TY - JOUR A1 - Terbishalieva, Baiansuluu A1 - Timmerman, Martin Jan A1 - Mikolaichuk, Alexander A1 - Altenberger, Uwe A1 - Slama, Jiri A1 - Schleicher, Anja Maria A1 - Sudo, Masafumi A1 - Sobel, Edward A1 - Cichy, Sarah Bettina T1 - Calc-alkaline volcanic rocks and zircon ages of the late Tonian BT - Early Cryogenian arc-related Big Naryn Complex in the Eastern Djetim-Too Range, Middle Tianshan block, Kyrgyzstan JF - International journal of earth sciences N2 - The Big Naryn Complex (BNC) in the East Djetim-Too Range of the Kyrgyz Middle Tianshan block is a tectonized, at least 2 km thick sequence of predominantly felsic to intermediate volcanic rocks intruded by porphyric rhyolite sills. It overlies a basement of metamorphic rocks and is overlain by late Neoproterozoic Djetim-Too Formation sediments; these also occur as tectonic intercalations in the BNC. The up to ca. 1100 m thick Lower Member is composed of predominantly rhyolites-to-dacites and minor basalts, while the at least 900 m thick pyroclastic Upper Member is dominated by rhyolitic-to-dacitic ignimbrites. Porphyric rhyolite sills are concentrated at the top of the Lower Member. A Lower Member rhyolite and a sill sample have LA-ICP-MS U-Pb zircon crystallization ages of 726.1 +/- 2.2 Ma and 720.3 +/- 6.5 Ma, respectively, showing that most of the magmatism occurred within a short time span in the late Tonian-early Cryogenian. Inherited zircons in the sill sample have Neoarchean (2.63, 2.64 Ga), Paleo- (2.33-1.81 Ga), Meso- (1.55 Ga), and Neoproterozoic (ca. 815 Ma) ages, and were derived from a heterogeneous Kuilyu Complex basement. A 1751 +/- 7 Ma Ar-40/Ar-39 age for amphibole from metagabbro is the age of cooling subsequent to Paleoproterozoic metamorphism of the Kuilyu Complex. The large amount of pyroclastic rocks, and their major and trace element compositions, the presence of Neoarchean to Neoproterozoic inherited zircons and a depositional basement of metamorphic rocks point to formation of the BNC in a continental magmatic arc setting. KW - Tianshan orogenic belt KW - Big Naryn complex KW - Tonian–Cryogenian KW - magmatic arc KW - calc-alkaline KW - Kuilyu complex Y1 - 2021 U6 - https://doi.org/10.1007/s00531-020-01956-z SN - 1437-3254 SN - 1437-3262 VL - 110 IS - 1 SP - 353 EP - 375 PB - Springer CY - New York ER - TY - JOUR A1 - Nguyen, Minh N. A1 - Meharg, Andy A. A1 - Carey, Manus A1 - Dultz, Stefan A1 - Marone, Federica A1 - Cichy, Sarah Bettina A1 - Tran, Chinh T. A1 - Le, Giang H. A1 - Mai, Nga T. A1 - Nguyen, Thinh T. H. T1 - Fern, Dicranopteris linearis, derived phytoliths in soil BT - Morphotypes, solubility and content in relation to soil properties JF - European journal of soil science N2 - Ferns are among the most popular groups of plants in the tropics and subtropics, and their role as carbon sequestrators has been widely recognized. However, there is little understanding of the silicaceous structures (phytoliths) of ferns, rate of phytolith turnover, the consequences for organic matter sequestered in phytoliths and consequences for other soil properties. In the study reported here, high-resolution X-ray tomographic microscopy and chemical characterization were applied to examine the traits of phytoliths of the fern Dicranopteris linearis (Burm.f.) Underw. (D. linearis), with a focus on their dissolution properties and accumulation in northern Vietnamese soils in relation to soil properties. Tomographic images revealed an inter-embedding structure of silica and organic matter, especially in leaf-derived material. We propose that organic matter and silica can preserve each other against decomposition. In batch experiments, there was a relatively small rate of dissolution of phytoliths with dry ashing and subsequent H2O2 treatment. Silicon (Si) dissolution for D. linearis phytolith samples was much less than that for rice phytoliths. Despite the fact that the aluminum (Al) content was large in D. linearis leaves, batch dissolution data did not confirm a relation between Al and the slow rate of phytolith dissolution. The soil phytolith content varied from 0.9 to 7.5 g kg(-1) in the topsoil across the mountainous areas in northern Vietnam, whereas it tended to be smaller in the subsoil. The data indicate a relation between phytolith and soil organic matter, clay content, oxalate-soluble Al and electrical conductivity, suggesting that these soil properties are among the important factors affecting the size of the soil phytolith Si pool. Highlights KW - accumulation in soils KW - dissolution properties KW - phytolith KW - silicon Y1 - 2019 U6 - https://doi.org/10.1111/ejss.12754 SN - 1351-0754 SN - 1365-2389 VL - 70 IS - 3 SP - 507 EP - 517 PB - Wiley CY - Hoboken ER - TY - JOUR A1 - Tran, C. T. A1 - Mai, N. T. A1 - Nguyen, V. T. A1 - Nguyen, H. X. A1 - Meharg, A. A1 - Carey, M. A1 - Dultz, S. A1 - Marone, F. A1 - Cichy, Sarah Bettina A1 - Nguyen, Minh N. T1 - Phytolith-associated potassium in fern BT - characterization, dissolution properties and implications for slash-and-burn agriculture JF - Soil use and Management N2 - In recent time, phytoliths (silicon deposition between plant cells) have been recognized as an important nutrient source for crops. The work presented here aims at highlighting the potential of phytolith-occluded K pool in ferns. Dicranopteris linearis (D.linearis) is a common fern in the humid subtropical and tropical regions. Burning of the fern D.linearis is, in slash-and-burn regions, a common practice to prepare the soil before planting. We characterised the phytolith-rich ash derived from the fern D.linearis and phytolith-associated potassium (K) (phytK), using X-ray tomographic microscopy in combination with kinetic batch experiments. D.linearis contains up to 3.9g K/kgd.wt, including K subcompartmented in phytoliths. X-ray tomographic microscopy visualized an interembedding structure between organic matter and silica, particularly in leaves. Corelease of K and Si observed in the batch experiments confirmed that the dissolution of ash phytoliths is one of major factors controlling K release. Under heat treatment, a part of the K is made available, while the remainder entrapped into phytoliths (ca. 2.0-3.3%) is unavailable until the phytoliths are dissolved. By enhanced removal of organic phases, or forming more stable silica phases, heat treatment changes dissolution properties of the phytoliths, affecting K release for crops and soils. The maximum releases of soluble K and Si were observed for the phytoliths treated at 500-800 degrees C. For quantitative approaches for the K provision of plants from the soil phytK pool in soils, factors regulating phytolith dissolution rate have to be considered. KW - Potassium KW - phytolith KW - fern KW - Dicranopteris linearis Y1 - 2018 U6 - https://doi.org/10.1111/sum.12409 SN - 0266-0032 SN - 1475-2743 VL - 34 IS - 1 SP - 28 EP - 36 PB - Wiley CY - Hoboken ER - TY - JOUR A1 - Kulahci, Gullu Deniz A1 - Cichy, Sarah Bettina A1 - Temel, Abidin A1 - Spallanzani, Roberta T1 - Pre-eruptive PTX fluid-conditions of the Afyon Volcanic Complex (Western Anatolia, Turkey) BT - Studies of natural rocks and phase equilibria experiments JF - Lithos : an international journal of mineralogy, petrology, and geochemistry N2 - This study is trying to understand the pre-eruptive magma storage and crystallization conditions of the Middle Miocene aged, silica-saturated trachytic rocks of the Afyon Volcanic Complex (AVC) in Western Anatolia, Turkey. Those rocks can be divided by their high K2O, K2O/Na2O ratio and Mg# into two groups, namely the intermediate-potassic (IPG) and the ultrapotassic (UPG). Here we are comparing calculated pressure (P) - temperature (T) conditions derived from geothermobarometric calculations of natural samples with results of high-pressure, high-temperature phase equilibria experiments. IPG samples are richer in silica (57-64 wt% SiO2), whereas UPG samples show intermediate SiO2 contents of 56-58 wt%. UPG are having high K2O contents ((>)9 wt %), K2O/Na2O ratios ((>)10 wt%) and Mg# values (75-77). IPG phenocrysts comprise plagioclase + biotite + amphibole + clinopyroxene +/- orthopyroxene +/- sanidine +/- phlogopite and oxides, while UPG mineralogical assemblage consists of amphibole + phlogopite + clinopyroxene + olivine + sanidine and oxides. IPG and UPG are enriched in Large-Ion Lithophile Elements (LILE), and both have negative anomalies in Nb, Sr, Zr and Ti elements. Additionally, IPG shows positive anomalies in Pb. Both IPG and UPG display enrichment in Light Rare Earth Elements (LREE), while IPG shows a more significant negative anomaly in Eu when compared to UPG. Plagioclase fractionation may play a role in magma generation. In IPG samples Ni and Cr values range between (3.3-18.8 ppm) and (2.6-27.8 ppm), respectively; whereas UPG samples have (119.1-120.7 ppm) Ni and (212.1-219.9 ppm) Cr. Dy/Yb ratios of IPG and UPG are higher than 2 and may indicate that garnet was present in the source. Geothermobarometric calculations for natural IPG clinopyroxene-melt pairs imply higher PT conditions (Dogan-Kulahci et al., 2015), while in this study high-pressure/high-temperature (HP/HT) phase equilibria experiments recreated the natural mineral assemblage at 2-4 kbar, 6-9 km and c. 900 degrees C. New plagioclase-melt calculations have confirmed lower mean magma storage temperatures, which are closer to the experimental results but still slightly elevated. Thus, trace element results of the natural rocks and experimental data may imply that a deep garnet-bearing magma source mixed with shallower magmas (IPG) was feeding the volcanic eruption. KW - Afyon volcanics KW - Geothermobarometry KW - Experimental petrology KW - High-pressure KW - High-temperature experiments Y1 - 2021 U6 - https://doi.org/10.1016/j.lithos.2021.106297 SN - 0024-4937 SN - 1872-6143 VL - 398 PB - Elsevier CY - Amsterdam ER -