TY  - JOUR
A1  - Schmidt, Bernd
A1  - Kunz, Oliver
T1  - One-Flask tethered ring closing Metathesis-Electrocyclic ring opening for the highly stereoselective synthesis of conjugated Z/E-Dienes
JF  - European journal of organic chemistry
N2  - A one-flask reaction sequence comprising ring closing metathesis (RCM) of butenoates derived from allylic alcohols and a base-mediated ring opening gives 2Z,4E-configured dienoic acids in high yields and stereoselectivities. Application of the method to the synthesis of the natural product fusanolide A suggests that the originally published structure was erroneously assigned and should be revised.
KW  - Natural products
KW  - Lactones
KW  - Macrocycles
KW  - Metathesis
KW  - Carboxylic -acids
Y1  - 2012
U6  - https://doi.org/10.1002/ejoc.201101497
SN  - 1434-193X
IS  - 5
SP  - 1008
EP  - 1018
PB  - Wiley-VCH
CY  - Weinheim
ER  -