TY - JOUR A1 - Lange, Dietrich A1 - Bedford, J. R. A1 - Moreno, M. A1 - Tilmann, F. A1 - Báez, Juan Carlos A1 - Bevis, M. A1 - Krüger, Frank T1 - Comparison of postseismic afterslip models with aftershock seismicity for three subduction-zone earthquakes: Nias 2005, Maule 2010 and Tohoku 2011 JF - Geophysical journal international N2 - We focus on the relation between seismic and total postseismic afterslip following the Maule M-w 8.8 earthquake on 2010 February 27 in central Chile. First, we calculate the cumulative slip released by aftershock seismicity. We do this by summing up the aftershock regions and slip estimated from scaling relations. Comparing the cumulative seismic slip with afterslip modelswe showthat seismic slip of individual aftershocks exceeds locally the inverted afterslip model from geodetic constraints. As the afterslip model implicitly contains the displacements from the aftershocks, this reflects the tendency of afterslip models to smear out the actual slip pattern. However, it also suggests that locally slip for a number of the larger aftershocks exceeds the aseismic slip in spite of the fact that the total equivalent moment of the afterslip exceeds the cumulative moment of aftershocks by a large factor. This effect, seen weakly for the Maule 2010 and also for the Tohoku 2011 earthquake, can be explained by taking into account the uncertainties of the seismicity and afterslip models. In spite of uncertainties, the hypocentral region of the Nias 2005 earthquake is suggested to release a large fraction of moment almost purely seismically. Therefore, these aftershocks are not driven solely by the afterslip but instead their slip areas have probably been stressed by interseismic loading and the mainshock rupture. In a second step, we divide the megathrust of the Maule 2010 rupture into discrete cells and count the number of aftershocks that occur within 50 km of the centre of each cell as a function of time. We then compare this number to a time-dependent afterslip model by defining the 'afterslip to aftershock ratio' (ASAR) for each cell as the slope of the best fitting line when the afterslip at time t is plotted against aftershock count. Although we find a linear relation between afterslip and aftershocks for most cells, there is significant variability in ASAR in both the downdip and along-strike directions of the megathrust. We compare the spatial distribution of ASAR with the spatial distribution of seismic coupling, coseismic slip and Bouguer gravity anomaly, and in each case we find no significant correlation. KW - Creep and deformation KW - Earthquake dynamics KW - Seismicity and tectonics KW - Continental margins: convergent Y1 - 2014 U6 - https://doi.org/10.1093/gji/ggu292 SN - 0956-540X SN - 1365-246X VL - 199 IS - 2 SP - 784 EP - 799 PB - Oxford Univ. Press CY - Oxford ER - TY - JOUR A1 - Douglas, John A1 - Akkar, Sinan A1 - Ameri, Gabriele A1 - Bard, Pierre-Yves A1 - Bindi, Dino A1 - Bommer, Julian J. A1 - Bora, Sanjay Singh A1 - Cotton, Fabrice A1 - Derras, Boumediene A1 - Hermkes, Marcel A1 - Kuehn, Nicolas Martin A1 - Luzi, Lucia A1 - Massa, Marco A1 - Pacor, Francesca A1 - Riggelsen, Carsten A1 - Sandikkaya, M. Abdullah A1 - Scherbaum, Frank A1 - Stafford, Peter J. A1 - Traversa, Paola T1 - Comparisons among the five ground-motion models developed using RESORCE for the prediction of response spectral accelerations due to earthquakes in Europe and the Middle East JF - Bulletin of earthquake engineering : official publication of the European Association for Earthquake Engineering N2 - This article presents comparisons among the five ground-motion models described in other articles within this special issue, in terms of data selection criteria, characteristics of the models and predicted peak ground and response spectral accelerations. Comparisons are also made with predictions from the Next Generation Attenuation (NGA) models to which the models presented here have similarities (e.g. a common master database has been used) but also differences (e.g. some models in this issue are nonparametric). As a result of the differing data selection criteria and derivation techniques the predicted median ground motions show considerable differences (up to a factor of two for certain scenarios), particularly for magnitudes and distances close to or beyond the range of the available observations. The predicted influence of style-of-faulting shows much variation among models whereas site amplification factors are more similar, with peak amplification at around 1s. These differences are greater than those among predictions from the NGA models. The models for aleatory variability (sigma), however, are similar and suggest that ground-motion variability from this region is slightly higher than that predicted by the NGA models, based primarily on data from California and Taiwan. KW - Strong-motion data KW - Ground-motion models KW - Ground-motion prediction equations KW - Style of faulting KW - Site amplification KW - Aleatory variability KW - Epistemic uncertainty KW - Europe KW - Middle East Y1 - 2014 U6 - https://doi.org/10.1007/s10518-013-9522-8 SN - 1570-761X SN - 1573-1456 VL - 12 IS - 1 SP - 341 EP - 358 PB - Springer CY - Dordrecht ER - TY - JOUR A1 - Spörer, Nadine A1 - Schuenemann, Nina T1 - competence: Analyzing effects on reading comprehension, reading strategy performance, and motivation for reading JF - Learning and instruction : the journal of the European Association for Research on Learning and Instruction N2 - In this study, reciprocal teaching (RT) was combined with specific self-regulation procedures to promote the reading comprehension of fifth grade students. Twenty four classes with N = 534 students were assigned to RT plus strategy implementation procedures (RT +SIP), RT plus outcome regulation procedures (RT + ORP), RT plus strategy implementation and outcome regulation procedures (RT+ SRL), or RT without explicit instruction in self-regulation. At maintenance students assigned to the three self-regulation conditions outperformed RT students according to a standardized measure of reading comprehension. RT+ SIP and RT + SRL students outperformed RI as well as RI + ORP students using a measure of reading strategy performance. However, reading comprehension was only mediated by strategy performance under the RT + SRL condition. Among students assigned to the RI + ORP condition, an improvement in reading motivation between pretest and posttest and between posttest and maintenance was observed. (C) 2014 Elsevier Ltd. All rights reserved. KW - Reading comprehension KW - Self-regulated learning KW - Reading strategies KW - Educational intervention research Y1 - 2014 U6 - https://doi.org/10.1016/j.learninstruc.2014.05.002 SN - 0959-4752 VL - 33 SP - 147 EP - 157 PB - Elsevier CY - Oxford ER - TY - JOUR A1 - Huber, Jasmina T1 - Competing Musical Traditions in the Holy Land in the 20th Century and How They Found Their Way into the Synagogue of Belgrade JF - PaRDeS : Zeitschrift der Vereinigung für Jüdische Studien e.V. N2 - The development of the current liturgical music used in the Belgrade synagogue is (in the last decades) heavily influenced by foreign traditions (mostly levantine) that are brought to Belgrade by modern communication systems. Therefore it is nearly impossible to speak of a status quo that might be possibly obsolete by tomorrow – at least with respect to the melodies. The great changes within the liturgical music occurred not due to acculturation into the Serbian majority but due to the personal preferences of the religious leaders of the Belgrade Jews. The alterations are a conscious process which is precisely the consequence of the musical taste of the local Rabbi and Cantor and not occurring autonomously. In order to understand the new nusah sepharadiyerushalmi that took the place of the forlorn nusah after the downfall of the Communist regime it is deemed necessary to look towards Israel where the rite developed. N2 - Die Analyse der Entwicklung der aktuellen liturgischen Musik in der Belgrader Synagoge zeigt, dass sie in den letzten Jahrzehnten mittels moderner Medien vielen Fremdeinflüssen, zumeist levantinischen, ausgesetzt war. Es ist daher fast unmöglich, von einem Status quo zu sprechen, da dieser alsbald zumindest in der Melodienwahl veraltet sein könnte. Der Wandel in den letzten zwanzig Jahren erfolgte nicht aufgrund von Akkulturation durch den Kontakt mit Serben, sondern auf Basis der individuellen musikalischen Präferenzen des Rabbiners und Kantors. Es ist kein Prozess, der automatisch als Anpassung abläuft, sondern bewusst gesteuerte Veränderung. Um den nach dem Fall des Kommunismus eingepflanzten neuen Ritus unter dem Namen nusah sepharadi-yerushalmi in seiner Entwicklung zu verstehen, muss man den regionalen Boden temporär verlassen und sich mit der ersten großen Aliah nach Israel begeben, um von dort aus seine Entstehung, Beschaffenheit und Verbreitung zurückzuverfolgen. Y1 - 2014 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus4-69234 SN - 1614-6492 SN - 1862-7684 VL - 20 SP - 87 EP - 98 PB - Universitätsverlag Potsdam CY - Potsdam ER - TY - THES A1 - Yeldesbay, Azamat T1 - Complex regimes of synchronization T1 - Komplexe Synchronisationszustände BT - modeling and analysis N2 - Synchronization is a fundamental phenomenon in nature. It can be considered as a general property of self-sustained oscillators to adjust their rhythm in the presence of an interaction. In this work we investigate complex regimes of synchronization phenomena by means of theoretical analysis, numerical modeling, as well as practical analysis of experimental data. As a subject of our investigation we consider chimera state, where due to spontaneous symmetry-breaking of an initially homogeneous oscillators lattice split the system into two parts with different dynamics. Chimera state as a new synchronization phenomenon was first found in non-locally coupled oscillators system, and has attracted a lot of attention in the last decade. However, the recent studies indicate that this state is also possible in globally coupled systems. In the first part of this work, we show under which conditions the chimera-like state appears in a system of globally coupled identical oscillators with intrinsic delayed feedback. The results of the research explain how initially monostable oscillators became effectivly bistable in the presence of the coupling and create a mean field that sustain the coexistence of synchronized and desynchronized states. Also we discuss other examples, where chimera-like state appears due to frequency dependence of the phase shift in the bistable system. In the second part, we make further investigation of this topic by modeling influence of an external periodic force to an oscillator with intrinsic delayed feedback. We made stability analysis of the synchronized state and constructed Arnold tongues. The results explain formation of the chimera-like state and hysteric behavior of the synchronization area. Also, we consider two sets of parameters of the oscillator with symmetric and asymmetric Arnold tongues, that correspond to mono- and bi-stable regimes of the oscillator. In the third part, we demonstrate the results of the work, which was done in collaboration with our colleagues from Psychology Department of University of Potsdam. The project aimed to study the effect of the cardiac rhythm on human perception of time using synchronization analysis. From our part, we made a statistical analysis of the data obtained from the conducted experiment on free time interval reproduction task. We examined how ones heartbeat influences the time perception and searched for possible phase synchronization between heartbeat cycles and time reproduction responses. The findings support the prediction that cardiac cycles can serve as input signals, and is used for reproduction of time intervals in the range of several seconds. N2 - Synchronisation ist ein fundamentales Naturphänomen. Es ist die grundlegende Eigenschaft sich selbsterhaltender Oszillatoren, in Gegenwart einer Wechselwirkung, danach zu streben, ihre Rhythmen anzupassen. In dieser Arbeit betrachten wir komplexe Synchronisationszustände sowohl mit Hilfe analytischer Methoden als auch durch numerische Simulation und in experimentellen Daten. Unser Untersuchungsobjekt sind die sogenannten Chimera Zustände, in welchen sich Ensemble von gekoppelten, identischen Oszillatoren auf Grund eines Symmetriebruches spontan in Gruppen mit unterschiedlicher Dynamik aufteilen. Die Entdeckung von Chimeras in zunächst nichtlokal gekoppelten Systemen hat in den letzten zehn Jahren ein großes Interesse an neuartigen Synchronisationsphänomenen geweckt. Neueste Forschungsergebnisse belegen, dass diese Zustände unter bestimmten Bedingungen auch in global gekoppelten Systemen existieren können. Solche Bedingungen werden im ersten Teil der Arbeit in Ensemblen global gekoppelter Oszillatoren mit zusätzlicher, zeitverzögerter Selbstkopplung untersucht. Wir zeigen, wie zunächst monostabile Oszillatoren in Gegenwart von dem Treiben der globalen Kopplung effektiv bistabil werden, und sich so in zwei Gruppen organisieren. Das mittlere Feld, welches durch diese Gruppen aufgebaut wird, ist quasiperiodisch wodurch der Chimera Zustand sich selbst stabilisiert. In einem anderen Beispiel zeigen wir, dass der Chimera Zustand auch durch einen frequenzabhängigen Phasenunterschied in der globalen Kopplung erreicht werden kann. Zur genaueren Untersuchung der Mechanismen, die zur effektiven Bistabilität führen, betrachten wir im zweiten Teil der Arbeit den Einfluss einer externen periodischen Kraft auf einzelne Oszillatoren mit zeitverzögerter Selbstkopplung. Wir führen die Stabilitätanalyse des synchronen Zustands durch, und stellen die Arnoldzunge dar. Im dritten Teil der Arbeit stellen wir die Ergebnisse einer Synchronisationsanalyse vor, welche in Kooperation mit Wissenschaftlern der Psychologischen Fakultät der Universität Potsdam durchgeführt wurde. In dem Projekt wurde die Auswirkung des Herzrhythmus auf die menschliche Zeitwahrnehmung erforscht. Unsere Aufgabe war es, die experimentellen Daten statistisch zu analysieren. Im Experiment sollten Probanden ein gegebenes Zeitintervall reproduzieren während gleichzeitig ihr Herzschlag aufgezeichnet wurde. Durch eine Phasenanalyse haben wir den Zusammenhang zwischen dem Herzschlag und der Start- bzw. Stoppzeit der zu reproduzierenden Zeitintervalle untersucht. Es stellt sich heraus, dass Herzschläge bei Zeitintervallen über einige Sekunden als Taktgeber dienen können. KW - synchronization KW - phase oscillators KW - chimera state KW - time perception KW - Synchronisation KW - Phasen Oszillatoren KW - chimera Zustände KW - zeitverzögerte Selbstkopplung KW - Synchronisationsanalyse KW - Zeitwahrnehmung Y1 - 2014 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus4-73348 ER - TY - JOUR A1 - Lorenz, Antje A1 - Heide, Judith A1 - Burchert, Frank T1 - Compound naming in aphasia: effects of complexity, part of speech, and semantic transparency JF - Language, cognition and neuroscience KW - compound production KW - morphology KW - decomposition KW - lemma KW - part of speech KW - semantic transparency KW - aphasia KW - word-finding difficulties Y1 - 2014 U6 - https://doi.org/10.1080/01690965.2013.766357 SN - 2327-3798 SN - 2327-3801 VL - 29 IS - 1 SP - 88 EP - 106 PB - Routledge, Taylor & Francis Group CY - Abingdon ER - TY - THES A1 - Brandt-Kobele, Oda-Christina T1 - Comprehension of verb inflection in German-speaking children T1 - Das Verständnis von Verbflexionsendungen bei deutschsprachigen Kindern N2 - Previous studies on the acquisition of verb inflection in normally developing children have revealed an astonishing pattern: children use correctly inflected verbs in their own speech but fail to make use of verb inflections when comprehending sentences uttered by others. Thus, a three-year old might well be able to say something like ‘The cat sleeps on the bed’, but fails to understand that the same sentence, when uttered by another person, refers to only one sleeping cat but not more than one. The previous studies that have examined children's comprehension of verb inflections have employed a variant of a picture selection task in which the child was asked to explicitly indicate (via pointing) what semantic meaning she had inferred from the test sentence. Recent research on other linguistic structures, such as pronouns or focus particles, has indicated that earlier comprehension abilities can be found when methods are used that do not require an explicit reaction, like preferential looking tasks. This dissertation aimed to examine whether children are truly not able to understand the connection the the verb form and the meaning of the sentence subject until the age of five years or whether earlier comprehension can be found when a different measure, preferential looking, is used. Additionally, children's processing of subject-verb agreement violations was examined. The three experiments of this thesis that examined children's comprehension of verb inflections revealed the following: German-speaking three- to four-year old children looked more to a picture showing one actor when hearing a sentence with a singular inflected verb but only when their eye gaze was tracked and they did not have to perform a picture selection task. When they were asked to point to the matching picture, they performed at chance-level. This pattern indicates asymmetries in children's language performance even within the receptive modality. The fourth experiment examined sensitivity to subject-verb agreement violations and did not reveal evidence for sensitivity toward agreement violations in three- and four-year old children, but only found that children's looking patterns were influenced by the grammatical violations at the age of five. The results from these experiments are discussed in relation to the existence of a production-comprehension asymmetry in the use of verb inflections and children's underlying grammatical knowledge. N2 - Experimentelle Studien zum Erwerb der Verbflexion bei sprachunauffälligen Kindern haben ein überraschendes Muster aufgezeigt. Kinder im Alter von drei und vier Jahren verwenden Verbflexionsendungen anscheinend korrekt in ihrer eigenen Sprachproduktion, aber sie scheinen unfähig zu sein, Verbflexionen in den Äußerungen anderer zu verstehen. Ein Kind ist also problemlos in der Lage “Sie schläft auf dem Bett.” zu sagen, wenn es die Position von z. B. einer Katze beschreiben möchte. Gleichzeitig scheint es nicht zu verstehen, dass sich ein Satz wie “Sie schläft auf dem Bett” auf nur eine schlafende Katze und nicht mehrere bezieht. Das Verständnis von Sätzen, in denen der einzige Hinweis auf die Anzahl der Handelnden (den Numerus des Subjekts) die Verbflexion ist, wurde bislang nur mit ‘Zeige-Experimenten’ untersucht. In solchen Sprachtests soll das Kind durch eine Zeigegeste auf eines von zwei vorgegebenen Bildern explizit anzeigen wie es den vorgegebenen Satz verstanden hat. Aktuelle Studien, die das Verständnis von sprachlichen Elementen wie Pronomen und Fokuspartikeln bei Kindern untersucht haben, lassen erkennen, dass die Testmethodik einen erheblichen Einfluss auf die kindlichen Sprachverständnisfähigkeiten zu haben scheint. Wenn man Methoden verwendet, die keine explizite Reaktion von Seiten der Kinder verlangen, findet man korrektes Verständnis schon bei jüngeren Kindern. Das Ziel dieser Dissertation war es zu untersuchen, ob drei- und vierjährige Kinder tatsächlich nicht in der Lage sind die Beziehung zwischen Verbform (Art der Verbflexion) und Subjektbedeutung (Numerus des Subjekts) zu verstehen oder ob man korrektes Sprachverständnis in jüngeren Populationen finden kann, wenn eine alternative Testmethode, die Messung der Augenbewegungen, verwendet wird. Zusätzlich wurde untersucht ob Kinder im gleichen Alter Verletzungen der Subjekt-Verb-Kongruenz in auditiv präsentierten Sätzen entdecken. Drei Experimente dieser Dissertation, die das kindliche Sprachverständnis in Bezug auf Verbflexion untersucht haben bringen folgendes Muster zum Vorschein: Deutsch-sprachige Kinder im Alter von drei bis vier Jahren schauten mehr zu einem Bild, auf dem nur ein Akteur zu sehen war, wenn sie einen Satz mit einem singular flektierten Verb hörten (Sie streichelt eine Katze). Andererseits schauten sie mehr zu einem Bild, auf dem zwei Akteure zu sehen waren, wenn sie einen Satz mit einem plural flektierten Verb hörten (Sie streicheln eine Katze). Wenn sie hingegen gebeten wurden, auf das korrekte Bild zu zeigen, reagierten sie nicht besser als es der Zufall erwartet hätte, d.h.~sie waren nicht in der Lage einen Satz einem entsprechenden Bild zuzuordnen. Dieses Ergebnismuster deutet auf die Existenz von (methoden-abhängigen) Asymmetrien innerhalb einer sprachlichen Modalität, dem Sprach\-verständnis, hin. Das vierte Experiment untersuchte die kindliche Sensitivität gegenüber der Verletzung von Subjekt-Verb-Kongruenz. Hier zeigte sich, dass das Blickverhalten von fünfjährigen Kindern von der Grammatikalität der Testsätze beeinflusst war, während keine Evidenz für das Erkennen von Grammatikalitätsverletzungen bei jüngeren Kindern gefunden werden konnte. Das asymmetrische Performanzmuster innerhalb der rezeptiven Modalität, das in dieser Arbeit gefunden wurde, erlaubt Rückschlüsse auf die Annahme einer Produktions-Verständnis-Aymmetrie und somit auch auf Theorien zur grammatischen Entwicklung bei Kindern. T3 - Spektrum Patholinguistik - Schriften - 6 KW - Spracherwerb KW - Verbflexion KW - Blickbewegungsmessung KW - Methoden KW - Sprachverständnis KW - Language acquisition KW - verb inflection KW - eye-tracking KW - methods KW - language comprehension Y1 - 2014 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus-62046 SN - 978-3-86956-216-2 SN - 1869-3822 SN - 1869-3830 PB - Universitätsverlag Potsdam CY - Potsdam ER - TY - JOUR A1 - Richter, Rico A1 - Döllner, Jürgen Roland Friedrich T1 - Concepts and techniques for integration, analysis and visualization of massive 3D point clouds JF - Computers, environment and urban systems N2 - Remote sensing methods, such as LiDAR and image-based photogrammetry, are established approaches for capturing the physical world. Professional and low-cost scanning devices are capable of generating dense 3D point clouds. Typically, these 3D point clouds are preprocessed by GIS and are then used as input data in a variety of applications such as urban planning, environmental monitoring, disaster management, and simulation. The availability of area-wide 3D point clouds will drastically increase in the future due to the availability of novel capturing methods (e.g., driver assistance systems) and low-cost scanning devices. Applications, systems, and workflows will therefore face large collections of redundant, up-to-date 3D point clouds and have to cope with massive amounts of data. Hence, approaches are required that will efficiently integrate, update, manage, analyze, and visualize 3D point clouds. In this paper, we define requirements for a system infrastructure that enables the integration of 3D point clouds from heterogeneous capturing devices and different timestamps. Change detection and update strategies for 3D point clouds are presented that reduce storage requirements and offer new insights for analysis purposes. We also present an approach that attributes 3D point clouds with semantic information (e.g., object class category information), which enables more effective data processing, analysis, and visualization. Out-of-core real-time rendering techniques then allow for an interactive exploration of the entire 3D point cloud and the corresponding analysis results. Web-based visualization services are utilized to make 3D point clouds available to a large community. The proposed concepts and techniques are designed to establish 3D point clouds as base datasets, as well as rendering primitives for analysis and visualization tasks, which allow operations to be performed directly on the point data. Finally, we evaluate the presented system, report on its applications, and discuss further research challenges. KW - 3D point clouds KW - System architecture KW - Classification KW - Out-of-core KW - Visualization Y1 - 2014 U6 - https://doi.org/10.1016/j.compenvurbsys.2013.07.004 SN - 0198-9715 SN - 1873-7587 VL - 45 SP - 114 EP - 124 PB - Elsevier CY - Oxford ER - TY - JOUR A1 - Plehn, Thomas A1 - Megow, Jörg A1 - May, Volkhard T1 - Concerted charge and energy transfer processes in a highly flexible fullerene-dye system: a mixed quantum-classical study JF - Physical chemistry, chemical physics : a journal of European Chemical Societies N2 - Photoinduced excitation energy transfer and accompanying charge separation are elucidated for a supramolecular system of a single fullerene covalently linked to six pyropheophorbide-a dye molecules. Molecular dynamics simulations are performed to gain an atomistic picture of the architecture and the surrounding solvent. Excitation energy transfer among the dye molecules and electron transfer from the excited dyes to the fullerene are described by a mixed quantum-classical version of the Forster rate and the semiclassical Marcus rate, respectively. The mean characteristic time of energy redistribution lies in the range of 10 ps, while electron transfer proceeds within 150 ps. In between, on a 20 to 50 ps time-scale, conformational changes take place in the system. This temporal hierarchy of processes guarantees efficient charge separation, if the structure is exposed to a solvent. The fast energy transfer can adopt the dye excitation to the actual conformation. In this sense, the probability to achieve charge separation is large enough since any dominance of unfavorable conformations that exhibit a large dye-fullerene distance is circumvented. And the slow electron transfer may realize an averaging with respect to different conformations. To confirm the reliability of our computations, ensemble measurements on the charge separation dynamics are simulated and a very good agreement with the experimental data is obtained. Y1 - 2014 U6 - https://doi.org/10.1039/c4cp01081g SN - 1463-9076 SN - 1463-9084 VL - 16 IS - 25 SP - 12949 EP - 12958 PB - Royal Society of Chemistry CY - Cambridge ER - TY - GEN A1 - Plehn, Thomas A1 - Megow, Jörg A1 - May, Volkhard T1 - Concerted charge and energy transfer processes in a highly flexible fullerene–dye system BT - a mixed quantum–classical study N2 - Photoinduced excitation energy transfer and accompanying charge separation are elucidated for a supramolecular system of a single fullerene covalently linked to six pyropheophorbide-a dye molecules. Molecular dynamics simulations are performed to gain an atomistic picture of the architecture and the surrounding solvent. Excitation energy transfer among the dye molecules and electron transfer from the excited dyes to the fullerene are described by a mixed quantum–classical version of the Förster rate and the semiclassical Marcus rate, respectively. The mean characteristic time of energy redistribution lies in the range of 10 ps, while electron transfer proceeds within 150 ps. In between, on a 20 to 50 ps time-scale, conformational changes take place in the system. This temporal hierarchy of processes guarantees efficient charge separation, if the structure is exposed to a solvent. The fast energy transfer can adopt the dye excitation to the actual conformation. In this sense, the probability to achieve charge separation is large enough since any dominance of unfavorable conformations that exhibit a large dye–fullerene distance is circumvented. And the slow electron transfer may realize an averaging with respect to different conformations. To confirm the reliability of our computations, ensemble measurements on the charge separation dynamics are simulated and a very good agreement with the experimental data is obtained. T3 - Zweitveröffentlichungen der Universität Potsdam : Mathematisch-Naturwissenschaftliche Reihe - 279 Y1 - 2014 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus4-98791 ER -