TY  - JOUR
A1  - Tranter, Morgan Alan
A1  - De Lucia, Marco
A1  - Kühn, Michael
T1  - Numerical investigation of barite scaling kinetics in fractures
JF  - Geothermics : an international journal of geothermal research and its applications
N2  - Barite stands out as one of the most ubiquitous scaling agents in deep geothermal systems, responsible for irreversible efficiency loss. Due to complex parameter interplay, it is imperative to utilise numerical simulations to investigate temporal and spatial precipitation effects. A one-dimensional reactive transport model is set up with heterogeneous nucleation and crystal growth kinetics. In line with geothermal systems in the North German Basin, the following parameters are considered in a sensitivity analysis: temperature (25 to 150 degrees C), pore pressure (10 to 50 MPa), fracture aperture (10(-4) to 10(-2) m), flow velocity (10(-3) to 10(0) m s(-1)), molar volume (50.3 to 55.6 cm(3) mol(-1)), contact angle for heterogeneous nucleation (0 degrees to 180 degrees), interfacial tension (0.07 to 0.134 J m(-2)), salinity (0.1 to 1.5 mol kgw(-1) NaCl), pH (5 to 7), and supersaturation ratio (1 to 30). Nucleation and consequently crystal growth can only begin if the threshold supersaturation is exceeded, therefore contact angle and interfacial tension are the most sensitive in terms of precipitation kinetics. If nucleation has occurred, crystal growth becomes the dominant process, which is mainly controlled by fracture aperture. Results show that fracture sealing takes place within months (median 33 days) and the affected range can be on the order of tens of metres (median 10 m). The presented models suggest that barite scaling must be recognised as a serious threat if the supersaturation threshold is exceeded, in which case, large fracture apertures could help to minimise kinetic rates. The models further are of use for adjusting the fluid injection temperature.
KW  - Geothermal
KW  - Fracture sealing
KW  - Reactive transport
KW  - Geochemical modelling
KW  - Crystal nucleation
KW  - PHREEQC
Y1  - 2021
SN  - 0375-6505
SN  - 1879-3576
VL  - 91
PB  - Elsevier
CY  - Amsterdam [u.a.]
ER  -