TY - JOUR A1 - Hoehnel, Desirée A1 - Reimold, Wolf Uwe A1 - Altenberger, Uwe A1 - Hofmann, Axel A1 - Mohr-Westheide, Tanja A1 - Oezdemir, Seda A1 - Köberl, Christian T1 - Petrographic and Micro-XRF analysis of multiple archean impact-derived spherule layers in drill core CT3 from the northern Barberton Greenstone Belt (South Africa) JF - Journal of African earth sciences / Geological Society of Africa N2 - The Archean spherule layers (SLs) of the Barberton Greenstone Belt (BGB, South Africa) and Pilbara Craton (Australia) are the only known evidence of early, large impact events on Earth. Spherules in these layers have been, alternatively, interpreted as molten impact ejecta, condensation products from an impact vapor cloud, or ejecta from impact craters melted during atmospheric re-entry. Recently, a new exploration drill core (CT3) from the northern BGB revealed 17 SL intersections. Spherules are densely packed, sand-sized, and variably rounded or deformed. The CT3 SLs are intercalated with black and brown shale, and laminated chert. The determination of the original number of impact events that are represented by these multiple SLs is central to the present paper. A comprehensive study of the sedimentary and petrographic characteristics of these SLs involved the determination of the size, shape and types of individual spherules, as well as their mineralogy. CT3 SLs consist of K-feldspar, phyllosilicate, siderite, dolomite, quartz, Ti- and Fe-oxides, as well as apatite. In addition, small amounts of carbonaceous, presumably organic material are observed in several spherules at 145 and 149 m depth. Only Ni-rich Cr-spinel (up to 11 wt% NiO) crystals, rare zircon grains, and alloys of platinum group elements ± Fe or Ni represent primary phases in these thoroughly altered strata. The 0.3 to 2.6-mm-sized spherules can be classified into four types: 1. Spherules crystallized completely with secondary K-feldspar (subtype 1A) or phyllosilicate (subtype 1B); spherules completely filled with Ti- and Fe-oxides (subtype 1C); spherules containing disordered or radially oriented, fibrous and lath-shaped K-feldspar textures (subtype 1D); or subtype 1B spherules that contain significant Cr-spinel (subtype 1E); 2. zoned compositions with these types 1A and/or 1B minerals (subtype 2A); spherules that contain central or marginal vesicles (subtype 2B); subtype 1B spherules whose rims consist of Ti and Fe-oxides (subtype 2C); 3. deformed spherules (subtype 3A) - of all types; (B) subtype 1B spherules are assimilated into groundmass; (C) open spherules or spherules with collapsed rims; and 4. interconnected spherules of type 1A. A few spherules show botryoidal devitrification textures interpreted to result from rapid cooling/devitrification of former melt droplets. SL 15 at a depth of 145 m is unique in being the only grain-size sorted SL; this bed may have been deposited by fallout through a water column. The SL and their host rocks can be easily distinguished by their significant differences in micro-XRF elemental distribution maps. Depending on which aspects of the SLs are primarily considered (such as similar geochemistry, similar layering, SL occurrences abundant at three different depth intervals), the 17 CT3 SLs can be assigned to three or up to 13 individual impact events. Uncertainty about the actual number of impact events represented remains, however, due to the complex folding deformation observed throughout the drill core. KW - Archean spherule layers KW - Barberton Greenstone Belt KW - Petrography KW - Micro-XRF KW - Record of multiple impacts Y1 - 2017 U6 - https://doi.org/10.1016/j.jafrearsci.2017.11.020 SN - 1464-343X SN - 1879-1956 VL - 138 SP - 264 EP - 288 PB - Elsevier Science CY - Oxford ER - TY - JOUR A1 - Nabhan, Sami A1 - Luber, Tim A1 - Scheffler, Franziska A1 - Heubeck, Christoph T1 - Climatic and geochemical implications of Archean pedogenic gypsum in the Moodies Group (similar to 3.2 Ga), Barberton Greenstone Belt, South Africa JF - Precambrian research N2 - Lithic sandstones of braided-fluvial to supratidal facies in the Paleoarchean Moodies Group (similar to 3.22 Ga, Barberton Greenstone Belt, South Africa) include several regionally traceable units with common to abundant, in places rock-forming, nodular concretions of megaquartz pseudomorphs after gypsum, barite and calcite. Concretionary accumulations are stratiform and commonly associated with aqueously reworked, fine-grained, tuffaceous sediment of originally rhyodacitic composition and can grow to fist sized agglomerates in crusts tens of m in lateral extent. Weathering of tuffaceous material and feldspar delivered alkali cations such as Ca, Ba, and K, while carbonates were likely supplied by silicate weathering of mafic to ultramafic volcanic rocks during exposure to a CO2-rich atmosphere. Sulfate ions were partly delivered by oxidative pyrite dissolution which may have included microbial and abiotic disproportionation of volcanic S or SO2. Concretionary growth apparently took place under pedogenic to early diagenetic conditions within unconsolidated granular sediment in the vadose zone, dominated by seasonal fluctuations of the groundwater level under evaporitic conditions. The concretions likely represent the oldest terrestrial evaporites known to date and form part of the oldest known compound paleosols. Their formation and composition constrain the local occurrence of sulfate in the Archean atmo- and hydrosphere, their interaction with the emerging biosphere, Archean weathering regime, local climate, and vadose-zone hydrodynamics. (C) 2016 Elsevier B.V. All rights reserved. KW - Barberton Greenstone Belt KW - Archean KW - Moodies Group KW - Evaporites KW - Sulfate KW - Paleosol Y1 - 2016 U6 - https://doi.org/10.1016/j.precamres.2016.01.011 SN - 0301-9268 SN - 1872-7433 VL - 275 SP - 119 EP - 134 PB - Elsevier CY - Amsterdam ER -