TY - JOUR A1 - Klaver, Martijn A1 - Steenstra, Edgar S. A1 - Borchert, Manuela A1 - Welter, Edmund A1 - Wilke, Max A1 - Berndt, Jasper A1 - Klemme, Stephan T1 - The effect of alkalinity on Ni-O bond length in silicate glasses BT - implications for Ni isotope geochemistry JF - Chemical geology : official journal of the European Association for Geochemistry N2 - Equilibrium mass-dependent ("stable") isotopic fractionation of an element during magmatic processes is driven by a contrast in bonding environment between minerals and silicate melt, which is expressed as an isotopic fractionation factor. A quantitative understanding of such isotopic fractionation factors is vital to interpret observed isotopic variations in magmatic rocks. It is well known that the local environment and the bond strength of an element dictate the sign and magnitude of isotopic fractionation between minerals, but it is uncertain how the structure and chemical composition of a silicate melt can affect mineral-melt isotopic fractionation factors. To explore this, we studied the coordination environment of nickel (Ni) in different silicate glasses using extended X-ray absorption fine structure (EXAFS) measurements at the German synchrotron X-ray source (DESY). We determined -Ni-O bond lengths in a suite of synthetic but near-natural silicate glasses using EXAFS and found that the former vary systematically with melt alkalinity, which is best described by the parameter ln[1 + (Na + K)/Ca]. With increasing melt alkalinity, Ni occupies more IV-fold coordinated sites, which are associated with a shorter -Ni-O bond length. Next, we use the ionic model, which allows to predict isotopic fractionation factors based on the difference in bond length between two phases. We find that more alkaline melts have a stronger preference for the heavier isotopes of Ni than less alkaline melts. This implies that the magnitude of mineral-melt Ni isotope fractionation factors, for instance between olivine and melt, will depend on the alkalinity of the melt. At magmatic temperatures, however, the variation in fractionation factors caused by melt alkalinity will rarely exceed 0.05 parts per thousand and is thus mostly negligible, in particular in the realm of basaltic melt compositions. Nevertheless, the relationship between melt alkalinity and fractionation factor reported here can be used to extrapolate empirical data for mineral-melt Ni isotope fractionation factors, once such data become available, to the full range of magma compositions on Earth and other Solar System bodies. KW - EXAFS KW - Ni-O bond length KW - silicate glasses KW - Ni isotopes KW - isotopic fractionation factors Y1 - 2022 U6 - https://doi.org/10.1016/j.chemgeo.2022.121070 SN - 0009-2541 SN - 1872-6836 VL - 610 PB - Elsevier CY - Amsterdam ER - TY - JOUR A1 - Regenspurg, Simona A1 - Virchow, Lioba A1 - Wilke, Franziska D. H. A1 - Zimmer, Martin A1 - Jolie, Egbert A1 - Hachenberger, Annika A1 - Yirgu, Gezahegn A1 - Gebru, Ermias Filfilu A1 - Vieth-Hillebrand, Andrea A1 - Gizaw, Berhanu T1 - Origin and migration of fluoride in the area of the Aluto Volcanic Complex (Main Ethiopian Rift) JF - Applied geochemistry : journal of the International Association of Geochemistry and Cosmochemistry N2 - Fluoride-enriched ground and surface waters represent a major health risk for the local population in many areas along the East African Rift. The present study investigates the origin of fluoride and the reason for its accumulation in the rift waters, following two hypotheses: (i) fluid-rock-interactions release fluoride from minerals into the water and (ii) magmatic-derived fluoride-containing liquids and gases migrate along permeable fault zones until they dissolve in ground-and surface water or be released to the atmosphere. Rock-, gas, water-, soil-, and plant samples were collected from the area within and close by the Aluto Volcanic Complex, which is part of the Main Ethiopian Rift. Most analyzed waters showed fluoride concentrations above the drinking water limit (> 1.5 mg/L) with the highest values in hot springs (up to 70 mg/L) and the geothermal well (76 mg/L). In the solid phase, a high fluoride content was found in acid volcanic rocks (ignimbrite: 4391 ppm; rhyolite: 3248 ppm) as well as in pumice (up to 1955 ppm). The fluoride content of soil samples collected within the volcanic complex varied between 82 and 1036 ppm, whereas former lake sediments from outside the Aluto Volcanic Complex showed higher fluoride contents ranging from 674 to 8171 ppm. Identified fluoride-rich minerals are various amphiboles (about 3 wt.-% F-), fluor-apatite (about 3 wt % F-), minerals of the fluorcaphite group (about 5 wt.-% F-), parisite (up to 9 wt.-% F-), and fluorite (CaF2). Elevated fluoride concentrations were also measured in some gas samples from fumaroles (up to 50 ppm) and in plant samples collected next to the fumaroles (up to 65 ppm). Leaching experiments of solid samples with deionized water demonstrated that fluoride can easily be mobilized from pumice and sediments but hardly from consolidated rocks. This fluoride release increased with temperature (up to 150 C) and correlated roughly with dis-solved silica indicating the binding of some fluoride to the amorphous or weakly crystalline silica fraction. Based on these results it was concluded that fluoride migrates via different pathways through the environment: At the depth of the magma chamber during magmatic differentiation fluoride enriches initially in the magmatic melt and accumulates in some late-crystallizing minerals of igneous rocks such as fluorite or mica. Upon volcanic eruption fluoride is predominantly incorporated in the glass (ignimbrite) and ash phase (pumice). On the surface, these rocks are exposed to weathering and fluoride leaches partly out into the aqueous phase. Soft and porous rocks such as pumice release fluoride first whereas hard extrusive/igneous rocks are less prone to weathering and retain the fluoride. Pumice and (lake) sediments might act both, as source and as sink for fluoride in the area. Although some fluoride might drain from the surface into the deeper subsoil, we conclude that magmatic fluids (liquid and gas) contribute more substantially to the overall fluoride ground water content because (i) of the much higher fluoride content in deep geothermal waters and hot springs as compared to surface-near waters; (ii) active geothermal surface manifestations located along fault zones indicate that fluids migrate from deep magmatic intrusions (as gas and liquid) towards the surface, where fluoride dissolves in groundwater; (iii) and the good correlation between bicarbonate (deriving from dissolution of magmatic CO2) and fluoride content in all analyzed water samples. KW - fluoride KW - environmental contaminant main Ethiopian rift KW - volcanic area KW - Aluto volcanic complex KW - volcanic gases KW - pumice Y1 - 2022 U6 - https://doi.org/10.1016/j.apgeochem.2022.105403 SN - 0883-2927 SN - 1872-9134 VL - 146 PB - Elsevier CY - Oxford ER - TY - JOUR A1 - Van der Looven, Thomas A1 - Winterleitner, Gerd A1 - Betzler, Christian A1 - Mutti, Maria T1 - A biotic perspective on the Oligo-Miocene evolution of the Maldives carbonate platform from forward stratigraphic modelling (Indian Ocean) JF - Marine and petroleum geology N2 - Forward stratigraphic modelling is a fast-developing modelling approach, used to test conceptual models, and predict stratigraphic architecture and depositional facies from basin to reservoir scales. Published subsurface applications demonstrate its added value by integrating multidisciplinary data as well as geological concepts into its constraints. When applied to carbonate depositional systems, composed of multiple sediment factories, the cooperating and interdependent production mechanisms remain poorly studied. By applying the technique to a well-studied section of the Maldives carbonate platform, a specific model design-adapted to the geological age and setting, and constrained by available data-sheds light on the interaction of its carbonate producers. The results yield a naturalistic depositional facies distribution and offer insight in the changing relationship between biotic communities during the platform evolution. After calibration, the reference model unequivocally links the formerly proposed genetic model to the seismostratigraphic architecture. Furthermore, the results show how environmental changes (seemingly of secondary impact compared to changes in physical accommodation in the stratigraphic record) can induce substantial fluctuations in carbonate production rates of biotic communities, affect the ecological accommodation, and thus impact the platform architecture. Therefore, it is crucial to treat carbonate production rates during periods of environmental change as variables with associated uncertainties in a forward stratigraphic model setup. KW - neogene KW - Maldives carbonate platform KW - forward stratigraphic modelling KW - sequence stratigraphy KW - carbonate production Y1 - 2022 U6 - https://doi.org/10.1016/j.marpetgeo.2022.105907 SN - 0264-8172 SN - 1873-4073 VL - 145 PB - Elsevier CY - Oxford ER - TY - JOUR A1 - Singh, Manudeo A1 - Sinha, Rajiv T1 - Integrating hydrological connectivity in a process-response framework for restoration and monitoring prioritisation of floodplain wetlands in the Ramganga Basin, India JF - Water N2 - Floodplain wetlands are critical for sustaining various ecological and hydrological functions in a riverine environment. Severe anthropogenic alterations and human occupation of floodplains have threatened these wetlands in several parts of the world. A major handicap in designing sustainable restoration and monitoring strategies for these wetlands is the lack of scientific process-based understanding and information on the basin-scale controls of their degradation. Here, we offer a novel approach to integrate the connectivity of the wetlands with the surrounding landscape along with other attributes such as stream density, hydrometeorological parameters, and groundwater dynamics to explain their degradation and then to prioritise them for restoration and monitoring. We hypothesise that the best possible connectivity scenario for the existence of a wetland would be if (a) the wetland has a high connectivity with its upslope area, and (b) the wetland has a low connectivity with its downslope region. The first condition ensures the flow of water into the wetland and the second condition allows longer water residence time in the wetland. Accordingly, we define four connectivity-based wetland health scenarios-good, no impact, bad, and worst. We have implemented the proposed method in 3226 wetlands in the Ramganga Basin in north India. Further, we have applied specific selection criteria, such as distance from the nearest stream and stream density, to prioritise the wetlands for restoration and monitoring. We conclude that the connectivity analysis offers a quick process-based assessment of wetlands' health status and serves as an important criterion to prioritise the wetlands for developing appropriate management strategies. KW - floodplain protection KW - ganga plains KW - hydrological connectivity KW - wetland health KW - wetland management Y1 - 2022 U6 - https://doi.org/10.3390/w14213520 SN - 2073-4441 VL - 14 IS - 21 PB - MDPI CY - Basel ER - TY - JOUR A1 - Loh, Yvonne Sena Akosua A1 - Fynn, Obed Fiifi A1 - Manu, Evans A1 - Afrifa, George Yamoah A1 - Addai, Millicent Obeng A1 - Akurugu, Bismark Awinbire A1 - Yidana, Sandow Mark T1 - Groundwater-surface water interactions BT - application of hydrochemical and stable isotope tracers to the lake bosumtwi area in Ghana JF - Environmental earth sciences N2 - This research demonstrated the application of hydrochemical data and stable water isotopes of delta O-18 and delta D (or delta 2H) for evaluating the relationship between surface water in Lake Bosumtwi and the underlying groundwater system. It aimed at determining the presence or absence of a hydraulic relationship and for evaluating the possible direction of flow at the interface between the two reservoirs. The study also estimated evaporative losses of infiltrating rainwater as it transits the unsaturated zone and provided important information on the hydrological processes prevailing in the area. The results of Q-Mode hierarchical cluster analysis (HCA) clearly differentiate the lake water from the groundwater based on their spatial relationship. These results indicated that groundwater recharge occurs on the hilltops of the crater, where it is slightly acidic with low levels of dissolved ions, characterised by short residence time and rapid unrestricted vertical infiltration and recharge. The groundwater becomes more mineralized with longer contact times and deeper circulation with the host rock, while it flows from the recharge areas towards the lake at lower elevations. Analyses of delta O-18 and delta D showed a high evaporation rate on the lake surface (90%) with a significant evaporative enrichment, whereas groundwater showed no significant isotopic variations. Thus suggesting that the aquifers have been recharged by recent meteoric water that has undergone some evaporative enrichment since the study established an evaporation rate of water infiltrating the unsaturated zone ranging from 54 to 60%. Both reservoirs do not appear to be hydraulically connected, and where such a connection exists, it is expected to favour the lake. KW - Lake Bosumtwi KW - stable isotopes KW - kinetic fractionation KW - surface water KW - groundwater KW - Ghana Y1 - 2022 U6 - https://doi.org/10.1007/s12665-022-10644-x SN - 1866-6280 SN - 1866-6299 VL - 81 IS - 22 PB - Springer CY - New York ER - TY - JOUR A1 - Lipus, Daniel A1 - Jia, Zeyu A1 - Bartholomäus, Alexander A1 - Burckhardt, Oliver A1 - Sondermann, Megan A1 - Wagner, Dirk A1 - Kallmeyer, Jens T1 - Circular metagenome-assembled genome of Methanobacterium sp. strain ERen5, a putative methanogenic, H2-utilizing terrestrial subsurface archaeon JF - Microbiology Resource Announcements N2 - A circular, single-contig Methanobacterium sp. metagenome-assembled genome (MAG) was recovered from high-CO2 enrichments inoculated with drill core material from the tectonic Eger Rift terrestrial subsurface. Annotation of the recovered MAG highlighted putative methanogenesis genes, providing valuable information on archaeal activity in the deep biosphere. Y1 - 2022 U6 - https://doi.org/10.1128/mra.00676-22 SN - 2576-098X VL - 11 IS - 10 PB - American Society for Microbiology CY - Washington ER - TY - JOUR A1 - Schifferle, Lukas A1 - Speziale, Sergio A1 - Lobanov, Sergey S. T1 - High-pressure evolution of the refractive index of MgO up to 140 GPa JF - Journal of applied physics N2 - Refractive index provides fundamental insights into the electronic structure of materials. At high pressure, however, the determination of refractive index and its wavelength dispersion is challenging, which limits our understanding of how physical properties of even simple materials, such as MgO, evolve with pressure. Here, we report on the measurement of room-temperature refractive index of MgO up to similar to 140 GPa. The refractive index of MgO at 600 nm decreases by similar to 2.4% from similar to 1.737 at 1 atm to similar to 1.696 (+/- 0.017) at similar to 140 GPa. Despite the index at 600 nm is essentially pressure independent, the absolute wavelength dispersion of the refractive index at 550-870 nm decreases by similar to 28% from similar to 0.015 at 1 atm to similar to 0.011 (+/- 8.04 x 10(-4)) at similar to 103 GPa. Single-effective-oscillator analysis of our refractive index data suggests that the bandgap of MgO increases by similar to 1.1 eV from 7.4 eV at 1 atm to similar to 8.5 (+/- 0.6) eV at similar to 103 GPa. Y1 - 2022 U6 - https://doi.org/10.1063/5.0106626 SN - 0021-8979 SN - 1089-7550 VL - 132 IS - 12 PB - AIP Publishing CY - Melville ER - TY - JOUR A1 - Bartholomäus, Alexander A1 - Mitzscherling, Julia A1 - Lipus, Daniel A1 - MacLean, Joana A1 - Wagner, Dirk T1 - Draft genome sequence of Paenalcaligenes niemegkensis NGK35T, isolated from plastic-polluted soil of an abandoned landfill JF - Microbiology Resource Announcements N2 - The Gram-negative bacterium Paenalcaligenes niemegkensis NGK35(T) was isolated from plastic debris in an abandoned landfill. It has the ability to grow on polyethylene and hexadecane as the sole carbon sources. Here, we report the corresponding draft genome, which contains 3.66 Mbp and is characterized by a G+C content of 52.1%. Y1 - 2022 U6 - https://doi.org/10.1128/mra.00671-22 SN - 2576-098X VL - 11 IS - 10 PB - American Society for Microbiology CY - Washington ER - TY - JOUR A1 - Rikani, Albano A1 - Frieler, Katja A1 - Schewe, Jacob T1 - Climate change and international migration BT - exploring the macroeconomic channel JF - PLoS one N2 - International migration patterns, at the global level, can to a large extent be explained through economic factors in origin and destination countries. On the other hand, it has been shown that global climate change is likely to affect economic development over the coming decades. Here, we demonstrate how these future climate impacts on national income levels could alter the global migration landscape. Using an empirically calibrated global migration model, we investigate two separate mechanisms. The first is through destination-country income, which has been shown consistently to have a positive effect on immigration. As countries' income levels relative to each other are projected to change in the future both due to different rates of economic growth and due to different levels of climate change impacts, the relative distribution of immigration across destination countries also changes as a result, all else being equal. Second, emigration rates have been found to have a complex, inverted U-shaped dependence on origin-country income. Given the available migration flow data, it is unclear whether this dependence-found in spatio-temporal panel data-also pertains to changes in a given migration flow over time. If it does, then climate change will additionally affect migration patterns through origin countries' emigration rates, as the relative and absolute positions of countries on the migration "hump" change. We illustrate these different possibilities, and the corresponding effects of 3 degrees C global warming (above pre-industrial) on global migration patterns, using climate model projections and two different methods for estimating climate change effects on macroeconomic development. Y1 - 2022 U6 - https://doi.org/10.1371/journal.pone.0276764 SN - 1932-6203 VL - 17 IS - 11 PB - PLoS CY - San Fransisco ER - TY - JOUR A1 - Dahm, Torsten A1 - Hainzl, Sebastian T1 - A Coulomb stress response model for time-dependent earthquake forecasts JF - Journal of geophysical research : Solid earth N2 - Seismicity models are probabilistic forecasts of earthquake rates to support seismic hazard assessment. Physics-based models allow extrapolating previously unsampled parameter ranges and enable conclusions on underlying tectonic or human-induced processes. The Coulomb Failure (CF) and the rate-and-state (RS) models are two widely used physics-based seismicity models both assuming pre-existing populations of faults responding to Coulomb stress changes. The CF model depends on the absolute Coulomb stress and assumes instantaneous triggering if stress exceeds a threshold, while the RS model only depends on stress changes. Both models can predict background earthquake rates and time-dependent stress effects, but the RS model with its three independent parameters can additionally explain delayed aftershock triggering. This study introduces a modified CF model where the instantaneous triggering is replaced by a mean time-to-failure depending on the absolute stress value. For the specific choice of an exponential dependence on stress and a stationary initial seismicity rate, we show that the model leads to identical results as the RS model and reproduces the Omori-Utsu relation for aftershock decays as well stress-shadowing effects. Thus, both CF and RS models can be seen as special cases of the new model. However, the new stress response model can also account for subcritical initial stress conditions and alternative functions of the mean time-to-failure depending on the problem and fracture mode. KW - seismicity KW - physics based model KW - earthquake physics Y1 - 2022 U6 - https://doi.org/10.1029/2022JB024443 SN - 2169-9313 SN - 2169-9356 VL - 127 IS - 9 PB - American Geophysical Union CY - Washington ER - TY - JOUR A1 - Sieber, Melanie J. A1 - Wilke, Max A1 - Appelt, Oona A1 - Oelze, Marcus A1 - Koch-Müller, Monika T1 - Melting relations of Ca-Mg carbonates and trace element signature of carbonate melts up to 9 GPa - a proxy for melting of carbonated mantle lithologies JF - European journal of mineralogy N2 - The most profound consequences of the presence of Ca-Mg carbonates (CaCO3-MgCO3) in the Earth's upper mantle may be to lower the melting temperatures of the mantle and control the melt composition. Low-degree partial melting of a carbonate-bearing mantle produces CO2-rich, silica-poor melts compositionally imposed by the melting relations of carbonates. Thus, understanding the melting relations in the CaCO3-MgCO3 system facilitates the interpretation of natural carbonate-bearing silicate systems. We report the melting relations of the CaCO3-MgCO3 system and the partition coefficient of trace elements between carbonates and carbonate melt from experiments at high pressure (6 and 9 GPa) and temperature (1300-1800 degrees C) using a rocking multi-anvil press. In the absence of water, Ca-Mg carbonates are stable along geothermal gradients typical of subducting slabs. Ca-Mg carbonates ( similar to Mg0.1-0.9Ca0.9-0.1CO3) partially melt beneath mid-ocean ridges and in plume settings. Ca-Mg carbonates melt incongruently, forming periclase crystals and carbonate melt between 4 and 9 GPa. Furthermore, we show that the rare earth element (REE) signature of Group-I kimberlites, namely strong REE fractionation and depletion of heavy REE relative to the primitive mantle, is resembled by carbonate melt in equilibrium with Ca-bearing magnesite and periclase at 6 and 9 GPa. This suggests that the dolomite-magnesite join of the CaCO3-MgCO3 system might be useful to approximate the REE signature of carbonate-rich melts parental to kimberlites. Y1 - 2022 U6 - https://doi.org/10.5194/ejm-34-411-2022 SN - 0935-1221 SN - 1617-4011 VL - 34 IS - 5 SP - 411 EP - 424 PB - Copernicus CY - Göttingen ER - TY - JOUR A1 - Jia, Zeyu A1 - Lipus, Daniel A1 - Bartholomaeus, Alexander A1 - Burckhardt, Oliver A1 - Sondermann, Megan A1 - Wagner, Dirk A1 - Kallmeyer, Jens T1 - Metagenome-assembled genome of a putative methanogenic Methanosarcina sp. strain enriched from terrestrial high-CO2 subsurface sediments JF - Microbiology Resource Announcements N2 - A metagenome-assembled genome (MAG), named Methanosarcina sp. strain ERenArc_MAG2, was obtained from a 3-month-old H-2/CO2 atmosphere enrichment culture, originally inoculated with 60-m deep drill core sediment collected from the tectonic Eger Rift terrestrial subsurface. Annotation of the recovered draft genome revealed putative archaeal methanogenesis genes in the deep biosphere. A metagenome-assembled genome (MAG), named Methanosarcina sp. strain ERenArc_MAG2, was obtained from a 3-month-old H-2/CO2 atmosphere enrichment culture, originally inoculated with 60-m deep drill core sediment collected from the tectonic Eger Rift terrestrial subsurface. Annotation of the recovered draft genome revealed putative archaeal methanogenesis genes in the deep biosphere. Y1 - 2022 U6 - https://doi.org/10.1128/mra.01039-22 SN - 2576-098X VL - 11 IS - 12 PB - American Society for Microbiology CY - Washington ER - TY - JOUR A1 - Lück, Erika A1 - Guillemoteau, Julien A1 - Tronicke, Jens A1 - Rummel, Udo A1 - Hierold, Wilfried T1 - From point to field scale-indirect monitoring of soil moisture variations at the DWD test site in Falkenberg JF - Geoderma : an international journal of soil science N2 - Information regarding the spatial distribution of soil water content is key in many disciplines and applications including soil and atmospheric sciences, hydrology, and agricultural engineering. Thus, within the past decades various experimental methods and strategies have been developed to map spatial variations in soil moisture distribution and to monitor temporal changes. Our study examines the combination of electrical resistivity mapping and point observations of soil moisture to infer the spatial and the temporal variability of soil moisture. Over a period of around two years, we performed field measurements on six days to collect repeated electrical resistivity mapping data for a nine-hectare test site south-east of Berlin, Germany. Permanently installed TDR probes, temporary TDR measurements within permanently installed tubes, and gravimetric measurements using soil samples provided soil moisture data at various selected points. In addition, soil analysis and classification results are available for 132 regularly distributed positions up to depths of 1.2 m. We compare and link three-dimensional resistivity models obtained via data inversion to soil composition and soil moisture as provided by our point data. Both the soil samples and the resistivity models indicate a two-layer medium characterized by a sandy top layer with varying thickness and a loamy bottom soil. For all six field campaigns, we observe similar resistivity patterns reflecting the temporally stable influence of soil texture. While the overall patterns are stable, the range of resistivity values changes with soil moisture. Finally, to estimate spatial models of soil moisture, we link our soil moisture and resistivity data using empirical petrophysical models relying on a second order polynomial function. We observe a mean prediction error for soil moisture of +/-0.034 m3 & BULL; m? 3 using all observation points while we notice that point-specific models further reduce the error. Thus, we conclude that our experimental and data analysis strategies represent a reliable approach to establish site-specific models and to estimate three-dimensional moisture distribution including temporal variations. KW - earth boundary layer KW - electrical conductivity KW - electrical resistivity KW - near-surface geophysics KW - soil moisture at field scale Y1 - 2022 U6 - https://doi.org/10.1016/j.geoderma.2022.116134 SN - 0016-7061 SN - 1872-6259 VL - 427 PB - Elsevier CY - Amsterdam ER - TY - THES A1 - Heckenbach, Esther Lina T1 - Geodynamic modeling of process interactions at continental plate boundaries N2 - Plate tectonic boundaries constitute the suture zones between tectonic plates. They are shaped by a variety of distinct and interrelated processes and play a key role in geohazards and georesource formation. Many of these processes have been previously studied, while many others remain unaddressed or undiscovered. In this work, the geodynamic numerical modeling software ASPECT is applied to shed light on further process interactions at continental plate boundaries. In contrast to natural data, geodynamic modeling has the advantage that processes can be directly quantified and that all parameters can be analyzed over the entire evolution of a structure. Furthermore, processes and interactions can be singled out from complex settings because the modeler has full control over all of the parameters involved. To account for the simplifying character of models in general, I have chosen to study generic geological settings with a focus on the processes and interactions rather than precisely reconstructing a specific region of the Earth. In Chapter 2, 2D models of continental rifts with different crustal thicknesses between 20 and 50 km and extension velocities in the range of 0.5-10 mm/yr are used to obtain a speed limit for the thermal steady-state assumption, commonly employed to address the temperature fields of continental rifts worldwide. Because the tectonic deformation from ongoing rifting outpaces heat conduction, the temperature field is not in equilibrium, but is characterized by a transient, tectonically-induced heat flow signal. As a result, I find that isotherm depths of the geodynamic evolution models are shallower than a temperature distribution in equilibrium would suggest. This is particularly important for deep isotherms and narrow rifts. In narrow rifts, the magnitude of the transient temperature signal limits a well-founded applicability of the thermal steady-state assumption to extension velocities of 0.5-2 mm/yr. Estimation of the crustal temperature field affects conclusions on all temperature-dependent processes ranging from mineral assemblages to the feasible exploitation of a geothermal reservoir. In Chapter 3, I model the interactions of different rheologies with the kinematics of folding and faulting using the example of fault-propagation folds in the Andean fold-and-thrust belt. The evolution of the velocity fields from geodynamic models are compared with those from trishear models of the same structure. While the latter use only geometric and kinematic constraints of the main fault, the geodynamic models capture viscous, plastic, and elastic deformation in the entire model domain. I find that both models work equally well for early, and thus relatively simple stages of folding and faulting, while results differ for more complex situations where off-fault deformation and secondary faulting are present. As fault-propagation folds can play an important role in the formation of reservoirs, knowledge of fluid pathways, for example via fractures and faults, is crucial for their characterization. Chapter 4 deals with a bending transform fault and the interconnections between tectonics and surface processes. In particular, the tectonic evolution of the Dead Sea Fault is addressed where a releasing bend forms the Dead Sea pull-apart basin, while a restraining bend further to the North resulted in the formation of the Lebanese mountains. I ran 3D coupled geodynamic and surface evolution models that included both types of bends in a single setup. I tested various randomized initial strain distributions, showing that basin asymmetry is a consequence of strain localization. Furthermore, by varying the surface process efficiency, I find that the deposition of sediment in the pull-apart basin not only controls basin depth, but also results in a crustal flow component that increases uplift at the restraining bend. Finally, in Chapter 5, I present the computational basis for adding further complexity to plate boundary models in ASPECT with the implementation of earthquake-like behavior using the rate-and-state friction framework. Despite earthquakes happening on a relatively small time scale, there are many interactions between the seismic cycle and the long time spans of other geodynamic processes. Amongst others, the crustal state of stress as well as the presence of fluids or changes in temperature may alter the frictional behavior of a fault segment. My work provides the basis for a realistic setup of involved structures and processes, which is therefore important to obtain a meaningful estimate for earthquake hazards. While these findings improve our understanding of continental plate boundaries, further development of geodynamic software may help to reveal even more processes and interactions in the future. N2 - Plattentektonische Grenzen bilden die Nahtstellen zwischen tektonischen Platten. Sie werden durch eine Vielzahl von unterschiedlichen und miteinander verknüpften Prozessen geformt und spielen eine Schlüsselrolle im Bereich der Georisiken und der Entstehung von Georessourcen. Viele dieser Prozesse sind bereits erforscht, während viele andere noch unbearbeitet oder unentdeckt sind. In dieser Arbeit wird die geodynamische numerische Modellierungssoftware ASPECT verwendet, um weitere Prozessinteraktionen an kontinentalen Plattengrenzen zu untersuchen. Im Gegensatz zu natürlichen Daten hat die geodynamische Modellierung den Vorteil, dass Prozesse direkt quantifiziert und alle Parameter über die gesamte Entwicklung einer Struktur analysiert werden können. Außerdem können Prozesse und Wechselwirkungen aus komplexen Zusammenhängen herausgefiltert werden, da der Modellierer volle Kontrolle über alle beteiligten Parameter hat. Um dem vereinfachenden Charakter von Modellen im Allgemeinen Rechnung zu tragen, habe ich mich für die Untersuchung allgemeiner geologischer Gegeben-heiten entschieden, wobei der Schwerpunkt auf den Prozessen und Wechselwirkungen liegt, anstatt eine bestimmte Region der Erde genau zu rekonstruieren. In Kapitel 2 werden 2D-Modelle von kontinentalen Rifts mit unterschiedlichen Krustendicken zwischen 20 und 50 km, sowie Extensionsgeschwindigkeiten im Bereich von 0,5-10 mm/Jahr verwendet, um eine Geschwindigkeitsgrenze für die Annahme eines thermischen Gleichgewichtszustandes zu erhalten, welcher üblicherweise verwendet wird, um die Temperaturfelder kontinentaler Rifts weltweit zu beschreiben. Da die Geschwindigkeit der tektonischen Deformation die der Wärmeleitung übersteigt, befindet sich das Temperaturfeld nicht im Gleichgewicht, sondern ist durch ein transientes, tektonisch induziertes Wärmestromsignal gekennzeichnet. Daraus ergibt sich, dass die Tiefen der Isothermen in den geodynamischen Entwicklungsmodellen flacher liegen, als es eine Temperaturverteilung im Gleichgewichtszustand vermuten ließe. Dies macht sich besondersbei tiefen Isothermen und narrow Rifts bemerkbar. In narrow Rifts begrenzt die Magnitude des transienten Temperatursignals eine fundierte Anwendbarkeit der thermischen Gleichgewichtsannahme auf Extensionsgeschwindigkeiten im Bereich von 0,5-2 mm/Jahr. Die Abschätzung des Temperaturfeldes der Erdkruste wirkt sich auf alle temperaturabhängigen Prozesse aus, von der Mineralzusammensetzung bis hin zur möglichen Nutzung eines geothermischen Reservoirs. In Kapitel 3 modelliere ich die Wechselwirkungen verschiedener Rheologien mit der Kinematik von Auffaltungen und Verwerfungen am Beispiel von fault-propagation folds im andinen Falten- und Überschiebungsgürtel. Die Entwicklung der Geschwindigkeitsfelder aus geodynamischen Modellen wird mit denen aus Trishear-Modellen für dieselbe Struktur verglichen. Während letztere nur geometrische und kinematische Charakteristika der Hauptverwerfung verwenden, erfassen die geodynamischen Modelle sowohl viskose, wie auch plastische und elastische Verformung im gesamten Modellbereich. Meine Forschung zeigt, dass beide Modelle für frühe und damit vergleichbar einfache Phasen der Auffaltung und Verwerfung gleichermaßen gut anwendbar sind, während die Ergebnisse für komplexere Situationen, in denen Verfor-mungen außerhalb der Hauptstörung sowie sekundäre Verwerfungen auftreten, auseinander gehen. Da fault-propagation folds eine wichtige Rolle bei der Bildung von Lagerstätten spielen können, ist Kenntnis zu Migrationswegen von Fluiden, zum Beispiel über Klüfte und Verwerfungen, für ihre Charakterisierung von entscheidender Bedeutung. Kapitel 4 befasst sich mit Biegungen von Transformstörungen sowie den Zusammenhängen zwischen Tektonik und Oberflächenprozessen. Insbesondere wird die tektonische Entwicklung der Verwerfung am Toten Meer behandelt, wo eine von Extension geprägte Biegung der Verwerfung das Pull-Apart-Becken des Toten Meeres bildet, während eine weiter nördlich gelegene von Kompression geprägte Biegung zur Bildung eines Gebirgszuges im Libanon führte. Für dieses Kapitel habe ich gekoppelte 3D Modelle der Geodynamik und Oberflächenentwicklung genutzt sowie beide Arten von Biegungen in einem Modell erforscht. Das Testen von verschiedenen, zufälligen Initialspannungsverteilungen zeigte, dass die Asymmetrie des Beckens eine Folge der Spannungslokalisierung ist. Außerdem habe ich durch Variation der Oberflächenprozesseffizienz herausgearbeitet, dass die Sedimentierung im Pull-Apart-Becken nicht nur die Beckentiefe steuert, sondern auch zu einer Strömungskomponente von Erdkrustenmaterial führt, die die Ablift an der von Kompression geprägten Biegung der Transformstörung erhöht. Anschließend stelle ich in Kapitel 5 die Implementierung von erdbebenähnlichem Verhalten unter Verwendung der Rate-and-State Gleichungen vor, welche die Grundlage für die Erweiterung der Komplexität von Plattengrenzenmodellen in ASPECT bildet. Obwohl Erdbeben auf einer relativ kurzen Zeitskala stattfinden, gibt es viele Wechselwirkungen zwischen dem seismischen Zyklus und den langen Zeitspannen anderer geodynamischer Prozesse. Unter anderem können der Spannungszustand der Kruste sowie das Vorhandensein von Fluiden oder Änderungen der Temperatur das Reibungsverhalten eines Störungssegmentes verändern. Meine Arbeit liefert die Grundlage für einen realistischen Aufbau der beteiligten Strukturen und Prozesse, der wichtig ist, um eine aussagekräftige Abschätzung der Erdbebengefährdung zu erhalten. Während diese Ergebnisse unser Verständnis der kontinentalen Plattengrenzen verbessern, kann die Weiterentwicklung geodynamischer Software dazu beitragen, in Zukunft weitere Prozesse und Wechselwirkungen aufzudecken. T2 - Geodynamische Modellierung von Prozessinteraktionen an kontinentalen Plattengrenzen KW - geodynamic modeling KW - plate boundaries KW - continental crust KW - heat flow KW - landscape evolution KW - geodynamische Modellierung KW - Plattengrenzen KW - kontinentale Kruste KW - Wärmediffusion KW - Oberflächenmodellierung Y1 - 2024 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus4-647500 ER - TY - JOUR A1 - Scherbaum, Frank A1 - Mzhavanadze, Nana A1 - Rosenzweig, Sebastian A1 - Müller, Meinard T1 - Tuning systems of traditional Georgian singing determined from a new corpus of field recordings JF - Musicologist N2 - In this study we examine the tonal organization of the 2016 GVM dataset, a newly-created corpus of high-quality multimedia field recordings of traditional Georgian singing with a focus on Svaneti. For this purpose, we developed a new processing pipeline for the computational analysis of non-western polyphonic music which was subsequently applied to the complete 2016 GVM dataset. To evaluate under what conditions a single tuning system is representative of current Svan performance practice, we examined the stability of the obtained tuning systems from an ensemble-, a song-, and a corpus-related perspective. Furthermore, we compared the resulting Svan tuning systems with the tuning systems obtained for the Erkomaishvili dataset (Rosenzweig et al., 2020) in the study by Scherbaum et al. (2020). In comparison to a 12-TET (12-tone-equal-temperament) system, the Erkomaishvili and the Svan tuning systems are surprisingly similar. Both systems show a strong presence of pure fourths (500 cents) and fifths (700 cents), and 'neutral' thirds (peaking around 350 cents) as well as 'neutral' sixths. In addition, the sizes of the melodic and the harmonic seconds in both tuning systems differ systematically from each other, with the size of the harmonic second being systematically larger than the melodic one. KW - traditional Georgian music KW - tuning KW - computational ethnomusicology Y1 - 2022 U6 - https://doi.org/10.33906/musicologist.1068947 SN - 2618-5652 VL - 6 IS - 2 SP - 142 EP - 168 PB - Trabzon Univ State Conservatory CY - Trabzon ER - TY - JOUR A1 - Bannister, Stephen A1 - Bertrand, Edward A. A1 - Heimann, Sebastian A1 - Bourguignon, Sandra A1 - Asher, Cameron A1 - Shanks, Jackson A1 - Harvison, Adrian T1 - Imaging sub-caldera structure with local seismicity, Okataina Volcanic Centre, Taupo Volcanic Zone, using double-difference seismic tomography JF - Journal of volcanology and geothermal research N2 - We examine sub-caldera structure and seismicity in and around the Okataina Volcanic Centre (OVC), Taupo Volcanic Zone, New Zealand, using seismic data collected over 4+ years with a temporary array of broadband and short-period seismometers, supplementing data from the permanent New Zealand seismometer network. We derive a new 3-D image of P-wave seismic velocity for the upper crust in the region, using double-difference seismic tomography and utilising waveform cross-correlations. We subsequently relocate 6989 earthquakes which occurred in the region over the 2010-2021 time period, using the 3D velocity model. The seismicity distribution shows spatial clusters west of Lake Rotomahana, as well as beneath Haroharo and the Makatiti Dome, inside the Okataina caldera. Beneath Makatiti Dome 90% of the events are shallower than 7.7 +/- 0.5 km. Outside of the Okataina caldera event relocations highlight short (similar to 3-4 km long) streaks of activity in the Ngakuru graben, part of the active Taupo Rift southwest of Okataina caldera. Inside the OVC the relocated seismicity beneath Makatiti appears closely associated with low (similar to 10%) P-wave velocity anomalies, which we resolve in the similar to 5-to-8-km depth range beneath the Okataina caldera, and which are likely related to partial melt and/or fluid-volatile pathways. Moment tensor analyses for two larger-magnitude events (M(L)4.5 and M(L)4.9) near Haroharo indicate normal faulting, with NNE-SSW fault strike, but with positive CLVD and positive isotropic components when allowing for a full moment tensor, consistent with a magmatic environment with degassing and/or fluid migration. KW - Okataina Caldera KW - Taupo Rift KW - seismic tomography KW - sub-caldera structure KW - Volcanic system Y1 - 2022 U6 - https://doi.org/10.1016/j.jvolgeores.2022.107653 SN - 0377-0273 SN - 1872-6097 VL - 431 PB - Elsevier CY - Amsterdam ER - TY - GEN A1 - Schoenfeldt, Elisabeth A1 - Panek, Tomas A1 - Winocur, Diego A1 - Silhan, Karel A1 - Korup, Oliver T1 - Corrigendum to: postglacial Patagonian mass movement BT - from rotational slides and spreads to earthflows T2 - Geomorphology : an international journal on pure and applied geomorphology Y1 - 2020 U6 - https://doi.org/10.1016/j.geomorph.2020.107471 SN - 0169-555X SN - 1872-695X VL - 373 PB - Elsevier CY - Amsterdam ER - TY - JOUR A1 - Kothari, Kritika A1 - Battisti, Rafael A1 - Boote, Kenneth J. A1 - Archontoulis, Sotirios A1 - Confalone, Adriana A1 - Constantin, Julie A1 - Cuadra, Santiago A1 - Debaeke, Philippe A1 - Faye, Babacar A1 - Grant, Brian A1 - Hoogenboom, Gerrit A1 - Jing, Qi A1 - van der Laan, Michael A1 - Macena da Silva, Fernando Antonio A1 - Marin, Fabio R. A1 - Nehbandani, Alireza A1 - Nendel, Claas A1 - Purcell, Larry C. A1 - Qian, Budong A1 - Ruane, Alex C. A1 - Schoving, Celine A1 - Silva, Evandro H. F. M. A1 - Smith, Ward A1 - Soltani, Afshin A1 - Srivastava, Amit A1 - Vieira, Nilson A. A1 - Slone, Stacey A1 - Salmeron, Montserrat T1 - Are soybean models ready for climate change food impact assessments? JF - European journal of agronomy : the official journal of the European Society for Agronomy N2 - An accurate estimation of crop yield under climate change scenarios is essential to quantify our ability to feed a growing population and develop agronomic adaptations to meet future food demand. A coordinated evaluation of yield simulations from process-based eco-physiological models for climate change impact assessment is still missing for soybean, the most widely grown grain legume and the main source of protein in our food chain. In this first soybean multi-model study, we used ten prominent models capable of simulating soybean yield under varying temperature and atmospheric CO2 concentration [CO2] to quantify the uncertainty in soybean yield simulations in response to these factors. Models were first parametrized with high quality measured data from five contrasting environments. We found considerable variability among models in simulated yield responses to increasing temperature and [CO2]. For example, under a + 3 degrees C temperature rise in our coolest location in Argentina, some models simulated that yield would reduce as much as 24%, while others simulated yield increases up to 29%. In our warmest location in Brazil, the models simulated a yield reduction ranging from a 38% decrease under + 3 degrees C temperature rise to no effect on yield. Similarly, when increasing [CO2] from 360 to 540 ppm, the models simulated a yield increase that ranged from 6% to 31%. Model calibration did not reduce variability across models but had an unexpected effect on modifying yield responses to temperature for some of the models. The high uncertainty in model responses indicates the limited applicability of individual models for climate change food projections. However, the ensemble mean of simulations across models was an effective tool to reduce the high uncertainty in soybean yield simulations associated with individual models and their parametrization. Ensemble mean yield responses to temperature and [CO2] were similar to those reported from the literature. Our study is the first demonstration of the benefits achieved from using an ensemble of grain legume models for climate change food projections, and highlights that further soybean model development with experiments under elevated [CO2] and temperature is needed to reduce the uncertainty from the individual models. KW - Agricultural Model Inter-comparison and Improvement Project (AgMIP); KW - Model ensemble KW - Model calibration KW - Temperature KW - Atmospheric CO2 KW - concentration KW - Legume model Y1 - 2022 U6 - https://doi.org/10.1016/j.eja.2022.126482 SN - 1161-0301 SN - 1873-7331 VL - 135 PB - Elsevier CY - Amsterdam ER - TY - JOUR A1 - Rajewar, S. K. A1 - Mohana Lakshmi, Ch. A1 - Mohanty, Aditya A1 - Pandey, Dwijendra N. A1 - Pandey, Anshuman A1 - Chaurasia, Anurag A1 - Pandey, Ananya A1 - Rajeswar Rao, V. A1 - Naidu, M. S. A1 - Kumar, Amit A1 - Mondal, Saroj K. A1 - Yadav, Rajeev K. A1 - Catherine, J. K. A1 - Giri, R. K. A1 - Gahalaut, Vineet Kumar T1 - Constraining plate motion and crustal deformation from GNSS measurements BT - CSIR-NGRI contribution JF - Journal of the Geological Society of India N2 - Geodetic studies of crustal deformation using Global Navigation Satellite System (GNSS, earlier commonly referred to as Global Positioning System, GPS) measurements at CSIR-NGRI started in 1995 with the installation of a permanent GNSS station at CSIR-NGRI Hyderabad which later became an International GNSS Service (IGS) site. The CSIR-NGRI started expanding its GNSS networks after 2003 with more focussed studies through installation in the NE India, Himalayan arc, Andaman subduction zone, stable and failed rift regions of India plate. In each instance, these measurements helped in unravelling the geodynamics of the region and seismic hazard assessment, e.g., the discovery of a plate boundary fault in the Indo-Burmese wedge, rate and mode of strain accumulation and its spatial variation in the Garhwal-Kumaun and Kashmir region of the Himalayan arc, the influence of non-tectonic deformation on tectonic deformation in the Himalayan arc, nature of crustal deformation through earthquake cycle in the Andaman Sumatra subduction zone, and localised deformation in the intraplate region and across the paleo rift regions. Besides these, GNSS measurements initiated in the Antarctica region have helped in understanding the plate motion and influence of seasonal variations on deformation. Another important by-product of the GNSS observations is the capabilities of these observations in understanding the ionospheric variations due to earthquake processes and also due to solar eclipse. We summarize these outcomes in this article. Y1 - 2021 U6 - https://doi.org/10.1007/s12594-021-1850-8 SN - 0974-6889 VL - 97 IS - 10 SP - 1207 EP - 1213 PB - Springer India CY - New Delhi ER - TY - JOUR A1 - Płóciennik, Mateusz A1 - Zawiska, Izabela A1 - Rzodkiewicz, Monika A1 - Noryśkiewicz, Agnieszka M. A1 - Słowiński, Michał A1 - Müller, Daniela A1 - Brauer, Achim A1 - Antczak-Orlewska, Olga A1 - Kramkowski, Mateusz A1 - Peyron, Odile A1 - Nevalainen, Liisa A1 - Luoto, Tomi P. A1 - Kotrys, Bartosz A1 - Seppä, Heikki A1 - Bidaurreta, Jon Camuera A1 - Rudna, Marta A1 - Mielczarek, Małgorzata A1 - Zawisza, Edyta A1 - Janowska, Ewa A1 - Błaszkiewicz, Mirosław T1 - Climatic and hydrological variability as a driver of the Lake Gościąż biota during the Younger Dryas JF - Catena N2 - The Younger Dryas (YD) is a roughly 1,100-year cold period marking the end of the last glaciation. Climate modelling for northern Europe indicates high summer temperatures and strong continentality. In eastern Europe, the scale of temperature variation and its influence on ecosystems is weakly recognised. Here, we present a multi-proxy reconstruction of YD conditions from Lake Gos ' ciaz (central Poland). The decadal-resolution analysis of its annually varved sediments indicates an initial decrease in Chironomidae-inferred mean July air temperature followed by steady warming. The pollen-inferred winter-to-summer temperature amplitude and annual precip-itation is highest at the Allerod/YD transition and the early YD (ca. 12.7-12.4 ky cal BP) and YD/Holocene (11.7-11.4 ka cal BP) transition. Temperature and precipitation were the main reasons for lake level fluctuations as reflected in the planktonic/littoral Cladocera ratio. The lake's diatom-inferred total phosphorus decreased with increasing summer temperature from about mid YD. Windy conditions in the early YD until ~12.3 ka cal BP caused water mixing and a short-lived/temporary increase in nutrient availability for phytoplankton. The Chironomidae-inferred summer temperature and pollen inferred summer temperature, winter temperature and annual precipitation herein are one of only a few in eastern Europe conducted with such high resolution. KW - Late Glacial KW - Varved sediments KW - Climate reconstructions KW - Chironomidae KW - Cladocera KW - Pollen KW - Diatoms Y1 - 2022 U6 - https://doi.org/10.1016/j.catena.2022.106049 SN - 0341-8162 SN - 1872-6887 VL - 212 PB - Elsevier CY - Amsterdam ER -