incorporation) and bacterial community composition (BCC) in surface waters of humic Lake Grosse Fuchskuhle (North-eastern Germany). For this purpose, experiments with water samples collected from the lake were conducted in July 2006, September 2008 and August 2009. Artificially increased O-1(2) and H2O2 concentrations inhibited microbial activity in water samples to a similar extent, but the effect of the respective ROS on BCC varied strongly. BCC analysis by 16S rRNA gene clone libraries and RT-PCR DGGE revealed ROS specific changes in relative abundance and activity of major bacterial groups and composition of dominating phylotypes. These changes were consistent in the three experiments performed in different years. The relative abundance of Polynucleobacter necessarius, Limnohabitans-related phylotypes (Betaproteobacteria), and Novosphingobium acidiphilum (Alphaproteobacteria) increased or was not affected by photo-sensitized O-1(2) exposure, but decreased after H2O2 exposure. The opposite pattern was found for Actinobacteria of the freshwater AcI-B cluster which were highly sensitive to O-1(2) but not to H2O2 exposure. Furthermore, group-specific RT-PCR DGGE analysis revealed that particle-attached P. necessarius and Limnohabitans-related phylotypes exhibit higher resistance to O-1(2) exposure compared to free-living populations. These results imply that O-1(2) acts as a factor in niche separation of closely affiliated Polynucleobacter and Limnohabitans-related phylotypes. Consequently, oxidative stress caused by photochemical ROS generation should be regarded as an environmental variable determining abundance, activity, and phylotype composition of environmentally relevant bacterial groups, in particular in illuminated and humic matter rich waters. Y1 - 2014 U6 - https://doi.org/10.1371/journal.pone.0092518 SN - 1932-6203 VL - 9 IS - 3 PB - PLoS CY - San Fransisco ER - TY - JOUR A1 - Azuma, Yusuke A1 - Kuekenshoener, Tim A1 - Ma, Guangyong A1 - Yasunaga, Jun-ichiro A1 - Imanishi, Miki A1 - Tanaka, Gen A1 - Nakase, Ikuhiko A1 - Maruno, Takahiro A1 - Kobayashi, Yuji A1 - Arndt, Katja Maren A1 - Matsuoka, Masao A1 - Futaki, Shiroh T1 - Controlling leucine-zipper partner recognition in cells through modification of a-g interactions JF - Chemical communications N2 - By focusing on the a-g interactions, successful design and selection were accomplished to obtain a leucine-zipper segment that discriminates the appropriate partner over another that provides very similar patterns of electrostatic interactions. Y1 - 2014 U6 - https://doi.org/10.1039/c4cc00555d SN - 1359-7345 SN - 1364-548X VL - 50 IS - 48 SP - 6364 EP - 6367 PB - Royal Society of Chemistry CY - Cambridge ER - TY - GEN A1 - Azuma, Yusuke A1 - Kükenshöner, Tim A1 - Ma, Guangyong A1 - Yasunaga, Jun-ichiro A1 - Imanishi, Miki A1 - Tanaka, Gen A1 - Nakase, Ikuhiko A1 - Maruno, Takahiro A1 - Kobayashi, Yuji A1 - Arndt, Katja Maren A1 - Matsuoka, Masao A1 - Futaki, Shiroh T1 - Controlling leucine-zipper partner recognition in cells through modification of a–g interactions N2 - By focusing on the a–g interactions, successful design and selection were accomplished to obtain a leucine-zipper segment that discriminates the appropriate partner over another that provides very similar patterns of electrostatic interactions. T3 - Zweitveröffentlichungen der Universität Potsdam : Mathematisch-Naturwissenschaftliche Reihe - 276 Y1 - 2016 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus4-98758 ER - TY - JOUR A1 - Klaus, Julian A1 - Zehe, Erwin A1 - Elsner, Martin A1 - Palm, Juliane A1 - Schneider, Dorothee A1 - Schroeder, Boris A1 - Steinbeiss, Sibylle A1 - van Schaik, Loes A1 - West, Stephanie T1 - Controls of event-based pesticide leaching in natural soils: A systematic study based on replicated field scale irrigation experiments JF - Journal of hydrology N2 - Tile drains strongly influence the water cycle in agricultural catchment in terms of water quantity and quality. The connectivity of preferential flow to tile drains can create shortcuts for rapid transport of solutes into surface waters. The leaching of pesticides can be linked to a set of main factors including, rainfall characteristics, soil moisture, chemical properties of the pesticides, soil properties, and preferential flow paths. The connectivity of the macropore system to the tile drain is crucial for pesticide leaching. Concurring influences of the main factors, threshold responses and the role of flow paths are still poorly understood. The objective of this study is to investigate these influences by a replica series of three irrigation experiments on a tile drain field site using natural and artificial tracers together with applied pesticides. We found a clear threshold behavior in the initialization of pesticide transport that was different between the replica experiments. Pre-event soil water contributed significantly to the tile drain flow, and creates a flow path for stored pesticides from the soil matrix to the tile drain. This threshold is controlled by antecedent soil moisture and precipitation characteristics, and the interaction between the soil matrix and preferential flow system. Fast transport of pesticides without retardation and the remobilization could be attributed to this threshold and the interaction between the soil matrix and the preferential flow system. Thus, understanding of the detailed preferential flow processes clearly enhances the understanding of pesticide leaching on event and long term scale, and can further improve risk assessment and modeling approaches. (C) 2014 Elsevier B.V. All rights reserved. KW - Irrigation experiment KW - Preferential flow KW - Threshold KW - Pesticide transport Y1 - 2014 U6 - https://doi.org/10.1016/j.jhydrol.2014.03.020 SN - 0022-1694 SN - 1879-2707 VL - 512 SP - 528 EP - 539 PB - Elsevier CY - Amsterdam ER - TY - THES A1 - Hermawan, Romy T1 - Coordination and civil service reform in Indonesia (1999-2009) N2 - The background of civil service reform in Indonesia reveals the emergence of the reformation movement in 1998, following the fall of the authoritarian New Order regime. The reformation movement has seen the introduction of reforms in Indonesia's various governmental institutions, including the civil service. The civil service reforms were marked by the revision of Act 8/ 74 with Act 43 of 1999 on Civil Service Administration. The implementation of the civil service reform program, which was carried out by both central and local governments, required cooperation between the actors (in particular, Ministries, agencies and local governments), known as coordination. Currently, the coordination that occurs between actors tends to be rigid and hierarchical. As a result, targets are not efficiently and effectively met. Hierarchical coordination, without a strong public sector infrastructure, tends to have a negative impact on achieving the desired outcomes of the civil service reform program. As an intrinsic part of the New Order regime, hierarchical coordination resulted in inefficiency and lack of efficacy. Despite these inefficiencies, the administration and the political environment have changed significantly as a result of the reform process. Obvious examples of the reforms are changes in recruitment patterns, placement and remuneration policies. However, in the case of Indonesia, it appears that every state institution has its own policy. Thus, it appears that there has not been policy coherence in the civil service reform program, resulting in the lack of a sustainable program. The important thing to examine is how the coordination mechanisms of the civil service reform program in the central government have developed during the reform era in Indonesia The purpose of this study is to analyse the linkages between coordination mechanisms and the actual implementation of civil service reform programs. This is undertaken as a basis for intervention based on the structures and patterns of coordination mechanisms in the implementation of civil service reform programs. The next step is to formulate the development coordination mechanisms, particularly to create structures and patterns of civil service reforms which are more sustainable to the specific characteristics of public sector organisations in Indonesia. The benefits of this research are a stronger understanding of the linkages between the mechanisms of coordination and implementation of civil service reform programs. Through this analysis, the findings can then be applied as a basic consideration in planning a sustainable civil service reform program. In the basis of theoretical issues concerning the linkages between coordination mechanisms and implementation of civil service reform program sustainability, this book explores the type of coordination, which is needed to test the proportional and sustainable concept of the intended civil service reform program in Indonesia. Research conducted through studies, surveys and donors has shown that poor coordination is the major hindrance to the civil service program reform in Indonesia. This research employs a qualitative approach. In this study, the coordination mechanisms and implementations of civil service reform programs are demonstrated by means of case studies of the State Ministry for Administrative Reform, the National Civil Service Agency and the National Public Administration Institute. The coordination mechanisms in these Ministries and agencies were analysed using indicators of effective and efficient coordination. The analysis of the coordination mechanisms shows a tendency towards rigid hierarchical coordination. This raises concerns about fragmentation among departments and agencies at the central government level and calls for integrated civil service reform both at central and local governmental levels. In the context of implementation programs, a hierarchical mechanism of coordination leverages on various aspects, such as the program formulation, implementation flow of the program, the impact of policies, and achievement targets. In particular, there was a shift process of the mainstream civil service reform in the Ministries and agencies which are marked by the emergence of sectoral interest and inefficiencies in the civil service reform program. The primary result of successful civil service reform is increased professionalism in the civil service. The findings on hierarchical mechanisms and the prescriptions which will follow show that the professionalism of Indonesia’s civil service is at stake. The implementation of the program through coordination mechanisms in Ministries and agencies is measured in various dimensions: the centre of coordination, integration of coordination, sustainability of coordination and multidimensionality of coordination. The results of this analysis show that coordination mechanisms and the implementation of civil service reform are more successful when they are integration rather than hierarchical mechanisms. For a successful implementation of the reform program, it is crucial to intervene and change the type of coordination at the central government through the integration approach (hierarchy, market, and network). Furthermore, in order to move towards the integration type mechanism of coordination the separation of the administration and politics in the practice of good governance needs to be carried out immediately and simultaneously. Based on this analysis, it can be concluded that the integration type mechanism of coordination is a suitable for Indonesia for a sustainable civil service reform program. Finally, to achieve coherent civil service reforms, national policies developed according to the central government's priorities are indispensable, establishing a coordination mechanism that can be adhered to throughout all reform sectors. N2 - Seit dem Sturz des autoritären und dem Wechsel zum Regime des „New Order“ im Jahre 1998 haben die Reformbemühungen in der öffentlichen Verwaltung in Indonesien stark zugenommen. Ihren Ursprung nahmen sie mit der Revision des Gesetzes 8/74 und 43 im Jahre 1999 betreffend die Grundlagen der öffentlichen Verwaltung. Implementiert wurde die Reform sowohl durch die Zentralregierung als auch durch die Lokalregierungen. Jedoch erforderte die Implementierung dieses Programmes auch die Zusammenarbeit bzw. die Koordination verschiedener Akteure, wie beispielsweise Ministerien, Behörden, und Lokalregierungen. Die gegenwärtige Koordination zwischen diesen Akteuren ist rigide und hierarchisch. Daraus ergibt sich, dass die gesteckten Ziele nicht effizient und effektiv erreicht werden. Hierarchische Koordination ohne eine gefestigte Verwaltungsstruktur verhindert die Umsetzung des Reformprogrammes. Als intrinsisches Merkmal des „New Order“ Regimes führt die hierarchische Koordination zur Ineffizienz und einem Mangel an Effektivität. Trotz dieser Ineffizienzen haben die Reformen zu signifikanten Veränderungen in der Verwaltung und im politischen Umfeld geführt. Offensichtliche Beispiele der Verwaltungsreform sind Änderungen in der Einstellungs-, Beförderungs- und Entlohnungspraxis. Im Falle Indonesiens jedoch scheint jede einzelne Institution ihr eigenes Regelwerk zu besitzen. Dies deutet darauf hin, dass das Verwaltungsreformprogramm keine allzu große Kohärenz aufgewiesen hat. Es ist hierbei wichtig zu untersuchen wie die Koordinationsmechanismen dieses Programmes sich nach der Reformära in Indonesien entwickelt haben. Diese Studie hat die Absicht, die Verbindungen zwischen den Koordinationsmechanismen und den tatsächlichen Durchführung des Reformprogrammes der öffentlichen Verwaltung zu analysieren. Offensichtlich zeichnete sich dieseweder durch Kohärenz noch eine nachhaltige Implementierung aus. Es ist nun wichtig, eine Richtung zu bestimmen, wie die Koordinationsmechanismen sich entwickeln müssten um Strukturen und Mechanismen zu schaffen, die besser zu den spezifischen Charakteristiken der öffentlichen Verwaltungen in Indonesien passen. Diese Untersuchung trägt dazu bei, die Zusammenhänge zwischen Koordinationsmechanismen und des tatsächlichen Implementationserfolges von Reformprogrammen der öffentlichen Verwaltung zu verstehen. Ein solches Analyseergebnis kann dann zu nachhaltigen Reformbemühungen beitragen. Ausgehend von theoretischen Überlegungen bezüglich der Verbindung von Koordinationsmechanismen und der Implementierung von Reformprogrammen der öffentlichen Verwaltung, erforscht diese Studie verschiedene Aspekte des Koordinationstypus, der notwendig scheint, um das verhältnismäßige und nachhaltigeKonzept des beabsichtigten Reformprogrammes in Indonesien zu testen. Bisherige Forschung auf dem Gebiet der Koordination zeigt, dass das größte Hindernis für ein erfolgreiches Reformprogramm der öffentlichen Verwaltung ein Mangel an Koordination ist. Diese Studie wählt einen qualitativen Ansatz. Sie zeigt die Koordinationsmechanismen bei der Implementation von Reformprogrammen in der öffentlichen Verwaltung an den Fallbeispielen des „Staatsministeriums für Administrative Reformen“, der „Nationalen Agentur für den Öffentlichen Dienst“ und des „Nationalen Instituts für die Öffentliche Verwaltung“. Die Koordinationsmechanismen dieser Ministerien und Institute wurden dabei auf Grundlage von Indikatoren für effektive und effiziente Koordination untersucht. Die Analyse zeit tendenziell, dass die Koordination einerigide und hierarchische Form annimmt. Dies lässt Bedenken über die Fragmentierung der Abteilungen und Agenturen der Zentralregierung aufkommen und verdeutlicht die Notwendigkeit einer integrierten Reform der öffentlichen Verwaltung sowohl auf der Ebene der Zentralregierung als auch der Lokalregierungen. Im Kontext der Implementierungsbemühungen berührt eine hierarchische Koordination verschiedene Aspekte wie zum Beispiel die Formulierung des Programmes, der Ablauf der Implementation, der Einfluss des Regelwerks und die Erreichung der gesteckten Ziele. Insbesondere konnte beobachtet werden, dass sich der grundlegende Verwaltungsprozesses in den Ministerien und den Agenturen verlagert hat, was sich durch die Verstärkung sektoraler Interessen und zunehmender Ineffizienzen des Reformprogrammes ausdrückt. Das derzeitige Ergebnis ist im Wesentlichen eine zunehmende Professionalisierung des öffentlichen Dienstes. Die Befunde über hierarchische Mechanismen und die danach folgenden Vorgaben stellen die Professionalität des öffentlichen Dienstes in Indonesien in Frage. Die Implementierung des Reformprogrammes durch Koordinationsmechanismen in Ministerien und Agenturen werden auf mehreren Dimensionen gemessen: der Ausgangspunkt der Koordination, ihre Einbindung, Nachhaltigkeit und Mehrdimensionalität. Die Ergebnisse dieser Analyse zeigen, dass integrative Koordinationsmechanismen und Implementationen erfolgreicher sind als hierarchische. Um das restliche Reformprogramm erfolgreich zu einem Ende zu bringen, erscheint es wesentlich einzugreifen und die vorherrschende Koordination in der Zentralregierung durch einen integrativen Ansatz zu ersetzen (Hierarchie, Markt, Netzwerk). Darüber hinaus muss, um dies zu erreichen, die Trennung von Verwaltung und Politik im Sinne der guten Regierungsführung gleichzeitig umgesetzt werden. Auf Grundlage dieser Analyse kann gefolgert werden, dass der integrative Ansatz bei der Koordination geeignet erscheint, um das Reformprogramm der öffentlichen Verwaltung in Indonesien umzusetzen. Schlussendlich, um eine einheitliche Reform der öffentlichen Verwaltung zu erreichen bedarf es einer zentralen Koordinationsstrategie der Zentralregierung, die einheitlich in allen Reformsektoren befolgt wird. KW - Indonesien KW - Verwaltungsreform KW - Geschichte 1999-2009 KW - Coordination KW - Civil Service Reform KW - Bureaucracy Y1 - 2014 SN - 978-602-284-061-9 PB - Center of South South Cooperation Studies, Univ. CY - Brawijaya ER - TY - JOUR A1 - van Driel-Gesztelyi, L. A1 - Baker, Daniel N. A1 - Toeroek, T. A1 - Pariat, E. A1 - Green, L. M. A1 - Williams, D. R. A1 - Carlyle, J. A1 - Valori, G. A1 - Demoulin, Pascal A1 - Kliem, Bernhard A1 - Long, D. M. A1 - Matthews, S. A. A1 - Malherbe, J. -M. T1 - Coronal magnetic reconnection driven by CME expansion-the 2011 June 7 event JF - The astrophysical journal : an international review of spectroscopy and astronomical physics N2 - Coronal mass ejections (CMEs) erupt and expand in a magnetically structured solar corona. Various indirect observational pieces of evidence have shown that the magnetic field of CMEs reconnects with surrounding magnetic fields, forming, e.g., dimming regions distant from the CME source regions. Analyzing Solar Dynamics Observatory (SDO) observations of the eruption from AR 11226 on 2011 June 7, we present the first direct evidence of coronal magnetic reconnection between the fields of two adjacent active regions during a CME. The observations are presented jointly with a data-constrained numerical simulation, demonstrating the formation/intensification of current sheets along a hyperbolic flux tube at the interface between the CME and the neighboring AR 11227. Reconnection resulted in the formation of new magnetic connections between the erupting magnetic structure from AR 11226 and the neighboring active region AR 11227 about 200 Mm from the eruption site. The onset of reconnection first becomes apparent in the SDO/AIA images when filament plasma, originally contained within the erupting flux rope, is redirected toward remote areas in AR 11227, tracing the change of large-scale magnetic connectivity. The location of the coronal reconnection region becomes bright and directly observable at SDO/AIA wavelengths, owing to the presence of down-flowing cool, dense (1010 cm(-3)) filament plasma in its vicinity. The high-density plasma around the reconnection region is heated to coronal temperatures, presumably by slow-mode shocks and Coulomb collisions. These results provide the first direct observational evidence that CMEs reconnect with surrounding magnetic structures, leading to a large-scale reconfiguration of the coronal magnetic field. KW - magnetic reconnection KW - magnetohydrodynamics (MHD) KW - Sun: corona KW - Sun: coronal mass ejections (CMEs) KW - Sun: magnetic fields KW - Sun: UV radiation Y1 - 2014 U6 - https://doi.org/10.1088/0004-637X/788/1/85 SN - 0004-637X SN - 1538-4357 VL - 788 IS - 1 PB - IOP Publ. Ltd. CY - Bristol ER - TY - JOUR A1 - Schubert, Marcel A1 - Collins, Brian A. A1 - Mangold, Hannah A1 - Howard, Ian A. A1 - Schindler, Wolfram A1 - Vandewal, Koen A1 - Roland, Steffen A1 - Behrends, Jan A1 - Kraffert, Felix A1 - Steyrleuthner, Robert A1 - Chen, Zhihua A1 - Fostiropoulos, Konstantinos A1 - Bittl, Robert A1 - Salleo, Alberto A1 - Facchetti, Antonio A1 - Laquai, Frederic A1 - Ade, Harald W. A1 - Neher, Dieter T1 - Correlated donor/acceptor crystal orientation controls photocurrent generation in all-polymer solar cells JF - Advanced functional materials N2 - New polymers with high electron mobilities have spurred research in organic solar cells using polymeric rather than fullerene acceptors due to their potential of increased diversity, stability, and scalability. However, all-polymer solar cells have struggled to keep up with the steadily increasing power conversion efficiency of polymer: fullerene cells. The lack of knowledge about the dominant recombination process as well as the missing concluding picture on the role of the semi-crystalline microstructure of conjugated polymers in the free charge carrier generation process impede a systematic optimization of all-polymer solar cells. These issues are examined by combining structural and photo-physical characterization on a series of poly(3-hexylthiophene) (donor) and P(NDI2OD-T2) (acceptor) blend devices. These experiments reveal that geminate recombination is the major loss channel for photo-excited charge carriers. Advanced X-ray and electron-based studies reveal the effect of chloronaphthalene co-solvent in reducing domain size, altering domain purity, and reorienting the acceptor polymer crystals to be coincident with those of the donor. This reorientation correlates well with the increased photocurrent from these devices. Thus, effi cient split-up of geminate pairs at polymer/polymer interfaces may necessitate correlated donor/acceptor crystal orientation, which represents an additional requirement compared to the isotropic fullerene acceptors. Y1 - 2014 U6 - https://doi.org/10.1002/adfm.201304216 SN - 1616-301X SN - 1616-3028 VL - 24 IS - 26 SP - 4068 EP - 4081 PB - Wiley-VCH CY - Weinheim ER - TY - JOUR A1 - Sandev, Trifce A1 - Metzler, Ralf A1 - Tomovski, Zivorad T1 - Correlation functions for the fractional generalized Langevin equation in the presence of internal and external noise JF - Journal of mathematical physics N2 - We study generalized fractional Langevin equations in the presence of a harmonic potential. General expressions for the mean velocity and particle displacement, the mean squared displacement, position and velocity correlation functions, as well as normalized displacement correlation function are derived. We report exact results for the cases of internal and external friction, that is, when the driving noise is either internal and thus the fluctuation-dissipation relation is fulfilled or when the noise is external. The asymptotic behavior of the generalized stochastic oscillator is investigated, and the case of high viscous damping (overdamped limit) is considered. Additional behaviors of the normalized displacement correlation functions different from those for the regular damped harmonic oscillator are observed. In addition, the cases of a constant external force and the force free case are obtained. The validity of the generalized Einstein relation for this process is discussed. The considered fractional generalized Langevin equation may be used to model anomalous diffusive processes including single file-type diffusion. Y1 - 2014 U6 - https://doi.org/10.1063/1.4863478 SN - 0022-2488 SN - 1089-7658 VL - 55 IS - 2 PB - American Institute of Physics CY - Melville ER - TY - CHAP A1 - Engel, Tilman A1 - Kopinski, Stephan A1 - Carlsohn, Anja A1 - Cassel, Michael A1 - Mayer, Frank T1 - Correlation of sonographic subcutaneous adipose tissue measurements with air displacement plethysmography and calipermetry T2 - Medicine and science in sports and exercise : official journal of the American College of Sports Medicine Y1 - 2014 SN - 0195-9131 SN - 1530-0315 VL - 46 IS - 5 SP - 539 EP - 539 PB - Lippincott Williams & Wilkins CY - Philadelphia ER - TY - JOUR A1 - Yue, Jinxing A1 - Bastiaanse, Roelien A1 - Alter, Kai T1 - Cortical plasticity induced by rapid Hebbian learning of novel tonal word-forms: Evidence from mismatch negativity JF - Brain & language : a journal of the neurobiology of language N2 - Although several experiments reported rapid cortical plasticity induced by passive exposure to novel segmental patterns, few studies have devoted attention to the neural dynamics during the rapid learning of novel tonal word-forms in tonal languages, such as Chinese. In the current study, native speakers of Mandarin Chinese were exposed to acoustically matched real and novel segment-tone patterns. By recording their Mismatch Negativity (MMN) responses (an ERP indicator of long-term memory traces for spoken words), we found enhanced MMNs to the novel word-forms over the left-hemispheric region in the late exposure phase relative to the early exposure phase. In contrast, no significant changes were identified in MMN responses to the real word during familiarisation. Our results suggest a rapid Hebbian learning mechanism in the human neocortex which develops long-term memory traces for a novel segment-tone pattern by establishing new associations between the segmental and tonal representations. (C) 2014 Elsevier Inc. All rights reserved. KW - Language KW - Rapid learning KW - Hebbian learning KW - Event-related potential KW - Novel word KW - Mismatch Negativity (MMN) KW - Oddball paradigm KW - Lexical tone KW - Mandarin Chinese Y1 - 2014 U6 - https://doi.org/10.1016/j.bandl.2014.09.007 SN - 0093-934X SN - 1090-2155 VL - 139 SP - 10 EP - 22 PB - Elsevier CY - San Diego ER - TY - INPR A1 - Kreibich, Heidi A1 - van den Bergh, Jeroen C. J. M. A1 - Bouwer, Laurens M. A1 - Bubeck, Philip A1 - Ciavola, Paolo A1 - Green, Colin A1 - Hallegatte, Stephane A1 - Logar, Ivana A1 - Meyer, Volker A1 - Schwarze, Reimund A1 - Thieken, Annegret T1 - Costing natural hazards T2 - Nature climate change Y1 - 2014 SN - 1758-678X SN - 1758-6798 VL - 4 IS - 5 SP - 303 EP - 306 PB - Nature Publ. Group CY - London ER - TY - JOUR A1 - Shojaei-Fard, Ali T1 - Counterterms in the context of the universal Hopf algebra of renormalization JF - International journal of modern physics : A, Particles and fields, gravitation, cosmology, nuclear physics N2 - The manuscript discovers a new interpretation of counterterms of renormalizable Quantum Field Theories in terms of formal expansions of decorated rooted trees. KW - Perturbative renormalization KW - renormalization Hopf algebra KW - counterterms KW - rooted trees Y1 - 2014 U6 - https://doi.org/10.1142/S0217751X14500456 SN - 0217-751X SN - 1793-656X VL - 29 IS - 8 PB - World Scientific CY - Singapore ER - TY - JOUR A1 - Gabsi, Faten A1 - Hammers-Wirtz, Monika A1 - Grimm, Volker A1 - Schaeffer, Andreas A1 - Preuss, Thomas G. T1 - Coupling different mechanistic effect models for capturing individual- and population-level effects of chemicals: Lessons from a case where standard risk assessment failed JF - Ecological modelling : international journal on ecological modelling and engineering and systems ecolog N2 - Current environmental risk assessment (ERA) of chemicals for aquatic invertebrates relies on standardized laboratory tests in which toxicity effects on individual survival, growth and reproduction are measured. Such tests determine the threshold concentration of a chemical below which no population-level effects are expected. How well this procedure captures effects on individuals and populations, however, remains an open question. Here we used mechanistic effect models, combining individual-level reproduction and survival models with an individual-based population model (IBM), to understand the individuals' responses and extrapolate them to the population level. We used a toxicant (Dispersogen A) for which adverse effects on laboratory populations were detected at the determined threshold concentration and thus challenged the conservatism of the current risk assessment method. Multiple toxicity effects on reproduction and survival were reported, in addition to effects on the F1 generation. We extrapolated commonly tested individual toxicity endpoints, reproduction and survival, to the population level using the IBM. Effects on reproduction were described via regression models. To select the most appropriate survival model, the IBM was run assuming either stochastic death (SD) or individual tolerance (IT). Simulations were run for different scenarios regarding the toxicant's effects: survival toxicity, reproductive toxicity, or survival and reproductive toxicity. As population-level endpoints, we used population size and structure and extinction risk. We found that survival represented as SD explained population dynamics better than IT. Integrating toxicity effects on both reproduction and survival yielded more accurate predictions of population effects than considering isolated effects. To fully capture population effects observed at high toxicant concentrations, toxicity effects transmitted to the F1 generation had to be integrated. Predicted extinction risk was highly sensitive to the assumptions about individual-level effects. Our results demonstrate that the endpoints used in current standard tests may not be sufficient for assessing the risk of adverse effects on populations. A combination of laboratory population experiments with mechanistic effect models is a powerful tool to better understand and predict effects on both individuals and populations. Mechanistic effect modelling thus holds great potential to improve the accuracy of ERA of chemicals in the future. (C) 2013 The Authors. Published by Elsevier B.V. All rights reserved. KW - Individual-based modelling KW - TK/TD modelling KW - Daphnia magna KW - Risk assessment Y1 - 2014 U6 - https://doi.org/10.1016/j.ecolmodel.2013.06.018 SN - 0304-3800 SN - 1872-7026 VL - 280 SP - 18 EP - 29 PB - Elsevier CY - Amsterdam ER - TY - THES A1 - Balzer, Arnim T1 - Crab flare observations with H.E.S.S. phase II T1 - Crab Flare Observations with H.E.S.S. Phase II N2 - The H.E.S.S. array is a third generation Imaging Atmospheric Cherenkov Telescope (IACT) array. It is located in the Khomas Highland in Namibia, and measures very high energy (VHE) gamma-rays. In Phase I, the array started data taking in 2004 with its four identical 13 m telescopes. Since then, H.E.S.S. has emerged as the most successful IACT experiment to date. Among the almost 150 sources of VHE gamma-ray radiation found so far, even the oldest detection, the Crab Nebula, keeps surprising the scientific community with unexplained phenomena such as the recently discovered very energetic flares of high energy gamma-ray radiation. During its most recent flare, which was detected by the Fermi satellite in March 2013, the Crab Nebula was simultaneously observed with the H.E.S.S. array for six nights. The results of the observations will be discussed in detail during the course of this work. During the nights of the flare, the new 24 m × 32 m H.E.S.S. II telescope was still being commissioned, but participated in the data taking for one night. To be able to reconstruct and analyze the data of the H.E.S.S. Phase II array, the algorithms and software used by the H.E.S.S. Phase I array had to be adapted. The most prominent advanced shower reconstruction technique developed by de Naurois and Rolland, the template-based model analysis, compares real shower images taken by the Cherenkov telescope cameras with shower templates obtained using a semi-analytical model. To find the best fitting image, and, therefore, the relevant parameters that describe the air shower best, a pixel-wise log-likelihood fit is done. The adaptation of this advanced shower reconstruction technique to the heterogeneous H.E.S.S. Phase II array for stereo events (i.e. air showers seen by at least two telescopes of any kind), its performance using MonteCarlo simulations as well as its application to real data will be described. N2 - Das H.E.S.S. Experiment misst sehr hochenergetische Gammastrahlung im Khomas Hochland von Namibia. Es ist ein sogenanntes abbildendes atmosphärisches Cherenkov-Teleskopsystem welches in der 1. Phase, die im Jahr 2004 mit der Datennahme begann, aus vier identischen 13 m Spiegelteleskopen bestand. Seitdem hat sich H.E.S.S. als das erfolgreichstes Experiment in der bodengebundenen Gammastrahlungsastronomie etabliert. Selbst die älteste der mittlerweile fast 150 entdeckten Quellen von sehr hochenergetischer Gammastrahlung, der Krebsnebel, fasziniert immernoch Wissenschaftler mit neuen bisher unbekannten und unerwarteten Phänomenen. Ein Beispiel dafür sind die vor kurzem entdeckten sehr energiereichen Ausbrüche von hochenergetischer Gammastrahlung. Bei dem letzten deratigen Ausbruch des Krebsnebels im März 2013 hat das H.E.S.S. Experiment für sechs Nächte simultan mit dem Fermi-Satelliten, welcher den Ausbruch entdeckte, Daten genommen. Die Analyse der Daten, deren Ergebnis und deren Interpretation werden im Detail in dieser Arbeit vorgestellt. Während dieser Beobachtungen befand sich ein neues 24 m × 32 m großes Spiegelteleskop, das H.E.S.S. II- Teleskop, noch in seiner Inbetriebnahme, trotzdem hat es für eine dieser sechs Nächte an der Datennahme des gesamten Teleskopsystems teilgenommen. Um die Daten rekonstruieren und analysieren zu können, mussten die für die 1. Phase des Experiments entwickelten Algorithmen und die Software des H.E.S.S.- Experiments angepasst werden. Die fortschrittlichste Schauerrekonstruktionsmethode, welche von de Naurois und Rolland entwickelt wurde, basiert auf dem Vergleich von echten Schauerbildern, die mit Hilfe der Cherenkov-Kameras der einzelnen Teleskope aufgenommen wurden, mit Schauerschablonen die mit Hilfe eines semianalytischen Modells erzeugt wurden. Das am besten passende Bild und damit auch alle relevanten Schauerparameter, wird mit Hilfe einer pixelweisen Loglikelihood-Anpassung ermittelt. Die nötigen Änderungen um Multiteleskopereignisse, welche vom heterogenen H.E.S.S. Phase II Detektor gemessen wurden, mit Hilfe dieser fortschrittlichen Schauerrekonstruktionsmethode analysieren zu können, sowie die resultierenden Ergebnisse von MonteCarlo-Simulationen, als auch die Anwendung auf echte Daten, werden im Rahmen dieser Arbeit präsentiert. KW - Gammastrahlungsastronomie KW - Rekonstruktionsmethoden KW - Datenanalyse KW - Krebsnebel KW - gamma-ray astronomy KW - reconstruction methods KW - data analysis KW - Crab Nebula Y1 - 2014 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus-72545 ER - TY - JOUR A1 - Noack, Franziska T1 - CREADED: Colored-Relief application for digital elevation data JF - Process design for natural scientists: an agile model-driven approach N2 - In the geoinformatics field, remote sensing data is often used for analyzing the characteristics of the current investigation area. This includes DEMs, which are simple raster grids containing grey scales representing the respective elevation values. The project CREADED that is presented in this paper aims at making these monochrome raster images more significant and more intuitively interpretable. For this purpose, an executable interactive model for creating a colored and relief-shaded Digital Elevation Model (DEM) has been designed using the jABC framework. The process is based on standard jABC-SIBs and SIBs that provide specific GIS functions, which are available as Web services, command line tools and scripts. Y1 - 2014 SN - 978-3-662-45005-5 SN - 1865-0929 IS - 500 SP - 186 EP - 199 PB - Springer CY - Berlin ER - TY - JOUR A1 - Kind, Josephine T1 - Creation of topographic maps JF - Process design for natural scientists: an agile model-driven approach N2 - Location analyses are among the most common tasks while working with spatial data and geographic information systems. Automating the most frequently used procedures is therefore an important aspect of improving their usability. In this context, this project aims to design and implement a workflow, providing some basic tools for a location analysis. For the implementation with jABC, the workflow was applied to the problem of finding a suitable location for placing an artificial reef. For this analysis three parameters (bathymetry, slope and grain size of the ground material) were taken into account, processed, and visualized with the The Generic Mapping Tools (GMT), which were integrated into the workflow as jETI-SIBs. The implemented workflow thereby showed that the approach to combine jABC with GMT resulted in an user-centric yet user-friendly tool with high-quality cartographic outputs. Y1 - 2014 SN - 978-3-662-45005-5 IS - 500 SP - 229 EP - 238 PB - Springer CY - Berlin ER - TY - JOUR A1 - de Carvalho, Sidney J. A1 - Metzler, Ralf A1 - Cherstvy, Andrey G. T1 - Critical adsorption of polyelectrolytes onto charged Janus nanospheres JF - Physical chemistry, chemical physics : a journal of European Chemical Societies N2 - Based on extensive Monte Carlo simulations and analytical considerations we study the electrostatically driven adsorption of flexible polyelectrolyte chains onto charged Janus nanospheres. These net-neutral colloids are composed of two equally but oppositely charged hemispheres. The critical binding conditions for polyelectrolyte chains are analysed as function of the radius of the Janus particle and its surface charge density, as well as the salt concentration in the ambient solution. Specifically for the adsorption of finite-length polyelectrolyte chains onto Janus nanoparticles, we demonstrate that the critical adsorption conditions drastically differ when the size of the Janus particle or the screening length of the electrolyte are varied. We compare the scaling laws obtained for the adsorption-desorption threshold to the known results for uniformly charged spherical particles, observing significant disparities. We also contrast the changes to the polyelectrolyte chain conformations close to the surface of the Janus nanoparticles as compared to those for simple spherical particles. Finally, we discuss experimentally relevant physicochemical systems for which our simulations results may become important. In particular, we observe similar trends with polyelectrolyte complexation with oppositely but heterogeneously charged proteins. Y1 - 2014 U6 - https://doi.org/10.1039/c4cp02207f SN - 1463-9076 SN - 1463-9084 VL - 16 IS - 29 SP - 15539 EP - 15550 PB - Royal Society of Chemistry CY - Cambridge ER - TY - GEN A1 - de Carvalho, Sidney J. A1 - Metzler, Ralf A1 - Cherstvy, Andrey G. T1 - Critical adsorption of polyelectrolytes onto charged Janus nanospheres N2 - Based on extensive Monte Carlo simulations and analytical considerations we study the electrostatically driven adsorption of flexible polyelectrolyte chains onto charged Janus nanospheres. These net-neutral colloids are composed of two equally but oppositely charged hemispheres. The critical binding conditions for polyelectrolyte chains are analysed as function of the radius of the Janus particle and its surface charge density, as well as the salt concentration in the ambient solution. Specifically for the adsorption of finite-length polyelectrolyte chains onto Janus nanoparticles, we demonstrate that the critical adsorption conditions drastically differ when the size of the Janus particle or the screening length of the electrolyte are varied. We compare the scaling laws obtained for the adsorption–desorption threshold to the known results for uniformly charged spherical particles, observing significant disparities. We also contrast the changes to the polyelectrolyte chain conformations close to the surface of the Janus nanoparticles as compared to those for simple spherical particles. Finally, we discuss experimentally relevant physico-chemical systems for which our simulations results may become important. In particular, we observe similar trends with polyelectrolyte complexation with oppositely but heterogeneously charged proteins. T3 - Zweitveröffentlichungen der Universität Potsdam : Mathematisch-Naturwissenschaftliche Reihe - 278 Y1 - 2014 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus4-98783 ER - TY - JOUR A1 - Schmidt, Bernd A1 - Hauke, Sylvia T1 - Cross metathesis of allyl alcohols: how to suppress and how to promote double bond isomerization N2 - Under standard conditions the cross metathesis of allyl alcohols and methyl acrylate is accompanied by the formation of ketones, resulting from uncontrolled and undesired double bond isomerization. By conducting the CM in the presence of phenol, the catalyst loading and the reaction time required for quantiative conversion can be reduced, and isomerization can be suppressed. On the other hand, consecutive isomerization can be deliberately promoted by evaporating excess methyl acrylate after completing cross metathesis and by adding a base or silane as chemical triggers. Y1 - 2014 UR - http://pubs.rsc.org/en/content/articlepdf/2013/ob/c3ob40167g U6 - https://doi.org/10.1039/c3ob40167g SN - 1477-0520 ER - TY - THES A1 - Reiter, Karsten T1 - Crustal stress variability across spatial scales - examples from Canada, Northern Switzerland and a South African gold mine T1 - Die Variabilität der krustalen Spannungen auf räumlichen unterschiedlichen Skalen – Beispiele von Kanada, der Nordschweiz und einer Südafrikanischen Goldmine N2 - The quantitative descriptions of the state of stress in the Earth’s crust, and spatial-temporal stress changes are of great importance in terms of scientific questions as well as applied geotechnical issues. Human activities in the underground (boreholes, tunnels, caverns, reservoir management, etc.) have a large impact on the stress state. It is important to assess, whether these activities may lead to (unpredictable) hazards, such as induced seismicity. Equally important is the understanding of the in situ stress state in the Earth’s crust, as it allows the determination of safe well paths, already during well planning. The same goes for the optimal configuration of the injection- and production wells, where stimulation for artificial fluid path ways is necessary. The here presented cumulative dissertation consists of four separate manuscripts, which are already published, submitted or will be submitted for peer review within the next weeks. The main focus is on the investigation of the possible usage of geothermal energy in the province Alberta (Canada). A 3-D geomechanical–numerical model was designed to quantify the contemporary 3-D stress tensor in the upper crust. For the calibration of the regional model, 321 stress orientation data and 2714 stress magnitude data were collected, whereby the size and diversity of the database is unique. A calibration scheme was developed, where the model is calibrated versus the in situ stress data stepwise for each data type and gradually optimized using statistically test methods. The optimum displacement on the model boundaries can be determined by bivariate linear regression, based on only three model runs with varying deformation ratio. The best-fit model is able to predict most of the in situ stress data quite well. Thus, the model can provide the full stress tensor along any chosen virtual well paths. This can be used to optimize the orientation of horizontal wells, which e.g. can be used for reservoir stimulation. The model confirms regional deviations from the average stress orientation trend, such as in the region of the Peace River Arch and the Bow Island Arch. In the context of data compilation for the Alberta stress model, the Canadian database of the World Stress Map (WSM) could be expanded by including 514 new data records. This publication of an update of the Canadian stress map after ~20 years with a specific focus on Alberta shows, that the maximum horizontal stress (SHmax) is oriented southwest to northeast over large areas in Northern America. The SHmax orientation in Alberta is very homogeneous, with an average of about 47°. In order to calculate the average SHmax orientation on a regular grid as well as to estimate the wave-length of stress orientation, an existing algorithm has been improved and is applied to the Canadian data. The newly introduced quasi interquartile range on the circle (QIROC) improves the variance estimation of periodic data, as it is less susceptible to its outliers. Another geomechanical–numerical model was built to estimate the 3D stress tensor in the target area ”Nördlich Lägern” in Northern Switzerland. This location, with Opalinus clay as a host rock, is a potential repository site for high-level radioactive waste. The performed modelling aims to investigate the sensitivity of the stress tensor on tectonic shortening, topography, faults and variable rock properties within the Mesozoic sedimentary stack, according to the required stability needed for a suitable radioactive waste disposal site. The majority of the tectonic stresses caused by the far-field shortening from the South are admitted by the competent rock units in the footwall and hanging wall of the argillaceous target horizon, the Upper Malm and Upper Muschelkalk. Thus, the differential stress within the host rock remains relatively low. East-west striking faults release stresses driven by tectonic shortening. The purely gravitational influence by the topography is low; higher SHmax magnitudes below topographical depression and lower values below hills are mainly observed near the surface. A complete calibration of the model is not possible, as no stress magnitude data are available for calibration, yet. The collection of this data will begin in 2015; subsequently they will be used to adjust the geomechanical–numerical model again. The third geomechanical–numerical model investigates the stress variation in an ultra-deep gold mine in South Africa. This reservoir model is spatially one order of magnitude smaller than the previous local model from Northern Switzerland. Here, the primary focus is to investigate the hypothesis that the Mw 1.9 earthquake on 27 December 2007 was induced by stress changes due to the mining process. The Coulomb failure stress change (DeltaCFS) was used to analyse the stress change. It confirmed that the seismic event was induced by static stress transfer due to the mining progress. The rock was brought closer to failure on the derived rupture plane by stress changes of up to 1.5–15MPa, in dependence of the DeltaCFS analysis type. A forward modelling of a generic excavation scheme reveals that with decreasing distance to the dyke the DeltaCFS values increase significantly. Hence, even small changes in the mining progress can have a significant impact on the seismic hazard risk, i.e. the change of the occurrence probability to induce a seismic event of economic concern. N2 - Die quantitative Beschreibung des Spannungszustandes in der Erdkruste sowie dessen räumlichzeitliche Änderung ist von großer Bedeutung für wissenschaftliche Fragestellungen, sowie für industrielle Anwendung im geotechnischen Bereich. Bei jedem Eingriff des Menschen in den Untergrund (Bohrungen, Tunnel, Kavernen, Reservoirmanagement etc.) wird der Spannungszustand verändert. Entscheidend ist dabei, ob davon möglicherweise (unvorhersehbare) Gefahren, wie zum Beispiel induzierte Seismizität ausgehen können. Genauso wichtig ist auch ein Verständnis des ungestörten Spannungszustandes in der Erdkruste, um zum Beispiel sichere Bohrlochpfade bereits in der Planungsphase zu bestimmen. Selbiges gilt für eine optimale Konfiguration von Injektions- und Produktionsbohrung, wenn künstliche Fluidwegsamkeiten stimuliert werden müssen. Die vorliegende kumulative Dissertation besteht aus vier Manuskripten, welche teilweise bereits publiziert sind. Fokus der beiden ersten Publikationen ist die potentielle Nutzung von Geothermie in der Provinz Alberta (Kanada). Dafür wurde ein 3-D-geomechanisch-numerisches Modell erstellt, das den kompletten gegenwärtigen 3-D-Spannungstensor in der oberen Erdkruste quantifiziert. Für die Kalibrierung des regionalen Modells wurde ein Datensatz von 321 Spannungsorientierungen und 2714 Spannungsmagnituden zusammengetragen, dessen Größe und Diversität einmalig ist. Aufgrund der vorhandenen Datenbasis wurde ein Kalibrierungsschema entwickelt, bei dem das Modell statistisch abgesichert an jedem einzelnen vorhandenen Datentyp schrittweise getestet und optimiert wird. Das optimale Verhältnis der Randbedingungen des Modells kann dabei durch bivariate lineare Regression, auf der Basis von nur drei Modellläufen bestimmt werden. Das Best-fit-Modell kann den Großteil der in situ Spannungsdaten sehr gut reproduzieren. So kann das Modell den 3-D-Spannungstensor entlang beliebiger virtueller Bohrlochpfade liefern, die zum Beispiel für die Planung der optimalen Orientierung horizontaler Stimulationsbohrungen genutzt werden können. Das Modell bestätigt regionale Abweichungen der Spannungsorientierung vom generellen Trend, wie z.B. in der Region des Peace River Bogens und des Bow Island Bogen. Im Zusammenhang mit der Erstellung des Alberta-Spannungsmodells wurde die Datenbank der Weltspannungskarte (WSM) in der Region Kanada um 514 neue Datensätzen erweitert und alle bestehenden Datensätze überprüft. Dies ermöglichte es nach ca. 20 Jahren, eine aktualisierte Spannungskarte für Kanada mit einem vertiefenden Fokus auf die Provinz Alberta zu publizieren. Die maximale horizontale Spannung (SHmax) in weiten Teilen Nordamerikas ist Südwest nach Nordost orientiert. Die SHmax Orientierung in Alberta ist sehr homogen, im Mittel etwa 47°. Zur Berechnung der mittleren SHmax–Orientierung auf einem regelmäßigen Gitter und zur Ableitung des Spannungsmusters dieser Orientierung wurde ein existierender Algorithmus verbessert und auf den kanadischen Datensatz angewendet. Dabei wurde der Quasi Interquartilsabstand am Kreis (QIROC) neu eingeführt, um die Varianz eines periodischen Datensatzes besser abschätzen zu können. Der modifizierte Algorithmus ist weniger anfällig gegenüber Ausreißern in periodischen Datensätzen, als der Vorgänger. Ein weiteres geomechanisch-numerisches Modell zur kontinuierlichen Beschreibung des 3-D-Spannungstensors wurde für das Gebiet „Nördlich Lägern” in der Nordschweiz erstellt. Diese Region ist ein potentieller Endlagerstandort für hochradioaktiven Abfall, eingelagert im Wirtsgestein Opalinuston. Der Fokus des Modells ist es, die Sensitivität des Spannungsfeldes von tektonischem Schub, Topographie, Störungen und den variablen Gesteinseigenschaften im mesozoischen Sedimentstapel auf den Spannungstensor zu untersuchen. Der Hauptanteil der tektonischen Spannungen, verursacht durch den Fernfeldschub von Süden, wird vor allem durch die mechanisch kompetenten Schichten im Liegenden und Hangenden des tonigen Zielhorizontes, dem Oberen Malm und dem Oberen Muschelkalk aufgenommen. Dadurch bleiben die Differenzspannungen in den tonigen Formationen relativ gering. Ost-West streichende Störungen bauen zudem Spannungen des Fernfeldes ab. Der rein gravitative Einfluss der Topographie ist gering; höhere SHmax–Magnituden unterhalb topographischer Depressionen und geringere Werte unter Anhöhen sind vor allem oberflächennah zu beobachten. Eine Kalibrierung des Modells ist nicht abschließend möglich, da im Untersuchungsgebiet keine Spannungsmagnituden zur Verfügung stehen. Diese werden erst in der nächsten Etappe der Endlagersuche, die in 2015 beginnen wird erhoben, sodass das Modell dann gegebenenfalls angepasst werden muss. Das dritte geomechanisch-numerische Modell eines Abschnitts einer tiefliegenden Goldmine in Südafrika ist räumlich gesehen nochmals eine Größenordnung kleiner als das vorherige lokale Modell in der Nordschweiz. Es wurde die Hypothese untersucht, ob das Mw 1.9 Erdbeben am 27. Dezember 2007 durch den Abbau verursacht wurde. Die Analyse der durch die Abbautätigkeit umgelagerten Spannungen unter Nutzung der Spannungsänderung des Coulomb Versagenskriteriums (DeltaCFS) zeigt klar, dass das seismische Ereignis induziert wurde. Das Gestein wurde entlang der Bruchfläche um 1.5 bis 15MPa dem Versagen näher gebracht, je nachdem welche DeltaCFS Analysemethode angewendet wird und unter Berücksichtigung der Unsicherheiten in der Orientierung der Herdflächenlösung sowie der Modellparameter. Eine Vorwärtsmodellierung eines generischen Abbauprozesses zeigt exponentiell steigende DeltaCFS–Werte mit abnehmender Distanz des Abbaus zu dem magmatischen Aufstiegskanal, in dem das Beben stattfand. Folglich haben geringe Änderungen des Abbauprozesses entscheidenden Einfluss auf die Eintretenswahrscheinlichkeit eines seismischen Ereignisses. KW - stress pattern KW - tectonic stress KW - circular statistics KW - 3D geomechanical numerical model KW - crustal stress KW - tektonische Spannungen KW - Spannungsmuster KW - krustale Spannungen KW - zirkulare Statistik KW - 3D geomechanisch-nummerische Modellierung Y1 - 2014 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus4-76762 ER - TY - THES A1 - Feld, Christian T1 - Crustal structure of the Eratosthenes Seamount, Cyprus and S. Turkey from an amphibian wide-angle seismic profile T1 - Die Krustenstruktur von dem Eratosthenes Seeberg, Zypern und der Süd-Türkei anhand eines amphibischen seismischen Weitwinkel Profils N2 - In March 2010, the project CoCoCo (incipient COntinent-COntinent COllision) recorded a 650 km long amphibian N-S wide-angle seismic profile, extending from the Eratosthenes Seamount (ESM) across Cyprus and southern Turkey to the Anatolian plateau. The aim of the project is to reveal the impact of the transition from subduction to continent-continent collision of the African plate with the Cyprus-Anatolian plate. A visual quality check, frequency analysis and filtering were applied to the seismic data and reveal a good data quality. Subsequent first break picking, finite-differences ray tracing and inversion of the offshore wide-angle data leads to a first-arrival tomographic model. This model reveals (1) P-wave velocities lower than 6.5 km/s in the crust, (2) a variable crustal thickness of about 28 - 37 km and (3) an upper crustal reflection at 5 km depth beneath the ESM. Two land shots on Turkey, also recorded on Cyprus, airgun shots south of Cyprus and geological and previous seismic investigations provide the information to derive a layered velocity model beneath the Anatolian plateau and for the ophiolite complex on Cyprus. The analysis of the reflections provides evidence for a north-dipping plate subducting beneath Cyprus. The main features of this layered velocity model are (1) an upper and lower crust with large lateral changes of the velocity structure and thickness, (2) a Moho depth of about 38 - 45 km beneath the Anatolian plateau, (3) a shallow north-dipping subducting plate below Cyprus with an increasing dip and (4) a typical ophiolite sequence on Cyprus with a total thickness of about 12 km. The offshore-onshore seismic data complete and improve the information about the velocity structure beneath Cyprus and the deeper part of the offshore tomographic model. Thus, the wide-angle seismic data provide detailed insights into the 2-D geometry and velocity structures of the uplifted and overriding Cyprus-Anatolian plate. Subsequent gravity modelling confirms and extends the crustal P-wave velocity model. The deeper part of the subducting plate is constrained by the gravity data and has a dip angle of ~ 28°. Finally, an integrated analysis of the geophysical and geological information allows a comprehensive interpretation of the crustal structure related to the collision process. N2 - Im März 2010 wurden im Rahmen des "CoCoCo"-Projektes ein 650km langes amphibisches, seismisches Weitwinkel Profil aufgenommen. Dieses erstreckte sich von dem Eratosthenes Seeberg (ESM) über Zypern und der Süd-Türkei bis zum anatolischen Plateau. Das Hauptziel des Projektes ist es, den Einfluss zu untersuchen, der von dem Übergang eines Subduktion Prozesses hin zu einer Kontinent-Kontinent Kollision der afrikanischen Platte mit der zyprisch-anatolischen Platte hervorgerufen wird. Die seismischen Daten wurden einer visuelle Qualitätsüberprüfung, Frequenz-Analyse und Filterung unterzogen und zeigten eine gute Qualität. Das darauf folgende Picken der Ersteinstätze, eine Finite-Differenzen Raytracing und eine Inversion der offshore Weitwinkel Daten, führte zu einem Laufzeit Tomographie Model. Das Modell zeigt (1) P-Wellengeschwindigkeiten kleiner als 6.5 km/s in der Kruste, (2) eine variable Krustenmächtigkeit von 28 - 37 km und (3) eine obere Krustenreflektion in 5 km Tiefe unter dem ESM. Zwei Landschüsse in der Türkei, ebenfalls aufgenommen auf Zypern, Luftkanonen-Schüsse südlich von Zypern und vorausgegangene geologische und seismische Untersuchungen lieferten die Grundlage, um ein geschichtetes Geschwindigkeitsmodell für das anatolische Plateau und für den Ophiolith-Komplex auf Zypern abzuleiten. Die Analyse der Reflexionen liefert den Beweis für eine nach Norden einfallende Platte welche unter Zypern subduziert. Die Hauptkennzeichen dieses geschichteten Geschwindigkeitsmodelles sind (1) eine obere und untere Kruste mit starken lateral Änderungen in Geschwindigkeit und Mächtigkeit, (2) eine Mohotiefe in 38 - 45 km unter dem anatolischen Plateau, (3) eine flach nach Norden einfallende Platte unter Zypern mit ansteigendem Einfallwinkel und (4) eine typische Ophiolith Sequenz auf Zypern mit einer Gesamtmächtigkeit von 12 km. Die seismischen offshore / onshore Daten komplettieren und verbessern die bisherigen Kenntnisse über die Geschwindigkeitsstruktur unter Zypern und des tieferen Bereiches der offshore Tomographie. Damit liefert die Weitwinkel Seismik detaillierte Einblicke in die 2-D Geometrie und die Geschwindigkeitsstrukturen der angehobenen und überlagerten zyprisch-anatolischen Platte. Die darauf folgende Gravimetrie Modellierung bestätigt und erweitert das P-Wellen Krusten-Geschwindigkeits Modell. Der tiefere Teil der subduzierten Platte, welche einen Einfallswinkel von ~ 28° hat, wurde durch die Gravimetrie Daten belegt. Letztlich erlaubt eine ganzheitliche Analyse von geophysikalischen und geologischen Informationen die umfassende Interpretation der Krustenstruktur welche in Verbindung mit dem Kollisions Prozess steht. KW - incipient continent-continent collision KW - crustal structure of the Eratosthenes Seamount KW - controlled source wide angle seismic KW - crustal structure of south central Turkey KW - Cyprus arc KW - aktive Weitewinkel-Seismik KW - Krustenstruktur des Eratosthenes Seeberges KW - beginnende Kontinent-Kontinent Kollision KW - Krustenstruktur der Süd-Türkei KW - Zypernbogen Y1 - 2014 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus4-73479 ER -