TY  - GEN
A1  - Abouserie, Ahed
A1  - Schilde, Uwe
A1  - Taubert, Andreas
T1  - The crystal structure of N-butylpyridinium bis(μ2-dichlorido)-tetrachloridodicopper(II), C₁₈H₂₈N₂Cu₂Cl₆
T2  - Zeitschrift für Kristallographie - New Crystal Structures
N2  - C₉H₁₄Cl₃CuN, monoclinic, P2₁/n (no. 14), a = 9.6625(6) Å, b = 9.3486(3) Å, c = 14.1168(8) Å, β = 102.288(5)°, V = 1245.97(11) ų, Z = 4, Rgₜ(F) = 0.0182, wRᵣₑf(F²) = 0.0499, T = 210(2) K.
T3  - Zweitveröffentlichungen der Universität Potsdam : Mathematisch-Naturwissenschaftliche Reihe - 465 
KW  - Ionic Liquid Precursor
KW  - Thermochromism
KW  - Salts
KW  - Nanostructures
KW  - Catalysis
KW  - Solvents
KW  - Complex
KW  - Gas
Y1  - 2018
U6  - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus4-417310
ER  - 
TY  - GEN
A1  - Mirskova, Anna N.
A1  - Adamovich, Sergey N.
A1  - Mirskov, Rudolf G.
A1  - Schilde, Uwe
T1  - Reaction of pharmacological active tris-(2-hydroxyethyl)ammonium 4-chlorophenylsulfanylacetate with ZnCl2 or NiCl2
BT  - first conversion of a protic ionic liquid into metallated ionic liquid
N2  - The reaction of pharmacological active protic ionic liquid tris-(2-hydroxyethyl)ammonium 4-chlorophenylsulfanylacetate H + N(CH 2 CH 2 OH) 3 ∙ ( - OOCCH 2 SC 6 H 4 Cl-4) (1) with zinc or nickel chloride in a ratio of 2:1 affords stable at room temperature powder-like adducts [H + N(CH 2 CH 2 OH) 3 ] 2 ∙ [M(OOCCH 2 SC 6 H 4 Cl-4) 2 Cl 2 ] 2- , M = Zn (2), Ni (3). By recrystallization from aqueous alcohol compound 2 unexpectedly gives Zn(OOCCH 2 SC 6 H 4 Cl-4) 2 ∙ 2H 2 O (4). Unlike 2, compound 3 gives crystals [N(CH 2 CH 2 OH) 3 ] 2 Ni 2+ · [ - OOCCH 2 SC 6 H 4 Cl-4] 2 (5), which have a structure of metallated ionic liquid. The structure of 5 has been proved by X-ray diffraction analysis. It is the first example of the conversion of a protic ionic liquid into potentially biological active metallated ionic liquid (1 → 3 → 5).
T3  - Zweitveröffentlichungen der Universität Potsdam : Mathematisch-Naturwissenschaftliche Reihe - 377 
KW  - Formate
KW  - Salts
KW  - Acids
Y1  - 2017
U6  - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus4-401099
ER  -