TY  - JOUR
A1  - Aksu, Yilmaz
A1  - Frasca, Stefano
A1  - Wollenberger, Ursula
A1  - Driess, Matthias
A1  - Thomas, Arne
T1  - A molecular precursor approach to tunable porous tin-rich indium tin oxide with durable high electrical conductivity for bioelectronic devices
JF  - Chemistry of materials : a publication of the American Chemical Society
N2  - The preparation of porous, i.e., high surface area electrodes from transparent conducting oxides, is a valuable goal in materials chemistry as such electrodes can enable further development of optoelectronic, electrocatalytic, or bioelectronic devices. In this work the first tin-rich mesoporous indium tin oxide is prepared using the molecular heterobimetallic single-source precursor, indium tin tris-tert-butoxide, together with an appropriate structure-directing template, yielding materials with high surface areas and tailorable pore size. The resulting mesoporous tin-rich ITO films show a high and durable electrical conductivity and transparency, making them interesting materials for hosting electroactive biomolecules such as proteins. In fact, its unique performance in bioelectronic applications has been demonstrated by immobilization of high amounts of cytochrome c into the mesoporous film which undergo redox processes directly with the conductive electrode material.
KW  - indium tin oxide ITO
KW  - electrode
KW  - bioelectrochemistry
KW  - device
KW  - cytochrome c
Y1  - 2011
U6  - https://doi.org/10.1021/cm103087p
SN  - 0897-4756
VL  - 23
IS  - 7
SP  - 1798
EP  - 1804
PB  - American Chemical Society
CY  - Washington
ER  - 
TY  - JOUR
A1  - Krylov, Andrey. V.
A1  - Adamzig, H.
A1  - Walter, A. D.
A1  - Loechel, B.
A1  - Kurth, E.
A1  - Pulz, O.
A1  - Szeponik, Jan
A1  - Wegerich, Franziska
A1  - Lisdat, Fred
T1  - Parallel generation and detection of superoxide and hydrogen peroxide in a fluidic chip
JF  - Sensors and actuators : B, Chemical
N2  - A fluidic chip system was developed, which combines a stable generation of superoxide radicals and hydrogen peroxide with their sensorial detection. The generation of both reactive oxygen species was achieved by immobilization of xanthine oxidase on controlled pore glass in a reaction chamber. Antioxidants can be introduced into the fluidic chip system by means of mixing chamber. The detection of both species is based on the amperometric principle using a biosensor chip with two working electrodes. As sensing protein for both electrodes cytochrome c was used. The novel system was designed for the quantification of the antioxidant efficiency of different potential scavengers of the respective reactive species in an aqueous medium. Several model antioxidants such as ascorbic acid or catalase have been tested under flow conditions.
KW  - biosensor
KW  - cytochrome c
KW  - flow system
KW  - reactive oxygen species
KW  - antioxidant
Y1  - 2006
U6  - https://doi.org/10.1016/j.snb.2005.11.062
SN  - 0925-4005
VL  - 119
IS  - 1
SP  - 118
EP  - 126
PB  - Elsevier
CY  - Lausanne
ER  -