@article{LueckGebbersRuehlmannetal.2009, author = {L{\"u}ck, Erika and Gebbers, Robin and Ruehlmann, Joerg and Spangenberg, Ulrike}, title = {Electrical conductivity mapping for precision farming}, issn = {1569-4445}, doi = {10.3997/1873-0604.2008031}, year = {2009}, abstract = {Precision farming overcomes the paradigm of uniform field treatment by site-specific data acquisition and treatment to cope with within-field variability. Precision farming heavily relies on spatially dense information about soil and crop status. While it is often difficult and expensive to obtain precise soil information by traditional soil sampling and laboratory analysis some geophysical methods offer means to obtain subsidiary data in an efficient way. In particular, geoelectrical soil mapping has become widely accepted in precision farming. At present it is the most successful geophysical method providing the spatial distribution of relevant agronomic information that enables us to determine management zones for precision farming. Much work has been done to test the applicability of existing geoelectrical methods and to develop measurement systems applicable in the context of precision farming. Therefore, the aim of this paper was to introduce the basic ideas of precision farming, to discuss current precision farming applied geoelectrical methods and instruments and to give an overview about our corresponding activities during recent years. Different experiments were performed both in the laboratory and in the field to estimate first, electrical conductivity affecting factors, second, relationships between direct push and surface measurements, third, the seasonal stability of electrical conductivity patterns and fourth, the relationship between plant yield and electrical conductivity. From the results of these experiments, we concluded that soil texture is a very dominant factor in electrical conductivity mapping. Soil moisture affects both the level and the dynamic range of electrical conductivity readings. Nevertheless, electrical conductivity measurements can be principally performed independent of season. However, electrical conductivity field mapping does not produce reliable maps of spatial particle size distribution of soils, e.g., necessary to generate input parameters for water and nutrient transport models. The missing step to achieve this aim may be to develop multi-sensor systems that allow adjusting the electrical conductivity measurement from the influence of different soil water contents.}, language = {en} } @misc{RiebeErlerBrinkmannetal.2019, author = {Riebe, Daniel and Erler, Alexander and Brinkmann, Pia and Beitz, Toralf and L{\"o}hmannsr{\"o}ben, Hans-Gerd and Gebbers, Robin}, title = {Comparison of Calibration Approaches in Laser-Induced Breakdown Spectroscopy for Proximal Soil Sensing in Precision Agriculture}, series = {Postprints der Universit{\"a}t Potsdam Mathematisch-Naturwissenschaftliche Reihe}, journal = {Postprints der Universit{\"a}t Potsdam Mathematisch-Naturwissenschaftliche Reihe}, number = {786}, issn = {1866-8372}, doi = {10.25932/publishup-44007}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-440079}, pages = {16}, year = {2019}, abstract = {The lack of soil data, which are relevant, reliable, affordable, immediately available, and sufficiently detailed, is still a significant challenge in precision agriculture. A promising technology for the spatial assessment of the distribution of chemical elements within fields, without sample preparation is laser-induced breakdown spectroscopy (LIBS). Its advantages are contrasted by a strong matrix dependence of the LIBS signal which necessitates careful data evaluation. In this work, different calibration approaches for soil LIBS data are presented. The data were obtained from 139 soil samples collected on two neighboring agricultural fields in a quaternary landscape of northeast Germany with very variable soils. Reference analysis was carried out by inductively coupled plasma optical emission spectroscopy after wet digestion. The major nutrients Ca and Mg and the minor nutrient Fe were investigated. Three calibration strategies were compared. The first method was based on univariate calibration by standard addition using just one soil sample and applying the derived calibration model to the LIBS data of both fields. The second univariate model derived the calibration from the reference analytics of all samples from one field. The prediction is validated by LIBS data of the second field. The third method is a multivariate calibration approach based on partial least squares regression (PLSR). The LIBS spectra of the first field are used for training. Validation was carried out by 20-fold cross-validation using the LIBS data of the first field and independently on the second field data. The second univariate method yielded better calibration and prediction results compared to the first method, since matrix effects were better accounted for. PLSR did not strongly improve the prediction in comparison to the second univariate method.}, language = {en} } @article{GebbersLueckDabasetal.2009, author = {Gebbers, Robin and Lueck, Erika and Dabas, Michel and Domsch, Horst}, title = {Comparison of instruments for geoelectrical soil mapping at the field scale}, issn = {1569-4445}, doi = {10.3997/1873-0604.2009011}, year = {2009}, abstract = {In precision agriculture geoelectrical methods have shown their capability to detect spatial variation of important physico-chemical soil parameters in an efficient way. Nevertheless, relationships between the electrical parameters (electrical conductivity or resistivity) and other soil properties are not always consistent over different fields. This can, to some extent, be due to the characteristics of instruments used for soil mapping. However, a limited amount of research has addressed this issue. In this study, seven instruments for mobile mapping (continuous geoelectrical measurements) available on the market were tested (ARP 03, CM-138, EM38, EM38-DD, EM38-MK2, OhmMapper and Veris 3100). Instruments were employed on a sandy site in north-east Germany. Measurements were compared to a profile, which has been investigated with a high accuracy reference. Additional investigations were conducted concerning the influences of temperature drift, seasonal variations and soil properties on soil EC. Marked differences between the instruments were found with respect to depth of investigation, accuracy and handling that have to be taken into account when geoelectrical surveys are planned or interpreted. Regarding depth of investigation and robustness of the measurements, ARP 03 and Veris 3100 seem to be the most suitable instruments for precision agriculture.}, language = {en} } @article{RiebeErlerBrinkmannetal.2019, author = {Riebe, Daniel and Erler, Alexander and Brinkmann, Pia and Beitz, Toralf and L{\"o}hmannsr{\"o}ben, Hans-Gerd and Gebbers, Robin}, title = {Comparison of Calibration Approaches in Laser-Induced Breakdown Spectroscopy for Proximal Soil Sensing in Precision Agriculture}, series = {Sensors}, volume = {19}, journal = {Sensors}, number = {23}, publisher = {MDPI}, address = {Basel}, issn = {1424-8220}, doi = {10.3390/s19235244}, pages = {16}, year = {2019}, abstract = {The lack of soil data, which are relevant, reliable, affordable, immediately available, and sufficiently detailed, is still a significant challenge in precision agriculture. A promising technology for the spatial assessment of the distribution of chemical elements within fields, without sample preparation is laser-induced breakdown spectroscopy (LIBS). Its advantages are contrasted by a strong matrix dependence of the LIBS signal which necessitates careful data evaluation. In this work, different calibration approaches for soil LIBS data are presented. The data were obtained from 139 soil samples collected on two neighboring agricultural fields in a quaternary landscape of northeast Germany with very variable soils. Reference analysis was carried out by inductively coupled plasma optical emission spectroscopy after wet digestion. The major nutrients Ca and Mg and the minor nutrient Fe were investigated. Three calibration strategies were compared. The first method was based on univariate calibration by standard addition using just one soil sample and applying the derived calibration model to the LIBS data of both fields. The second univariate model derived the calibration from the reference analytics of all samples from one field. The prediction is validated by LIBS data of the second field. The third method is a multivariate calibration approach based on partial least squares regression (PLSR). The LIBS spectra of the first field are used for training. Validation was carried out by 20-fold cross-validation using the LIBS data of the first field and independently on the second field data. The second univariate method yielded better calibration and prediction results compared to the first method, since matrix effects were better accounted for. PLSR did not strongly improve the prediction in comparison to the second univariate method.}, language = {en} } @article{ErlerRiebeBeitzetal.2020, author = {Erler, Alexander and Riebe, Daniel and Beitz, Toralf and L{\"o}hmannsr{\"o}ben, Hans-Gerd and Gebbers, Robin}, title = {Soil Nutrient Detection for Precision Agriculture Using Handheld Laser-Induced Breakdown Spectroscopy (LIBS) and Multivariate Regression Methods (PLSR, Lasso and GPR)}, series = {Sensors}, volume = {20}, journal = {Sensors}, number = {2}, publisher = {MDPI}, address = {Basel}, issn = {1424-8220}, doi = {10.3390/s20020418}, pages = {17}, year = {2020}, abstract = {Precision agriculture (PA) strongly relies on spatially differentiated sensor information. Handheld instruments based on laser-induced breakdown spectroscopy (LIBS) are a promising sensor technique for the in-field determination of various soil parameters. In this work, the potential of handheld LIBS for the determination of the total mass fractions of the major nutrients Ca, K, Mg, N, P and the trace nutrients Mn, Fe was evaluated. Additionally, other soil parameters, such as humus content, soil pH value and plant available P content, were determined. Since the quantification of nutrients by LIBS depends strongly on the soil matrix, various multivariate regression methods were used for calibration and prediction. These include partial least squares regression (PLSR), least absolute shrinkage and selection operator regression (Lasso), and Gaussian process regression (GPR). The best prediction results were obtained for Ca, K, Mg and Fe. The coefficients of determination obtained for other nutrients were smaller. This is due to much lower concentrations in the case of Mn, while the low number of lines and very weak intensities are the reason for the deviation of N and P. Soil parameters that are not directly related to one element, such as pH, could also be predicted. Lasso and GPR yielded slightly better results than PLSR. Additionally, several methods of data pretreatment were investigated.}, language = {en} } @misc{ErlerRiebeBeitzetal.2019, author = {Erler, Alexander and Riebe, Daniel and Beitz, Toralf and L{\"o}hmannsr{\"o}ben, Hans-Gerd and Gebbers, Robin}, title = {Soil Nutrient Detection for Precision Agriculture Using Handheld Laser-Induced Breakdown Spectroscopy (LIBS) and Multivariate Regression Methods (PLSR, Lasso and GPR)}, series = {Postprints der Universit{\"a}t Potsdam : Mathematisch-Naturwissenschaftliche Reihe}, journal = {Postprints der Universit{\"a}t Potsdam : Mathematisch-Naturwissenschaftliche Reihe}, number = {815}, issn = {1866-8372}, doi = {10.25932/publishup-44418}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-444183}, pages = {19}, year = {2019}, abstract = {Precision agriculture (PA) strongly relies on spatially differentiated sensor information. Handheld instruments based on laser-induced breakdown spectroscopy (LIBS) are a promising sensor technique for the in-field determination of various soil parameters. In this work, the potential of handheld LIBS for the determination of the total mass fractions of the major nutrients Ca, K, Mg, N, P and the trace nutrients Mn, Fe was evaluated. Additionally, other soil parameters, such as humus content, soil pH value and plant available P content, were determined. Since the quantification of nutrients by LIBS depends strongly on the soil matrix, various multivariate regression methods were used for calibration and prediction. These include partial least squares regression (PLSR), least absolute shrinkage and selection operator regression (Lasso), and Gaussian process regression (GPR). The best prediction results were obtained for Ca, K, Mg and Fe. The coefficients of determination obtained for other nutrients were smaller. This is due to much lower concentrations in the case of Mn, while the low number of lines and very weak intensities are the reason for the deviation of N and P. Soil parameters that are not directly related to one element, such as pH, could also be predicted. Lasso and GPR yielded slightly better results than PLSR. Additionally, several methods of data pretreatment were investigated.}, language = {en} }