TY - GEN A1 - Spiekermann, Georg A1 - Harder, M. A1 - Gilmore, Keith A1 - Zalden, Peter A1 - Sahle, Christoph J. A1 - Petitgirard, Sylvain A1 - Wilke, Max A1 - Biedermann, Nicole A1 - Weis, Thomas A1 - Morgenroth, Wolfgang A1 - Tse, John S. A1 - Kulik, E. A1 - Nishiyama, Norimasa A1 - Yavaş, Hasan A1 - Sternemann, Christian T1 - Persistent Octahedral Coordination in Amorphous GeO₂ Up to 100 GPa by Kβ'' X-Ray Emission Spectroscopy T2 - Postprints der Universität Potsdam Mathematisch-Naturwissenschaftliche Reihe N2 - We measure valence-to-core x-ray emission spectra of compressed crystalline GeO₂ up to 56 GPa and of amorphous GeO₂ up to 100 GPa. In a novel approach, we extract the Ge coordination number and mean Ge-O distances from the emission energy and the intensity of the Kβ'' emission line. The spectra of high-pressure polymorphs are calculated using the Bethe-Salpeter equation. Trends observed in the experimental and calculated spectra are found to match only when utilizing an octahedral model. The results reveal persistent octahedral Ge coordination with increasing distortion, similar to the compaction mechanism in the sequence of octahedrally coordinated crystalline GeO₂ high-pressure polymorphs. T3 - Zweitveröffentlichungen der Universität Potsdam : Mathematisch-Naturwissenschaftliche Reihe - 699 KW - rutile-type KW - glass KW - crystalline KW - pressures KW - complexes KW - silicon KW - oxygen KW - SIO₂ KW - MO KW - CU Y1 - 2019 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus4-427755 SN - 1866-8372 IS - 699 ER - TY - JOUR A1 - Spiekermann, Georg A1 - Harder, M. A1 - Gilmore, Keith A1 - Zalden, Peter A1 - Sahle, Christoph J. A1 - Petitgirard, Sylvain A1 - Wilke, Max A1 - Biedermann, Nicole A1 - Weis, Thomas A1 - Morgenroth, Wolfgang A1 - Tse, John S. A1 - Kulik, E. A1 - Nishiyama, Norimasa A1 - Yavaş, Hasan A1 - Sternemann, Christian T1 - Persistent Octahedral Coordination in Amorphous GeO₂ Up to 100 GPa by Kβ'' X-Ray Emission Spectroscopy JF - Physical Review X N2 - We measure valence-to-core x-ray emission spectra of compressed crystalline GeO₂ up to 56 GPa and of amorphous GeO₂ up to 100 GPa. In a novel approach, we extract the Ge coordination number and mean Ge-O distances from the emission energy and the intensity of the Kβ'' emission line. The spectra of high-pressure polymorphs are calculated using the Bethe-Salpeter equation. Trends observed in the experimental and calculated spectra are found to match only when utilizing an octahedral model. The results reveal persistent octahedral Ge coordination with increasing distortion, similar to the compaction mechanism in the sequence of octahedrally coordinated crystalline GeO₂ high-pressure polymorphs. KW - rutile-type KW - glass KW - crystalline KW - pressures KW - complexes KW - silicon KW - oxygen KW - SIO₂ KW - MO KW - CU Y1 - 2019 U6 - https://doi.org/10.1103/PhysRevX.9.011025 SN - 2469-9926 SN - 0556-2791 SN - 1050-2947 SN - 1094-1622 VL - 9 IS - 1 PB - American Physical Society by the American Institute of Physics CY - Melville, NY ER - TY - GEN A1 - Löhmannsröben, Hans-Gerd A1 - Beck, Michael A1 - Hildebrandt, Niko A1 - Schmälzlin, Elmar A1 - van Dongen, Joost T. T1 - New challenges in biophotonics : laser-based fluoroimmuno analysis and in-vivo optical oxygen monitoring N2 - Two examples of our biophotonic research utilizing nanoparticles are presented, namely laser-based fluoroimmuno analysis and in-vivo optical oxygen monitoring. Results of the work include significantly enhanced sensitivity of a homogeneous fluorescence immunoassay and markedly improved spatial resolution of oxygen gradients in root nodules of a legume species. T3 - Zweitveröffentlichungen der Universität Potsdam : Mathematisch-Naturwissenschaftliche Reihe - paper 018 KW - Sauerstoff KW - Quantenpunkt KW - Lumineszenz KW - Immunoassay KW - Energietransfer KW - Fluoreszenz-Resonanz-Energie-Transfer KW - Nanopartikel KW - Lanthanoide KW - Optode KW - Förster Resonanz Energie Transfer KW - Biophotonik KW - biophotonics KW - nanoparticles KW - immunoassay KW - oxygen KW - optode Y1 - 2006 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus-10120 ER - TY - JOUR A1 - Pilar Yeste, Maria A1 - Carlos Hernandez-Garrido, Juan A1 - Kumke, Michael Uwe A1 - Alvarado, Sarah A1 - Cauqui, Miguel Angel A1 - Juan Calvino, Jose A1 - Primus, Philipp-Alexander T1 - Low-temperature growth of reactive pyrochlore nanostructures on Zirconia-supported ceria BT - implications for improved catalytic behavior JF - ACS applied nano materials N2 - The use of a catalyst support for the design of nanoscale heterogeneous catalysts based on cerium oxide offers vast possibilities for future catalyst development, particularly with regard to an increased focus on the use of renewable biogas and an emerging hydrogen economy. In this study, zirconia-supported ceria catalysts were synthesized, activated by using different thermochemical treatments, and characterized by way of temperature-programmed reduction (TPR), oxygen storage capacity, Xray diffraction, electron microscopy, and luminescence spectroscopy using Eu3+ as a spectroscopic probe. Through reduction-oxidation pretreatment routines, reactive pyrochlore structures were created at temperatures as low as 600 degrees C and identified through TPR and electron microscopy experiments. A structural relationship and alignment of the crystal planes is revealed in high-resolution scanning transmission electron microscopy experiments through the digital diffraction patterns. Low-temperature pretreatment induces the formation of reactive pyrochlore domains under retention of the surface area of the catalyst system, and no further morphological changes are detected. Furthermore, the formation of pyrochlore domains achieved through severe reduction and mild reoxidation (SRMO) treatments is reversible. Over multiple alternating SRMO and severe reduction and severe reoxidation (SRSO) treatments, europium spectroscopy and TPR results indicate that pyrochlore structures are recreated over consecutive treatments, whenever the mild oxidation step at 500 degrees C is the last treatment (SRMO, SRMO-SRSO-SRMO, etc.). KW - pyrochlore KW - nanocomposite KW - ceria KW - zirconia KW - supported catalyst KW - oxygen KW - storage capacity Y1 - 2022 U6 - https://doi.org/10.1021/acsanm.2c00416 SN - 2574-0970 VL - 5 IS - 5 SP - 6316 EP - 6326 PB - American Chemical Society CY - Washington ER - TY - JOUR A1 - Munzke, Dorit A1 - Böhm, Michael A1 - Reich, Oliver T1 - Gaseous Oxygen Detection Using Hollow-Core Fiber-Based Linear Cavity Ring-Down Spectroscopy JF - Journal of lightwave technology N2 - We demonstrate a method for the calibration-free and quantitative analysis of small volumes of gaseous samples. A 10 m hollow-core photonic bandgap fiber is used as the sample cell (volume = 0.44 mu L) and is placed inside a linear resonator setup. The application of cavity ring-down spectroscopy and in consideration of rather small coupling losses, this leads to an increased effective optical path length of up to 70 m. This implies a volume per optical interaction path length of 6.3 nL.m(-1). We used tunable diode laser spectroscopy at 760 nm and scanned the absorption for oxygen sensing. The optical loss due to sample absorption is obtained by measuring the ring-down time of light propagating inside the cavity. The resultant absorption coefficient shows a discrepancy of only 5.1% comparing to the HITRAN database. This approach is applicable for sensitive measurements if only submicroliter sample volumes are available. KW - Cavity ring-down spectroscopy KW - gas sensing KW - hollow-core photonic bandgap fiber KW - oxygen Y1 - 2015 U6 - https://doi.org/10.1109/JLT.2015.2397177 SN - 0733-8724 SN - 1558-2213 VL - 33 IS - 12 SP - 2524 EP - 2529 PB - Inst. of Electr. and Electronics Engineers CY - Piscataway ER - TY - JOUR A1 - Lukas, Marcus A1 - Wacker, Alexander T1 - Constraints by oxygen and food quality on carbon pathway regulation: a co-limitation study with an aquatic key herbivore JF - Ecology : a publication of the Ecological Society of America N2 - In food webs, herbivores are often constrained by low food quality in terms of mineral and biochemical limitations, which in aquatic ecosystems can co-occur with limited oxygen conditions. As low food quality implies that carbon (C) is available in excess, and therefore a regulation to get rid of excess C is crucial for the performance of consumers, we examined the C pathways (ingestion, feces release, excretion, and respiration) of a planktonic key herbivore (Daphnia magna). We tested whether consumer C pathways increase due to mineral (phosphorus, P) or biochemical (cholesterol and fatty acid) limitations and how these regulations vary when in addition oxygen is low. Under such conditions, at least the capability of the upregulation of respiration may be restricted. Furthermore, we discussed the potential role of the oxygen-transporting protein hemoglobin (Hb) in the regulation of C budgets. Different food quality constraints led to certain C regulation patterns to increase the removal of excess dietary C: P-limited D. magna increased excretion and respiration, while cholesterol-limited Daphnia in addition upregulated the release of feces. In contrast, the regulative effort was low and only feces release increased when D. magna was limited by a long-chain polyunsaturated fatty acid (eicosapentaenoic acid, EPA). Co-limiting oxygen did not always impact the discharge of excess C. We found the food-quality-induced upregulation of respiration was still present at low oxygen. In contrast, higher excretion of excess C was diminished at low oxygen supply. Besides the effect that the Hb concentration increased under low oxygen, our results indicate a low food-quality-induced increase in the Hb content of the animals. Overall, C budgeting is phenotypically plastic towards different (co-) limiting scenarios. These trigger specific regulation responses that could be the result of evolutionary adaptations. KW - carbon budget KW - carbon stoichiometry KW - cholesterol KW - co-limitation KW - Daphnia KW - EPA KW - hemoglobin KW - oxygen KW - phosphorus KW - polyunsaturated fatty acid KW - zooplankton Y1 - 2014 SN - 0012-9658 SN - 1939-9170 VL - 95 IS - 11 SP - 3068 EP - 3079 PB - Wiley CY - Washington ER - TY - THES A1 - Rudolph-Mohr, Nicole T1 - A novel non-invasive optical method for quantitative visualization of pH and oxygen dynamics in soils T1 - Entwicklung einer neuen, nicht invasiven, optischen Methode für die quantitative Darstellung von pH und Sauerstoffdynamiken in Böden N2 - In soils and sediments there is a strong coupling between local biogeochemical processes and the distribution of water, electron acceptors, acids and nutrients. Both sides are closely related and affect each other from small scale to larger scales. Soil structures such as aggregates, roots, layers or macropores enhance the patchiness of these distributions. At the same time it is difficult to access the spatial distribution and temporal dynamics of these parameter. Noninvasive imaging techniques with high spatial and temporal resolution overcome these limitations. And new non-invasive techniques are needed to study the dynamic interaction of plant roots with the surrounding soil, but also the complex physical and chemical processes in structured soils. In this study we developed an efficient non-destructive in-situ method to determine biogeochemical parameters relevant to plant roots growing in soil. This is a quantitative fluorescence imaging method suitable for visualizing the spatial and temporal pH changes around roots. We adapted the fluorescence imaging set-up and coupled it with neutron radiography to study simultaneously root growth, oxygen depletion by respiration activity and root water uptake. The combined set up was subsequently applied to a structured soil system to map the patchy structure of oxic and anoxic zones induced by a chemical oxygen consumption reaction for spatially varying water contents. Moreover, results from a similar fluorescence imaging technique for nitrate detection were complemented by a numerical modeling study where we used imaging data, aiming to simulate biodegradation under anaerobic, nitrate reducing conditions. N2 - In Böden und Sedimenten sind biogeochemische Prozesse und die Verteilung von Größen wie Wasser, Elektronenakzeptoren, Säuregehalte und Nährstoffe in enger Weise miteinander gekoppelt. Diese wechselseitige Beeinflussung ist skalenübergreifend und reicht von sehr kleinen bis zu größeren Skalen. Die in realen Böden vorhandene Struktur z. Bsp. Aggregate, Pflanzenwurzeln, Schichten und Makroporen bedingen eine starke räumlich Heterogenität und zeitliche Dynamik dieser Größen. Gleichzeitig sind Verteilung und Dynamik sehr schwer zu beobachten, zumindest ohne ihre gleichzeitige Störung. Bildgebende Verfahren bieten eine sehr gute räumliche und zeitliche Auflösung und ermöglichen die Darstellung dieser Größen. Um die dynamische Wechselwirkung zwischen Pflanzenwurzeln und Boden, aber auch die komplexen physikalisch – chemischen Prozesse in Böden zu verstehen, sind neue bildgebende Verfahren notwendig. Ziel dieser Arbeit war es, eine neue nicht-invasive Methode zu entwickeln, die es ermöglicht biogeochemische Parameter in der Wurzelzone zu visualisieren. Innerhalb dieser Studie wurde ein quantitatives bildgebendes Verfahren entwickelt, dass die räumlichen und zeitlichen Dynamiken des pH Wertes in der Rhizosphäre erfasst. Diese auf Fluoreszenzemissionen basierende Methode wurde ebenso für Sauerstoffdetektion entwickelt und mit Neutronen Radiographie kombiniert um gleichzeitig Aussagen über Wurzelwachstum, Sauerstoffzehrung durch Wurzelatmung und Wurzelwasseraufnahme treffen zu können. Die kombinierte bildgebende Methode wurde dann in einem künstlichen Boden genutzt um Nischen und Übergangsbereiche von Sauerstoff bei variierenden Wassergehalten zu charakterisieren. Das große Potential von bildgebenden Verfahren zeigt sich bei Modellierungsstudien. In dieser Studie wurden Bilddaten als Eingabeparameter für die Simulierung von denitrifizierendem biologischem Schadstoffabbau genutzt. KW - Optische Sensoren KW - pH KW - Sauerstoff KW - Fluoreszenzbildgebung KW - Rhizosphere KW - Optical sensor KW - pH KW - oxygen KW - fluorescence imaging KW - rhizosphere Y1 - 2013 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus-66993 ER -