TY  - JOUR
A1  - Brietzke, Thomas Martin
A1  - Kelling, Alexandra
A1  - Schilde, Uwe
A1  - Mickler, Wulfhard
A1  - Holdt, Hans-Jürgen
T1  - Heterodinuclear Ruthenium(II) Complexes of the Bridging Ligand 1,6,7,12-Tetraazaperylene with Iron(II), Cobalt(II), Nickel(II), as well as Palladium(II) and Platinum(II)
JF  - Zeitschrift für anorganische und allgemeine Chemie
N2  - The first heterodinuclear ruthenium(II) complexes of the 1,6,7,12-tetraazaperylene (tape) bridging ligand with iron(II), cobalt(II), and nickel(II) were synthesized and characterized. The metal coordination sphere in this complexes is filled by the tetradentate N,N-dimethyl-2,11-diaza[3.3](2,6)-pyridinophane (L-N4Me2) ligand, yielding complexes of the general formula [(L-N4Me2)Ru(mu-tape)M(L-N4Me2)](ClO4)(2)(PF6)(2) with M = Fe {[2](ClO4)(2)(PF6)(2)}, Co {[3](ClO4)(2)(PF6)(2)}, and Ni {[4](ClO4)(2)(PF6)(2)}. Furthermore, the heterodinuclear tape ruthenium(II) complexes with palladium(II)- and platinum(II)-dichloride [(bpy)(2)Ru(-tape)PdCl2](PF6)(2) {[5](PF6)(2)} and [(dmbpy)(2)Ru(-tape)PtCl2](PF6)(2) {[6](PF6)(2)}, respectively were also prepared. The molecular structures of the complex cations [2](4+) and [4](4+) were discussed on the basis of the X-ray structures of [2](ClO4)(4)MeCN and [4](ClO4)(4)MeCN. The electrochemical behavior and the UV/Vis absorption spectra of the heterodinuclear tape ruthenium(II) complexes were explored and compared with the data of the analogous mono- and homodinuclear ruthenium(II) complexes of the tape bridging ligand.
KW  - N ligands
KW  - Ruthenium
KW  - Structure elucidation
KW  - Charge transfer
KW  - Electrochemistry
Y1  - 2016
U6  - https://doi.org/10.1002/zaac.201500645
SN  - 0044-2313
SN  - 1521-3749
VL  - 642
SP  - 8
EP  - 13
PB  - Wiley-VCH
CY  - Weinheim
ER  - 
TY  - JOUR
A1  - Ast, Sandra
A1  - Rutledge, Peter J.
A1  - Todd, Matthew H.
T1  - Reversing the triazole topology in a cyclam-triazole-dye ligand gives a 10-fold brighter signal response to Zn2+ in aqueous solution
JF  - European journal of inorganic chemistry : a journal of ChemPubSoc Europe
N2  - The fluorescence response of a set of cyclam-triazole-dye ligands is controlled by the appended dye, but simple reversal of the triazole topology affords a novel probe for Zn2+ with a longer fluorescence lifetime and higher fluorescence quantum yield upon Zn2+ binding (<tau t > = 2.0 ns, Phi(f) = 0.76).
KW  - Sensors
KW  - Zinc
KW  - Click chemistry
KW  - Fluorescence
KW  - Electrochemistry
Y1  - 2012
U6  - https://doi.org/10.1002/ejic.201201072
SN  - 1434-1948
IS  - 34
SP  - 5611
EP  - 5615
PB  - Wiley-VCH
CY  - Weinheim
ER  - 
TY  - GEN
A1  - Anton, Peter
A1  - Laschewsky, André
A1  - Ward, M. D.
T1  - Solubilization control by redox-switching of polysoaps
N2  - Reversible changes in the self-organization of polysoaps may be induced by controlling their charge numbers via covalently bound redox moieties. This is illustrated with two viologen polysoaps, which in response to an electrochemical stimulus, change their solubility and aggregation in water, leading from homogeneously dissolved and aggregated molecules to collapsed ones and vice verse. Using the electrochemical quartz crystal microbalance (EQCM), it could be shown that the reversibility of this process is better than 95% in 16 cycles.
T3  - Zweitveröffentlichungen der Universität Potsdam : Mathematisch-Naturwissenschaftliche Reihe - paper 084 
KW  - Quartz Crystal
KW  - microbalance
KW  - films
KW  - Electrochemistry
KW  - viologen
Y1  - 1995
U6  - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus-17336
ER  -