@misc{SparkesHoviusGalyetal.2020, author = {Sparkes, Robert B. and Hovius, Niels and Galy, Albert and Liu, James T.}, title = {Survival of graphitized petrogenic organic carbon through multiple erosional cycles}, series = {Postprints der Universit{\"a}t Potsdam : Mathematisch-Naturwissenschaftliche Reihe}, journal = {Postprints der Universit{\"a}t Potsdam : Mathematisch-Naturwissenschaftliche Reihe}, issn = {1866-8372}, doi = {10.25932/publishup-53354}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-533541}, pages = {8}, year = {2020}, abstract = {Graphite forms the endpoint for organic carbon metamorphism; it is extremely resilient to physical, biological and chemical degradation. Carbonaceous materials (CM) contained within sediments, collected across Taiwan and from the Gaoping submarine canyon, were analyzed using Raman spectroscopy to determine the crystallinity. This allowed the erosional and orogenic movements of petrogenic organic carbon (OCpetro) during the Taiwanese orogeny to be deduced. After automatically fitting and classifying spectra, the distribution of four groups of CM within the sediments provides evidence that many forms of OCpetro have survived at least one previous cycle of erosion, transport and burial before forming rocks in the Western Foothills of the island. There is extensive detrital graphite present in rocks that have not experienced high-grade metamorphism, and graphite flakes are also found in recently deposited marine sediments off Taiwan. The tectonic and geological history of the island shows that these graphite flakes must have survived at least three episodes of recycling. Therefore, transformation to graphite during burial and orogeny is a mechanism for stabilizing organic carbon over geological time, removing biospheric carbon from the active carbon cycle and protecting it from oxidation during future erosion events.}, language = {en} } @article{ScheingrossHoviusDellingeretal.2019, author = {Scheingross, Joel S. and Hovius, Niels and Dellinger, M. and Hilton, R. G. and Repasch, M. and Sachse, Dirk and Grocke, D. R. and Vieth-Hillebrand, Andrea and Turowski, Jens M.}, title = {Preservation of organic carbon during active fluvial transport and particle abrasion}, series = {Geology}, volume = {47}, journal = {Geology}, number = {10}, publisher = {American Institute of Physics}, address = {Boulder}, issn = {0091-7613}, doi = {10.1130/G46442.1}, pages = {958 -- 962}, year = {2019}, abstract = {Oxidation of particulate organic carbon (POC) during fluvial transit releases CO2 to the atmosphere and can influence global climate. Field data show large POC oxidation fluxes in lowland rivers; however, it is unclear if POC losses occur predominantly during in-river transport, where POC is in continual motion within an aerated environment, or during transient storage in floodplains, which may be anoxic. Determination of the locus of POC oxidation in lowland rivers is needed to develop process-based models to predict POC losses, constrain carbon budgets, and unravel links between climate and erosion. However, sediment exchange between rivers and floodplains makes differentiating POC oxidation during in-river transport from oxidation during floodplain storage difficult. Here, we isolated inriver POC oxidation using flume experiments transporting petrogenic and biospheric POC without floodplain storage. Our experiments showed solid phase POC losses of 0\%-10\% over similar to 10(3) km of fluvial transport, compared to similar to 7\% to >50\% losses observed in rivers over similar distances. The production of dissolved organic carbon (DOC) and dissolved rhenium (a proxy for petrogenic POC oxidation) was consistent with small POC lasses, and replicate experiments in static water tanks gave similar results. Our results show that fluvial sediment transport, particle abrasion, and turbulent mixing have a minimal role on POC oxidation, and they suggest that POC losses may accrue primarily in floodplain storage.}, language = {en} } @misc{RepaschWittmannScheingrossetal.2020, author = {Repasch, Marisa and Wittmann, Hella and Scheingross, Joel S. and Sachse, Dirk and Szupiany, Ricardo and Orfeo, Oscar and Fuchs, Margret and Hovius, Niels}, title = {Sediment Transit Time and Floodplain Storage Dynamics in Alluvial Rivers Revealed by Meteoric 10Be}, series = {Postprints der Universit{\"a}t Potsdam : Mathematisch-Naturwissenschaftliche Reihe}, journal = {Postprints der Universit{\"a}t Potsdam : Mathematisch-Naturwissenschaftliche Reihe}, number = {1119}, issn = {1866-8372}, doi = {10.25932/publishup-49432}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-494324}, pages = {21}, year = {2020}, abstract = {Quantifying the time scales of sediment transport and storage through river systems is fundamental for understanding weathering processes, biogeochemical cycling, and improving watershed management, but measuring sediment transit time is challenging. Here we provide the first systematic test of measuring cosmogenic meteoric Beryllium-10 (10Bem) in the sediment load of a large alluvial river to quantify sediment transit times. We take advantage of a natural experiment in the Rio Bermejo, a lowland alluvial river traversing the east Andean foreland basin in northern Argentina. This river has no tributaries along its trunk channel for nearly 1,300 km downstream from the mountain front. We sampled suspended sediment depth profiles along the channel and measured the concentrations of 10Bem in the chemically extracted grain coatings. We calculated depth-integrated 10Bem concentrations using sediment flux data and found that 10Bem concentrations increase 230\% from upstream to downstream, indicating a mean total sediment transit time of 8.4 ± 2.2 kyr. Bulk sediment budget-based estimates of channel belt and fan storage times suggest that the 10Bem tracer records mixing of old and young sediment reservoirs. On a reach scale, 10Bem transit times are shorter where the channel is braided and superelevated above the floodplain, and longer where the channel is incised and meandering, suggesting that transit time is controlled by channel morphodynamics. This is the first systematic application of 10Bem as a sediment transit time tracer and highlights the method's potential for inferring sediment routing and storage dynamics in large river systems.}, language = {en} } @article{EmbersonGalyHovius2018, author = {Emberson, Robert and Galy, Albert and Hovius, Niels}, title = {Weathering of Reactive Mineral Phases in Landslides Acts as a Source of Carbon Dioxide in Mountain Belts}, series = {Journal of geophysical research : Earth surface}, volume = {123}, journal = {Journal of geophysical research : Earth surface}, number = {10}, publisher = {American Geophysical Union}, address = {Washington}, issn = {2169-9003}, doi = {10.1029/2018JF004672}, pages = {2695 -- 2713}, year = {2018}, abstract = {Bedrock landsliding in mountain belts can elevate overall chemical weathering rates through rapid dissolution of exhumed reactive mineral phases in transiently stored deposits. This link between a key process of erosion and the resultant weathering affects the sequestering of carbon dioxide through weathering of silicate minerals and broader links between erosion in active orogens and climate change. Here we address the effect on the carbon cycle of weathering induced by bedrock landsliding in Taiwan and the Western Southern Alps of New Zealand. Using solute chemistry data from samples of seepage from landslide deposits and river discharge from catchments with variable proportions of landsliding, we model the proportion of silicate and carbonate weathering and the balance of sulfuric and carbonic acids that act as weathering agents. We correct for secondary precipitation, geothermal, and cyclic input, to find a closer approximation of the weathering explicitly occurring within landslide deposits. We find highly variable proportions of sulfuric and carbonic acids driving weathering in landslides and stable hillslopes. Despite this variability, the predominance of rapid carbonate weathering within landslides and catchments where mass wasting is prevalent results at best in limited sequestration of carbon dioxide by this process of rapid erosion. In many cases where sulfuric acid is a key weathering agent, a net release of CO2 to the atmosphere occurs. This suggests that a causal link between erosion in mountain belts and climate change through the sequestration of CO2, if it exists, must operate through a process other than chemical weathering driven by landsliding. Plain Language Summary There is a long-standing debate surrounding the link between erosion and climate. It is often suggested that as temperatures increase, rainier and stormier weather could increase erosion of rock; as that rock is exposed, silicate minerals within could break down, which, on long time scales, can remove CO2 from the atmosphere, lowering global temperatures and acting as a negative feedback. Recent studies have shown that landslide deposits are key locations for the link between chemical weathering and physical erosion in some mountain belts. To test how landslides affect the erosion-climate link, we used samples of water seeping through landslides in Taiwan and New Zealand to calculate the amount of carbon dioxide that is either absorbed or released through this chemical reaction. We find that the large amount of freshly exposed rock in Taiwanese landslide deposits contains significant carbonate rock and sulfide minerals; the net result of the weathering of these minerals is a release of carbon dioxide, which inverts the traditional perspective on the role erosion plays in controlling carbon dioxide release. In some mountain belts, it seems that increased erosion and resulting landsliding may act to increase carbon dioxide in the air, opening further questions into the nature of erosional-climatic links.}, language = {en} } @misc{DietzeKrautblatterIllienetal.2021, author = {Dietze, Michael and Krautblatter, Michael and Illien, Luc and Hovius, Niels}, title = {Seismic constraints on rock damaging related to a failing mountain peak}, series = {Zweitver{\"o}ffentlichungen der Universit{\"a}t Potsdam : Mathematisch-Naturwissenschaftliche Reihe}, journal = {Zweitver{\"o}ffentlichungen der Universit{\"a}t Potsdam : Mathematisch-Naturwissenschaftliche Reihe}, number = {2}, issn = {1866-8372}, doi = {10.25932/publishup-56878}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-568787}, pages = {15}, year = {2021}, abstract = {Large rock slope failures play a pivotal role in long-term landscape evolution and are a major concern in land use planning and hazard aspects. While the failure phase and the time immediately prior to failure are increasingly well studied, the nature of the preparation phase remains enigmatic. This knowledge gap is due, to a large degree, to difficulties associated with instrumenting high mountain terrain and the local nature of classic monitoring methods, which does not allow integral observation of large rock volumes. Here, we analyse data from a small network of up to seven seismic sensors installed during July-October 2018 (with 43 days of data loss) at the summit of the Hochvogel, a 2592 m high Alpine peak. We develop proxy time series indicative of cyclic and progressive changes of the summit. Modal analysis, horizontal-to-vertical spectral ratio data and end-member modelling analysis reveal diurnal cycles of increasing and decreasing coupling stiffness of a 260,000 m(3) large, instable rock volume, due to thermal forcing. Relative seismic wave velocity changes also indicate diurnal accumulation and release of stress within the rock mass. At longer time scales, there is a systematic superimposed pattern of stress increased over multiple days and episodic stress release within a few days, expressed in an increased emission of short seismic pulses indicative of rock cracking. Our data provide essential first order information on the development of large-scale slope instabilities towards catastrophic failure. (c) 2020 The Authors. Earth Surface Processes and Landforms published by John Wiley \& Sons Ltd}, language = {en} }