TY - JOUR A1 - Zhang, Heshou A1 - Yan, Huirong A1 - Richter, Philipp T1 - The influence of atomic alignment on absorption and emission spectroscopy JF - Monthly notices of the Royal Astronomical Society N2 - Spectroscopic observations play essential roles in astrophysics. They are crucial for determining physical parameters in our Universe, providing information about the chemistry of various astronomical environments. The proper execution of the spectroscopic analysis requires accounting for all the physical effects that are compatible to the signal-to-noise ratio. We find in this paper the influence on spectroscopy from the atomic/ground state alignment owing to anisotropic radiation and modulated by interstellar magnetic field, has significant impact on the study of interstellar gas. In different observational scenarios, we comprehensively demonstrate how atomic alignment influences the spectral analysis and provide the expressions for correcting the effect. The variations are even more pronounced for multiplets and line ratios. We show the variation of the deduced physical parameters caused by the atomic alignment effect, including alpha-to-iron ratio ([X/Fe]) and ionization fraction. Synthetic observations are performed to illustrate the visibility of such effect with current facilities. A study of Photodissociation regions in rho Ophiuchi cloud is presented to demonstrate how to account for atomic alignment in practice. Our work has shown that due to its potential impact, atomic alignment has to be included in an accurate spectroscopic analysis of the interstellar gas with current observational capability. KW - magnetic fields KW - submillimetre: ISM KW - ultraviolet: ISM KW - ISM: abundances KW - ISM: lines and bands KW - techniques: spectroscopic Y1 - 2018 U6 - https://doi.org/10.1093/mnras/sty1594 SN - 0035-8711 SN - 1365-2966 VL - 479 IS - 3 SP - 3923 EP - 3935 PB - Oxford Univ. Press CY - Oxford ER -