@article{FuehrerSchlaad2014,
  author    = {Fuehrer, Felix N. and Schlaad, Helmut},
  title     = {ADMET polymerization of amino-acid-based diene},
  series = {Macromolecular chemistry and physics},
  volume    = {215},
  journal   = {Macromolecular chemistry and physics},
  number    = {22},
  publisher = {Wiley-VCH},
  address   = {Weinheim},
  issn      = {1022-1352},
  doi       = {10.1002/macp.201400166},
  pages     = {2268 -- 2273},
  year      = {2014},
  abstract  = {1,4-Di(homo)allyl-2,5-diketopiperazines are synthesized and polymerized via ADMET using the Hoveyda-Grubbs 2nd generation catalyst. The but-3-enylated diketopiperazine can be converted into unsaturated tertiary polyamide with molar mass of <3000 g mol(-1), whereas the allylated diketopiperazine cannot. Double-bond isomerization occurs regardless of whether or not benzoquinone is present. A polyesteramide with a higher molar mass of ca. 4800 g mol(-1) is obtained by the alternating copolymerization (ALTMET) of 1,4-di(but-3-enyl)-2,5-di ketopiperazine and ethylene glycol diacrylate. A post-polymerization modification of the poly(ester)amides via radical thiol-ene chemistry, however, fails.},
  language  = {en}
}