TY - RPRT T1 - Umweltdaten aus Brandenburg BT - Bericht 2007 KW - Brandenburg KW - Umweltschutz KW - Öffentlichkeitsarbeit Y1 - 2007 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-bbdig-224 ER - TY - BOOK T1 - Tackling investment challenges in power generation BT - In IEA countries KW - Energieerzeugung KW - Investitionspolitik KW - Nachhaltigkeit Y1 - 2007 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-bbdig-70 SN - 978-92-64-03007-7 PB - OECD/IEA CY - Paris ER - TY - RPRT T1 - Kurzbericht zur Luftgüte des Jahres 2006 T2 - Materialien zur Umwelt KW - Report KW - Mecklenburg-Vorpommern KW - Ökologie KW - Luftverschmutzung Y1 - 2007 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-bbdig-102 IS - 1/2007 CY - Güstrow ER - TY - BOOK A1 - Fthenakis, Wassilios E. A1 - Gisbert, Kristin A1 - Griebel, Wilfried T1 - Auf den Anfang kommt es an BT - Perspektiven für eine Neuorientierung frühkindlicher Bildung T3 - Bildungsforschung KW - Deutschland KW - Vorschulerziehung KW - Schulwesen Y1 - 2007 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-bbdig-136 VL - 16 CY - Bonn [u.a.] ET - Unveränd. Nachdr. ER - TY - BOOK A1 - Strätz, Rainer A1 - Solbach, Regina A1 - Holst-Solbach, Friedemann T1 - Bildungshäuser für Kinder von drei bis zehn Jahren BT - Expertise KW - Kindergarten KW - Vorschulerziehung KW - Schulwesen Y1 - 2007 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-bbdig-128 CY - Berlin ER - TY - BOOK A1 - Taneja, Preti T1 - Assimilation, exodus, eradication BT - Iraq’s minority communities since 2003 KW - Irak KW - Minderheit KW - Geschichte 2003-2006 Y1 - 2007 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-bbdig-87 SN - 1-904584-60-8 PB - Minority Rights Group International CY - London ER - TY - BOOK A1 - Karg, Detlef A1 - Schopper, Franz A1 - Paschke, Ralph A1 - Meyer, Michael A1 - Ackermann, Irmgard A1 - Baxmann, Matthias A1 - Buchinger, Marie-Luise A1 - Cante, Marcus A1 - Dreger, Hans-Joachim A1 - Gramlich, Sybille A1 - Schwarz, Ulrike A1 - Hübener, Dieter A1 - Metzler, Matthias A1 - Niemann, Alexander A1 - Rohowski, Ilona A1 - Senst, Ingetraud A1 - Groß, Wera ED - Brandenburgisches Landesamt für Denkmalpflege und Archäologisches Landesmuseum, T1 - Denkmalentdeckungen BT - Bilder aus dem Land Brandenburg N2 - »Wenn du reisen willst, mußt du die Geschichte dieses Landes kennen und lieben. Das ist ganz unerläßlich. [...] Wag’ es getrost und du wirst es nicht bereuen. Eigentümliche Freuden und Genüsse werden dich begleiten. Du wirst Entdeckungen machen, denn überall wohin du kommst, wirst du, vom Touristenstandpunkt aus, eintreten wie in ›jungfräuliches Land‹. Du wirst Klosterruinen begegnen, von deren Existenz höchstens die nächste Stadt eine leise Kenntnis hatte; du wirst inmitten alter Dorfkirchen, deren zerbröckelter Schindelturm nur auf Elend deutete, große Wandbilder oder in den treppenlosen Grüften reiche Kupfersärge mit Kruzifix und vergoldeten Wappenschildern finden; du wirst Schlachtfelder überschreiten, Wendenkirchhöfe, Heidengräber, von denen die Menschen nichts mehr wissen.« Die in diesem Bildband gesammelten »Denkmalentdeckungen« verstehen sich als Einladung zu einer Reise durch das Land Brandenburg. Theodor Fontane hatte für ein solches Unternehmen genau den richtigen Blick, als er in seinen »Wanderungen durch die Mark Brandenburg« 1864 diese Sätze schrieb. Auch heute noch sollten wir seiner Anregung zu Begegnungen mit der Geschichte und der Kunstgeschichte des Landes folgen, die uns im Dialog der Kulturen und der Zeiten eine Standortbestimmung in der Gegenwart und eine Orientierung für die Zukunft zugleich bietet. KW - Brandenburg KW - Denkmal KW - Denkmalpflege KW - Bildband KW - Tourismus Y1 - 2007 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus4-72290 SN - 978-3-88462-244-5 PB - Wernersche Verlagsgesellschaft CY - Worms ET - 1200 ER - TY - JOUR A1 - Tomioka, Satoshi ED - Ishihara, Shinichiro ED - Petrova, Svetlana ED - Schwarz, Anne T1 - Intervention effects in focus BT - from a Japanese point of view JF - Interdisciplinary studies on information structure : ISIS ; working papers of the SFB 632 N2 - The most recent trend in the studies of LF intervention effects makes crucial reference to focusing effects on the interveners, and this paper critically examines the representative analyses of the focus-based approach. While each analysis has its own merits and shortcomings, I argue that a pragmatic analysis that does not make appeal to syntactic configurations is better equipped to deal with many of the complex and delicate facts surrounding intervention effects. KW - Intervention Effect KW - Alternative Semantics KW - Whinterrogatives KW - Focus KW - Topic KW - Post-Focus Reduction Y1 - 2007 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus-24502 SN - 1866-4725 SN - 1614-4708 VL - 9 SP - 97 EP - 118 PB - Universitätsverlag Potsdam CY - Potsdam ER - TY - JOUR A1 - Kitagawa, Yoshihisa ED - Ishihara, Shinichiro ED - Petrova, Svetlana ED - Schwarz, Anne T1 - When we fail to question in Japanese JF - Interdisciplinary studies on information structure : ISIS ; working papers of the SFB 632 N2 - When we pay close attention to the prosody of Wh-questions in Japanese, we discover many novel and interesting empirical puzzles that would require us to devise a much finer syntactic component of grammar. This paper addresses the issues that pose some problems to such an elaborated grammar, and offers solutions, making an appeal to the information structure and sentence processing involved in the interpretation of interrogative and focus constructions. KW - focus KW - (implicit) prosody KW - information structure KW - processing KW - Wh-question Y1 - 2007 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus-24481 SN - 1866-4725 SN - 1614-4708 VL - 9 SP - 29 EP - 64 PB - Universitätsverlag Potsdam CY - Potsdam ER - TY - JOUR A1 - Kubozono, Haruo ED - Ishihara, Shinichiro ED - Petrova, Svetlana ED - Schwarz, Anne T1 - Focus and intonation in Japanese BT - Does focus trigger pitch reset? JF - Interdisciplinary studies on information structure : ISIS ; working papers of the SFB 632 N2 - This paper discusses how focus changes prosodic structure in Tokyo Japanese. It is generally believed that focus blocks the intonational process of downstep and causes a pitch reset. This paper presents experimental evidence against this traditional view by looking at the prosodic behavior of Wh words, which receive focus lexically in Japanese as in other languages. It is demonstrated, specifically, that the focused Wh element does not block downstep although it receives a much higher pitch than its preceding element. This suggests that presence of lexical focus does not trigger pitch reset in Japanese. KW - Focus KW - Intonation KW - Japanese KW - Pitch Reset KW - Downstep Y1 - 2007 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus-24472 SN - 1866-4725 SN - 1614-4708 VL - 9 SP - 1 EP - 27 PB - Universitätsverlag Potsdam CY - Potsdam ER - TY - GEN A1 - Kleinwächter, Kai T1 - Wasser weltweit : [Statistik] N2 - Inhalt: Zugang zu Trinkwasser Zugang zu sanitären Anlagen Erneuerbare Wasserbestände – eine Auswahl Struktur des weltweiten Wasserverbrauchs Durchschnittliches Todesalter bei Diarrhoe Y1 - 2007 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus-23262 ER - TY - GEN A1 - Dombrowsky, Ines T1 - Konflikt und Kooperation an grenzüberschreitenden Flüssen N2 - Werden im 21. Jahrhundert die Kriege um Wasser geführt? Von dieser Frage ausgehend diskutiert der Artikel das Konflikt- und Kooperationspotenzial an grenzüberschreitenden Flüssen. Welche Anreize gibt es für Kooperation und was führt zu Konflikten? Den theoretischen Überlegungen werden Erfahrungen an der Elbe sowie am Jordan gegenübergestellt. KW - Grenzüberschreitende Flüsse KW - Wasserkonflikte KW - Kooperation Y1 - 2007 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus-23251 ER - TY - GEN A1 - von Braunmühl, Claudia T1 - Partizipation in der Wasserversorgung N2 - Einerseits führt in Entwicklungsländern die Privatisierung von Wasserbetrieben zu Kostensenkungen. Andererseits verändert sie bisherige Möglichkeiten der Teilnahme. Diese wiederspruchsvollen Entwicklungen diskutiert die Autorin an Beispielen aus Südamerika und Südafrika. Künftige Privatisierungen im Bereich Wasser sollten dauerhafte Formen der Mitwirkung ermöglichen. KW - Entwicklung KW - Wasserversorgung KW - Privatisierung KW - Partizipation Y1 - 2007 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus-23247 ER - TY - GEN A1 - Kleinwächter, Kai T1 - Statistik : Struktur und Einsatzkräfte der Bundeswehr N2 - Inhalt: Personalstruktur der Bundeswehr Strucktur der Bundeswehr und des Einsatzführungskommandos Stärke der deutschen Einsatzkontingente Y1 - 2007 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus-23236 ER - TY - GEN A1 - Siedschlag, Alexander T1 - Im Banne friedenspolitischer Beschwörungsformeln : deutsche Militärpolitik zwischen Interessen und Ideologie N2 - Inhalt: Von ewigen Friedensprozessen Verwaltete Krisenprävention Aktionismus der Beliebigkeit Ausweitung unter Ausdünnung des Werterahmens Universelle Friedensziele moralisch vertretbar? Y1 - 2007 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus-23221 ER - TY - GEN A1 - Rose, Jürgen T1 - Wider den „euro-atlantischen Internationalismus“ : Berliner Republik und Entgrenzung der Bundeswehr N2 - Inhalt: Frieden mit aller Gewalt schaffen? Tatbestand: Staatsterrorismus Das Weißbuch 2006 Bundesverfassungsgericht versus Bundesverwaltungsgericht Weltweites Interventionsrecht Lizenz zum Völkerrechtsbruch „Re-Transformation“ der Bundeswehr Prinzipien für einen sicherheitspolitischen Grundkonsens Breite öffentliche Debatte notwendig Y1 - 2007 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus-23212 ER - TY - GEN A1 - Kleinwächter, Kai T1 - Macht und Ohnmacht in Zahlen : statistische Angaben zu G8 und mehr N2 - Inhalt: Beiträge und Stimmrechte in internationalen Organisationen Ökonomisches Potenzial Verfügbare Energierohstoffe (2006) Militärisches Potenzial Chronologie der Gipfeltreffen Y1 - 2007 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus-23203 ER - TY - GEN A1 - Deng, Chao T1 - Die G8 und Chinas Interessen N2 - Die G8 besitzt aus chinesischer Sicht große Entwicklungsmöglichkeiten. Verglichen mit anderen zwischenstaatlichen Organisationen hat die G8 einzigartige Vorteile angesichts ihrer Macht und Flexibilität. Um ihren Einfluss und ihre Kontrolle über die Weltangelegenheiten zu verstärken, sollte die Gruppe reformiert und erweitert werden. China ist gegenwärtig nicht an einem Beitritt zur G8 interessiert, wohl aber an einer engen Zusammenarbeit. Langfristig ist es allerdings nur eine Frage der Zeit, bis China der G8 beitreten wird. N2 - From the Chinese point of view, the G8 will have a great potential development space in the future. Compared with other intergovernmental organizations, the G8 has its unique advantages in view of power and flexibility. In order to improve its influence and control over the world affairs, the group should be extended and reformed. At the moment China is not interested in getting a member of G8, it is concentrating on close cooperation. But in the long run, it is only a matter of time for China to join the G8. KW - China KW - G8 KW - Internationale Organisationen KW - China KW - G8 KW - International Organisations Y1 - 2007 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus-23198 ER - TY - GEN A1 - Sengupta, Jayshree T1 - Indien und die G8 N2 - Seit 2005 ist Indien als eines der fünf Outreach-Länder in die Diskussionen der G8 eingebunden. Dies geschah wegen seiner Rolle als eine der Kraftquellen der Weltwirtschaft sowie als viertgrößter globaler Markt. Indien betrachtet ein offenes Welthandelregime und einen größeren Kapitalfluss in die Entwicklungsländer als notwendig, um diesen zu helfen, deren Exporte zu steigern, neue Jobs zu schaffen und den Wohlstand ihrer Produzenten zu erhöhen. N2 - Since 2005 India is as one of the five outreach-countries included in the G8 discussions because of its role as one of the world’s economic powerhouses and the fourth biggest market in the world. India regards a more open world trading regime and more capital flows into developing countries necessary to help them to increase their exports, create jobs and increase the wealth of its producers. KW - Klimawandel KW - Welthandel KW - Globalisisierung KW - Indien KW - G8 KW - Climate Change KW - World Trade KW - Globalization KW - India KW - G8 Y1 - 2007 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus-23189 ER - TY - GEN A1 - Nassauer, Otfried T1 - Militärmacht Deutschland? N2 - Inhalt: Im Widerspruch zum Völkerrecht Kooperativer Multilateralismus und Selbstbeschränkung Sicherheitspolitik - Rahmenbedingungen und Risiken Offene Fragen und notwendige Diskussionspunkte Y1 - 2007 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus-23177 ER - TY - GEN A1 - Kleinwächter, Kai T1 - Sprache und Identität in der Europäischen Union : statistische Angaben N2 - Inhalt: Anteil von „Hauptsprachen“ an der EU-Bevölkerung (%) Kenntnis einer Fremdsprache (%) Fremdsprachen in den 27 EU-Staaten (%) Amts- und Minderheitensprachen in der EU (Auswahl) Y1 - 2007 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus-23165 ER - TY - GEN A1 - Stieglitz, Stefan A1 - Fuchß, Christoph A1 - Hillmann, Oliver A1 - Lattemann, Christoph T1 - Mobile learning by using ad hoc messaging network N2 - The requirements of modern e-learning techniques change. Aspects such as community interaction, flexibility, pervasive learning and increasing mobility in communication habits become more important. To meet these challenges e-learning platforms must provide support on mobile learning. Most approaches try to adopt centralised and static e-learning mechanisms to mobile devices. However, often technically it is not possible for all kinds of devices to be connected to a central server. Therefore we introduce an application of a mobile e-learning network which operates totally decentralised with the help of an underlying ad hoc network architecture. Furthermore the concept of ad hoc messaging network (AMNET) is used as basis system architecture for our approach to implement a platform for pervasive mobile e-learning. T3 - Zweitveröffentlichungen der Universität Potsdam : Wirtschafts- und Sozialwissenschaftliche Reihe - paper 015 KW - Mobile learning KW - ad hoc learning KW - community KW - e-learning platform KW - AMNET KW - ad hoc messaging network KW - pervasive learning Y1 - 2007 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus-19960 SN - 1867-5808 ER - TY - BOOK A1 - Ehrke, Jürgen T1 - Zentralisieren durch Dezentralisierung? : Die Reform der Kommunalfinanzen in Georgien N2 - Under the influence of orientation towards European integration, Georgia has introduced a variety of new laws with the apparent aim to decentralize legislative and executive powers. This paper shows that the Georgian efforts of decentralization remain superficial, mainly because they are not backed by additional fiscal competences at the municipality level. Following an initial description of the pre-reform situation as of 2006 and based upon a detailed account of the structural changes since 2007, the author gives insight into the conflicts which arise from the lack of institutional congruency. Neither the extraordinary status of the capital Tbilisi nor the seeming autonomy of the Rebublic of Adjara are likely to sway the renegade territories of Abchasia and Ossetia towards a reintegration under Georgian centralized rule as it continues to exist today. Likewise, the success of the proposed and discussed fiscal equalization scheme depends on whether the President and his ruling party are willing to delegate powers to the subodinate jurisdictions. T3 - Finanzwissenschaftliche Diskussionsbeiträge / Special series G, Arbeitspapiere des Deutsch-Georgischen Arbeitskreises für Finanz- und Sozialpolitik - G-03 KW - decentralization KW - institutional reform KW - fiscal equalization KW - regional autonomy Y1 - 2007 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus-18515 ER - TY - THES A1 - Schröder, Birgit Eva T1 - Spatial and temporal dynamics of the terrestrial carbon cycle : assimilation of two decades of optical satellite data into a process-based global vegetation model T1 - Räumliche und zeitliche Dynamik des terrestrischen Kohlenstoffhaushaltes anhand der Assimilation von 20 Jahren optischer Satellitendaten in ein prozessbasiertes dynamisches globales Vegetationsmodell (DGVM) N2 - This PhD thesis presents the spatio-temporal distribution of terrestrial carbon fluxes for the time period of 1982 to 2002 simulated by a combination of the process-based dynamic global vegetation model LPJ and a 21-year time series of global AVHRR-fPAR data (fPAR – fraction of photosynthetically active radiation). Assimilation of the satellite data into the model allows improved simulations of carbon fluxes on global as well as on regional scales. As it is based on observed data and includes agricultural regions, the model combined with satellite data produces more realistic carbon fluxes of net primary production (NPP), soil respiration, carbon released by fire and the net land-atmosphere flux than the potential vegetation model. It also produces a good fit to the interannual variability of the CO2 growth rate. Compared to the original model, the model with satellite data constraint produces generally smaller carbon fluxes than the purely climate-based stand-alone simulation of potential natural vegetation, now comparing better to literature estimates. The lower net fluxes are a result of a combination of several effects: reduction in vegetation cover, consideration of human influence and agricultural areas, an improved seasonality, changes in vegetation distribution and species composition. This study presents a way to assess terrestrial carbon fluxes and elucidates the processes contributing to interannual variability of the terrestrial carbon exchange. Process-based terrestrial modelling and satellite-observed vegetation data are successfully combined to improve estimates of vegetation carbon fluxes and stocks. As net ecosystem exchange is the most interesting and most sensitive factor in carbon cycle modelling and highly uncertain, the presented results complementary contribute to the current knowledge, supporting the understanding of the terrestrial carbon budget. N2 - In der vorliegenden Arbeit wird anhand der Kombination eines dynamischen globalen Vegetationsmodells mit einer Zeitreihe von 21 Jahren optischer Satellitendaten eine realistische Abschätzung der terrestrischen Quellen und Senken von CO2 ermöglicht. Grundlage des hier vorgestellten neuen Modells stellt das dynamische globale Vegetationsmodell LPJ dar, ein prozessorientiertes Vegetationsmodell, das basierend auf ökophysiologischen Grundlagen die Vegetationsverteilung und -dynamik, Störungen (z.B. Feuer) und den Kohlenstoff- sowie den Wasserkreislauf modelliert. Die Kopplung des LPJ-DGVM erfolgte mit einer Zeitreihe globaler AVHRR-fPAR Daten (fPAR – Anteil photosynthetisch aktiver Strahlung), für den Zeitraum 1982 bis 2002 in einer räumlichen Auflösung von 0.5°. Als Ergebnis liegt nun eine globale raum-zeitliche Verteilung aller relevanten Kohlenstoffflüsse vor: Nettoprimärproduktion, Bodenrespiration, Nettoökosystemproduktion, durch Feuer und Ernte emittierter Kohlenstoff, sowie der in Biomasse und Boden gespeicherte Kohlenstoff. Verglichen mit dem Originalmodell haben sich durch die Einspeisung der Satellitendaten alle relevanten Kohlenstoffkomponenten verringert und zeigen nun bessere Übereinstimmung mit Literaturwerten. Die geringeren Kohlenstoffflüsse resultieren aus einer Kombination verschiedener Effekte: geringere Vegetationsbedeckung, Berücksichtigung der landwirtschaftlichen Nutzfläche, realistischere Abbildung der Saisonalität, Veränderung der Vegetationsverteilung und Verschiebung der Artenzusammensetzung. Die globalen Kohlenstoffflüsse werden mit dem vorgestellten Modell realistischer abgebildet als mit Ansätzen, die nur die potentiell natürliche Vegetation simulieren. Insbesondere die Quellen- und Senkendynamik unterliegt vielfältigen Prozessen, die mit einem Modell, dass auch die Bodenrespiration prozessorientiert berücksichtigt, verlässlich geschätzt wird. KW - Vegetationsmodell KW - Kohlenstoffmodell KW - DGVM KW - LPJ KW - Kohlenstoffhaushalt KW - vegetation model KW - carbon cycle KW - DGVM KW - LPJ KW - global change Y1 - 2007 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus-17596 ER - TY - GEN A1 - Fay, Doris A1 - Guillaume, Yves R. F. T1 - Team diversity N2 - Team diversity refers to the differences between team members on any attribute that may lead each single member of the group to perceive any other member of the group as being different from the self of this particular member. These attributes and perceptions refer to all dimensions people can differ on, such as age, gender, ethnicity, religious and functional background, personality, skills, abilities, beliefs, and attitudes. T3 - Zweitveröffentlichungen der Universität Potsdam : Humanwissenschaftliche Reihe - paper 029 KW - Diversity KW - Information Processing KW - Social Identity Theory KW - Team Composition KW - Team Development Y1 - 2007 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus-18295 ER - TY - GEN A1 - Frese, Michael A1 - Garst, Harry A1 - Fay, Doris T1 - Making things happen : reciprocal relationships between work characteristics and personal initiative in a four-wave longitudinal structural equation model N2 - The authors used the frameworks of reciprocal determinism and occupational socialization to study the effects of work characteristics (consisting of control and complexity of work) on personal initiative (PI)--mediated by control orientation (a 2nd-order factor consisting of control aspiration, perceived opportunity for control, and self-efficacy) and the reciprocal effects of PI on changes in work characteristics. They applied structural equation modeling to a longitudinal study with 4 measurement waves (N = 268) in a transitional economy: East Germany. Results confirm the model plus 1 additional, nonhypothesized effect. Work characteristics had a synchronous effect on PI via control orientation (full mediation). There were also effects of control orientation and of PI on later changes in work characteristics: As predicted, PI functioned as partial mediator, changing work characteristics in the long term (reciprocal effect); unexpectedly, there was a 2nd reciprocal effect of an additional lagged partial mediation of control orientation on later work characteristics. T3 - Zweitveröffentlichungen der Universität Potsdam : Humanwissenschaftliche Reihe - paper 028 KW - personal initiative KW - job characteristics KW - reciprocal relationship KW - transition economy KW - selfefficacy Y1 - 2007 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus-18278 ER - TY - CHAP A1 - Reimer, A. T1 - Clumping effects on non-thermal particle spectra in massive star systems N2 - Observational evidence exists that winds of massive stars are clumped. Many massive star systems are known as non-thermal particle production sites, as indicated by their synchrotron emission in the radio band. As a consequence they are also considered as candidate sites for non-thermal high-energy photon production up to gamma-ray energies. The present work considers the effects of wind clumpiness expected on the emitting relativistic particle spectrum in colliding wind systems, built up from the pool of thermal wind particles through diffusive particle acceleration, and taking into account inverse Compton and synchrotron losses. In comparison to a homogeneous wind, a clumpy wind causes flux variations of the emitting particle spectrum when the clump enters the wind collision region. It is found that the spectral features associated with this variability moves temporally from low to high energy bands with the time shift between any two spectral bands being dependent on clump size, filling factor, and the energy-dependence of particle energy gains and losses. Y1 - 2007 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus-18246 ER - TY - CHAP A1 - Weis, K. T1 - Wind relics : clumps, inhomogeneities and outflows in LBV nebulae N2 - The most massive stars are those with the shortest but most active life. One group of massive stars, the Luminous Blue Variables (LBVs), of which only a few objects are known, are in particular of interest concerning the stability of stars. They have a high mass loss rate and are close to being instable. This is even more likely as rotation becomes an important factor in stellar evolution of these stars. Through massive stellar winds and sometimes giant eruptions, LBV nebulae are formed. Various aspects in the evolution in the LBV phase lead, beside the large scale morphological and kinematical differences, to a diversity of small structures like clumps, rims, and outflows in these nebulae. Y1 - 2007 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus-18235 ER - TY - CHAP A1 - Romero, G. E. A1 - Owocki, S. P. A1 - Araudo, A. T. A1 - Townsend, R. H. D. A1 - Benaglia, P. T1 - Using gamma-rays to probe the clumped structure of stellar winds N2 - Gamma-rays can be produced by the interaction of a relativistic jet and the matter of the stellar wind in the subclass of massive X-ray binaries known as “microquasars”. The relativistic jet is ejected from the surroundings of the compact object and interacts with cold protons from the stellar wind, producing pions that then quickly decay into gamma-rays. Since the resulting gamma-ray emissivity depends on the target density, the detection of rapid variability in microquasars with GLAST and the new generation of Cherenkov imaging arrays could be used to probe the clumped structure of the stellar wind. In particular, we show here that the relative fluctuation in gamma rays may scale with the square root of the ratio of porosity length to binary separation, $\sqrt{h/a}$, implying for example a ca. 10% variation in gamma ray emission for a quite moderate porosity, h/a ∼ 0.01. Y1 - 2007 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus-18210 ER - TY - CHAP A1 - Nielsen, K. E. T1 - On irregular line profiles in the optical spectrum of Eta Carinae N2 - The optical spectrum of Eta Carinae (η Car) is prominent in H I, He i and Fe ii wind lines, all of which vary both in absorption and emission with phase. The phase dependance is a consequence of the interaction between the two objects in the η Car binary (η Car A & B). The binary system is enshrouded by ejecta from previous mass ejection events and consequently, η Car B is not directly observable. We have traced the He i lines over η Car’s spectroscopic period, using HST/STIS data obtained with medium spectral, but high angular, resolving power, and created a radial velocity curve for the system. The He I lines are formed in the core of the system, and appear to be a composite of multiple features formed in spatially separated regions. The sources of their irregular line profiles are still not fully understood, but can be attributed to emission/absorption near the wind-wind interface and/or a direct consequence of the η Car A’s, massive, clumpy wind. This paper will discuss the spectral variability, the narrow emission structure of the He i lines and how clumpiness of the winds may impede the construction of the reliable radial velocity curve, necessary for characterizations of especially η Car B. Y1 - 2007 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus-18227 ER - TY - CHAP A1 - Gull, T. R. T1 - Eta Carinae viewed from different vantages N2 - The spatially-resolved winds of the massive binary, Eta Carinae, extend an arcsecond on the sky, well beyond the 10 to 20 milliarcsecond binary orbital dimension. Stellar wind line profiles, observed at very different angular resolutions of VLTI/AMBER, HST/STIS and VLT/UVES, provide spatial information on the extended wind interaction structure as it changes with orbital phase. These same wind lines, observable in the starlight scattered off the foreground lobe of the dusty Homunculus, provide time-variant line profiles viewed from significantly different angles. Comparisons of direct and scattered wind profiles observed in the same epoch and at different orbital phases provide insight on the extended wind structure and promise the potential for three-dimensional imaging of the outer wind structures. Massive, long-lasting clumps, including the nebularWeigelt blobs, originated during the two historical ejection events. Wind interactions with these clumps are quite noticeable in spatially-resolved spectroscopy. As the 2009.0 minimum approaches, analysis of existing spectra and 3-D modeling are providing bases for key observations to gain further understanding of this complex massive binary. Y1 - 2007 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus-18200 ER - TY - CHAP A1 - Cassinelli, Joseph P. T1 - Discussion: Magnetic fields, variability Y1 - 2007 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus-18195 ER - TY - CHAP A1 - Reimer, O. A1 - Aharonian, Felix A. A1 - Hinton, J. A1 - Hofmann, W. A1 - Hoppe, S. A1 - Raue, M. A1 - Reimer, A. T1 - VHE gamma-rays from Westerlund 2 and implications for the inferred energetics N2 - The H.E.S.S. collaboration recently reported the discovery of VHE γ-ray emission coincident with the young stellar cluster Westerlund 2. This system is known to host a population of hot, massive stars, and, most particularly, the WR binary WR 20a. Particle acceleration to TeV energies in Westerlund 2 can be accomplished in several alternative scenarios, therefore we only discuss energetic constraints based on the total available kinetic energy in the system, the actual mass loss rates of respective cluster members, and implied gamma-ray production from processes such as inverse Compton scattering or neutral pion decay. From the inferred gammaray luminosity of the order of 1035erg/s, implications for the efficiency of converting available kinetic energy into non-thermal radiation associated with stellar winds in the Westerlund 2 cluster are discussed under consideration of either the presence or absence of wind clumping. Y1 - 2007 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus-18172 ER - TY - CHAP A1 - Kholtygin, A. F. T1 - Modelling the induced clumping stochastic line profile variability N2 - We model the line profile variability (lpv) in spectra of clumped stellar atmospheres using the Stochastic Clump Model (SCM) of the winds of early-type stars. In this model the formation of dense inhomogeneities (clumps) in the line driven winds is considered as being a stochastic process. It is supposed that the emission due to clumps mainly contributes to the intensities of emission lines in the stellar spectra. It is shown that in the framework of the SCM it is possible to reproduce both the mean line profiles and a common pattern of the lpv. Y1 - 2007 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus-18180 ER - TY - CHAP A1 - Chené, A.-N. A1 - Moffat, Anthony F. J. A1 - Crowther, P. A. T1 - Rapidly accelerating clumps in the winds of the very hot WNE Stars N2 - We study the time variability of emission lines in three WNE stars : WR 2 (WN2), WR 3 (WN3ha) and WR152 (WN3). While WR 2 shows no variability above the noise level, the other stars do show variation, which are like other WR stars in WR 152 but very fast in WR 3. From these motions, we deduce a value of β ∼1 for WR 3 that is like that seen in O stars and β ∼2–3 for WR 152, that is intermediate between other WR stars and WR 3. Y1 - 2007 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus-18163 ER - TY - CHAP A1 - St-Louis, N. T1 - Discussion: Binaries, colliding winds, LBVs and high energy radiation N2 - Clumping in hot-star winds : proceedings of an international workshop held in Potsdam, Germany, 18. - 22. June 2007 Y1 - 2007 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus-18155 ER - TY - CHAP A1 - Szeifert, T. T1 - Wind variabilities and asymmetries in Luminous Blue Variables N2 - Luminous Blue Variables show strong changes in their stellar wind on time scales of typically years to decades when they expand and contract radially at approximately constant luminosity. Micro-variability on shorter time scales and amplitudes can be observed superimposed to the larger scale radial changes. I will show long-term time series of high resolution spectra which we have collected in the past 20 years for many of the well known LBVs together with a few time series of weekly sampling (HR Car, R40, R71, R110, R127, S Dor) covering a time windows of up to a few months. Wind variability is seen on short and intermediate time scales with the line profiles changing from P Cygni to inverse P Cygni and double peeked profiles sometimes for the same star and spectral line. On longer time scales the ionisation levels for all chemical elements change drastically due to the strong change of the temperature on the stellar surface. While on the long term the characteristic radial changes may have impact on the over all mass loss rates, the variabilities and asymmetries on short and intermediate time scales may cause false estimates of the mass loss rates when confronting models with the observed line profiles Y1 - 2007 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus-18146 ER - TY - CHAP A1 - Morrison, N. D. A1 - Rother, R. A1 - Kurschat, N. T1 - Hα line profile variability in the B8Ia-type supergiant Rigel (β Ori) N2 - Hα observations of Rigel obtained on 184 nights during the past ten years with the 1-m telescope and ´echelle spectrograph of Ritter Observatory are surveyed. The line profiles were classified in terms of morphology. About 1/4 of them are of P Cygni type, about 15% inverse P Cygni, about 25% double-peaked, about 1/3 pure absorption, and a few are single emission lines. Transformation of the profile from one type to another typically takes a few days. Although the line stays in absorption for extended intervals, only one high-velocity absorption event of the intensity reported by Kaufer et al. (1996a) was observed, in late 2006. Late in this event, Hα absorption occurred farther to the red than the red wing of a plausible photospheric absorption component, an indication of infalling material. In general, as the absorption events come to an end, the emission typically returns with an inverse P Cygni profile. The Hα profile class shows no obvious correlation with the radial velocity of C II λ6578, a photospheric absorption line. Y1 - 2007 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus-18120 ER - TY - CHAP A1 - Cohen, David H. A1 - Leutenegger, M. A. A1 - Townsend, R. H. D. T1 - Quantitative analysis of resolved X-ray emission line profiles of O stars N2 - By quantitatively fitting simple emission line profile models that include both atomic opacity and porosity to the Chandra X-ray spectrum of ζ Pup, we are able to explore the trade-offs between reduced mass-loss rates and wind porosity. We find that reducing the mass-loss rate of ζ Pup by roughly a factor of four, to 1.5 × 10−6 M⊙ yr−1, enables simple non-porous wind models to provide good fits to the data. If, on the other hand, we take the literature mass-loss rate of 6×10−6 M⊙ yr−1, then to produce X-ray line profiles that fit the data, extreme porosity lengths – of h∞ ≈ 3 R∗ – are required. Moreover, these porous models do not provide better fits to the data than the non-porous, low optical depth models. Additionally, such huge porosity lengths do not seem realistic in light of 2-D numerical simulations of the wind instability. Y1 - 2007 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus-18115 ER - TY - CHAP A1 - Blomme, R. T1 - Corotating Interaction Regions and clumping N2 - We present hydrodynamical models for Corotating Interaction Regions, which were used by Lobel (2007) to model the Discrete Absorption Components in HD 64760. We also discuss our failure to model the rotational modulations seen in the same star. Y1 - 2007 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus-18100 ER - TY - CHAP A1 - Massa, D. L. A1 - Prinja, R. K. A1 - Fullerton, A. W. T1 - The effects of clumping on wind line variability N2 - We review the effects of clumping on the profiles of resonance doublets. By allowing the ratio of the doublet oscillator strenghts to be a free parameter, we demonstrate that doublet profiles contain more information than is normally utilized. In clumped (or porous) winds, this ratio can lies between unity and the ratio of the f-values, and can change as a function of velocity and time, depending on the fraction of the stellar disk that is covered by material moving at a particular velocity at a given moment. Using these insights, we present the results of SEI modeling of a sample of B supergiants, ζ Pup and a time series for a star whose terminal velocity is low enough to make the components of its Si VIλλ1400 independent. These results are interpreted within the framewrok of the Oskinova et al. (2007) model, and demonstrate how the doublet profiles can be used to extract infromation about wind structure. Y1 - 2007 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus-18095 ER - TY - CHAP A1 - Leutenegger, M. A. A1 - Cohen, David H. A1 - Kahn, S. M. A1 - Owocki, S. P. A1 - Paerels, F. B. S. T1 - Resonance scattering in the X-ray emission lines profiles of ζ Puppis N2 - We present XMM-Newton Reflection Grating Spectrometer observations of pairs of X-ray emission line profiles from the O star ζ Pup that originate from the same He-like ion. The two profiles in each pair have different shapes and cannot both be consistently fit by models assuming the same wind parameters. We show that the differences in profile shape can be accounted for in a model including the effects of resonance scattering, which affects the resonance line in the pair but not the intercombination line. This implies that resonance scattering is also important in single resonance lines, where its effect is difficult to distinguish from a low effective continuum optical depth in the wind. Thus, resonance scattering may help reconcile X-ray line profile shapes with literature mass-loss rates. Y1 - 2007 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus-18085 ER - TY - CHAP A1 - Schnerr, R. S. A1 - Henrichs, H. F. T1 - Magnetic fields and wind variability in massive stars N2 - This paper describes the thesis work of Schnerr (2007) entitled ”Magnetic fields and mass loss in massive stars“, which aimed at a better understanding of the impact of magnetic fields on the winds of massive stars. Y1 - 2007 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus-18075 ER - TY - CHAP A1 - Ignace, R. A1 - Gayley, K. G. T1 - Circumstellar Magnetic Field Diagnostics from Line Polarization Y1 - 2007 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus-18066 ER - TY - CHAP A1 - Cassinelli, Joseph P. A1 - Ignace, R. A1 - Waldron, W. A1 - Cho, J. A1 - Murphy, N. A1 - Lazarian, A. T1 - X-ray line emission produced in clump bow shocks N2 - We summarize Chandra observations of the emission line profiles from 17 OB stars. The lines tend to be broad and unshifted. The forbidden/intercombination line ratios arising from Helium-like ions provide radial distance information for the X-ray emission sources, while the H-like to He-like line ratios provide X-ray temperatures, and thus also source temperature versus radius distributions. OB stars usually show power law differential emission measure distributions versus temperature. In models of bow shocks, we find a power law differential emission measure, a wide range of ion stages, and the bow shock flow around the clumps provides transverse velocities comparable to HWHM values. We find that the bow shock results for the line profile properties, consistent with the observations of X-ray line emission for a broad range of OB star properties. Y1 - 2007 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus-18057 ER - TY - CHAP A1 - Vink, J. S. T1 - Discussion: Hydrodynamic modeling Y1 - 2007 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus-18046 ER - TY - CHAP A1 - Runacres, M. C. T1 - Hydrodynamical models of clumping beyond 50 R∗ N2 - We present one-dimensional, time-dependent models of the clumps generated by the linedeshadowing instability. In order to follow the clumps out to distances of more than 1000 R∗, we use an efficient moving-box technique. We show that, within the approximations, the wind can remain clumped well into the formation region of the radio continuum. Y1 - 2007 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus-18030 ER - TY - CHAP A1 - Walter, R. A1 - Zurita-Heras, J. A1 - Leyder, J.-C. T1 - Probing clumpy stellar winds with a neutron star N2 - INTEGRAL tripled the number of super-giant high-mass X-ray binaries (sgHMXB) known in the Galaxy by revealing absorbed and fast transient (SFXT) systems. Quantitative constraints on the wind clumping of massive stars can be obtained from the study of the hard X-ray variability of SFXT. A large fraction of the hard X-ray emission is emitted in the form of flares with a typical duration of 3 ksec, frequency of 7 days and luminosity of $10^{36}$ erg/s. Such flares are most probably emitted by the interaction of a compact object orbiting at $\sim10~R_*$ with wind clumps ($10^{22 ... 23}$ g) representing a large fraction of the stellar mass-loss rate. The density ratio between the clumps and the inter-clump medium is $10^{2 ... 4}$. The parameters of the clumps and of the inter-clump medium, derived from the SFXT flaring behavior, are in good agreement with macro-clumping scenario and line-driven instability simulations. SFXT are likely to have larger orbital radius than classical sgHMXB. Y1 - 2007 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus-18024 ER - TY - CHAP A1 - ud-Doula, A. T1 - Large-scale wind structure due to magnetic fields N2 - Magnetic fields influence the dynamics of hot-star winds and create large scale structure. Based on numerical magnetohydrodynamic (MHD) simulations, we model the wind of θ¹ Ori C, and then use the SEI method to compute synthetic line profiles for a range of viewing angles as function of rotational phase. The resulting dynamic spectrum for a moderately strong line shows a distinct modulation, but with a phase that seems at odds with available observations. Y1 - 2007 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus-18010 ER - TY - CHAP A1 - Puls, Joachim T1 - Discussion : X-rays N2 - Clumping in hot-star winds : proceedings of an international workshop held in Potsdam, Germany, 18. - 22. June 2007 Y1 - 2007 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus-18000 ER - TY - CHAP A1 - Owocki, S. P. T1 - Dynamical simulation of the “velocity-porosity” reduction in observed strength of stellar wind lines N2 - I use dynamical simulations of the line-driven instability to examine the potential role of the resulting flow structure in reducing the observed strength of wind absorption lines. Instead of the porosity length formalism used to model effects on continuum absorption, I suggest reductions in line strength can be better characterized in terms of a velocity clumping factor that is insensitive to spatial scales. Examples of dynamic spectra computed directly from instability simulations do exhibit a net reduction in absorption, but only at a modest 10-20% level that is well short of the ca. factor 10 required by recent analyses of PV lines. Y1 - 2007 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus-17992 ER - TY - CHAP A1 - Sonneborn, G. T1 - Imaging and spectroscopy with the James Webb Space Telescope N2 - The James Webb Space Telescope (JWST) is a large, infrared-optimized space telescope scheduled for launch in 2013. JWST will find the first stars and galaxies that formed in the early universe, connecting the Big Bang to our own Milky Way galaxy. JWST will peer through dusty clouds to see stars forming planetary systems, connecting the MilkyWay to our own Solar System. JWST’s instruments are designed to work primarily in the infrared range of 1 - 28 μm, with some capability in the visible range. JWST will have a large mirror, 6.5 m in diameter, and will be diffraction-limited at 2 μm (0.1 arcsec resolution). JWST will be placed in an L2 orbit about 1.5 million km from the Earth. The instruments will provide imaging, coronography, and multi-object and integral-field spectroscopy across the 1 - 28 μm wavelength range. The breakthrough capabilities of JWST will enable new studies of massive star winds from the Milky Way to the early universe. Y1 - 2007 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus-17983 ER - TY - CHAP A1 - Moffat, Anthony F. J. A1 - Hillier, D. J. A1 - Hamann, Wolf-Rainer A1 - Owocki, S. P. T1 - General Discussion N2 - Clumping in hot-star winds : proceedings of an international workshop held in Potsdam, Germany, 18. - 22. June 2007 Y1 - 2007 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus-17953 ER - TY - CHAP A1 - Krtička, Jiri A1 - Puls, Joachim A1 - Kubát, Jiří T1 - The influence of clumping on predicted O star wind parameters N2 - We study the influence of clumping on the predicted wind structure of O-type stars. For this purpose we artificially include clumping into our stationary wind models. When the clumps are assumed to be optically thin, the radiative line force increases compared to corresponding unclumped models, with a similar effect on either the mass-loss rate or the terminal velocity (depending on the onset of clumping). Optically thick clumps, alternatively, might be able to decrease the radiative force. Y1 - 2007 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus-17969 ER - TY - CHAP A1 - Vink, J. S. A1 - Benaglia, P. A1 - Davies, B. A1 - de Koter, A. A1 - Oudmaijer, R. D. T1 - Advances in mass-loss predictions N2 - We present the results of Monte Carlo mass-loss predictions for massive stars covering a wide range of stellar parameters. We critically test our predictions against a range of observed massloss rates – in light of the recent discussions on wind clumping. We also present a model to compute the clumping-induced polarimetric variability of hot stars and we compare this with observations of Luminous Blue Variables, for which polarimetric variability is larger than for O and Wolf-Rayet stars. Luminous Blue Variables comprise an ideal testbed for studies of wind clumping and wind geometry, as well as for wind strength calculations, and we propose they may be direct supernova progenitors. Y1 - 2007 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus-17948 ER - TY - CHAP A1 - Davies, B. A1 - Vink, J. S. A1 - Oudmaijer, R. D. T1 - Modelling the polarimetric variability of hot stars N2 - Many hot stars exhibit stochastic polarimetric variability, thought to arise from clumping low in the wind. Here we investigate the wind properties required to reproduce this variability using analytic models, with particular emphasis on Luminous Blue Variables. We find that the winds must be highly structured, consisting of a large number of optically-thin clumps; while we find that the overall level of polarization should scale with mass-loss rate – consistent with observations of LBVs. The models also predict variability on very short timescales, which is supported by the results of a recent polarimetric monitoring campaign. Y1 - 2007 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus-17939 ER - TY - CHAP A1 - Fullerton, A. W. T1 - Discussion: Spectral modeling Y1 - 2007 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus-17917 ER - TY - CHAP A1 - Hillier, D. J. T1 - On the influence of clumping on O and Wolf-Rayet spectra N2 - Overwhelming observational and theoretical evidence suggests that the winds of massive stars are highly clumped. We briefly discuss the influence of clumping on model diagnostics and the difficulties of allowing for the influence of clumping on model spectra. Because of its simplicity, and because of computational ease, most spectroscopic analyses incorporate clumping using the volume filling factor. The biases introduced by this approach are uncertain. To investigate alternative clumping models, and to help determine the validity of parameters derived using the volume filling factor method, we discuss results derived using an alternative model in which we assume that the wind is composed of optically thick shells. Y1 - 2007 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus-17903 ER - TY - CHAP A1 - Iping, R.C. A1 - Sonneborn, G. A1 - Massa, D.L. A1 - Gies, D. A1 - Williams, Simon E. T1 - Far-ultraviolet spectroscopy of O+O binaries in the Magellanic Clouds N2 - We report FUSE observations in 2005–2006 of three O-type, double-lined spectroscopic binaries in the Magellanic Clouds. The systems have very short periods (1.4–2.25 d), represent rare, young evolutionary stages of massive stars and binaries, and provide a unique glimpse at some of the most massive systems that form in dense clusters of massive stars. Improved orbit parameters, including revised masses, for LH54-425 are derived from new ctio spectroscopy. The systems are: LH54-425 in the LMC (O3V + O5V, P=2.25d, 62+37M⊙), J053441-693139 in the LMC (O2-3If+O6V, P=1.4 d, 41+27M⊙), and Hodge 53-47 in the SMC (O6V + O4-5IIIf, P=2.2 d, 24+14M⊙, where the O4 star appears to be less massive than the O6 star). Their short periods indicates that wind interaction and mass transfer are likely important factors in their evolution. The spectra provide quantitative and systematic studies of phase-dependent stellar wind properties, wind collision effects in O+O binaries at lower metallicities, improved radial velocity curves, and FUV spectro-photometric changes as a function of orbital phase. Y1 - 2007 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus-17896 ER - TY - CHAP A1 - Schnurr, O. A1 - Crowther, P. A. T1 - Mid-IR observations of WC stars, and the connection to wind clumping N2 - We present preliminary results of a tailored atmosphere analysis of six Galactic WC stars using UV, optical, and mid-infrared Spitzer IRS data. With these data, we are able to sample regions from 10 to 10³ stellar radii, thus to determine wind clumping in different parts of the wind. Ultimately, derived wind parameters will be used to accuratelymeasure neon abundances, and to so test predicted nuclear-reaction rates. Y1 - 2007 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus-17884 ER - TY - CHAP A1 - Townsend, R. H. D. T1 - Techniques for simulating radiative transfer through porous media N2 - In this contribution, I discuss some basic techniques that can be used to simulate radiative transfer through porous media. As specific examples, I consider scattering transfer through a clumped slab, and X-ray emission line formation in a clumped wind. Y1 - 2007 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus-17866 ER - TY - CHAP A1 - Kubát, Jiří A1 - Saad, S. M. T1 - Moving absorption bumps in the spectra of Be stars N2 - Several Be binaries exhibit an absorption bump moving across the blue wing of hydrogen emission lines towards the line center. This bump is demonstrated for the case of two bright Be stars, κ Dra and 4 Her. It is not clear what is the reason for this travelling bump. Y1 - 2007 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus-17879 ER - TY - CHAP A1 - Kusterer, D.-J. A1 - Nagel, T. A1 - Werner, K. A1 - Feldmeier, Achim T1 - Radiative transfer in CV disk winds N2 - Mass accretion onto compact objects through accretion disks is a common phenomenon in the universe. It is seen in all energy domains from active galactic nuclei through cataclysmic variables (CVs) to young stellar objects. Because CVs are fairly easy to observe, they provide an ideal opportunity to study accretion disks in great detail and thus help us to understand accretion also in other energy ranges. Mass accretion in these objects is often accompanied by mass outflow from the disks. This accretion disk wind, at least in CVs, is thought to be radiatively driven, similar to O star winds. WOMPAT, a 3-D Monte Carlo radiative transfer code for accretion disk winds of CVs is presented. Y1 - 2007 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus-17847 ER - TY - CHAP A1 - Lobel, A. T1 - Modeling DACs in UV lines of massive hot stars N2 - We apply the 3-dimensional radiative transport codeWind3D to 3D hydrodynamic models of Corotating Interaction Regions to fit the detailed variability of Discrete Absorption Components observed in Si iv UV resonance lines of HD 64760 (B0.5 Ib). We discuss important effects of the hydrodynamic input parameters on these large-scale equatorial wind structures that determine the detailed morphology of the DACs computed with 3D transfer. The best fit model reveals that the CIR in HD 64760 is produced by a source at the base of the wind that lags behind the stellar surface rotation. The non-corotating coherent wind structure is an extended density wave produced by a local increase of only 0.6% in the smooth symmetric wind mass-loss rate. Y1 - 2007 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus-17856 ER - TY - CHAP A1 - Liermann, A. A1 - Hamann, Wolf-Rainer T1 - Clumping in Galactic WN stars : a comparison of mass loss rates from UV/optical & radio diagnostics N2 - The mass loss rates and other parameters for a large sample of Galactic WN stars have been revised by Hamann et al. (2006), using the most up-to date Potsdam Wolf-Rayet (PoWR) model atmospheres. For a sub-sample of these stars exist measurements of their radio free-free emission. After harmonizing the adopted distance and terminal wind velocities, we compare the mass loss rates obtained from the two diagnostics. The differences are discussed as a possible consequence of different clumping contrast in the line-forming and radio-emitting regions. Y1 - 2007 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus-17816 ER - TY - CHAP A1 - Massa, D. L. T1 - Discussion: Spectroscopy and Mass-Loss Diagnostics Y1 - 2007 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus-17821 ER - TY - CHAP A1 - Urbaneja, M. A. A1 - Kudritzki, R.-P. A1 - Puls, Joachim T1 - Clumping in the winds of O-type CSPNs N2 - Recent studies of massive O-type stars present clear evidences of inhomogeneous and clumped winds. O-type (H-rich) central stars of planetary nebulae (CSPNs) are in some ways the low mass–low luminosity analogous of those massive stars. In this contribution, we present preliminary results of our on-going multi-wavelength (FUV, UV and optical) study of the winds of Galactic CSPNs. Particular emphasis will be given to the clumping factors derived by means of optical lines (Hα and Heii 4686) and “classic” FUV (and UV) lines. Y1 - 2007 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus-17801 ER - TY - CHAP A1 - Kholtygin, A. F. T1 - Wavelets for looking for clumping in the wind of OB stars N2 - Clumping in hot-star winds : proceedings of an international workshop held in Potsdam, Germany, 18. - 22. June 2007 Y1 - 2007 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus-17796 ER - TY - CHAP A1 - Prinja, R. K. A1 - Hodges, S. E. A1 - Massa, D. L. A1 - Fullerton, A. W. A1 - Burnley, A. W. T1 - Structure in the fast wind of NGC6543 N2 - We exploit time-series $FUSE$ spectroscopy to {\it uniquely} probe spatial structure and clumping in the fast wind of the central star of the H-rich planetary nebula NGC~6543 (HD~164963). Episodic and recurrent optical depth enhancements are discovered in the P{\sc v} absorption troughs, with some evidence for a $\sim$ 0.17-day modulation time-scale. The characteristics of these features are essentially identical to the discrete absorption components' (DACs) commonly seen in the UV lines of massive OB stars, suggesting the temporal structures seen in NGC~6543 likely have a physical origin that is similar to that operating in massive, luminous stars. The mechanism for forming coherent perturbations in the outflows is therefore apparently operating equally in the radiation-pressure-driven winds of widely differing momenta ($\mdot$$v_\infty$$R_\star^{0.5}$) and flow times, as represented by OB stars and CSPN. Y1 - 2007 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus-17788 ER - TY - CHAP A1 - Groh, J. H. A1 - Hillier, D. J. A1 - Damineli, A. T1 - Mass-loss rate and clumping in LBV stars : the impact of time-dependent effects N2 - This paper outlines a newly-developed method to include the effects of time variability in the radiative transfer code CMFGEN. It is shown that the flow timescale is often large compared to the variability timescale of LBVs. Thus, time-dependent effects significantly change the velocity law and density structure of the wind, affecting the derivation of the mass-loss rate, volume filling factor, wind terminal velocity, and luminosity. The results of this work are directly applicable to all active LBVs in the Galaxy and in the LMC, such as AG Car, HR Car, S Dor and R 127, and could result in a revision of stellar and wind parameters. The massloss rate evolution of AG Car during the last 20 years is presented, highlighting the need for time-dependent models to correctly interpret the evolution of LBVs. Y1 - 2007 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus-17773 ER - TY - CHAP A1 - Raassen, A. J. J. A1 - Hucht, K. A. van der A1 - Miller, N. A. A1 - Cassinelli, Joseph P. T1 - XMM-Newton observations of zeta Orionis (O9.7 Ib) : a collisional ionization equilibrium model N2 - We present the analysis of XMM-Newton observations of ζ Orionis. The analysis is based on fitting to the total spectrum as well as diagnostics of individual line. Y1 - 2007 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus-17747 ER - TY - CHAP A1 - Marchenko, S. V. T1 - Wind inhomogeneities in low-Z environment : observations N2 - We discuss the results of time-resolved spectroscopy of three presumably single Population I Wolf-Rayet stars in the Small Magellanic Cloud, where the ambient metallicity is $\sim 1/5 Z_\odot$. We were able to detect and follow numerous small-scale wind-embedded inhomogeneities in all observed stars. The general properties of the moving features, such as their velocity dispersions, emissivities and average accelerations, closely match the corresponding characteristics of small-scale inhomogeneities in the winds of Galactic Wolf-Rayet stars. Y1 - 2007 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus-17769 ER - TY - CHAP A1 - Kraus, M. A1 - Kubát, Jiří A1 - Krtička, Jiri T1 - Wind emission of OB supergiants and the influence of clumping N2 - The influence of the wind to the total continuum of OB supergiants is discussed. For wind velocity distributions with β > 1.0, the wind can have strong influence to the total continuum emission, even at optical wavelengths. Comparing the continuum emission of clumped and unclumped winds, especially for stars with high β values, delivers flux differences of up to 30% with maximum in the near-IR. Continuum observations at these wavelengths are therefore an ideal tool to discriminate between clumped and unclumped winds of OB supergiants. Y1 - 2007 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus-17757 ER - TY - CHAP A1 - Reyes-Iturbide, J. A1 - Velázquez, P. A1 - Rosado, M. T1 - 3D numerical model for an asymmetrical superbubble N2 - Massive stars usually form groups such as OB associations. Their fast stellar winds sweep up collectively the surrounding insterstellar medium (ISM) to generate superbubbles. Observations suggest that superbubble evolution on the surrounding ISM can be very irregular. Numerical simulations considering these conditions could help to understand the evolution of these superbubbles and to clarify the dynamics of these objects as well as the difference between observed X-ray luminosities and the predicted ones by the standard model (Weaver et al. 1977). Y1 - 2007 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus-17724 ER - TY - CHAP A1 - de Koter, A. A1 - Vink, J. S. A1 - Muijres, L. T1 - Constraints on wind clumping from the empirical mass-loss vs. metallicity relation for early-type stars N2 - We present the latest results on the observational dependence of the mass-loss rate in stellar winds of O and early-B stars on the metal content of their atmospheres, and compare these with predictions. Absolute empirical rates for the mass loss of stars brighter than 10$^{5.2} L_{\odot}$, based on H$\alpha$ and ultraviolet (UV) wind lines, are found to be about a factor of two higher than predictions. If this difference is attributed to inhomogeneities in the wind this would imply that luminous O and early-B stars have clumping factors in their H$\alpha$ and UV line forming regime of about a factor of 3--5. The investigated stars cover a metallicity range $Z$ from 0.2 to 1 $Z_{\odot}$. We find a hint towards smaller clumping factors for lower $Z$. The derived clumping factors, however, presuppose that clumping does not impact the predictions of the mass-loss rate. We discuss this assumption and explain how we intend to investigate its validity in more detail. Y1 - 2007 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus-17736 ER - TY - CHAP A1 - Najarro, F. A1 - Puls, Joachim A1 - Herrero, A. A1 - Hanson, M. M. A1 - Martín-Pintado, J. A1 - Hillier, D. J. T1 - Tracking the Clumping in OB Stars from UV to radio N2 - We review different line and continua diagnostics from the UV to radio, which can be utilized to simultaneously constrain the clumping structure throughout the stellar wind of massive OB stars. Y1 - 2007 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus-17701 ER - TY - CHAP A1 - St-Louis, N. A1 - Moffat, Anthony F. J. T1 - Do clumping corrections increase with decreasing mass-loss rates? N2 - We report on new mass-loss rate estimates for O stars in six massive binaries using the amplitude of orbital-phase dependent, linear-polarimetric variability caused by electron scattering off free electrons in the winds. Our estimated mass-loss rates for luminous O stars are independent of clumping. They suggest similar clumping corrections as for WR stars and do not support the recently proposed reduction in mass-loss rates of O stars by one or two orders of magnitude. Y1 - 2007 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus-17696 ER - TY - CHAP A1 - Votruba, V. A1 - Feldmeier, Achim A1 - Kubát, Jiří A1 - Rätzel, D. T1 - Multicomponent stellar wind of hot stars N2 - We developed a time-dependent multicomponent hydrodynamical code for simulation of the stellar wind from hot stars and applied it to stars with high and low density winds. Y1 - 2007 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus-17677 ER - TY - CHAP A1 - Puls, Joachim A1 - Markova, N. A1 - Najarro, F. A1 - Hanson, M. M. T1 - Clumping in O-star winds N2 - We review various diagnostics of clumping in O-star winds, with special emphasis on its radial stratification. Implications and problems are discussed, and promising NIR methods are presented. Y1 - 2007 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus-17683 ER - TY - CHAP A1 - Bouret, J.-C. A1 - Lanz, T. A1 - Hillier, D. J. A1 - Foellmi, C. T1 - Clumping in O-type Supergiants N2 - We have analyzed the spectra of seven Galactic O4 supergiants, with the NLTE wind code CMFGEN. For all stars, we have found that clumped wind models match well lines from different species spanning a wavelength range from FUV to optical, and remain consistent with Hα data. We have achieved an excellent match of the P V λλ1118, 1128 resonance doublet and N IV λ1718, as well as He II λ4686 suggesting that our physical description of clumping is adequate. We find very small volume filling factors and that clumping starts deep in the wind, near the sonic point. The most crucial consequence of our analysis is that the mass loss rates of O stars need to be revised downward significantly, by a factor of 3 and more compared to those obtained from smooth-wind models. Y1 - 2007 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus-17662 ER - TY - CHAP A1 - Smith, Nathan T1 - Independent signs of lower mass-loss rates for O-type stars N2 - I discuss observational evidence – independent of the direct spectral diagnostics of stellar winds themselves – suggesting that mass-loss rates for O stars need to be revised downward by roughly a factor of three or more, in line with recent observed mass-loss rates for clumped winds. These independent constraints include the large observed mass-loss rates in LBV eruptions, the large masses of evolved massive stars like LBVs and WNH stars, WR stars in lower metallicity environments, observed rotation rates of massive stars at different metallicity, supernovae that seem to defy expectations of high mass-loss rates in stellar evolution, and other clues. I pay particular attention to the role of feedback that would result from higher mass-loss rates, driving the star to the Eddington limit too soon, and therefore making higher rates appear highly implausible. Some of these arguments by themselves may have more than one interpretation, but together they paint a consistent picture that steady line-driven winds of O-type stars have lower mass-loss rates and are significantly clumped. Y1 - 2007 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus-17659 ER - TY - CHAP A1 - Fullerton, A. W. A1 - Massa, D. L. A1 - Prinja, R. K. T1 - Revised mass-loss rates for O stars from the Pv resonance line N2 - The P v λλ1118, 1128 resonance doublet is an extraordinarily useful diagnostic of O-star winds, because it bypasses the traditional problems associated with determining mass-loss rates from UV resonance lines. We discuss critically the assumptions and uncertainties involved with using P v to diagnose mass-loss rates, and conclude that the large discrepancies between massloss rates determined from P v and the rates determined from “density squared” emission processes pose a significant challenge to the “standard model” of hot-star winds. The disparate measurements can be reconciled if the winds of O-type stars are strongly clumped on small spatial scales, which in turn implies that mass-loss rates based on Hα or radio emission are too large by up to an order of magnitude. Y1 - 2007 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus-17647 ER - TY - CHAP A1 - Moffat, Anthony F. J. T1 - Observational overview of clumping in hot stellar winds N2 - In the old days (pre ∼1990) hot stellar winds were assumed to be smooth, which made life fairly easy and bothered no one. Then after suspicious behaviour had been revealed, e.g. stochastic temporal variability in broadband polarimetry of single hot stars, it took the emerging CCD technology developed in the preceding decades (∼1970-80’s) to reveal that these winds were far from smooth. It was mainly high-S/N, time-dependent spectroscopy of strong optical recombination emission lines in WR, and also a few OB and other stars with strong hot winds, that indicated all hot stellar winds likely to be pervaded by thousands of multiscale (compressible supersonic turbulent?) structures, whose driver is probably some kind of radiative instability. Quantitative estimates of clumping-independent mass-loss rates came from various fronts, mainly dependent directly on density (e.g. electron-scattering wings of emission lines, UV spectroscopy of weak resonance lines, and binary-star properties including orbital-period changes, electron-scattering, and X-ray fluxes from colliding winds) rather than the more common, easier-to-obtain but clumping-dependent density-squared diagnostics (e.g. free-free emission in the IR/radio and recombination lines, of which the favourite has always been Hα). Many big questions still remain, such as: What do the clumps really look like? Do clumping properties change as one recedes from the mother star? Is clumping universal? Does the relative clumping correction depend on $\dot{M}$ itself? Y1 - 2007 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus-17633 ER - TY - CHAP A1 - Hirschi, Raphael T1 - The impact of reduced mass loss rates on the evolution of massive stars N2 - Mass loss is a very important aspect of the life of massive stars. After briefly reviewing its importance, we discuss the impact of the recently proposed downward revision of mass loss rates due to clumping (difficulty to form Wolf-Rayet stars and production of critically rotating stars). Although a small reduction might be allowed, large reduction factors around ten are disfavoured. We then discuss the possibility of significant mass loss at very low metallicity due to stars reaching break-up velocities and especially due to the metal enrichment of the surface of the star via rotational and convective mixing. This significant mass loss may help the first very massive stars avoid the fate of pair-creation supernova, the chemical signature of which is not observed in extremely metal poor stars. The chemical composition of the very low metallicity winds is very similar to that of the most metal poor star known to date, HE1327-2326 and offer an interesting explanation for the origin of the metals in this star. We also discuss the importance of mass loss in the context of long and soft gamma-ray bursts and pair-creation supernovae. Finally, we would like to stress that mass loss in cooler parts of the HR-diagram (luminous blue variable and yellow and red supergiant stages) are much more uncertain than in the hot part. More work needs to be done in these areas to better constrain the evolution of the most massive stars. Y1 - 2007 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus-17616 ER - TY - CHAP ED - Hamann, Wolf-Rainer ED - Feldmeier, Achim ED - Oskinova, Lida T1 - Clumping in hot-star winds : proceedings of an international workshop held in Potsdam, Germany, 18. - 22. June 2007 N2 - Stellar winds play an important role for the evolution of massive stars and their cosmic environment. Multiple lines of evidence, coming from spectroscopy, polarimetry, variability, stellar ejecta, and hydrodynamic modeling, suggest that stellar winds are non-stationary and inhomogeneous. This is referred to as 'wind clumping'. The urgent need to understand this phenomenon is boosted by its far-reaching implications. Most importantly, all techniques to derive empirical mass-loss rates are more or less corrupted by wind clumping. Consequently, mass-loss rates are extremely uncertain. Within their range of uncertainty, completely different scenarios for the evolution of massive stars are obtained. Settling these questions for Galactic OB, LBV and Wolf-Rayet stars is prerequisite to understanding stellar clusters and galaxies, or predicting the properties of first-generation stars. In order to develop a consistent picture and understanding of clumped stellar winds, an international workshop on 'Clumping in Hot Star Winds' was held in Potsdam, Germany, from 18. - 22. June 2007. About 60 participants, comprising almost all leading experts in the field, gathered for one week of extensive exchange and discussion. The Scientific Organizing Committee (SOC) included John Brown (Glasgow), Joseph Cassinelli (Madison), Paul Crowther (Sheffield), Alex Fullerton (Baltimore), Wolf-Rainer Hamann (Potsdam, chair), Anthony Moffat (Montreal), Stan Owocki (Newark), and Joachim Puls (Munich). These proceedings contain the invited and contributed talks presented at the workshop, and document the extensive discussions. KW - Sternwinde KW - Massenverlust KW - Strahlungstransport KW - hydrodynamische Modellierung KW - massereiche Sterne KW - stellar winds KW - mass loss KW - radiative transfer KW - hydrodynamic modeling KW - massive stars Y1 - 2007 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus-13981 SN - 978-3-940793-33-1 PB - Universitätsverlag Potsdam CY - Potsdam ER - TY - GEN A1 - Imkeller, Peter A1 - Roelly, Sylvie T1 - Die Wiederentdeckung eines Mathematikers: Wolfgang Döblin N2 - "Considerons une particule mobile se mouvant aleatoirement sur la droite (ou sur un segment de droite). Supposons qu'il existe une probabilite F(x,y;s,t) bien definie pour que la particule se trouvant a l'instant s dans la position x se trouve a l'instant t (> s) a gauche de y, probabilite independante du mouvement anterieur de la particule...." Mit diesen Worten beginnt eines der berühmtesten mathematischen Manuskripte des letzten Jahrhunderts. Es stammt vom Soldaten Wolfgang Döblin, Sohn des deutschen Schriftstellers Alfred Döblin, und trägt den Titel "Sur l'equation de Kolmogoroff". Seine Veröffentlichung verbindet sich mit einer unglaublichen Geschichte. Wolfgang Döblin, stationiert mit seiner Einheit in den Ardennen im Winter 1939/1940, arbeitete an diesem Manuskript. Er entschloss sich, es als versiegeltes Manuskript an die Academie des Sciences in Paris zu schicken. Aber er kehrte nie aus diesem Krieg zurück. Sein Manuskript blieb 60 Jahre unter Verschluss im Archiv, und wurde erst im Jahre 2000 geöffnet. Wie weit Döblin damit seiner Zeit voraus war, wurde erkannt, nachdem es von Bernard Bru und Marc Yor ausgewertet worden war. Im ersten Satz umschreibt W. Döblin gleichzeitig das Programm des Manuskripts: "Wir betrachten ein bewegliches Teilchen, das sich zufällig auf der Geraden (oder einem Teil davon) bewegt." Er widmet sich damit der Aufgabe, die Fundamente eines Gebiets zu legen, das wir heute als stochastische Analysis bezeichnen. T3 - Zweitveröffentlichungen der Universität Potsdam : Mathematisch-Naturwissenschaftliche Reihe - paper 035 KW - Kolmogorov-Gleichung KW - Stochastische Analysis KW - Döblin KW - Wolfgang KW - Doblin KW - Vincent KW - Doeblin KW - Wolfgang Y1 - 2007 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus-16397 ER - TY - THES A1 - Köchert, Karl T1 - Development of a method to assess EAAT1 transcription levels in Alzheimer's disease N2 - Zur Zeit leiden ca. 24 Millionen Menschen auf der ganzen Welt unter Demenz, Alzheimer macht dabei 50-60% aller Demenzfälle aus. Da der Anteil der Bevölkerung, der an Demenz leidet, proportional zum Alter zunimmt und der Anteil älterer Menschen in der Gesellschaft von Jahr zu Jahr steigt, wird Alzheimer immer mehr zu einem ernstzunehmenden, gesellschaftlichen Problem. Zum Stand der heutigen Forschung ist es etabliert, dass die Aminosäure Glutamat - quantitativ einer der wichtigsten Neurotransmitter im Zentralen Nervensystem (ZNS) - toxische Konzentrationen erreichen kann wenn sie - im Zuge der Übertragung von Aktionspotentialen - nach ihrer Freisetzung nicht aus dem Synaptischen Spalt entfernt wird. Viele Studien haben gezeigt, dass in der Alzheimerschen Krankheit die Glutamataufnahme beeinträchtigt ist, was zu toxischen Konzentrationen von Glutamat und dem daraus folgenden Absterben von Neuronen führt. Der exitatorische Aminosäuretransporter 1 (EAAT1) gehört zu der Familie der Na+-abhängigen Glutamattransporter und stellt nach EAAT2 den quantitativ wichtigsten Glutamattransporter im ZNS dar. In diesem Projekt wurde eine bis dahin für den Menschen nicht bekannte EAAT1 Spleißvariante, in der Exon 3 ausgeschnitten wird, nachgewiesen. Diese Variante wurde EAAT1Δ3 genannt und stellt damit mit EAAT1Δ9 die zweite für EAAT1 nachgewiesene Spleißvariante dar. Eine auf real-time RT-PCR basierende Methode wurde entwickelt, um die Transkripte von EAAT1 wildtyp (EAAT1 wt), EAAT1Δ3 und EAAT1Δ9 zu quantifizieren. Proben aus verschiedenen Hirnarealen wurden aus einem Set von Kontrollen und Alzheimerfällen bei der Quantifizierung verwendet. Die gewählten Areale sind von der Alzheimerschen Krankheit unterschiedlich stark betroffen. Dies diente als interne Kontrolle für die durchgeführten Experimente und ermöglichte so die Differenzierung zwischen beobachteten Effekten: Nur Effekte die alleinig in von Alzheimer betroffenen Gehirnarealen auftreten, können als spezifisch für die Krankheit angesehen werden. Die Resultate diese Projektes zeigen, dass EAAT1Δ3 in sehr geringer Anzahl transkribiert wird, die nur 0.15% der EAAT1 wt Transkription entspricht. Dahingegen entspricht das EAAT1 Δ9 Transkript im Durchschnitt 26.6% des EAAT1 wt Transkripts. Es wurde nachgewiesen, dass die Transkriptionsrate aller EAAT1 Varianten in Alzheimerfällen signifikant reduziert ist (P<0.0001). Dies unterstützt die Theorie, dass bei Alzheimerfällen die EAAT1 Proteinexpression stark reduziert und der Glutamattransport, der normalerweise durch diesen Transporter gewährleistet wird, stark eingeschränkt ist. Dies wiederum resultiert in toxisch hohen Glutamatkonzentrationen und damit dem Absterben von Neuronen. Die gefundene Reduktion der EAAT1Transkription ist nicht spezifisch für Gehirnareale die von Alzheimer betroffen sind, sondern tritt in selbem Maße in nicht von Alzheimer betroffenen Gehirnarealen auf. Daraus lässt sich schließen, dass die Reduktion der EAAT1 Transkription eher ein Resultat eines in der Alzheimerschen Krankheit präsenten, grundlegenden Krankheitsmechanismus ist als deren Ursache. N2 - Today about 24 Million people worldwide suffer from dementia, Alzheimer’s Disease accounts for approximately 50-60% of all dementia cases. As the prevalence of dementia grows with increasing age Alzheimer’s Disease becomes more and more of an issue for society as the proportion of elderly people increases from year to year. It is well established, that the amino acid glutamate - quantitatively being the most important neurotransmitter in the central nervous system (CNS) - may reach toxic concentrations if not cleared from the synaptic cleft into which it is released during transmittance of action potentials. In Alzheimer’s Disease there is strong evidence for a generally impaired glutamate uptake system which in turn is thought to result in toxic levels of the amino acid with the potential to kill off neurons. The excitatory amino acid transporter 1 (EAAT1) belongs to the family of Na+-dependent glutamate transporter and accounts together with EAAT2 for most of the glutamate uptake in the CNS. In this project a new splice variant of EAAT1, skipping exon 3 was detected in human brain samples and subsequently called EAAT1Δ3, this being the second splice variant found after the recent detection of EAAT1Δ9. A method was developed to quantify the transcript of EAAT1 wt, EAAT1Δ3 and EAAT1Δ9 by means of real-time PCR. Samples were taken from different brain areas of a set of control and AD cases. The areas chosen for examination are affected differently in Alzheimer’s Disease, this was used an internal control for the experiments done in this project as to determine whether any effect observed is specific for AD, i.e. AD affected areas or is generally seen in all areas examined. The results of this project show that EAAT1Δ3 is transcribed in very low copy numbers making up a proportion of 0.15% of EAAT1 wt whereas EAAT1Δ9 is transcribed in a considerably large proportion of EAAT1 wt of 26.6%. It was moreover found that all EAAT1 variants are transcribed at significantly lower rates (P<0.0001) in AD cases, supporting the theory that EAAT1 protein expression is reduced to a point where glutamate uptake normally mediated by this transporter is impaired. This in turn is thought to result in toxic levels glutamate accounting for neuronal loss in the disease. No area-dependent effects were found, suggesting that the reduction of EAAT1 transcription is rather a result of an underlying general mechanism present in AD. Further research will have to be done to assess the degree of EAAT1 expression in AD and whether those future findings match with the result of this project. KW - Morbus Alzheimer KW - Glutamat KW - EAAT1 KW - Spleißvariante KW - Alzheimer's Disease KW - Glutamate KW - EAAT1 KW - Splice Variant Y1 - 2007 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus-15965 ER - TY - THES A1 - Weber, Jens T1 - Meso- und mikroporöse Hochleistungspolymere : Synthese, Analytik und Anwendungen T1 - Meso- and microporous high performance polymers : synthesis, characterisation and application N2 - Die Arbeit beschreibt die Synthese, Charakterisierung und Anwendung von meso- und mikroporösen Hochleistungspolymeren. Im ersten Teil wird die Synthese von mesoporösen Polybenzimidazol (PBI) auf der Basis einer Templatierungsmethode vorgestellt. Auf der Grundlage kommerzieller Monomere und Silikatnanopartikel sowie eines neuen Vernetzers wurde ein Polymer-Silikat-Hybridmaterial aufgebaut. Das Herauslösen des Silikats mit Ammoniumhydrogendifluorid führt zu mesoporösen Polybenzimidazolen mit spherischen Poren von 9 bis 11 nm Durchmesser. Die Abhängigkeit der beobachteten Porosität vom Massenverhältnis Silikat zu Polymer wurde ebenso untersucht wie die Abhängigkeit der Porosität vom Vernetzergehalt. Die Porosität vollvernetzter Proben zeigt eine lineare Abhängigkeit vom Verhältnis Silikat zu Polymer bis zu einem Grenzwert von 1. Wird der Grenzwert überschritten, ist teilweiser Porenkollaps zu beobachten. Die Abhängigkeit der Porosität vom Vernetzergehalt bei festem Silikatgehalt ist nichtlinear. Oberhalb einer kritischen Vernetzerkonzentration wird eine komplette Replikation der Nanopartikel gefunden. Ist die Vernetzerkonzentration dagegen kleiner als der kritische Wert, so ist der völlige Kollaps einiger Poren bei Stabilität der verbleibenden Poren zu beobachten. Ein komplett unporöses PBI resultiert bei Abwesenheit des Vernetzers. Die mesoporösen PBI-Netzwerke konnten kontrolliert mit Phosphorsäure beladen werden. Die erhaltenen Addukte wurden auf ihre Protonenleitfähigkeit untersucht. Es kann gezeigt werden, dass die Nutzung der vordefinierten Morphologie im Vergleich zu einem unstrukturierten PBI in höheren Leitfähigkeiten resultiert. Durch die vernetzte Struktur war des Weiteren genügend mechanische Stabilität gegeben, um die Addukte reversibel und bei sehr guten Leitfähigkeiten bis zu Temperaturen von 190°C bei 0% relativer Feuchtigkeit zu untersuchen. Dies ist für unstrukturierte Phosphorsäure/PBI - Addukte aus linearem PBI nicht möglich. Im zweiten Teil der Arbeit wird die Synthese intrinsisch mikroporöser Polyamide und Polyimide vorgestellt. Das Konzept intrinsisch mikroporöser Polymere konnte damit auf weitere Polymerklassen ausgeweitet werden. Als zentrales, strukturinduzierendes Motiv wurde 9,9'-Spirobifluoren gewählt. Dieses Molekül ist leicht und vielfältig zu di- bzw. tetrafunktionellen Monomeren modifizierbar. Dabei wurden bestehende Synthesevorschriften modifiziert bzw. neue Vorschriften entwickelt. Ein erster Schwerpunkt innerhalb des Kapitels lag in der Synthese und Charakterisierung von löslichen, intrinsisch mikroporösen, aromatischen Polyamid und Polyimid. Es konnte gezeigt werden, dass das Beobachten von Mikroporosität stark von der molekularen Architektur und der Verarbeitung der Polymere abhängig ist. Die Charakterisierung der Porosität erfolgte unter Nutzung von Stickstoffsorption, Kleinwinkelröntgenstreuung und Molecular Modeling. Es konnte gezeigt werden, dass die Proben stark vom Umgebungsdruck abhängigen Deformationen unterliegen. Die starke Quellung der Proben während des Sorptionsvorgangs konnte durch Anwendung des "dual sorption" Modells, also dem Auftreten von Porenfüllung und dadurch induzierter Henry-Sorption, erklärt werden. Der zweite Schwerpunkt des Kapitels beschreibt die Synthese und Charakterisierung mikroporöser Polyamid- und Polyimidnetzwerke. Während Polyimidnetzwerke auf Spirobifluorenbasis ausgeprägte Mikroporosität und spezifische Oberflächen von ca. 1100 m²/g aufwiesen, war die Situation für entsprechende Polyamidnetzwerke abweichend. Mittels Stickstoffsorption konnte keine Mikroporosität nachgewiesen werden, jedoch konnte mittels SAXS eine innere Grenzfläche von ca. 300 m²/g nachgewiesen werden. Durch die in dieser Arbeit gezeigten Experimente kann die Grenze zwischen Polymeren mit hohem freien Volumen und mikroporösen Polymeren somit etwas genauer gezogen werden. ausgeprägte Mikroporosität kann nur in extrem steifen Strukturen nachgewiesen werden. Die Kombination der Konzepte "Mesoporosität durch Templatierung" und "Mikroporosität durch strukturierte Monomere" hatte ein hierarchisch strukturiertes Polybenzimidazol zum Ergebnis. Die Präsenz einer Strukturierung im molekularen Maßstab konnte SAXS bewiesen werden. Das so strukturierte Polybenzimidazol zeichnete sich durch eine höhere Protonenleitfähigkeit im Vergleich zu einem rein mesoporösen PBI aus. Der letzte Teil der Arbeit beschäftigte sich mit der Entwicklung einer neuen Synthesemethode zur Herstellung von Polybenzimidazol. Es konnte gezeigt werden, dass lineares PBI in einer eutektischen Salzschmelze aus Lithium- und Kaliumchlorid synthetisiert werden kann. Die Umsetzung der spirobifluorenbasierten Monomere zu löslichem oder vernetztem PBI ist in der Salzschmelze möglich. N2 - The first part of the thesis describes the synthesis and characterisation of cross linked, mesoporous poly(benzimidazole) (PBI) prepared by a hard templating approach. Silica nanoparticles were used as template and removed after the polycondensation by immersing the hybrid material in aqueous NH4HF2 solution. The resulting mesoporous PBI showed surface areas up to 200 m²/g as established by N2 BET and porosities up to 37 vol.-%. The influence of the template and cross linker content on the observable porosity was investigated. Nitrogen sorption and small angle x-ray scattering (SAXS) were employed as analytical techniques. The template morphology was reproduced almost perfectly, yielding spherical pores of 11 nm in diameter if the samples were fully cross linked. It was shown that there is a linear dependence of the porosity on the template content up to a critical weight ratio of silica/polymer. If the silica content is raised above 50 wt.-% partial collapse of pores is observed. The dependence of the porosity on the cross linker content at constant amount of template was found to be non-linear. At the absence of any cross linker, no porosity was observed after template removal. At 10 mol-% cross linker the onset of porosity could be observed. At higher cross linker contents, the porosity was nearly the same as for the fully cross linked PBI. The mesoporous PBI could be loaded with crystalline phosphoric acid to yield highly proton conductive materials. It was shown that the material retains its nanostructure when loaded with phosphoric acid even after annealing at 180_C for 12 h. The conductivity of the nanostructured samples was one to two orders of magnitude higher than the conductivity of a nonstructured sample. The impact of the cross linking density on the conductivity was also investigated. The second part of the work describes the synthesis and characterisation of microporous poly(amide)s and poly(imide)s. 9,9'-spirobifluorene derivatives were used to introduce a rigid, structure-directing motif which prevents the polymer chains from close packing. Firstly, the synthesis of soluble poly(amide)s and poly(imide) is described. It was observed that the microporosity is strongly dependent on the processing of the soluble polymers. In the case when polymers were precipitated from solvents of high polarity no microporosity was observed, while polymers prone to solvation in solvents of lower polarity exhibited microporosity as observed in nitrogen sorption measurements. Wide angle x-ray scattering (WAXS) showed that the microstructure was indeed dependent on the processing conditions. SAXS measurements of the polymers revealed that nitrogen sorption alone is not sufficient for the analysis of the porosity. A significant mismatch between the results obtained by the two methods indicated that only a fraction of the pore volume of the polymers was accessible for nitrogen molecules. The second part of the chapter describes the synthesis, characterisation and application of spirobifluorene based, cross linked poly(amide)s and poly(imide)s. The poly(amide) networks did not show any microporosity when analysed by nitrogen sorption. This led to the conclusion that the amide bond is too weak to withstand the interfacial forces. In contrast, poly(imide) networks exhibited pronounced microporosity with surface areas of around 1000 m2/g. The analysis of these networks was again done by nitrogen sorption and SAXS. Furthermore, molecular modelling was used to calculate the true and apparent densities of the networks. In case of the poly(imide) networks, the results of the various measurement techniques were in reasonable agreement. This indicates that the pore volume was nearly completely accessible. Finally it was established that the structure directing motif is necessary to obtain microporous polymers, as a poly(imide) prepared from a spatially undefined monomer did not feature microporosity. Pressure dependent SAXS measurements showed that the polymer networks undergo significant elastic deformations upon evacuation. This behavior complicates the analysis of the nitrogen sorption data, making it impossible to extract reliable pore size distributions. The third and last part of the thesis deals with the development of a new reaction medium for the synthesis of poly(benzimidazole). An eutectic salt melt, composed of lithium chloride and potassium chloride was used in an ionothermal synthesis of linear PBI, opening a green chemistry route towards PBI. The influence of the reaction conditions on the properties of the resulting polymers was investigated. The new reaction medium allowed furthermore the synthesis of linear and cross linked spirobifluorene based PBIs. This is not easily possible by using the classical synthetic pathways towards PBI. The spirobifluorene based PBIs synthesized in this work did, however not feature intrinsic microporosity. KW - poröse Polymere KW - Röntgenkleinwinkelstreuung KW - Gassorption KW - Protonenleitfähigkeit KW - porous polymers KW - small-angle x-ray scattering KW - gas sorption KW - proton conductivity Y1 - 2007 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus-15994 ER - TY - JOUR A1 - Levinger, Israel Meir T1 - Schechita und Kaschrut BT - Jüdischer Standpunkt zum Schlachten von Tieren JF - PaRDeS : Zeitschrift der Vereinigung für Jüdische Studien e.V. N2 - Inhalt: 1. Die Gesetze der Torah bezüglich verbotener Speisen 2. Die zum Genuss erlaubten Tiere 2.1. Säugetiere 2.2. Vögel 2.3. Fische 2.4. Insekten 3. Das Schächten 4. Gründe für das Schächten in der jüdischen Literatur 5. Trefot – religiöse Fleischbeschau 6. Das Porschen 7. Das Salzen Y1 - 2007 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus-16021 SN - 1614-6492 SN - 1862-7684 VL - 13 SP - 62 EP - 86 ER - TY - THES A1 - Wagner, Dirk T1 - Microbial perspectives of the methane cycle in permafrost ecosystems in the Eastern Siberian Arctic : implications for the global methane budget N2 - The Arctic plays a key role in Earth’s climate system as global warming is predicted to be most pronounced at high latitudes and because one third of the global carbon pool is stored in ecosystems of the northern latitudes. In order to improve our understanding of the present and future carbon dynamics in climate sensitive permafrost ecosystems, the present study concentrates on investigations of microbial controls of methane fluxes, on the activity and structure of the involved microbial communities, and on their response to changing environmental conditions. For this purpose an integrated research strategy was applied, which connects trace gas flux measurements to soil ecological characterisation of permafrost habitats and molecular ecological analyses of microbial populations. Furthermore, methanogenic archaea isolated from Siberian permafrost have been used as potential keystone organisms for studying and assessing life under extreme living conditions. Long-term studies on methane fluxes were carried out since 1998. These studies revealed considerable seasonal and spatial variations of methane emissions for the different landscape units ranging from 0 to 362 mg m-2 d-1. For the overall balance of methane emissions from the entire delta, the first land cover classification based on Landsat images was performed and applied for an upscaling of the methane flux data sets. The regionally weighted mean daily methane emissions of the Lena Delta (10 mg m-2 d-1) are only one fifth of the values calculated for other Arctic tundra environments. The calculated annual methane emission of the Lena Delta amounts to about 0.03 Tg. The low methane emission rates obtained in this study are the result of the used remotely sensed high-resolution data basis, which provides a more realistic estimation of the real methane emissions on a regional scale. Soil temperature and near soil surface atmospheric turbulence were identified as the driving parameters of methane emissions. A flux model based on these variables explained variations of the methane budget corresponding to continuous processes of microbial methane production and oxidation, and gas diffusion through soil and plants reasonably well. The results show that the Lena Delta contributes significantly to the global methane balance because of its extensive wetland areas. The microbiological investigations showed that permafrost soils are colonized by high numbers of microorganisms. The total biomass is comparable to temperate soil ecosystems. Activities of methanogens and methanotrophs differed significantly in their rates and distribution patterns along both the vertical profiles and the different investigated soils. The methane production rates varied between 0.3 and 38.9 nmol h-1 g-1, while the methane oxidation ranged from 0.2 to 7.0 nmol h-1 g-1. Phylogenetic analyses of methanogenic communities revealed a distinct diversity of methanogens affiliated to Methanomicrobiaceae, Methanosarcinaceae and Methanosaetaceae, which partly form four specific permafrost clusters. The results demonstrate the close relationship between methane fluxes and the fundamental microbiological processes in permafrost soils. The microorganisms do not only survive in their extreme habitat but also can be metabolic active under in situ conditions. It was shown that a slight increase of the temperature can lead to a substantial increase in methanogenic activity within perennially frozen deposits. In case of degradation, this would lead to an extensive expansion of the methane deposits with their subsequent impacts on total methane budget. Further studies on the stress response of methanogenic archaea, especially Methanosarcina SMA-21, isolated from Siberian permafrost, revealed an unexpected resistance of the microorganisms against unfavourable living conditions. A better adaptation to environmental stress was observed at 4 °C compared to 28 °C. For the first time it could be demonstrated that methanogenic archaea from terrestrial permafrost even survived simulated Martian conditions. The results show that permafrost methanogens are more resistant than methanogens from non-permafrost environments under Mars-like climate conditions. Microorganisms comparable to methanogens from terrestrial permafrost can be seen as one of the most likely candidates for life on Mars due to their physiological potential and metabolic specificity. N2 - Die Arktis spielt eine Schlüsselrolle im Klimasystem unserer Erde aus zweierlei Gründen. Zum einen wird vorausgesagt, dass die globale Erwärmung in den hohen Breiten am ausgeprägtesten sein wird. Zum anderen ist ein Drittel des globalen Kohlenstoffs in Ökosystemen der nördlichen Breiten gespeichert. Um ein besseres Verständnis der gegenwärtigen und zukünftigen Entwicklung der Kohlenstoffdynamik in klimaempfindlichen Permafrostökosystemen zu erlangen, konzentriert sich die vorliegende Arbeit auf Untersuchungen zur Kontrolle der Methanflüsse durch Mikroorganismen, auf die Aktivität und Struktur der beteiligten Mikroorganismen-gemeinschaften und auf ihre Reaktion auf sich ändernde Umweltbedingungen. Zu diesem Zweck wurde eine integrierte Forschungsstrategie entwickelt, die Spurengasmessungen mit boden- und molekularökologischen Untersuchungen der Mikroorganismengemeinschaften verknüpft. Langzeitmessungen zu den Methanflüssen werden seit 1998 durchgeführt. Diese Untersuchungen zeigten beträchtliche saisonale und räumliche Schwankungen der Methanemissionen auf, die zwischen 0 und 362 mg m-2 d-1 für die untersuchten Landschaftseinheiten schwankten. Für die Bilanzierung der Methanemissionen für das gesamte Delta wurde erstmals eine Klassifikation der unterschiedlichen Landschaftseinheiten anhand von Landsat-Aufnahmen durchgeführt und für eine Hochrechnung der Methandaten genutzt. Die Mittelwerte der regional gewichteten täglichen Methanemissionen des Lenadeltas (10 mg m-2 d-1) sind nur ein Fünftel so hoch wie die berechneten Werte für andere arktische Tundren. Die errechnete jährliche Methanemission des Lenadeltas beträgt demnach ungefähr 0,03 Tg. Die geringen Methanemissionsraten dieser Studie können durch den bisher noch nicht realisierten integrativen Ansatz, der Langzeitmessungen und Landschafts-klassifizierungen beinhaltet, erklärt werden. Bodentemperatur und oberflächennahe atmosphärische Turbulenzen wurden als die antreibenden Größen der Methanfreisetzung identifiziert. Ein Modell, das auf diesen Variablen basiert, erklärt die Veränderungen der Methanflüsse gemäß der dynamischen mikrobiellen Prozesse und der Diffusion von Methan durch den Boden und die Pflanzen zutreffend. Die Ergebnisse zeigen, dass das Lenadelta erheblich zur globalen Methanemission aufgrund seiner weitreichenden Feuchtgebiete beiträgt. Die mikrobiologischen Untersuchungen zeigten, dass Permafrostböden durch eine hohe Anzahl von Mikroorganismen besiedelt wird. Die Gesamtbiomasse ist dabei mit Bodenökosystemen gemäßigter Klimate vergleichbar. Die Stoffwechselaktivitäten von methanogenen Archaeen und methanotrophen Bakterien unterschieden sich erheblich in ihrer Rate und Verteilung im Tiefenprofil sowie zwischen den verschiedenen untersuchten Böden. Die Methanbildungsrate schwankte dabei zwischen 0,3 und 38,9 nmol h-1 g-1, während die Methanoxidation eine Rate von 0,2 bis 7,0 nmol h-1 g-1 aufwies. Phylogenetische Analysen der methanogenen Mikro-organismengemeinschaften zeigten eine ausgeprägte Diversität der methanogenen Archaeen auf. Die Umweltsequenzen bildeten vier spezifische Permafrostcluster aus, die den Gruppen Methanomicrobiaceae, Methanosarcinaceae und Methano-saetaceae zugeordnet werden konnten. Die Ergebnisse zeigen, dass die Methanfreisetzung durch die zugrunde liegenden mikrobiologischen Prozesse im Permafrostboden gesteuert wird. Die beteiligten Mikroorganismen überleben nicht nur in ihrem extremen Habitat, sondern zeigten auch Stoffwechselaktivität unter in-situ-Bedingungen. Ferner konnte gezeigt werden, dass eine geringfügige Zunahme der Temperatur zu einer erheblichen Zunahme der Methanbildungsaktivität in den ständig gefrorenen Permafrostablagerungen führen kann. Im Falle der Permafrostdegradation würde dieses zu einer gesteigerten Freisetzung von Methan führen mit bisher unbekannten Auswirkungen auf das Gesamtbudget der Methanfreistzung aus arktischen Gebieten. Weitere Untersuchungen zur Stresstoleranz von methanogenen Archaeen – insbesondere des neuen Permafrostisolates Methanosarcina SMA-21 - weisen eine unerwartete Widerstandsfähigkeit der Mikroorganismen gegenüber ungünstigen Lebensbedingungen auf. Eine bessere Anpassung an Umweltstress wurde bei 4°C im Vergleich zu 28°C beobachtet. Zum ersten Mal konnte gezeigt werden, dass methanogene Archaeen aus terrestrischem Permafrost unter simulierten Marsbedingungen unbeschadet überleben. Die Ergebnisse zeigen, dass methanogene Archaeen aus Permafrostböden resistenter gegenüber Umweltstress und Marsbedingungen sind als entsprechende Mikroorganismen aus Habitaten, die nicht durch Permafrost gekennzeichnet sind. Mikroorganismen, die den Archaeen aus terrestrischen Permafrosthabitaten ähneln, können als die wahrscheinlichsten Kandidaten für mögliches Leben auf dem Mars angesehen werden. KW - Methankreislauf KW - mikrobielle Prozesse KW - Diversität KW - Spurengasflüsse KW - Permafrostökosysteme KW - methane cycle KW - microbial processes KW - diversity KW - trace gas fluxes KW - permafrost ecosystems Y1 - 2007 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus-15434 ER - TY - THES A1 - Hoffmann, Toni T1 - Cloning and characterisation of the HMA3 gene and its promoter from Arabidopsis halleri (L.) O'Kane and Al'Shehbaz and Arabidopsis thaliana (L.) Heynhold T1 - Klonierung und Charakterisierung des HMA3 Genes und seines Promotors aus Arabidopsis halleri (L.) O'Kane und Al'Shehbaz und Arabidopsis thaliana (L.) Heynhold N2 - Being living systems unable to adjust their location to changing environmental conditions, plants display homeostatic networks that have evolved to maintain transition metal levels in a very narrow concentration range in order to avoid either deficiency or toxicity. Hence, plants possess a broad repertoire of mechanisms for the cellular uptake, compartmentation and efflux, as well as for the chelation of transition metal ions. A small number of plants are hypertolerant to one or a few specific transition metals. Some metal tolerant plants are also able to hyperaccumulate metal ions. The Brassicaceae family member Arabidopis halleri ssp. halleri (L.) O´KANE and AL´SHEHBAZ is a hyperaccumulator of zinc (Zn), and it is closely related to the non-hypertolerant and non-hyperaccumulating model plant Arabidopsis thaliana (L.) HEYNHOLD. The close relationship renders A. halleri a promising emerging model plant for the comparative investigation of the molecular mechanisms behind hypertolerance and hyperaccumulation. Among several potential candidate genes that are probably involved in mediating the zinc-hypertolerant and zinc-hyperaccumulating trait is AhHMA3. The AhHMA3 gene is highly similar to AtHMA3 (AGI number: At4g30120) in A. thaliana, and its encoded protein belongs to the P-type IB ATPase family of integral membrane transporter proteins that transport transition metals. In contrast to the low AtHMA3 transcript levels in A. thaliana, the gene was found to be constitutively highly expressed across different Zn treatments in A. halleri, especially in shoots. In this study, the cloning and characterisation of the HMA3 gene and its promoter from Arabidopsis halleri (L.) O´KANE and AL´SHEHBAZ and Arabidopsis thaliana (L.) HEYNHOLD is described. Heterologously expressed AhHMA3 mediated enhanced tolerance to Zn and to a much lesser degree to cadmium (Cd) but not to cobalt (Co) in metal-sensitive mutant strains of budding yeast. It is demonstrated that the genome of A. halleri contains at least four copies of AhHMA3, AhHMA3-1 to AhHMA3-4. A copy-specific real-time RT-PCR indicated that an AhHMA3-1 related gene copy is the source of the constitutively high transcript level in A. halleri and not a gene copy similar to AhHMA3-2 or AhHMA3-4. In accordance with the enhanced AtHMA3mRNA transcript level in A. thaliana roots, an AtHMA3 promoter-GUS gene construct mediated GUS activity predominantly in the vascular tissues of roots and not in shoots. However, the observed AhHMA3-1 and AhHMA3-2 promoter-mediated GUS activity in A. thaliana or A. halleri plants did not reflect the constitutively high expression of AhHMA3 in shoots of A. halleri. It is suggested that other factors e. g. characteristic sequence inserts within the first intron of AhHMA3-1 might enable a constitutively high expression. Moreover, the unknown promoter of the AhHMA3-3 gene copy could be the source of the constitutively high AhHMA3 transcript levels in A. halleri. In that case, the AhHMA3-3 sequence is predicted to be highly homologous to AhHMA3-1. The lack of solid localisation data for the AhHMA3 protein prevents a clear functional assignment. The provided data suggest several possible functions of the AhHMA3 protein: Like AtHMA2 and AtHMA4 it might be localised to the plasma membrane and could contribute to the efficient translocation of Zn from root to shoot and/or to the cell-to-cell distribution of Zn in the shoot. If localised to the vacuolar membrane, then a role in maintaining a low cytoplasmic zinc concentration by vacuolar zinc sequestration is possible. In addition, AhHMA3 might be involved in the delivery of zinc ions to trichomes and mesophyll leaf cells that are major zinc storage sites in A. halleri. N2 - Pflanzen sind lebende Systeme, die nicht in der Lage sind ihren Standort sich ändernden Umweltbedingungen anzupassen. Infolgedessen weisen Pflanzen homöostatischeNetzwerke auf, welche die Mengen an intrazellulären Übergangsmetallen in einem sehr engen Konzentrationsbereich kontrollieren um somit Vergiftungs- oder Mangelerscheinungen zu vermeiden. Eine kleine Anzahl von Pflanzen ist hypertolerant gegenüber einem oder mehreren Übergangsmetallen. Einige wenige dieser metalltoleranten Pflanzen sind fähig Übergangsmetalle in beträchtlichen Mengen zu speichern, sprich zu hyperakkumulieren, ohne Vergiftungserscheinungen zu zeigen. Die Haller’sche Schaumkresse (Arabidopis halleri ssp. halleri (L.) O´KANE und AL´SHEHBAZ) aus der Familie der Kreuzblütler (Brassicaceae) ist ein solcher Hyperakkumulator für Zink (Zn). Sie ist nah verwandt mit der Modellpflanze Ackerschmalwand (Arabidopsis thaliana (L.) HEYNHOLD), die jedoch nicht-hypertolerant und nicht-hyperakkumulierend für Übergangsmetalle ist. Diese nahe Verwandtschaft erlaubt vergleichende Studien der molekularen Mechanismen, die Hypertoleranz und Hyperakkumulation zu Grunde liegen. Zu der Gruppe von Kandidatengenen, die möglicherweise von Bedeutung für die Zink-hypertoleranten und -hyperakkumulierenden Eigenschaften von A. halleri sind, gehört AhHMA3, ein Gen mit großer Ähnlichkeit zu AtHMA3 (AGI Nummer: At4g30120) aus A. thaliana. Es kodiert ein Protein aus der Familie transmembraner Übergangsmetall-Transportproteine, den P-typ IB ATPasen. Im Gegensatz zu den niedrigen AtHMA3 Transkriptmengen in A. thaliana wird das AhHMA3 Gen in A. halleri in Gegenwart verschiedener Zn Konzentrationen konstitutiv hoch exprimiert, insbesondere im Spross der Pflanze. Diese Arbeit beschreibt die Klonierung und Charakterisierung des HMA3 Gens und seines Promoters aus A. halleri und A. thaliana. Es wurde gezeigt, dass heterolog exprimiertes AhHMA3 Protein in metallsensitiven Hefestämmen eine erhöhte Toleranz gegenüber Zink und zu einem geringen Grad gegenüber Kadmium (Cd) jedoch nicht gegenüber Kobalt (Co) vermittelt.Weiterhin wurden im Genom von A. halleri mindestens vier AhHMA3 Genkopien, AhHMA3-1 bis AhHMA3-4, nachgewiesen. Eine Genkopie-spezifische Echtzeit-RT-PCR (real-time RT-PCR) deutete darauf hin, dass eine zu AhHMA3-1 und nicht zu AhHMA3-2 oder AhHMA3-4 ähnliche Genkopie die Quelle der konstitutiv hohen Transkriptmengen in A. halleri ist. In Übereinstimmung mit erhöhten mRNS Transkriptmengen inWurzeln von A. thaliana, vermittelte ein AtHMA3 Promoter-GUS (ß-Glucuronidase) Genkonstrukt GUS-Aktivität hauptsächlich in den Leitgeweben der Wurzeln jedoch nicht des Sprosses. Die vermittelte GUS-Aktivität durch Promoterfragmente von AhHMA3-1 und AhHMA3-2 in A. thaliana oder A. halleri Pflanzen spiegelte jedoch nicht die konstitutiv hohe AhHMA3 Expression im Spross von A. halleri wieder. Es wird vermutet, dass andere Faktoren die konstitutiv hohe Expression ermöglichen wie zum Beispiel die gefundenen kopiespezifischen Sequenzinsertionen innerhalb des ersten AhHMA3-1 Introns. Weiterhin ist es denkbar, dass der unbekannte Promoter der AhHMA3-3 Genkopie die Quelle der konstitutiv hohen AhHMA3 Transkriptmengen ist. In diesem Fall wird eine sehr hohe Ähnlichkeit zwischen den Sequenzen von AhHMA3-3 und der AhHMA3-1 vorhergesagt. Es konnten keine deutlichen Ergebnisse zur intrazellulären Lokalisierung gemacht werden, die eine exakte Einordnung der Funktion des AhHMA3 Proteins erlauben würden. Die bisher ermittelten Ergebnisse schlagen jedoch mehrere mögliche Funktionen für AhHMA3 vor: Ähnlich den AhHMA3 homologen Proteinen, AtHMA2 und AtHMA4, könnte AhHMA3 in der Plasmamembran der Zelle sitzen und dort zur effizienten Translokation von Zink aus der Wurzel in den Spross und/oder zur Zell-zu-Zell Verteilung von Zn im Spross beitragen. Falls AhHMA3 in der Membran der Vakuole sitzt, könnte es eine Rolle bei der Aufrechterhaltung niedriger zytoplasmatischer Zinkkonzentrationen durch vakuoläre Zinksequestrierung spielen. Zusätzlich ist es denkbar, dass AhHMA3 an der Abgabe von Zinkionen an Trichome und Blattmesophyllzellen beteiligt ist, die die Haupteinlagerungsorte für Zink in A. halleri darstellen. KW - P-Typ ATPase KW - Übergangsmetalle KW - Hyperakkumulation KW - Zink KW - HMA KW - p-type ATPase KW - transition metals KW - hyperaccumulation KW - zinc KW - HMA Y1 - 2007 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus-15259 ER - TY - CHAP ED - Kurths, Jürgen ED - Fradkov, Alexander ED - Chen, Guanrong T1 - The 3rd international IEEE scientific conference on physics and control (PhysCon 2007) : September 3rd-7th 2007 at the University of Potsdam N2 - During the last few years there was a tremendous growth of scientific activities in the fields related to both Physics and Control theory: nonlinear dynamics, micro- and nanotechnologies, self-organization and complexity, etc. New horizons were opened and new exciting applications emerged. Experts with different backgrounds starting to work together need more opportunities for information exchange to improve mutual understanding and cooperation. The Conference "Physics and Control 2007" is the third international conference focusing on the borderland between Physics and Control with emphasis on both theory and applications. With its 2007 address at Potsdam, Germany, the conference is located for the first time outside of Russia. The major goal of the Conference is to bring together researchers from different scientific communities and to gain some general and unified perspectives in the studies of controlled systems in physics, engineering, chemistry, biology and other natural sciences. We hope that the Conference helps experts in control theory to get acquainted with new interesting problems, and helps experts in physics and related fields to know more about ideas and tools from the modern control theory. KW - nonlinear dynamics KW - micro- and nanotechnologies KW - self-organization KW - complexity Y1 - 2007 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus-15228 PB - Universitätsverlag Potsdam CY - Potsdam ER - TY - BOOK A1 - Dieter, Anne T1 - Maria Montessori und das Recht der Kinder auf Bildung T1 - Maria Montessori and the right of children to education N2 - Vor einhundert Jahren eröffnete die Wissenschaftlerin und Sozialreformerin Dr. med. Maria Montessori in Rom ihre erste Kindertagesstätte, das „Casa dei Bambini”. Inzwischen gibt es allein in Deutschland ca. eintausend Kindergärten und auch Schulen, die nach ihrem Konzept arbeiten. Der Beitrag will auf die Zusammenhänge zwischen dem Menschenrecht auf Bildung, dem pädagogischen Konzept der Maria Montessori und ihrem natur- und verhaltenswissenschaftlich begründeten Ansatz der Lernforschung hinweisen. N2 - One hundred years ago the scientist and reformist Dr. med Maria Montessori established her first kinder garden, called “Casa dei Bambini” in Rome. By now there are approximately one thousand kinder gardens and schools established in Germany which follow the concept of Maria Montessori. The article tries to point out the connection between the human right to education, the pedagogical concept of Maria Montessori and her nature- and behaviour-science-based approach of learning-research. KW - Menschenrechte KW - Kinderrechte KW - Recht auf Bildung KW - Alternative Bildung KW - Human Rights KW - Rights of Children KW - Right to Education KW - Progressive Education Y1 - 2007 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus-15089 ER - TY - BOOK A1 - Dieter, Anne T1 - Menschenrechte und Mediation : Wege zur Verwirklichung menschenwürdigen Lebens T1 - Human rights and mediation N2 - Was haben Menschenrechte und Mediation miteinander zu tun? Was bezwecken sie, und welche Rolle spielt das Wissen der Natur- und Verhaltenswissenschaften über zwischenmenschliche Kommunikation? Der Beitrag versucht, ausgehend von den Begriffen Menschenrechte und Mediation deren Beziehungsgefüge aus interdisziplinärer Sicht aufzudecken. N2 - What combines human rights and mediation? What do they aim at and which role plays the knowledge of science of nature and of behaviour about the interpersonal communication? This article tries to find out the relation between human rights and mediation from an interdisciplinary view. KW - Kommunikation KW - Konflikte KW - Menschenrechte KW - Mediation KW - Communication KW - Conflicts KW - Human Rights KW - Mediation Y1 - 2007 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus-15077 ER - TY - BOOK A1 - Heidenhain, Brigitte T1 - Juden in Wriezen BT - ihr Leben in der Stadt von 1677 bis 1940 und ihr Friedhof T3 - Pri ha-Pardes N2 - Pri ha-Pardes (Früchte des Obstgartens) ist eine Reihe der Vereinigung für Jüdische Studien e.V., welche in Verbindung mit dem Zentrum für Jüdische Studien der Universität Potsdam publiziert wird. Pri ha-Pardes möchte kleineren wissenschaftlichen Studien, Forschungen am Rande der großen Disziplinen und exzellenten Masterarbeiten eine Publikationsplattform bieten. Im ersten Band dieser Reihe zeichnet Brigitte Heidenhain die Geschichte der Juden in Wriezen nach, welche 1677 einsetzte und 1940 mit ihrer Vertreibung und Ermordung endete. Zahlreiche, zumeist bislang unbeachtete Quellen des 18. und 19. Jahrhunderts aus brandenburgischen und Berliner Archiven lassen die Auswirkungen der preußischen Judenpolitik im Leben des Einzelnen und der Gemeinde lebendig vor uns erstehen. Im 18. Jahrhundert war die Existenz der Wriezener Juden vom Kampf um die Aufenthaltserlaubnis und gegen drohende Verarmung geprägt. Die im 19. Jahrhundert neu gewonnene Niederlassungsfreiheit brachte eine Vergrößerung der jüdischen Gemeinde mit sich und gegen Ende des Jahrhunderts eine leichte Verbesserung der wirtschaftlichen Lage. Über das schnelle und vollständige Ende jüdischen Lebens in Wriezen nach 1938 gibt es kaum schriftliche Informationen. Die wichtigste Quelle ist die Datenbank der Gedächtnisstätte JadwaSchem in Jerusalem. In ihr wird die Erinnerung an 56 namentlich bekannte ermordete Wriezener Juden aufbewahrt. Der Band wird mit der Beschreibung des seit 1730 existierenden jüdischen Friedhofes und der Erfassung der hebräischen Grabinschriften abgeschlossen. N2 - The history of jews in Wriezen begins in 1677, shortly after Kurfürst Friedrich Wilhelm allowed jews to settle in Brandenburg again through his edict of 1671. However, during the whole of the 18th century Prussian policy toward jews was extremely restrictive . The results of this policy are clearly visible in the life of the jews of Wriezen: they always remained a small congregation since this was the will of the king for small towns. Life was dominated by the struggle for the right of residence. Status as "Schutzjude" (i.e. "Protected Jew") was restricted to few individuals, leading to the separation of families as younger siblings were forced to leave. State regulated economic policy strongly restricted the freedom of trade, the main source of income for the jews, leading to the impoverishment of most jewish families in Wriezen. In the 18th century, there was no organized congregational activity. This only developed in the course of the 19th century. The jews of Wriezen built their first synagogue in 1820, replacing it with a new and larger one in 1886. The emancipation edict of 1812 improved the general situation of individuals and the new freedom of movement led to an influx of jews to Wriezen. But full legal equality with other citizens was not achieved until the German Empire was founded in 1871. In the first half of the 19th century, the economic situation of the jews of Wriezen was still quite modest, only improving toward the end of the century. There were numerous fluctuations in the membership of the jewish community in the last decades of the 19th and the beginning of the 20th century. But the number of jewish inhabitants of Wriezen remained relatively constant at 100 -120 individuals. There is hardly any written information on the sudden and complete end of jewish life in Wriezen after 1938. At least 59 jewish citizens of Wriezen were deported and murdered between 1940 and 1945. The victims are commemorated in the public database of the Yad-VaShem Memorial in Jerusalem. There has been a jewish cemetery in Wriezen since 1730, in which 131 gravestones still survive today. The oldest dates back to 1773, the last is from 1940. T3 - Pri ha-Pardes - 1 Y1 - 2007 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus-15198 SN - 978-3-939469-39-1 SN - 1863-7442 SN - 2191-4540 IS - 1 PB - Universitätsverlag Potsdam CY - Potsdam ER - TY - THES A1 - Adelhelm, Philipp T1 - Novel carbon materials with hierarchical porosity : templating strategies and advanced characterization T1 - Neue Kohlenstoffmaterialien mit hierarchischer Porosität : Strategien der Templatierung und erweiterte Charakterisierung N2 - The aim of this work was the generation of carbon materials with high surface area, exhibiting a hierarchical pore system in the macro- and mesorange. Such a pore system facilitates the transport through the material and enhances the interaction with the carbon matrix (macropores are pores with diameters > 50 nm, mesopores between 2 – 50 nm). Thereto, new strategies for the synthesis of novel carbon materials with designed porosity were developed that are in particular useful for the storage of energy. Besides the porosity, it is the graphene structure itself that determines the properties of a carbon material. Non-graphitic carbon materials usually exhibit a quite large degree of disorder with many defects in the graphene structure, and thus exhibit inherent microporosity (d < 2nm). These pores are traps and oppose reversible interaction with the carbon matrix. Furthermore they reduce the stability and conductivity of the carbon material, which was undesired for the proposed applications. As one part of this work, the graphene structures of different non-graphitic carbon materials were studied in detail using a novel wide-angle x-ray scattering model that allowed precise information about the nature of the carbon building units (graphene stacks). Different carbon precursors were evaluated regarding their potential use for the synthesis shown in this work, whereas mesophase pitch proved to be advantageous when a less disordered carbon microstructure is desired. By using mesophase pitch as carbon precursor, two templating strategies were developed using the nanocasting approach. The synthesized (monolithic) materials combined for the first time the advantages of a hierarchical interconnected pore system in the macro- and mesorange with the advantages of mesophase pitch as carbon precursor. In the first case, hierarchical macro- / mesoporous carbon monoliths were synthesized by replication of hard (silica) templates. Thus, a suitable synthesis procedure was developed that allowed the infiltration of the template with the hardly soluble carbon precursor. In the second case, hierarchical macro- / mesoporous carbon materials were synthesized by a novel soft-templating technique, taking advantage of the phase separation (spinodal decomposition) between mesophase pitch and polystyrene. The synthesis also allowed the generation of monolithic samples and incorporation of functional nanoparticles into the material. The synthesized materials showed excellent properties as an anode material in lithium batteries and support material for supercapacitors. N2 - Kohlenstoffmaterialien finden aufgrund ihrer Vielseitigkeit heute in den unterschiedlichsten Bereichen des täglichen Lebens ihren Einsatz. Bekannte Beispiele sind Kohlenstofffasern in Verbundwerkstoffen, Graphit als trockenes Schmiermittel, oder Aktivkohlen in Filtersystemen. Ferner wird Graphit als Elektrodenmaterial auch in Lithium-Ionen-Batterien verwendet. Wegen knapper werdender Ressourcen von Öl und Gas wurde in den letzten Jahren verstärkt an der Entwicklung neuer Materialien für die Speicherung von Wasserstoff und elektrischer Energie gearbeitet. Die Nanotechnologie ist dabei auch für neue Kohlenstoffmaterialien zukunftsweisend, denn sie stellt weitere Anwendungsmöglichkeiten in Aussicht. In dieser Arbeit wurden hierzu mittels des sogenannten Nanocastings neue Kohlenstoffmaterialien für Energieanwendungen, insbesondere zur Speicherung von elektrischer Energie entwickelt. Die Eigenschaften eines Kohlenstoffmaterials beruhen im Wesentlichen auf der Struktur des Kohlenstoffs im molekularen Bereich. Die in dieser Arbeit hergestellten Materialen bestehen aus nichtgraphitischem Kohlenstoff und wurden im ersten Teil der Arbeit mit den Methoden der Röntgenstreuung genau untersucht. Eine speziell für diese Art von Kohlenstoffen kürzlich entwickelte Modellfunktion wurde dazu an die experimentellen Streubilder angepasst. Das verwendete Modell basiert dabei auf den wesentlichen Strukturmerkmalen von nichtgraphitischem Kohlenstoff und ermöglichte von daher eine detaillierte Beschreibung der Materialien. Im Gegensatz zu den meisten nichtgraphitischen Kohlenstoffen konnte gezeigt werden, dass die Verwendung von Mesophasen-Pech als Vorläufersubstanz (Precursor) ein Material mit vergleichsweise geringem Grad an Unordnung ermöglicht. Solch ein Material erlaubt eine ähnlich reversible Einlagerung von Lithium-Ionen wie Graphit, weist aber gleichzeitig wegen des nichtgraphitischen Charakters eine deutlich höhere Speicherfähigkeit auf. Zur Beschreibung der Porosität eines Materials verwendet man die Begriffe der Makro-, Meso-, und Mikroporen. Die Aktivität eines Materials kann durch die Erhöhung der Oberfläche noch erheblich gesteigert werden. Hohe Oberflächen können insbesondere durch die Schaffung von Poren im Nanometerbereich erzielt werden. Um die Zugänglichkeit zu diesen Poren zu steigern, weist ein Material idealerweise zusätzlich ein kontinuierliches makroporöses Transportsystem (Porendurchmesser d > 50 nm) auf. Solch eine Art von Porosität über mehrere Größenordnungen wird allgemein als „hierarchische Porosität“ bezeichnet. Für elektrochemische Anwendungen sind sogenannte Mesoporen (d = 2 – 50 nm) relevant, da noch kleinere Poren (Mikroporen, d < 2 nm) z.B. zu einer irreversiblen Bindung von Lithium- Ionen führen können. Wird Mesophasen-Pech als Kohlenstoffprekursor verwendet, kann die Entstehung dieser Mikroporen verhindert werden. Im zweiten und dritten Teil der Arbeit konnte mit den Methoden des „Nanocastings“ zum ersten Mal die spezielle Struktur des Mesophasen-Pech basierenden Kohlenstoffmaterials mit den Vorteilen einer hierarchischen (makro- / meso-) Porosität kombiniert werden. Im ersten Syntheseverfahren wurde dazu ein sogenanntes „hartes Templat“ mit entsprechender Porosität aus Siliziumdioxid repliziert. Aufgrund der hohen Viskosität des Pechs und der geringen Löslichkeit wurde dazu ein Verfahren entwickelt, das die Infiltration des Templates auch auf der Nanometerebene ermöglicht. Das Material konnte in Form größerer Körper (Monolithen) hergestellt werden, die im Vergleich zu Pulvern eine bessere technische Verwendung ermöglichen. Im zweiten Syntheseverfahren konnte die Herstellung eines hierarchisch makro- / mesoporösen Kohlenstoffmaterials erstmals mittels eines weichen Templates (organisches Polymer) erreicht werden. Die einfache Entfernung von weichen Templaten durch eine geeignete Temperaturbehandlung, macht dieses Verfahren im Vergleich zu hart templatierten Materialien kostengünstiger und stellt eine technische Umsetzung in Aussicht. Desweiteren erlaubt das Syntheseverfahren die Herstellung von monolithischen Körpern und die Einbindung funktionaler Nanopartikel. Die hergestellten Materialien zeigen exzellente Eigenschaften als Elektrodenmaterial in Lithium-Ionen-Batterien und als Trägermaterial für Superkondensatoren. KW - Mesoporosität KW - hierarchische Porosität KW - weiche und harte Templatierung KW - Kohlenstoffmaterialien KW - Weitwinkelröntgenstreuung KW - Mesoporosity KW - hierarchical porosity KW - soft and hard templating KW - carbon materials KW - wide-angle x-ray scattering Y1 - 2007 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus-15053 ER - TY - THES A1 - Miteva, Rositsa Stoycheva T1 - Electron acceleration at localized wave structures in the solar corona T1 - Elektronenbeschleunigung an lokalen Wellenstrukturen in der Sonnenkorona N2 - Our dynamic Sun manifests its activity by different phenomena: from the 11-year cyclic sunspot pattern to the unpredictable and violent explosions in the case of solar flares. During flares, a huge amount of the stored magnetic energy is suddenly released and a substantial part of this energy is carried by the energetic electrons, considered to be the source of the nonthermal radio and X-ray radiation. One of the most important and still open question in solar physics is how the electrons are accelerated up to high energies within (the observed in the radio emission) short time scales. Because the acceleration site is extremely small in spatial extent as well (compared to the solar radius), the electron acceleration is regarded as a local process. The search for localized wave structures in the solar corona that are able to accelerate electrons together with the theoretical and numerical description of the conditions and requirements for this process, is the aim of the dissertation. Two models of electron acceleration in the solar corona are proposed in the dissertation: I. Electron acceleration due to the solar jet interaction with the background coronal plasma (the jet--plasma interaction) A jet is formed when the newly reconnected and highly curved magnetic field lines are relaxed by shooting plasma away from the reconnection site. Such jets, as observed in soft X-rays with the Yohkoh satellite, are spatially and temporally associated with beams of nonthermal electrons (in terms of the so-called type III metric radio bursts) propagating through the corona. A model that attempts to give an explanation for such observational facts is developed here. Initially, the interaction of such jets with the background plasma leads to an (ion-acoustic) instability associated with growing of electrostatic fluctuations in time for certain range of the jet initial velocity. During this process, any test electron that happen to feel this electrostatic wave field is drawn to co-move with the wave, gaining energy from it. When the jet speed has a value greater or lower than the one, required by the instability range, such wave excitation cannot be sustained and the process of electron energization (acceleration and/or heating) ceases. Hence, the electrons can propagate further in the corona and be detected as type III radio burst, for example. II. Electron acceleration due to attached whistler waves in the upstream region of coronal shocks (the electron--whistler--shock interaction) Coronal shocks are also able to accelerate electrons, as observed by the so-called type II metric radio bursts (the radio signature of a shock wave in the corona). From in-situ observations in space, e.g., at shocks related to co-rotating interaction regions, it is known that nonthermal electrons are produced preferably at shocks with attached whistler wave packets in their upstream regions. Motivated by these observations and assuming that the physical processes at shocks are the same in the corona as in the interplanetary medium, a new model of electron acceleration at coronal shocks is presented in the dissertation, where the electrons are accelerated by their interaction with such whistlers. The protons inflowing toward the shock are reflected there by nearly conserving their magnetic moment, so that they get a substantial velocity gain in the case of a quasi-perpendicular shock geometry, i.e, the angle between the shock normal and the upstream magnetic field is in the range 50--80 degrees. The so-accelerated protons are able to excite whistler waves in a certain frequency range in the upstream region. When these whistlers (comprising the localized wave structure in this case) are formed, only the incoming electrons are now able to interact resonantly with them. But only a part of these electrons fulfill the the electron--whistler wave resonance condition. Due to such resonant interaction (i.e., of these electrons with the whistlers), the electrons are accelerated in the electric and magnetic wave field within just several whistler periods. While gaining energy from the whistler wave field, the electrons reach the shock front and, subsequently, a major part of them are reflected back into the upstream region, since the shock accompanied with a jump of the magnetic field acts as a magnetic mirror. Co-moving with the whistlers now, the reflected electrons are out of resonance and hence can propagate undisturbed into the far upstream region, where they are detected in terms of type II metric radio bursts. In summary, the kinetic energy of protons is transfered into electrons by the action of localized wave structures in both cases, i.e., at jets outflowing from the magnetic reconnection site and at shock waves in the corona. N2 - Die Sonne ist ein aktiver Stern, was sich nicht nur in den allseits bekannten Sonnenflecken, sondern auch in Flares manifestiert. Während Flares wird eine große Menge gespeicherter, magnetischer Energie in einer kurzen Zeit von einigen Sekunden bis zu wenigen Stunden in der Sonnenkorona freigesetzt. Dabei werden u.a. energiereiche Elektronen erzeugt, die ihrerseits nichtthermische Radio- und Röntgenstrahlung, wie sie z.B. am Observatorium für solare Radioastronomie des Astrophysikalischen Instituts Potsdam (AIP) in Tremsdorf und durch den NASA-Satelliten RHESSI beobachtet werden, erzeugen. Da diese Elektronen einen beträchtlichen Anteil der beim Flare freigesetzten Energie tragen, ist die Frage, wie Elektronen in kurzer Zeit auf hohe Energien in der Sonnenkorona beschleunigt werden, von generellem astrophysikalischen Interesse, da solche Prozesse auch in anderen Sternatmosphären und kosmischen Objekten, wie z.B. Supernova-Überresten, stattfinden. In der vorliegenden Dissertation wird die Elektronenbeschleunigung an lokalen Wellenstrukturen im Plasma der Sonnenkorona untersucht. Solche Wellen treten in der Umgebung der magnetischen Rekonnektion, die als ein wichtiger Auslöser von Flares angesehen wird, und in der Nähe von Stoßwellen, die infolge von Flares erzeugt werden, auf. Generell werden die Elektronen als Testteilchen behandelt. Sie werden durch ihre Wechselwirkung mit den elektrischen und magnetischen Feldern, die mit den Plasmawellen verbunden sind, beschleunigt. Infolge der magnetischen Rekonnektion als Grundlage des Flares werden starke Plasmaströmungen (sogenannte Jets) erzeugt. Solche Jets werden im Licht der weichen Röntgenstrahlung, wie z.B. durch den japanischen Satelliten YOHKOH, beobachtet. Mit solchen Jets sind solare Typ III Radiobursts als Signaturen von energiereichen Elektronenstrahlen in der Sonnenkorona verbunden. Durch die Wechselwirkung eines Jets mit dem umgebenden Plasma werden lokal elektrische Felder erzeugt, die ihrerseits Elektronen beschleunigen können. Dieses hier vorgestellte Szenarium kann sehr gut die Röntgen- und Radiobeobachtungen von Jets und den damit verbundenen Elektronenstrahlen erklären. An koronalen Stoßwellen, die infolge Flares entstehen, werden Elektronen beschleunigt, deren Signatur man in der solaren Radiostrahlung in Form von sogenannten Typ II Bursts beobachten kann. Stoßwellen in kosmischen Plasmen können mit Whistlerwellen (ein spezieller Typ von Plasmawellen) verbunden sein. In der vorliegenden Arbeit wird ein Szenarium vorgestellt, das aufzeigt, wie solche Whistlerwellen an koronalen Stoßwellen erzeugt werden und durch ihre resonante Wechselwirkung mit den Elektronen dieselben beschleunigen. Dieser Prozess ist effizienter als bisher vorgeschlagene Mechanismen und kann deshalb auch auf andere Stoßwellen im Kosmos, wie z.B. an Supernova-Überresten, zur Erklärung der dort erzeugten Radio- und Röntgenstrahlung dienen. KW - Elektronenbeschleunigung KW - Sonnenkorona KW - Jets KW - Stoßwellen KW - Nichtlineare Wellen KW - Electron acceleration KW - Solar corona KW - Jets KW - Shock waves KW - Nonlinear waves Y1 - 2007 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus-14775 ER - TY - THES A1 - Nerlich, Annika T1 - Die Rolle der Phosphatidylserin Decarboxylase für die mitochondriale Phospholipid-Biosynthese in Arabidopsis thaliana T1 - Role of phosphatidylserine decarboxylase in mitochondrial phospholipid biosynthesis of Arabidopsis thaliana N2 - Die durch Phosphatidylserin Decarboxylase (PSD) katalysierte Decarboxylierung von Phosphatidylserin (PS) zu Phosphatidylethanolamin (PE) ist für Mitochondrien in Hefe und Mäusen von essentieller Bedeutung. Im Rahmen der vorliegenden Dissertation wurde erstmals die Rolle dieses PE-Syntheseweges in Pflanzen untersucht. Die drei in Arabidopsis identifizierten PSD Gene atPSD1, atPSD2, atPSD3 codieren für Enzyme, die in Membranen der Mitochondrien (atPSD1), der Tonoplasten (atPSD2) und des Endoplasmatischen Retikulums (atPSD3) lokalisiert sind. Der Beitrag der einzelnen PSDs zur PE-Synthese wurde anhand von psd Null-Mutanten untersucht. Dabei stellte sich atPSD3 als das Enzym mit der höchsten Aktivität heraus. Alternativ zum PSD-Weg wird in Arabidopsis PE auch mittels Aminoalkohol-phosphotransferase synthetisiert. Der Verlust der gesamten PSD-Aktivität, wie es in der erzeugten psd Dreifachmutante der Fall ist, wirkt sich ausschließlich auf die Lipidzusammensetzung in der Mitochondrienmembran aus. Demzufolge wird extramitochondriales PE hauptsächlich über die Aminoalkoholphosphotransferase synthetisiert. Die veränderte Lipidzusammensetzung der Mitochondrienmembran hatte jedoch keinen Einfluss auf die Anzahl, Größe und Ultrastruktur der Mitochondrien sowie auf das ADP/ATP-Verhältnis und die Respiration. Neben der Bereitstellung von Reduktionsäquivalenten beeinflusst die Funktionalität der Mitochondrien auch die Bildung von Blüten- und Staubblättern. Diese Blütenorgane waren in der psd Dreifachmutante stark verändert, und der Blütenphänotyp ähnelte der APETALA3-Mutante. Dieses homöotische Gen ist für die Ausbildung von Blüten- und Staubblättern verantwortlich. Für die Erzeugung der Mutanten psd2-1 und psd3-1 wurde ein T-DNA Vektor verwendet, der den Promotor des APETALA3 Gens enthielt, welcher in den Mutanten psd2-1, psd3-1 sowie psd2-1psd3-1 und der psd1psd2-1psd3-1 Dreifachmutante eine vergleichbare Co-Suppression des APETALA3 Gens hervorruft. Der Blütenphänotyp trat jedoch nur in der psd Dreifachmutante auf, da nur in ihr die Kombination von geringen Funktionstörungen der Mitochondrien, hervorgerufen durch veränderte Lipidzusammensetzung, mit der Co-Suppression von APETALA3 auftritt. N2 - Decarboxylation of phosphatidylserine (PS) to form phosphatidylethanolamine (PE) catalyzed by phosphatidylserine decarboxylase (PSD) is an essential reaction for mitochondria in yeast and mice. This dissertation describes the role of this biosynthesis pathway in plants for the first time. Three PSD genes were identified in Arabidopsis, atPSD1, atPSD2, atPSD3. The gene products localize to mitochondria (atPSD1), tonoplast (atPSD2) and endoplasmatic retikulum (atPSD3). Contribution to PE-synthesis of each PSD was analyzed using T-DNA insertion mutants. Thereby, atPSD3 was found to be the most active isoform. Alternatively, PE is also synthesized by the action of aminoalcohol phosphotransferase. Complete loss of PSD activity, like in the psd triple mutant, resulted in changes in lipid composition of mitochondria membranes exclusively. In conclusion the bulk of PE is synthesized by aminoalcohol phosphotransferase. Changed lipid composition of mitochondria did not result in changes of mitochondria number, structure, ADP/ATP ratio and respiration. Mitochondria functionality was formerly shown to effect formation of petals and stamens. These flower organs were drastically morphologically changed in psd triple mutants and showed strong similarities to APETALA3 mutants. APETALA3 is a homeotic gene responsible for specifying petals and stamens. Mutants psd2-1 and psd3-1 used for crossing psd double and triple mutants contained a T-DNA vector which include the promoter for APETALA3. This promoter caused co-suppression of the endogenous APETALA3 gene in all mutants isolated from the Arabidopsis Knockout Facility, whereas changed flower morphology occurred only in the triple mutant concluding a combined effect of co-suppression and a reduced functionality of mitochondria, caused by changed lipid composition. KW - Phospholipide KW - Phosphatidylserin Decarboxylase KW - Phosphatidylserin KW - Phosphatidylethanolamin KW - Mitochondrien KW - phospholipids KW - phosphatidylserine decarboxylase KW - phosphatidylserine KW - phosphatidylethanolamine KW - mitochondria Y1 - 2007 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus-14522 ER - TY - GEN A1 - Semprún, Jorge T1 - Philosophie als Überlebenswissenschaft N2 - Dem Schriftsteller Jorge Semprún wurde am 25. Mai 2007 die Ehrendoktorwürde der Philosophischen Fakultät der Universität Potsdam verliehen. Damit ehrt die Philosophische Fakultät seine Lebensleistung als Schriftsteller, Denker und engagierter Intellektueller unserer Zeit. Der Geehrte sprach zum Thema "Philosophie als Überlebenswissenschaft". Jorge Semprún, 1923 in Madrid/Spanien geboren, muss mit 14 Jahren zu Beginn des spanischen Bürgerkrieges mit seiner Familie nach Paris fliehen. Dort studiert er Philosophie an der Sorbonne. Im Jahre 1941 tritt er der kommunistischen Résistance-Bewegung "Francs- Tireurs et Partisans" bei. Zwei Jahre später wird er von der deutschen Gestapo verhaftet und in das Konzentrationslager Buchenwald deportiert. 1945 kehrt er nach Paris zurück. Zwischen 1957 und 1962 arbeitet er im Untergrund der Kommunistischen Partei im faschistischen Spanien. Seit 1964, dem Jahr, in dem er wegen der Abweichung von der Parteilinie aus der Kommunistischen Partei ausgeschlossen wurde, ist er schriftstellerisch tätig. Von 1988 bis 1991 war er Kultusminister Spaniens. Zu den bekanntesten Werken des Schriftstellers gehören "Die große Reise", "Der zweite Tod des Ramón Mercader", "Was für ein schöner Sonntag" sowie "Der weiße Berg". T3 - Potsdamer Universitätsreden - Bd. 06 Y1 - 2007 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus-13505 SN - 978-3-939469-75-9 ER - TY - THES A1 - Demircioglu, Aydin T1 - Reconstruction of deligne classes and cocycles T1 - Rekonstruktion von Deligne Klassen und Kozykeln N2 - In der vorliegenden Arbeit verallgemeinern wir im Wesentlichen zwei Theoreme von Mackaay-Picken und Picken (2002, 2004). Im ihrem Artikel zeigen Mackaay und Picken,dass es eine bijektive Korrespodenz zwischen Deligne 2-Klassen $\xi \in \check{H}^2(M, \mathcal{D}^2)$ und Holonomie Abbildungen von der zweiten dünnen Homotopiegruppe $\pi_2^2(M)$ in die abelsche Gruppe $U(1)$ gibt. Im zweiten Artikel wird eine Verallgemeinerung dieses Theorems bewiesen: Picken zeigt, dass es eine Bijektion gibt zwischen Deligne 2-Kozykeln und gewissen 2-dimensionalen topologischen Quantenfeldtheorien. In dieser Arbeit zeigen wir, dass diese beiden Theoreme in allen Dimensionen gelten.Wir betrachten zunächst den Holonomie Fall und können mittels simplizialen Methoden nachweisen, dass die Gruppe der glatten Deligne $d$-Klassen isomorph ist zu der Gruppe der glatten Holonomie Abbildungen von der $d$-ten dünnen Homotopiegruppe $\pi_d^d(M)$ nach $U(1)$, sofern $M$ eine $(d-1)$-zusammenhängende Mannigfaltigkeit ist. Wir vergleichen dieses Resultat mit einem Satz von Gajer (1999). Gajer zeigte, dass jede Deligne $d$-Klasse durch eine andere Klasse von Holonomie-Abbildungen rekonstruiert werden kann, die aber nicht nur Holonomien entlang von Sphären, sondern auch entlang von allgemeinen $d$-Mannigfaltigkeiten in $M$ enthält. Dieser Zugang benötigt dann aber nicht, dass $M$ hoch-zusammenhängend ist. Wir zeigen, dass im Falle von flachen Deligne $d$-Klassen unser Rekonstruktionstheorem sich von Gajers unterscheidet, sofern $M$ nicht als $(d-1)$, sondern nur als $(d-2)$-zusammenhängend angenommen wird. Stiefel Mannigfaltigkeiten besitzen genau diese Eigenschaft, und wendet man unser Theorem auf diese an und vergleicht das Resultat mit dem von Gajer, so zeigt sich, dass es zuviele Deligne Klassen rekonstruiert. Dies bedeutet, dass unser Rekonstruktionsthreorem ohne die Zusatzbedingungen an die Mannigfaltigkeit M nicht auskommt, d.h. unsere Rekonstruktion benötigt zwar weniger Informationen über die Holonomie entlang von d-dimensionalen Mannigfaltigkeiten, aber dafür muss M auch $(d-1)$-zusammenhängend angenommen werden. Wir zeigen dann, dass auch das zweite Theorem verallgemeinert werden kann: Indem wir das Konzept einer Picken topologischen Quantenfeldtheorie in beliebigen Dimensionen einführen, können wir nachweisen, dass jeder Deligne $d$-Kozykel eine solche $d$-dimensionale Feldtheorie mit zwei besonderen Eigenschaften, der dünnen Invarianz und der Glattheit, induziert. Wir beweisen, dass jede $d$-dimensionale topologische Quantenfeldtheorie nach Picken mit diesen zwei Eigenschaften auch eine Deligne $d$-Klasse definiert und prüfen nach, dass diese Konstruktion sowohl surjektiv als auch injektiv ist. Demzufolge sind beide Gruppen isomorph. N2 - In this thesis we mainly generalize two theorems from Mackaay-Picken and Picken (2002, 2004). In the first paper, Mackaay and Picken show that there is a bijective correspondence between Deligne 2-classes $\xi \in \check{H}^2(M,\mathcal{D}^2)$ and holonomy maps from the second thin-homotopy group $\pi_2^2(M)$ to $U(1)$. In the second one, a generalization of this theorem to manifolds with boundaries is given: Picken shows that there is a bijection between Deligne 2-cocycles and a certain variant of 2-dimensional topological quantum field theories. In this thesis we show that these two theorems hold in every dimension. We consider first the holonomy case, and by using simplicial methods we can prove that the group of smooth Deligne $d$-classes is isomorphic to the group of smooth holonomy maps from the $d^{th}$ thin-homotopy group $\pi_d^d(M)$ to $U(1)$, if $M$ is $(d-1)$-connected. We contrast this with a result of Gajer (1999). Gajer showed that Deligne $d$-classes can be reconstructed by a different class of holonomy maps, which not only include holonomies along spheres, but also along general $d$-manifolds in $M$. This approach does not require the manifold $M$ to be $(d-1)$-connected. We show that in the case of flat Deligne $d$-classes, our result differs from Gajers, if $M$ is not $(d-1)$-connected, but only $(d-2)$-connected. Stiefel manifolds do have this property, and if one applies our theorem to these and compare the result with that of Gajers theorem, it is revealed that our theorem reconstructs too many Deligne classes. This means, that our reconstruction theorem cannot live without the extra assumption on the manifold $M$, that is our reconstruction needs less informations about the holonomy of $d$-manifolds in $M$ at the price of assuming $M$ to be $(d-1)$-connected. We continue to show, that also the second theorem can be generalized: By introducing the concept of Picken-type topological quantum field theory in arbitrary dimensions, we can show that every Deligne $d$-cocycle induces such a $d$-dimensional field theory with two special properties, namely thin-invariance and smoothness. We show that any $d$-dimensional topological quantum field theory with these two properties gives rise to a Deligne $d$-cocycle and verify that this construction is surjective and injective, that is both groups are isomorphic. KW - Holonomie KW - Hauptfaserbündel KW - Gerben KW - Deligne Kohomologie KW - Globale Differentialgeometrie KW - Holonomy KW - Prinicipal Fibre Bundles KW - Gerbes KW - Deligne Cohomology KW - Global Differentialgeometry Y1 - 2007 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus-13755 ER -