TY  - JOUR
A1  - Hermanns, Jolanda
A1  - Keller, David
T1  - How do preservice chemistry teachers rate tasks following the construct of school-related content knowledge in a concept-orientated course on organic chemistry?
JF  - Journal of chemical education / Division of Chemical Education, Inc., American Chemical Society
N2  - In this paper, we describe a study on tasks following the construct of school-related content knowledge. We know from previous studies that such tasks were rated by the preservice chemistry teachers as important for their future profession. Those studies were conducted in a traditional course on organic chemistry which was organized around chemical families. Therefore, we used and evaluated the tasks again in a new course on organic chemistry which is organized around basic concepts in organic chemistry. The results of this evaluation show that the students rate the tasks equally well but use other arguments for their rating. They do not focus only on the content of the tasks and whether this content belongs to the school curriculum or not. The students of the conceptual course rated the content more often (95%) as important for their future profession compared with the students in the traditional course (57%). Both groups of students rated the importance of the nature of the task the same way.
KW  - Organic chemistry
KW  - Second-Year undergraduate
KW  - Alcohols
KW  - Curriculum
KW  - Molecular structure
KW  - Organic structure
KW  - Students
Y1  - 2021
U6  - https://doi.org/10.1021/acs.jchemed.1c00593
SN  - 0021-9584
SN  - 1938-1328
VL  - 98
IS  - 11
SP  - 3442
EP  - 3449
PB  - American Chemical Society
CY  - Washington
ER  - 
TY  - JOUR
A1  - Wolf, Thomas J. A.
A1  - Sanchez, David M.
A1  - Yang, J.
A1  - Parrish, R. M.
A1  - Nunes, J. P. F.
A1  - Centurion, M.
A1  - Coffee, R.
A1  - Cryan, J. P.
A1  - Gühr, Markus
A1  - Hegazy, Kareem
A1  - Kirrander, Adam
A1  - Li, R. K.
A1  - Ruddock, J.
A1  - Shen, Xiaozhe
A1  - Vecchione, T.
A1  - Weathersby, S. P.
A1  - Weber, Peter M.
A1  - Wilkin, K.
A1  - Yong, Haiwang
A1  - Zheng, Q.
A1  - Wang, X. J.
A1  - Minitti, Michael P.
A1  - Martinez, Todd J.
T1  - The photochemical ring-opening of 1,3-cyclohexadiene imaged by ultrafast electron diffraction
JF  - Nature chemistry
N2  - The ultrafast photoinduced ring-opening of 1,3-cyclohexadiene constitutes a textbook example of electrocyclic reactions in organic chemistry and a model for photobiological reactions in vitamin D synthesis. Although the relaxation from the photoexcited electronic state during the ring-opening has been investigated in numerous studies, the accompanying changes in atomic distance have not been resolved. Here we present a direct and unambiguous observation of the ring-opening reaction path on the femtosecond timescale and subangstrom length scale using megaelectronvolt ultrafast electron diffraction. We followed the carbon-carbon bond dissociation and the structural opening of the 1,3-cyclohexadiene ring by the direct measurement of time-dependent changes in the distribution of interatomic distances. We observed a substantial acceleration of the ring-opening motion after internal conversion to the ground state due to a steepening of the electronic potential gradient towards the product minima. The ring-opening motion transforms into rotation of the terminal ethylene groups in the photoproduct 1,3,5-hexatriene on the subpicosecond timescale.
KW  - Organic chemistry
KW  - Photochemistry
KW  - Physical chemistry
KW  - Theoretical chemistry
Y1  - 2019
U6  - https://doi.org/10.1038/s41557-019-0252-7
SN  - 1755-4330
SN  - 1755-4349
VL  - 11
IS  - 6
SP  - 504
EP  - 509
PB  - Nature Publ. Group
CY  - London
ER  - 
TY  - JOUR
A1  - Quirico, E.
A1  - Moroz, Liubov V.
A1  - Schmitt, B.
A1  - Arnold, Gabriele
A1  - Faure, M.
A1  - Beck, P.
A1  - Bonal, L.
A1  - Ciarniello, M.
A1  - Capaccioni, F.
A1  - Filacchione, G.
A1  - Erard, S.
A1  - Leyrat, C.
A1  - Bockelee-Morvan, D.
A1  - Zinzi, A.
A1  - Palomba, E.
A1  - Drossart, P.
A1  - Tosi, F.
A1  - Capria, M. T.
A1  - De Sanctis, M. C.
A1  - Raponi, A.
A1  - Fonti, S.
A1  - Mancarella, F.
A1  - Orofino, V.
A1  - Barucci, A.
A1  - Blecka, M. I.
A1  - Carlson, R.
A1  - Despan, D.
A1  - Faure, A.
A1  - Fornasier, S.
A1  - Gudipati, M. S.
A1  - Longobardo, A.
A1  - Markus, K.
A1  - Mennella, V.
A1  - Merlin, F.
A1  - Piccioni, G.
A1  - Rousseau, B.
A1  - Taylor, F.
T1  - Refractory and semi-volatile organics at the surface of comet 67P/Churyumov-Gerasimenko: Insights from the VIRTIS/Rosetta imaging spectrometer
JF  - Icarus : international journal of solar system studies
N2  - The VIRTIS (Visible, Infrared and Thermal Imaging Spectrometer) instrument aboard the Rosetta spacecraft has performed extensive spectral mapping of the surface of comet 67P/Churyumov-Gerasimenko in the range 0.3-5 mu m. The reflectance spectra collected across the surface display a low reflectance factor over the whole spectral range, two spectral slopes in the visible and near-infrared ranges and a broad absorption band centered at 3.2 mu m. The first two of these characteristics are typical of dark small bodies of the Solar System and are difficult to interpret in terms of composition. Moreover, solar wind irradiation may modify the structure and composition of surface materials and there is no unequivocal interpretation of these spectra devoid of vibrational bands. To circumvent these problems, we consider the composition of cometary grains analyzed in the laboratory to constrain the nature of the cometary materials and consider results on surface rejuvenation and solar wind processing provided by the OSIRIS and ROSINA instruments, respectively. Our results lead to five main conclusions: (i) The low albedo of comet 67P/CG is accounted for by a dark refractory polyaromatic carbonaceous component mixed with opaque minerals. VIRTIS data do not provide direct insights into the nature of these opaque minerals. However, according to the composition of cometary grains analyzed in the laboratory, we infer that they consist of Fe-Ni alloys and FeS sulfides. (ii) A semi-volatile component, consisting of a complex mix of low weight molecular species not volatilized at T similar to 220 K, is likely a major carrier of the 3.2 p.m band. Water ice contributes significantly to this feature in the neck region but not in other regions of the comet. COOH in carboxylic acids is the only chemical group that encompasses the broad width of this feature. It appears as a highly plausible candidate along with the NH4+ ion. (iii) Photolytic/thermal residues, produced in the laboratory from interstellar ice analogs, are potentially good spectral analogs. (iv) No hydrated minerals were identified and our data support the lack of genetic links with the CI, CR and CM primitive chondrites. This concerns in particular the Orgueil chondrite, previously suspected to have been of cometary origin. (v) The comparison between fresh and aged terrains revealed no effect of solar wind irradiation on the 3.2 mu m band. This is consistent with the presence of efficient resurfacing processes such as dust transport from the interior to the surface, as revealed by the OSIRIS camera. (C) 2016 Elsevier Inc. All rights reserved.
KW  - Comets
KW  - Organic chemistry
KW  - Infrared observations
KW  - Meteorites
KW  - Spectrophotometry
Y1  - 2016
U6  - https://doi.org/10.1016/j.icarus.2016.02.028
SN  - 0019-1035
SN  - 1090-2643
VL  - 272
SP  - 32
EP  - 47
PB  - Elsevier
CY  - San Diego
ER  -