TY - JOUR A1 - Koetz, Joachim A1 - Beitz, Toralf A1 - Tiersch, Brigitte T1 - Self assembled polymer-surfactant systems Y1 - 1999 ER - TY - JOUR A1 - Beitz, Toralf A1 - Bechmann, Wolfgang A1 - Mitzner, Rolf T1 - Investigation on the photoreactions of Nitrate and Nitrite ions with selected Azaarenes in water Y1 - 1999 ER - TY - JOUR A1 - Tessmann, Joachim A1 - Beitz, Toralf A1 - Bechmann, Wolfgang A1 - Mitzner, Rolf T1 - Untersuchungen zu Toxizitätsänderungen in Photoreaktionen von Azaarenen Y1 - 1999 ER - TY - JOUR A1 - Koetz, Joachim A1 - Beitz, Toralf A1 - Kosmella, Sabine A1 - Tiersch, Brigitte T1 - Polymer-modified microemulsions Y1 - 2000 ER - TY - JOUR A1 - Beitz, Toralf A1 - Koetz, Joachim A1 - Wolf, Gunter A1 - Kleinpeter, Erich A1 - Friberg, Stig E. T1 - Poly(N-vinyl-2-pyrrolidone) and 1-octyl-2-pyrrolidinone modified ionic microemulsions Y1 - 2001 ER - TY - JOUR A1 - Koetz, Joachim A1 - Kosmella, Sabine A1 - Beitz, Toralf T1 - Self-assembled Polyelectrolyte Systems Y1 - 2001 ER - TY - JOUR A1 - Beitz, Toralf A1 - Laudien, Robert A1 - Löhmannsröben, Hans-Gerd A1 - Kallies, Bernd T1 - Ion mobility spectrometric investigation of aromatic cations in the gas phase N2 - In this work, ion mobility (IM) spectra of more than 50 aromatic compounds were recorded with a laser-based IM spectrometer at atmospheric pressure. IM spectra of PAH in the laser desorption experiment show a high complexity resulting from the occurrence of monomeric, dimeric, and oligomeric cluster ions. The mobilities of all compounds were determined in helium as drift gas. This allows the calculation of the diffusion cross sections (Omega(calc)) on the basis of the exact hard sphere scattering model and their comparison with the experimentally determined diffusion cross sections (Omega(exp)). Extended Omega(exp)/Omega(calc) and Omega(exp/)mass correlations were performed in order to gain insight into conformational properties of cationic alkyl benzenes and internal rotation of phenyl rings in aromatic ions. This is demonstrated with some examples, such as the evaluation of the dihedral angle of the ions of 9,10- diphenylanthracene, o- and m-terphenyl, and 1,2,3- and 1,3,5-triphenylbenzene. Furthermore, sandwich and T-structures of dimeric PAH cations are discussed. The analysis was extended to oligomeric ions with up to nine monomer units. Experimental evidence is presented suggesting the formation of pi-stacks with a transition toward modified pi-stacks with increasing cluster size. The distance between monomeric units in dimeric and oligomeric ions was obtained Y1 - 2006 UR - http://pubs.acs.org/journal/jpcafh U6 - https://doi.org/10.1021/Jp055335n SN - 1089-5639 ER -