TY  - JOUR
A1  - von Klitzing, Regine
A1  - Stehl, Dimitrij
A1  - Pogrzeba, Tobias
A1  - Schomaäcker, Reinhard
A1  - Minullina, Renata
A1  - Panchal, Abhishek
A1  - Konnova, Svetlana
A1  - Fakhrullin, Rawil
A1  - Koetz, Joachim
A1  - Moehwald, Helmuth
A1  - Lvov, Yuri
T1  - Halloysites Stabilized Emulsions for Hydroformylation of Long Chain Olefins
JF  - Advanced materials interfaces
N2  - Halloysites as tubular alumosilicates are introduced as inexpensive natural nanoparticles to form and stabilize oil-water emulsions. This stabilized emulsion is shown to enable efficient interfacial catalytic reactions. Yield, selectivity, and product separation can be tremendously enhanced, e.g., for the hydroformylation reaction of dodecene to tridecanal. In perspective, this type of formulation may be used for oil spill dispersions. The key elements of the described formulations are clay nanotubes (halloysites) which are highly anisometric, can be filled by helper molecules, and are abundantly available in thousands of tons, making this technology scalable for industrial applications.
Y1  - 2016
U6  - https://doi.org/10.1002/admi.201600435
SN  - 2196-7350
VL  - 4
IS  - 1
PB  - Wiley
CY  - Hoboken
ER  -