TY - JOUR A1 - Qiu, Xunlin A1 - Benjamin, Aravindan Joseph A1 - Raman Venkatesan, Thulasinath A1 - Schmidt, Georg C. A1 - Soler, Ricardo Alonso Quintana A1 - Panicker, Pramul Muraleedhara A1 - Gerhard, Reimund A1 - Hübler, Arved Carl T1 - Dielectric and electroacoustic assessment of screen-printed piezoelectric polymer layers as flexible transducers BT - influence of the electrode material JF - IEEE transactions on dielectrics and electrical insulation N2 - Here, piezoelectric transducers consisting of a P(VDF-TrFE) layer with either silver or PEDOT:PSS screen-printed electrodes are studied. The influence of electrodes on the dielectric and electroacoustic properties are studied in dielectric-spectroscopy and ferroelectric-hysteresis measurements. Only when both the bottom and the top electrodes are made of silver, the typical dielectric relaxation of the P(VDF-TrFE) layer is clearly observed. When one or two of the electrodes are of PEDOT:PSS, a Debye-like relaxation is present. Compared with silver electrodes, PEDOT:PSS electrodes allow for moderate self-healing. Consequently, samples with bottom and top PEDOT:PSS electrodes can be poled to saturation, while samples with silver electrodes can hardly be poled to saturation due to destructive electric breakdown. Acoustic transducer measurements show that silver electrodes facilitate higher and broader frequency operation, while PEDOT:PSS electrodes bring slightly lower total harmonic distortion. Overall, the acoustic performance shows no significant deviations between differently electroded samples so that silver electrodes do not offer any advantages for the transducers studied here due to their much higher tendency for destructive electric breakdown. KW - poly(vinylidenefluoride-trifluoroethylene) P(VDF-TrFE) KW - dielectric KW - spectroscopy KW - ferroelectricity and piezoelectricity in polymers KW - screen KW - printing KW - printed electroacoustic thin-film transducers Y1 - 2020 U6 - https://doi.org/10.1109/TDEI.2020.008864 SN - 1070-9878 SN - 1558-4135 SN - 0018-9367 VL - 27 IS - 5 SP - 1683 EP - 1690 PB - Institute of Electrical and Electronics Engineers CY - New York, NY ER - TY - JOUR A1 - Schneider, Matthias A1 - Fritzsche, Nora A1 - Puciul-Malinowska, Agnieszka A1 - Baliś, Andrzej A1 - Mostafa, Amr A1 - Bald, Ilko A1 - Zapotoczny, Szczepan A1 - Taubert, Andreas T1 - Surface etching of 3D printed poly(lactic acid) with NaOH BT - a systematic approach JF - Polymers N2 - The article describes a systematic investigation of the effects of an aqueous NaOH treatment of 3D printed poly(lactic acid) (PLA) scaffolds for surface activation. The PLA surface undergoes several morphology changes and after an initial surface roughening, the surface becomes smoother again before the material dissolves. Erosion rates and surface morphologies can be controlled by the treatment. At the same time, the bulk mechanical properties of the treated materials remain unaltered. This indicates that NaOH treatment of 3D printed PLA scaffolds is a simple, yet viable strategy for surface activation without compromising the mechanical stability of PLA scaffolds. KW - surface modification KW - sodium hydroxide etching KW - poly(lactic acid) KW - 3D KW - printing KW - roughness KW - wettability KW - erosion Y1 - 2020 U6 - https://doi.org/10.3390/polym12081711 SN - 2073-4360 VL - 12 IS - 8 PB - MDPI CY - Basel ER -