@article{HuschbeckKnoopGahleitneretal.2020, author = {Huschbeck, Alina and Knoop, Michael and Gahleitner, Adrian and Koch, Stefan and Schrom, Thomas and Stoffel, Michael and Alfieri, Alex and Dengler, Julius}, title = {Recurrent laryngeal nerve palsy after anterior cervical discectomy and fusion}, series = {Journal of neurological surgery. Part A, Central European neurosurgery}, volume = {81}, journal = {Journal of neurological surgery. Part A, Central European neurosurgery}, number = {06}, publisher = {Thieme}, address = {New York}, issn = {2193-6315}, doi = {10.1055/s-0040-1710351}, pages = {508 -- 512}, year = {2020}, abstract = {Background and Study Aims Recurrent laryngeal nerve palsy (RLNP) is a potential complication of anterior discectomy and fusion (ACDF). There still is substantial disagreement on the actual prevalence of RLNP after ACDF as well as on risk factors for postoperative RLNP. The aim of this study was to describe the prevalence of postoperative RLNP in a cohort of consecutive cases of ACDF and to examine potential risk factors. Materials and Methods This retrospective study included patients who underwent ACDF between 2005 and 2019 at a single neurosurgical center. As part of clinical routine, RLNP was examined prior to and after surgery by independent otorhinolaryngologists using endoscopic laryngoscopy. As potential risk factors for postoperative RLNP, we examined patient's age, sex, body mass index, multilevel surgery, and the duration of surgery. Results 214 consecutive cases were included. The prevalence of preoperative RLNP was 1.4\% (3/214) and the prevalence of postoperative RLNP was 9\% (19/211). The number of operated levels was 1 in 73.5\% (155/211), 2 in 24.2\% (51/211), and 3 or more in 2.4\% (5/211) of cases. Of all cases, 4.7\% (10/211) were repeat surgeries. There was no difference in the prevalence of RLNP between the primary surgery group (9.0\%, 18/183) versus the repeat surgery group (10.0\%, 1/10;p = 0.91). Also, there was no difference in any characteristics between subjects with postoperative RLNP compared with those without postoperative RLNP. We found no association between postoperative RLNP and patient's age, sex, body mass index, duration of surgery, or number of levels (odds ratios between 0.24 and 1.05; p values between 0.20 and 0.97). Conclusions In our cohort, the prevalence of postoperative RLNP after ACDF was 9.0\%. The fact that none of the examined variables was associated with the occurrence of RLNP supports the view that postoperative RLNP may depend more on direct mechanical manipulation during surgery than on specific patient or surgical characteristics.}, language = {en} } @article{WeberAbuAyyashAbueladasetal.2009, author = {Weber, Michael H. and Abu-Ayyash, Khalil and Abueladas, Abdel-Rahman and Agnon, Amotz and Alasonati-Taš{\´a}rov{\´a}, Zuzana and Al-Zubi, Hashim and Babeyko, Andrey and Bartov, Yuval and Bauer, Klaus and Becken, Michael and Bedrosian, Paul A. and Ben-Avraham, Zvi and Bock, G{\"u}nter and Bohnhoff, Marco and Bribach, Jens and Dulski, Peter and Ebbing, Joerg and El-Kelani, Radwan J. and Foerster, Andrea and F{\"o}rster, Hans-J{\"u}rgen and Frieslander, Uri and Garfunkel, Zvi and G{\"o}tze, Hans-J{\"u}rgen and Haak, Volker and Haberland, Christian and Hassouneh, Mohammed and Helwig, Stefan L. and Hofstetter, Alfons and Hoffmann-Rothe, Arne and Jaeckel, Karl-Heinz and Janssen, Christoph and Jaser, Darweesh and Kesten, Dagmar and Khatib, Mohammed Ghiath and Kind, Rainer and Koch, Olaf and Koulakov, Ivan and Laske, Maria Gabi and Maercklin, Nils}, title = {Anatomy of the Dead Sea transform from lithospheric to microscopic scale}, issn = {8755-1209}, doi = {10.1029/2008rg000264}, year = {2009}, abstract = {Fault zones are the locations where motion of tectonic plates, often associated with earthquakes, is accommodated. Despite a rapid increase in the understanding of faults in the last decades, our knowledge of their geometry, petrophysical properties, and controlling processes remains incomplete. The central questions addressed here in our study of the Dead Sea Transform (DST) in the Middle East are as follows: (1) What are the structure and kinematics of a large fault zone? (2) What controls its structure and kinematics? (3) How does the DST compare to other plate boundary fault zones? The DST has accommodated a total of 105 km of left-lateral transform motion between the African and Arabian plates since early Miocene (similar to 20 Ma). The DST segment between the Dead Sea and the Red Sea, called the Arava/Araba Fault (AF), is studied here using a multidisciplinary and multiscale approach from the mu m to the plate tectonic scale. We observe that under the DST a narrow, subvertical zone cuts through crust and lithosphere. First, from west to east the crustal thickness increases smoothly from 26 to 39 km, and a subhorizontal lower crustal reflector is detected east of the AF. Second, several faults exist in the upper crust in a 40 km wide zone centered on the AF, but none have kilometer-size zones of decreased seismic velocities or zones of high electrical conductivities in the upper crust expected for large damage zones. Third, the AF is the main branch of the DST system, even though it has accommodated only a part (up to 60 km) of the overall 105 km of sinistral plate motion. Fourth, the AF acts as a barrier to fluids to a depth of 4 km, and the lithology changes abruptly across it. Fifth, in the top few hundred meters of the AF a locally transpressional regime is observed in a 100-300 m wide zone of deformed and displaced material, bordered by subparallel faults forming a positive flower structure. Other segments of the AF have a transtensional character with small pull-aparts along them. The damage zones of the individual faults are only 5-20 m wide at this depth range. Sixth, two areas on the AF show mesoscale to microscale faulting and veining in limestone sequences with faulting depths between 2 and 5 km. Seventh, fluids in the AF are carried downward into the fault zone. Only a minor fraction of fluids is derived from ascending hydrothermal fluids. However, we found that on the kilometer scale the AF does not act as an important fluid conduit. Most of these findings are corroborated using thermomechanical modeling where shear deformation in the upper crust is localized in one or two major faults; at larger depth, shear deformation occurs in a 20-40 km wide zone with a mechanically weak decoupling zone extending subvertically through the entire lithosphere.}, language = {en} } @article{StolterfohtCaprioglioWolffetal.2019, author = {Stolterfoht, Martin and Caprioglio, Pietro and Wolff, Christian Michael and Marquez, Jose A. and Nordmann, Joleik and Zhang, Shanshan and Rothhardt, Daniel and H{\"o}rmann, Ulrich and Amir, Yohai and Redinger, Alex and Kegelmann, Lukas and Zu, Fengshuo and Albrecht, Steve and Koch, Norbert and Kirchartz, Thomas and Saliba, Michael and Unold, Thomas and Neher, Dieter}, title = {The impact of energy alignment and interfacial recombination on the internal and external open-circuit voltage of perovskite solar cells}, series = {Energy \& environmental science}, volume = {12}, journal = {Energy \& environmental science}, number = {9}, publisher = {Royal Society of Chemistry}, address = {Cambridge}, issn = {1754-5692}, doi = {10.1039/c9ee02020a}, pages = {2778 -- 2788}, year = {2019}, abstract = {Charge transport layers (CTLs) are key components of diffusion controlled perovskite solar cells, however, they can induce additional non-radiative recombination pathways which limit the open circuit voltage (V-OC) of the cell. In order to realize the full thermodynamic potential of the perovskite absorber, both the electron and hole transport layer (ETL/HTL) need to be as selective as possible. By measuring the photoluminescence yield of perovskite/CTL heterojunctions, we quantify the non-radiative interfacial recombination currents in pin- and nip-type cells including high efficiency devices (21.4\%). Our study comprises a wide range of commonly used CTLs, including various hole-transporting polymers, spiro-OMeTAD, metal oxides and fullerenes. We find that all studied CTLs limit the V-OC by inducing an additional non-radiative recombination current that is in most cases substantially larger than the loss in the neat perovskite and that the least-selective interface sets the upper limit for the V-OC of the device. Importantly, the V-OC equals the internal quasi-Fermi level splitting (QFLS) in the absorber layer only in high efficiency cells, while in poor performing devices, the V-OC is substantially lower than the QFLS. Using ultraviolet photoelectron spectroscopy and differential charging capacitance experiments we show that this is due to an energy level mis-alignment at the p-interface. The findings are corroborated by rigorous device simulations which outline important considerations to maximize the V-OC. This work highlights that the challenge to suppress non-radiative recombination losses in perovskite cells on their way to the radiative limit lies in proper energy level alignment and in suppression of defect recombination at the interfaces.}, language = {en} } @article{GarbusowSchadSeboldetal.2016, author = {Garbusow, Maria and Schad, Daniel and Sebold, Miriam and Friedel, Eva and Bernhardt, Nadine and Koch, Stefan P. and Steinacher, Bruno and Kathmann, Norbert and Geurts, Dirk E. M. and Sommer, Christian and Mueller, Dirk K. and Nebe, Stephan and Paul, Soeren and Wittchen, Hans-Ulrich and Zimmermann, Ulrich S. and Walter, Henrik and Smolka, Michael N. and Sterzer, Philipp and Rapp, Michael A. and Huys, Quentin J. M. and Schlagenhauf, Florian and Heinz, Andreas}, title = {Pavlovian-to-instrumental transfer effects in the nucleus accumbens relate to relapse in alcohol dependence}, series = {Addiction biology}, volume = {21}, journal = {Addiction biology}, publisher = {Wiley-Blackwell}, address = {Hoboken}, issn = {1355-6215}, doi = {10.1111/adb.12243}, pages = {719 -- 731}, year = {2016}, abstract = {In detoxified alcohol-dependent patients, alcohol-related stimuli can promote relapse. However, to date, the mechanisms by which contextual stimuli promote relapse have not been elucidated in detail. One hypothesis is that such contextual stimuli directly stimulate the motivation to drink via associated brain regions like the ventral striatum and thus promote alcohol seeking, intake and relapse. Pavlovian-to-Instrumental-Transfer (PIT) may be one of those behavioral phenomena contributing to relapse, capturing how Pavlovian conditioned (contextual) cues determine instrumental behavior (e.g. alcohol seeking and intake). We used a PIT paradigm during functional magnetic resonance imaging to examine the effects of classically conditioned Pavlovian stimuli on instrumental choices in n=31 detoxified patients diagnosed with alcohol dependence and n=24 healthy controls matched for age and gender. Patients were followed up over a period of 3 months. We observed that (1) there was a significant behavioral PIT effect for all participants, which was significantly more pronounced in alcohol-dependent patients; (2) PIT was significantly associated with blood oxygen level-dependent (BOLD) signals in the nucleus accumbens (NAcc) in subsequent relapsers only; and (3) PIT-related NAcc activation was associated with, and predictive of, critical outcomes (amount of alcohol intake and relapse during a 3 months follow-up period) in alcohol-dependent patients. These observations show for the first time that PIT-related BOLD signals, as a measure of the influence of Pavlovian cues on instrumental behavior, predict alcohol intake and relapse in alcohol dependence.}, language = {en} } @article{KirchnerKoch2020, author = {Kirchner, Vera and Koch, Michael}, title = {Mehr als ein "bisschen" Haushalt - Haushalten als {\"o}konomisches Prinzip im Unterricht}, series = {Unterricht Wirtschaft + Politik}, journal = {Unterricht Wirtschaft + Politik}, number = {3}, editor = {Kirchner, Vera and Koch, Michael}, publisher = {Friedrich Verlag}, address = {Hannover}, issn = {2191-6624}, pages = {2 -- 7}, year = {2020}, language = {de} } @article{StarkeKochKammeretal.2018, author = {Starke, Ines and Koch, Andreas and Kammer, Stefan and Holdt, Hans-J{\"u}rgen and M{\"o}ller, Heiko Michael}, title = {Electrospray mass spectrometry and molecular modeling study of formation and stability of silver complexes with diazaperylene and bisisoquinoline}, series = {Journal of mass spectrometry}, volume = {53}, journal = {Journal of mass spectrometry}, number = {5}, publisher = {Wiley}, address = {Hoboken}, issn = {1076-5174}, doi = {10.1002/jms.4071}, pages = {408 -- 418}, year = {2018}, abstract = {The complex formation of the following diazaperylene ligands (L) 1,12-diazaperylene 1, 1,1-bisisoquinoline 2, 2,11-disubstituted 1,12-diazaperylenes (alkyl=methyl, ethyl, isopropyl, 3, 5, 7), 3,3-disubstituted 1,1-bisisoquinoline (alkyl=methyl, ethyl, isopropyl, 4, 6, 8 and with R=phenyl, 11 and with pyridine 12), and the 5,8-dimethoxy-substituted diazaperylene 9, 6,6-dimethoxy-substituted bisisoquinoline 10 with AgBF4 was investigated. Collision-induced dissociation measurements were used to evaluate the relative stabilities of the ligands themselves and for the [1:1](+) complexes as well as for the homoleptic and heteroleptic silver [1:2](+) complexes in the gas phase. This method is very useful in rapid screening of the stabilities of new complexes in the gas phase. The influence of the spatial arrangement of the ligands and the type of substituents employed for the complexation were examined. The effect of the preorganization of the diazaperylene on the threshold activation voltages and thus of the relative binding energies of the different complexes are discussed. Density functional theory calculations were used to calculate the optimized structures of the silver complexes and compared with the stabilities of the complexes in the gas phase for the first time.}, language = {en} } @article{WeberHelwigBaueretal.2012, author = {Weber, Michael H. and Helwig, S. L. and Bauer, Klaus and Haberland, Christian and Koch, Olaf and Ryberg, T. and Maercklin, N. and Ritter, O. and Schulze, A.}, title = {Near-surface properties of an active fault derived by joint interpretation of different geophysical methods - the Arava/Araba Fault in the Middle East}, series = {Near surface geophysics}, volume = {10}, journal = {Near surface geophysics}, number = {5}, publisher = {European Association of Geoscientists \& Engineers}, address = {Houten}, issn = {1569-4445}, doi = {10.3997/1873-0604.2012031}, pages = {381 -- 390}, year = {2012}, abstract = {The motion of tectonic plates is accommodated at fault zones. One of the unanswered questions about fault zones relates to the role they play in controlling shallow and local hydrology. This study focuses on the Arava/Araba Fault (AF) zone, the southern portion of the Dead Sea Transform (DST) in the Middle East. We combine seismic and electromagnetic methods (EM) to image the geometry and map the petro-physical properties and water occurrence in the top 100 m of this active fault. For three profiles, P-velocity and resistivity images were derived independently. Using a neural network cluster analysis three classes with similar P-velocity and resistivities could then be determined from these images. These classes correspond to spatial domains of specific material and wetness. The first class occurs primarily east of the fault consisting of 'wet' sand (dunes) and brecciated sediments, whereas the second class composed of similar material located west of the fault is 'dry'. The third class lies at depth below ca. 50 m and is composed of highly deformed and weathered Precambrian rocks that constitute the multi-branch fault zone of the AF at this location. The combination of two independent measurements like seismics and EM linked by a stringent mathematical approach has thus shown the potential to delineate the interplay of lithology and water near active faults.}, language = {en} } @article{KochTitzeSchroederetal.1999, author = {Koch, Sabine and Titze, Karl and Schr{\"o}der, Michael and Zimmermann, Ralf B. and Lehmkuhl, Gerd and Rauh, Hellgard}, title = {Longterm neurological consequences of maternal epilepsy and anticonvulsant treatment during pregnancy for school-age children and adolescents}, issn = {0013-9580}, year = {1999}, language = {en} } @article{AmbergausdemMooreBekketal.2022, author = {Amberg, Maximilian and aus dem Moore, Nils and Bekk, Anke and Bergmann, Tobias and Edenhofer, Ottmar and Flachsland, Christian and George, Jan and Haywood, Luke and Heinemann, Maik and Held, Anne and Kalkuhl, Matthias and Kellner, Maximilian and Koch, Nicolas and Luderer, Gunnar and Meyer, Henrika and Nikodinoska, Dragana and Pahle, Michael and Roolfs, Christina and Schill, Wolf-Peter}, title = {Reformoptionen f{\"u}r ein nachhaltiges Steuer- und Abgabensystem}, series = {Perspektiven der Wirtschaftspolitik}, volume = {23}, journal = {Perspektiven der Wirtschaftspolitik}, number = {3}, publisher = {De Gruyter}, address = {Berlin}, issn = {1465-6493}, doi = {10.1515/pwp-2021-0051}, pages = {165 -- 199}, year = {2022}, abstract = {Steuern und Abgaben auf Produkte oder Verbrauch mit gesellschaftlichen Folgekosten (externe Kosten) - sogenannte Pigou- oder Lenkungssteuern - sind ein gesellschaftliches „Win-Win-Instrument". Sie verbessern die Wohlfahrt und sch{\"u}tzen gleichzeitig die Umwelt und das Klima. Dies wird erreicht, indem umweltsch{\"a}digende Aktivit{\"a}ten einen Preis bekommen, der m{\"o}glichst exakt der H{\"o}he des Schadens entspricht. Eine konsequente Bepreisung der externen Kosten nach diesem Prinzip k{\"o}nnte in Deutschland erhebliche zus{\"a}tzliche Einnahmen erbringen: Basierend auf bisherigen Studien zu externen Kosten w{\"a}ren zus{\"a}tzliche Einnahmen in der Gr{\"o}ßenordnung von 348 bis 564 Milliarden Euro pro Jahr (44 bis 71 Prozent der gesamten Steuereinnahmen) m{\"o}glich. Die Autoren warnen allerdings, dass die Bezifferung der externen Kosten mit erheblichen Unsicherheiten verbunden ist. Damit Lenkungssteuern und -abgaben ihre positiven Lenkungs- und Wohlstandseffekte voll entfalten k{\"o}nnen, seien zudem institutionelle Reformen notwendig.}, language = {de} } @book{AkyaziBergmannDieterichsetal.2023, author = {Akyazi, Mehmet and Bergmann, Dana and Dieterichs, Michael and G{\"a}nz, Victoria and Hinz, Carsten and Huhn, Nicola and Klitsch, Constantin and Koch, Hayo and L{\"o}ffler, Robert and Meis, Robin and Penning, Isabelle and Rasky, Nicolai and Richter, Christin and Schellen, Ricarda and Schr{\"o}dter, Ayla and Schulz, Oliver and Simon, Veronika and Trojecka, Anetta and Verwohlt, Peter and Vogler, Christin and Vogt, Birgit}, title = {\#Gesellschaftslehre 9/10}, volume = {[Sch{\"u}lerband]}, publisher = {C.C. Buchner}, address = {Bamberg}, isbn = {978-3-661-70053-3}, pages = {464}, year = {2023}, language = {de} } @article{LepetitViereckPiperetal.2014, author = {Lepetit, Petra and Viereck, Lothar and Piper, John D. A. and Sudo, Masafumi and Gurel, Ali and Copuroglu, Ibrahim and Gruber, Manuela and Mayer, Bernhard and Koch, Michael and Tatar, Orhan and Gursoy, Halil}, title = {Ar-40/Ar-39 dating of ignimbrites and plinian air-fall layers from Cappadocia, Central Turkey: Implications to chronostratigraphic and Eastern Mediterranean palaeoenvironmental record}, series = {Chemie der Erde : interdisciplinary journal for chemical problems of the geo-sciences and geo-ecology}, volume = {74}, journal = {Chemie der Erde : interdisciplinary journal for chemical problems of the geo-sciences and geo-ecology}, number = {3}, publisher = {Elsevier}, address = {Jena}, issn = {0009-2819}, doi = {10.1016/j.chemer.2014.05.001}, pages = {471 -- 488}, year = {2014}, abstract = {Magmatism forming the Central Anatolian Volcanic Province of Cappadocia, central Turkey, records the last phase of Neotethyan subduction after similar to 11 Ma. Thirteen large calc-alkaline ignimbrite sheets form marker bands within the volcano-sedimentary succession (the Urgup Formation) and provide a robust chronostratigraphy for paleoecologic evaluation of the interleaved paleosols. This paper evaluates the chronologic record in the context of the radiometric, magnetostratigraphic and lithostratigraphic controls. Previous inconsistencies relating primarily to K/Ar evidence were reason for the initiation of an integrated study which includes Ar-40/Ar-39 dating, palaeomagnetic and stratigraphic evidence. The newly determined Ar-40/Ar-39-ages (Lepetit, 2010) are in agreement with Ar/Ar and U/Pb data meanwhile published by Pauquette and Le Pennec (2012) and Aydar et al. (2012). The Ar-40/Ar-39-ages restrict the end of the Urgup Formation to the late Miocene. The paleosol sequence enclosed by the ignimbrites is thus restricted to the late Miocene, the most intense formation of pedogene calcretes correlating with the Messinian Salinity Crisis.}, language = {en} } @book{EmrichGassmannHerrmannetal.2016, author = {Emrich, Eike and Gassmann, Freya and Herrmann, Konstantin and Koch, Michael and Meyer, Wolfgang}, title = {Die Universit{\"a}t Potsdam in sozio{\"o}konomischer Perspektive}, editor = {Emrich, Eike and Gassmann, Freya and Herrmann, Konstantin}, publisher = {Universit{\"a}tsverlag Potsdam}, address = {Potsdam}, isbn = {978-3-86956-367-1}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-90200}, publisher = {Universit{\"a}t Potsdam}, pages = {409}, year = {2016}, abstract = {Universit{\"a}ten erbringen wohlfahrtsf{\"o}rdernde Leistungen f{\"u}r die Gesellschaft, insbesondere indem sie Studierende ausbilden, {\"u}ber Forschung neues Wissen erzeugen sowie den Wissens- und Technologietransfer in Wirtschaft und Gesellschaft hinein betreiben. Die Erbringung dieser Leistungen wird erm{\"o}glicht durch eine gr{\"o}ßtenteils {\"o}ffentliche Finanzierung, die nicht nur in Zeiten wirtschaftlicher Krisen und Spargebote gerne hinterfragt wird. Die Politik ist daher ebenso wie die Hochschulen gut beraten, die Mittelzuweisungen immer wieder neu zu legitimieren. Die vorliegende Studie untersucht die sozio{\"o}konomischen Effekte der Universit{\"a}t Potsdam und schließt so vorhandene Informationsl{\"u}cken. Die Autoren zeigen, dass auch indirekte und unerwartete Effekte eine große Rolle spielen k{\"o}nnen, was die Wirkung einer Universit{\"a}t auf Wirtschaft und Wohlstand angeht.}, language = {de} } @article{AceroAloisioAmansetal.2017, author = {Acero, F. and Aloisio, R. and Amans, J. and Amato, Elena and Antonelli, L. A. and Aramo, C. and Armstrong, T. and Arqueros, F. and Asano, Katsuaki and Ashley, M. and Backes, M. and Balazs, C. and Balzer, A. and Bamba, Aya and Barkov, Maxim and Barrio, J. A. and Benbow, Wystan and Bernloehr, K. and Beshley, V. and Bigongiari, C. and Biland, A. and Bilinsky, A. and Bissaldi, Elisabetta and Biteau, J. and Blanch, O. and Blasi, P. and Blazek, J. and Boisson, C. and Bonanno, G. and Bonardi, A. and Bonavolonta, C. and Bonnoli, G. and Braiding, C. and Brau-Nogue, S. and Bregeon, J. and Brown, A. M. and Bugaev, V. and Bulgarelli, A. and Bulik, T. and Burton, Michael and Burtovoi, A. and Busetto, G. and Bottcher, M. and Cameron, R. and Capalbi, M. and Caproni, Anderson and Caraveo, P. and Carosi, R. and Cascone, E. and Cerruti, M. and Chaty, Sylvain and Chen, A. and Chen, X. and Chernyakova, M. and Chikawa, M. and Chudoba, J. and Cohen-Tanugi, J. and Colafrancesco, S. and Conforti, V. and Contreras, J. L. and Costa, A. and Cotter, G. and Covino, Stefano and Covone, G. and Cumani, P. and Cusumano, G. and Daniel, M. and Dazzi, F. and De Angelis, A. and De Cesare, G. and De Franco, A. and De Frondat, F. and Dal Pino, E. M. de Gouveia and De Lisio, C. and Lopez, R. de los Reyes and De Lotto, B. and de Naurois, M. and De Palma, F. and Del Santo, M. and Delgado, C. and della Volpe, D. and Di Girolamo, T. and Di Giulio, C. and Di Pierro, F. and Di Venere, L. and Doro, M. and Dournaux, J. and Dumas, D. and Dwarkadas, Vikram V. and Diaz, C. and Ebr, J. and Egberts, Kathrin and Einecke, S. and Elsaesser, D. and Eschbach, S. and Falceta-Goncalves, D. and Fasola, G. and Fedorova, E. and Fernandez-Barral, A. and Ferrand, Gilles and Fesquet, M. and Fiandrini, E. and Fiasson, A. and Filipovic, Miroslav D. and Fioretti, V. and Font, L. and Fontaine, Gilles and Franco, F. J. and Freixas Coromina, L. and Fujita, Yutaka and Fukui, Y. and Funk, S. and Forster, A. and Gadola, A. and Lopez, R. Garcia and Garczarczyk, M. and Giglietto, N. and Giordano, F. and Giuliani, A. and Glicenstein, J. and Gnatyk, R. and Goldoni, P. and Grabarczyk, T. and Graciani, R. and Graham, J. and Grandi, P. and Granot, Jonathan and Green, A. J. and Griffiths, S. and Gunji, S. and Hakobyan, H. and Hara, S. and Hassan, T. and Hayashida, M. and Heller, M. and Helo, J. C. and Hinton, J. and Hnatyk, B. and Huet, J. and Huetten, M. and Humensky, T. B. and Hussein, M. and Horandel, J. and Ikeno, Y. and Inada, T. and Inome, Y. and Inoue, S. and Inoue, T. and Inoue, Y. and Ioka, K. and Iori, Maurizio and Jacquemier, J. and Janecek, P. and Jankowsky, D. and Jung, I. and Kaaret, P. and Katagiri, H. and Kimeswenger, S. and Kimura, Shigeo S. and Knodlseder, J. and Koch, B. and Kocot, J. and Kohri, K. and Komin, N. and Konno, Y. and Kosack, K. and Koyama, S. and Kraus, Michaela and Kubo, Hidetoshi and Mezek, G. Kukec and Kushida, J. and La Palombara, N. and Lalik, K. and Lamanna, G. and Landt, H. and Lapington, J. and Laporte, P. and Lee, S. and Lees, J. and Lefaucheur, J. and Lenain, J. -P. and Leto, Giuseppe and Lindfors, E. and Lohse, T. and Lombardi, S. and Longo, F. and Lopez, M. and Lucarelli, F. and Luque-Escamilla, Pedro Luis and Lopez-Coto, R. and Maccarone, M. C. and Maier, G. and Malaguti, G. and Mandat, D. and Maneva, G. and Mangano, S. and Marcowith, Alexandre and Marti, J. and Martinez, M. and Martinez, G. and Masuda, S. and Maurin, G. and Maxted, N. and Melioli, Claudio and Mineo, T. and Mirabal, N. and Mizuno, T. and Moderski, R. and Mohammed, M. and Montaruli, T. and Moralejo, A. and Mori, K. and Morlino, G. and Morselli, A. and Moulin, Emmanuel and Mukherjee, R. and Mundell, C. and Muraishi, H. and Murase, Kohta and Nagataki, Shigehiro and Nagayoshi, T. and Naito, T. and Nakajima, D. and Nakamori, T. and Nemmen, R. and Niemiec, Jacek and Nieto, D. and Nievas-Rosillo, M. and Nikolajuk, M. and Nishijima, K. and Noda, K. and Nogues, L. and Nosek, D. and Novosyadlyj, B. and Nozaki, S. and Ohira, Yutaka and Ohishi, M. and Ohm, S. and Okumura, A. and Ong, R. A. and Orito, R. and Orlati, A. and Ostrowski, M. and Oya, I. and Padovani, Marco and Palacio, J. and Palatka, M. and Paredes, Josep M. and Pavy, S. and Persic, M. and Petrucci, P. and Petruk, Oleh and Pisarski, A. and Pohl, Martin and Porcelli, A. and Prandini, E. and Prast, J. and Principe, G. and Prouza, M. and Pueschel, Elisa and Puelhofer, G. and Quirrenbach, A. and Rameez, M. and Reimer, O. and Renaud, M. and Ribo, M. and Rico, J. and Rizi, V. and Rodriguez, J. and Fernandez, G. Rodriguez and Rodriguez Vazquez, J. J. and Romano, Patrizia and Romeo, G. and Rosado, J. and Rousselle, J. and Rowell, G. and Rudak, B. and Sadeh, I. and Safi-Harb, S. and Saito, T. and Sakaki, N. and Sanchez, D. and Sangiorgi, P. and Sano, H. and Santander, M. and Sarkar, S. and Sawada, M. and Schioppa, E. J. and Schoorlemmer, H. and Schovanek, P. and Schussler, F. and Sergijenko, O. and Servillat, M. and Shalchi, A. and Shellard, R. C. and Siejkowski, H. and Sillanpaa, A. and Simone, D. and Sliusar, V. and Sol, H. and Stanic, S. and Starling, R. and Stawarz, L. and Stefanik, S. and Stephan, M. and Stolarczyk, T. and Szanecki, M. and Szepieniec, T. and Tagliaferri, G. and Tajima, H. and Takahashi, M. and Takeda, J. and Tanaka, M. and Tanaka, S. and Tejedor, L. A. and Telezhinsky, Igor O. and Temnikov, P. and Terada, Y. and Tescaro, D. and Teshima, M. and Testa, V. and Thoudam, S. and Tokanai, F. and Torres, D. F. and Torresi, E. and Tosti, G. and Townsley, C. and Travnicek, P. and Trichard, C. and Trifoglio, M. and Tsujimoto, S. and Vagelli, V. and Vallania, P. and Valore, L. and van Driel, W. and van Eldik, C. and Vandenbroucke, Justin and Vassiliev, V. and Vecchi, M. and Vercellone, Stefano and Vergani, S. and Vigorito, C. and Vorobiov, S. and Vrastil, M. and Vazquez Acosta, M. L. and Wagner, S. J. and Wagner, R. and Wakely, S. P. and Walter, R. and Ward, J. E. and Watson, J. J. and Weinstein, A. and White, M. and White, R. and Wierzcholska, A. and Wilcox, P. and Williams, D. A. and Wischnewski, R. and Wojcik, P. and Yamamoto, T. and Yamamoto, H. and Yamazaki, Ryo and Yanagita, S. and Yang, L. and Yoshida, T. and Yoshida, M. and Yoshiike, S. and Yoshikoshi, T. and Zacharias, M. and Zampieri, L. and Zanin, R. and Zavrtanik, M. and Zavrtanik, D. and Zdziarski, A. and Zech, Alraune and Zechlin, Hannes and Zhdanov, V. and Ziegler, A. and Zorn, J.}, title = {Prospects for Cherenkov Telescope Array Observations of the Young Supernova Remnant RX J1713.7-3946}, series = {The astrophysical journal : an international review of spectroscopy and astronomical physics}, volume = {840}, journal = {The astrophysical journal : an international review of spectroscopy and astronomical physics}, number = {2}, publisher = {IOP Publ. Ltd.}, address = {Bristol}, issn = {0004-637X}, doi = {10.3847/1538-4357/aa6d67}, pages = {14}, year = {2017}, abstract = {We perform simulations for future Cherenkov Telescope Array (CTA) observations of RX J1713.7-3946, a young supernova remnant (SNR) and one of the brightest sources ever discovered in very high energy (VHE) gamma rays. Special attention is paid to exploring possible spatial (anti) correlations of gamma rays with emission at other wavelengths, in particular X-rays and CO/H I emission. We present a series of simulated images of RX J1713.7-3946 for CTA based on a set of observationally motivated models for the gamma-ray emission. In these models, VHE gamma rays produced by high-energy electrons are assumed to trace the nonthermal X-ray emission observed by XMM-Newton, whereas those originating from relativistic protons delineate the local gas distributions. The local atomic and molecular gas distributions are deduced by the NANTEN team from CO and H I observations. Our primary goal is to show how one can distinguish the emission mechanism(s) of the gamma rays (i.e., hadronic versus leptonic, or a mixture of the two) through information provided by their spatial distribution, spectra, and time variation. This work is the first attempt to quantitatively evaluate the capabilities of CTA to achieve various proposed scientific goals by observing this important cosmic particle accelerator.}, language = {en} } @article{ZuWolffRalaiarisoaetal.2019, author = {Zu, Fengshuo and Wolff, Christian Michael and Ralaiarisoa, Maryline and Amsalem, Patrick and Neher, Dieter and Koch, Norbert}, title = {Unraveling the Electronic Properties of Lead Halide Perovskites with Surface Photovoltage in Photoemission Studies}, series = {ACS applied materials \& interfaces}, volume = {11}, journal = {ACS applied materials \& interfaces}, number = {24}, publisher = {American Chemical Society}, address = {Washington}, issn = {1944-8244}, doi = {10.1021/acsami.9b05293}, pages = {21578 -- 21583}, year = {2019}, abstract = {The tremendous success of metal-halide perovskites, especially in the field of photovoltaics, has triggered a substantial number of studies in understanding their optoelectronic properties. However, consensus regarding the electronic properties of these perovskites is lacking due to a huge scatter in the reported key parameters, such as work function (Φ) and valence band maximum (VBM) values. Here, we demonstrate that the surface photovoltage (SPV) is a key phenomenon occurring at the perovskite surfaces that feature a non-negligible density of surface states, which is more the rule than an exception for most materials under study. With ultraviolet photoelectron spectroscopy (UPS) and Kelvin probe, we evidence that even minute UV photon fluxes (500 times lower than that used in typical UPS experiments) are sufficient to induce SPV and shift the perovskite Φ and VBM by several 100 meV compared to dark. By combining UV and visible light, we establish flat band conditions (i.e., compensate the surface-state-induced surface band bending) at the surface of four important perovskites, and find that all are p-type in the bulk, despite a pronounced n-type surface character in the dark. The present findings highlight that SPV effects must be considered in all surface studies to fully understand perovskites' photophysical properties.}, language = {en} } @article{ZuSchultzWolffetal.2020, author = {Zu, Fengshuo and Schultz, Thorsten and Wolff, Christian Michael and Shin, Dongguen and Frohloff, Lennart and Neher, Dieter and Amsalem, Patrick and Koch, Norbert}, title = {Position-locking of volatile reaction products by atmosphere and capping layers slows down photodecomposition of methylammonium lead triiodide perovskite}, series = {RSC Advances}, volume = {10}, journal = {RSC Advances}, number = {30}, publisher = {Royal Society of Chemistry}, address = {Cambridge}, issn = {2046-2069}, doi = {10.1039/d0ra03572f}, pages = {17534 -- 17542}, year = {2020}, abstract = {The remarkable progress of metal halide perovskites in photovoltaics has led to the power conversion efficiency approaching 26\%. However, practical applications of perovskite-based solar cells are challenged by the stability issues, of which the most critical one is photo-induced degradation. Bare CH3NH3PbI3 perovskite films are known to decompose rapidly, with methylammonium and iodine as volatile species and residual solid PbI2 and metallic Pb, under vacuum under white light illumination, on the timescale of minutes. We find, in agreement with previous work, that the degradation is non-uniform and proceeds predominantly from the surface, and that illumination under N-2 and ambient air (relative humidity 20\%) does not induce substantial degradation even after several hours. Yet, in all cases the release of iodine from the perovskite surface is directly identified by X-ray photoelectron spectroscopy. This goes in hand with a loss of organic cations and the formation of metallic Pb. When CH3NH3PbI3 films are covered with a few nm thick organic capping layer, either charge selective or non-selective, the rapid photodecomposition process under ultrahigh vacuum is reduced by more than one order of magnitude, and becomes similar in timescale to that under N-2 or air. We conclude that the light-induced decomposition reaction of CH3NH3PbI3, leading to volatile methylammonium and iodine, is largely reversible as long as these products are restrained from leaving the surface. This is readily achieved by ambient atmospheric pressure, as well as a thin organic capping layer even under ultrahigh vacuum. In addition to explaining the impact of gas pressure on the stability of this perovskite, our results indicate that covalently "locking" the position of perovskite components at the surface or an interface should enhance the overall photostability.}, language = {en} } @article{KoebschWinkelLiebneretal.2019, author = {Koebsch, Franziska and Winkel, Matthias and Liebner, Susanne and Liu, Bo and Westphal, Julia and Schmiedinger, Iris and Spitzy, Alejandro and Gehre, Matthias and Jurasinski, Gerald and K{\"o}hler, Stefan and Unger, Viktoria and Koch, Marian and Sachs, Torsten and B{\"o}ttcher, Michael E.}, title = {Sulfate deprivation triggers high methane production in a disturbed and rewetted coastal peatland}, series = {Biogeosciences}, volume = {16}, journal = {Biogeosciences}, number = {9}, publisher = {Copernicus}, address = {G{\"o}ttingen}, issn = {1726-4170}, doi = {10.5194/bg-16-1937-2019}, pages = {1937 -- 1953}, year = {2019}, abstract = {In natural coastal wetlands, high supplies of marine sulfate suppress methanogenesis. Coastal wetlands are, however, often subject to disturbance by diking and drainage for agricultural use and can turn to potent methane sources when rewetted for remediation. This suggests that preceding land use measures can suspend the sulfate-related methane suppressing mechanisms. Here, we unravel the hydrological relocation and biogeochemical S and C transformation processes that induced high methane emissions in a disturbed and rewetted peatland despite former brackish impact. The underlying processes were investigated along a transect of increasing distance to the coastline using a combination of concentration patterns, stable isotope partitioning, and analysis of the microbial community structure. We found that diking and freshwater rewetting caused a distinct freshening and an efficient depletion of the brackish sulfate reservoir by dissimilatory sulfate reduction (DSR). Despite some legacy effects of brackish impact expressed as high amounts of sedimentary S and elevated electrical conductivities, contemporary metabolic processes operated mainly under sulfate-limited conditions. This opened up favorable conditions for the establishment of a prospering methanogenic community in the top 30-40 cm of peat, the structure and physiology of which resemble those of terrestrial organic-rich environments. Locally, high amounts of sulfate persisted in deeper peat layers through the inhibition of DSR, probably by competitive electron acceptors of terrestrial origin, for example Fe(III). However, as sulfate occurred only in peat layers below 30-40 cm, it did not interfere with high methane emissions on an ecosystem scale. Our results indicate that the climate effect of disturbed and remediated coastal wetlands cannot simply be derived by analogy with their natural counterparts. From a greenhouse gas perspective, the re-exposure of diked wetlands to natural coastal dynamics would literally open up the floodgates for a replenishment of the marine sulfate pool and therefore constitute an efficient measure to reduce methane emissions.}, language = {en} } @misc{KochCasselLinneetal.2017, author = {Koch, Sarah and Cassel, Michael and Linne, Karsten and Mayer, Frank and Scharhag, J{\"u}rgen}, title = {ECG and echocardiographic findings in 10-15-year-old elite athletes}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-403186}, pages = {8}, year = {2017}, abstract = {Background: Data on electrocardiographic and echocardiographic pre-participation screening findings in paediatric athletes are limited. Methods and results: 10-15 year-old athletes (n = 343) were screened using electro- and echocardiography. The electrocardiogram (ECG) was normal in 220 (64\%), mildly abnormal in 108 (31\%), and distinctly abnormal in 15 (4\%) athletes. Echocardiographic upper reference limits (URL, 97.5 percentile) for the left ventricular (LV) wall thickness in 10-11-year-old boys and girls were 9-10 mm and 8-9 mm, respectively; in 12-13-year-old boys and girls 9-10 mm; and in 14-15-year-old boys and girls 10-11 mm and 9-10 mm, respectively. Three athletes were excluded from competitive sports: one for symptomatic Wolff-Parkinson-White syndrome with a normal echocardiogram; one for negative T-waves in V-1-V-4 and a dilated right ventricle by echocardiography suggestive of (arrhythmogenic) right ventricular disease; and one for normal ECG and biscupid aortic valve including an aneurysm of the ascending aorta detected by echocardiography. Related to echocardiographic findings, the sensitivity and specificity of the ECG to identify cardiovascular abnormalities was 38\% and 64\%, respectively. The ECG's positive-predictive and negative-predictive values were 13\% and 88\%, respectively. The numbers needed to screen and calculated costs were 172 for ECG ( 7049), 172 for echocardiography ( 11,530), and 114 combining ECG and echocardiography ( 9323). Conclusions: Compared to adults, paediatric athletes presented with fewer distinctly abnormal ECGs, and there was no gender difference in paediatric athletes' ECG-pattern distribution. A combination of ECG and echocardiography for pre-participation screening of paediatric athletes is superior to ECG alone but 30\% more costly.}, language = {en} } @article{NoonanTuckerFlemingetal.2018, author = {Noonan, Michael J. and Tucker, Marlee A. and Fleming, Christen H. and Akre, Thomas S. and Alberts, Susan C. and Ali, Abdullahi H. and Altmann, Jeanne and Antunes, Pamela Castro and Belant, Jerrold L. and Beyer, Dean and Blaum, Niels and Boehning-Gaese, Katrin and Cullen Jr, Laury and de Paula, Rogerio Cunha and Dekker, Jasja and Drescher-Lehman, Jonathan and Farwig, Nina and Fichtel, Claudia and Fischer, Christina and Ford, Adam T. and Goheen, Jacob R. and Janssen, Rene and Jeltsch, Florian and Kauffman, Matthew and Kappeler, Peter M. and Koch, Flavia and LaPoint, Scott and Markham, A. Catherine and Medici, Emilia Patricia and Morato, Ronaldo G. and Nathan, Ran and Oliveira-Santos, Luiz Gustavo R. and Olson, Kirk A. and Patterson, Bruce D. and Paviolo, Agustin and Ramalho, Emiliano Estero and Rosner, Sascha and Schabo, Dana G. and Selva, Nuria and Sergiel, Agnieszka and da Silva, Marina Xavier and Spiegel, Orr and Thompson, Peter and Ullmann, Wiebke and Zieba, Filip and Zwijacz-Kozica, Tomasz and Fagan, William F. and Mueller, Thomas and Calabrese, Justin M.}, title = {A comprehensive analysis of autocorrelation and bias in home range estimation}, series = {Ecological monographs : a publication of the Ecological Society of America.}, volume = {89}, journal = {Ecological monographs : a publication of the Ecological Society of America.}, number = {2}, publisher = {Wiley}, address = {Hoboken}, issn = {0012-9615}, doi = {10.1002/ecm.1344}, pages = {21}, year = {2018}, abstract = {Home range estimation is routine practice in ecological research. While advances in animal tracking technology have increased our capacity to collect data to support home range analysis, these same advances have also resulted in increasingly autocorrelated data. Consequently, the question of which home range estimator to use on modern, highly autocorrelated tracking data remains open. This question is particularly relevant given that most estimators assume independently sampled data. Here, we provide a comprehensive evaluation of the effects of autocorrelation on home range estimation. We base our study on an extensive data set of GPS locations from 369 individuals representing 27 species distributed across five continents. We first assemble a broad array of home range estimators, including Kernel Density Estimation (KDE) with four bandwidth optimizers (Gaussian reference function, autocorrelated-Gaussian reference function [AKDE], Silverman's rule of thumb, and least squares cross-validation), Minimum Convex Polygon, and Local Convex Hull methods. Notably, all of these estimators except AKDE assume independent and identically distributed (IID) data. We then employ half-sample cross-validation to objectively quantify estimator performance, and the recently introduced effective sample size for home range area estimation ( N̂ area ) to quantify the information content of each data set. We found that AKDE 95\% area estimates were larger than conventional IID-based estimates by a mean factor of 2. The median number of cross-validated locations included in the hold-out sets by AKDE 95\% (or 50\%) estimates was 95.3\% (or 50.1\%), confirming the larger AKDE ranges were appropriately selective at the specified quantile. Conversely, conventional estimates exhibited negative bias that increased with decreasing N̂ area. To contextualize our empirical results, we performed a detailed simulation study to tease apart how sampling frequency, sampling duration, and the focal animal's movement conspire to affect range estimates. Paralleling our empirical results, the simulation study demonstrated that AKDE was generally more accurate than conventional methods, particularly for small N̂ area. While 72\% of the 369 empirical data sets had >1,000 total observations, only 4\% had an N̂ area >1,000, where 30\% had an N̂ area <30. In this frequently encountered scenario of small N̂ area, AKDE was the only estimator capable of producing an accurate home range estimate on autocorrelated data.}, language = {en} } @article{ZuAmsalemEggeretal.2019, author = {Zu, Fengshuo and Amsalem, Patrick and Egger, David A. and Wang, Rongbin and Wolff, Christian Michael and Fang, Honghua and Loi, Maria Antonietta and Neher, Dieter and Kronik, Leeor and Duhm, Steffen and Koch, Norbert}, title = {Constructing the Electronic Structure of CH3NH3PbI3 and CH3NH3PbBr3 Perovskite Thin Films from Single-Crystal Band Structure Measurements}, series = {The journal of physical chemistry letters}, volume = {10}, journal = {The journal of physical chemistry letters}, number = {3}, publisher = {American Chemical Society}, address = {Washington}, issn = {1948-7185}, doi = {10.1021/acs.jpclett.8b03728}, pages = {601 -- 609}, year = {2019}, abstract = {Photovoltaic cells based on halide perovskites, possessing remarkably high power conversion efficiencies have been reported. To push the development of such devices further, a comprehensive and reliable understanding of their electronic properties is essential but presently not available. To provide a solid foundation for understanding the electronic properties of polycrystalline thin films, we employ single-crystal band structure data from angle-resolved photoemission measurements. For two prototypical perovskites (CH3NH3PbBr3 and CH3NH3PbI3), we reveal the band dispersion in two high-symmetry directions and identify the global valence band maxima. With these benchmark data, we construct "standard" photoemission spectra from polycrystalline thin film samples and resolve challenges discussed in the literature for determining the valence band onset with high reliability. Within the framework laid out here, the consistency of relating the energy level alignment in perovskite-based photovoltaic and optoelectronic devices with their functional parameters is substantially enhanced.}, language = {en} } @article{KochCasselLinneetal.2014, author = {Koch, Sarah and Cassel, Michael and Linne, Karsten and Mayer, Frank and Scharhag, J{\"u}rgen}, title = {ECG and echocardiographic findings in 10-15-year-old elite athletes}, series = {European journal of preventive cardiology : the official ESC journal for primary \& secondary cardiovascular prevention, rehabilitation and sports cardiology}, volume = {21}, journal = {European journal of preventive cardiology : the official ESC journal for primary \& secondary cardiovascular prevention, rehabilitation and sports cardiology}, number = {6}, publisher = {Sage Publ.}, address = {London}, issn = {2047-4873}, doi = {10.1177/2047487312462147}, pages = {774 -- 781}, year = {2014}, abstract = {Background: Data on electrocardiographic and echocardiographic pre-participation screening findings in paediatric athletes are limited.}, language = {en} } @article{WolffZuPaulkeetal.2017, author = {Wolff, Christian Michael and Zu, Fengshuo and Paulke, Andreas and Perdig{\´o}n-Toro, Lorena and Koch, Norbert and Neher, Dieter}, title = {Reduced Interface-Mediated Recombination for High Open-Circuit Voltages in CH3NH3PbI3 Solar Cells}, series = {Advanced materials}, volume = {29}, journal = {Advanced materials}, publisher = {Wiley-VCH}, address = {Weinheim}, issn = {0935-9648}, doi = {10.1002/adma.201700159}, pages = {8}, year = {2017}, abstract = {Perovskite solar cells with all-organic transport layers exhibit efficiencies rivaling their counterparts that employ inorganic transport layers, while avoiding high-temperature processing. Herein, it is investigated how the choice of the fullerene derivative employed in the electron-transporting layer of inverted perovskite cells affects the open-circuit voltage (V-OC). It is shown that nonradiative recombination mediated by the electron-transporting layer is the limiting factor for the V-OC in the cells. By inserting an ultrathin layer of an insulating polymer between the active CH3NH3PbI3 perovskite and the fullerene, an external radiative efficiency of up to 0.3\%, a V-OC as high as 1.16 V, and a power conversion efficiency of 19.4\% are realized. The results show that the reduction of nonradiative recombination due to charge-blocking at the perovskite/organic interface is more important than proper level alignment in the search for ideal selective contacts toward high V-OC and efficiency.}, language = {en} } @article{CaprioglioZuWolffetal.2019, author = {Caprioglio, Pietro and Zu, Fengshuo and Wolff, Christian Michael and Prieto, Jose A. Marquez and Stolterfoht, Martin and Becker, Pascal and Koch, Norbert and Unold, Thomas and Rech, Bernd and Albrecht, Steve and Neher, Dieter}, title = {High open circuit voltages in pin-type perovskite solar cells through strontium addition}, series = {Sustainable Energy \& Fuels}, volume = {3}, journal = {Sustainable Energy \& Fuels}, number = {2}, publisher = {Royal Society of Chemistry}, address = {Cambridge}, issn = {2398-4902}, doi = {10.1039/c8se00509e}, pages = {550 -- 563}, year = {2019}, abstract = {The incorporation of even small amounts of strontium (Sr) into lead-base hybrid quadruple cation perovskite solar cells results in a systematic increase of the open circuit voltage (V-oc) in pin-type perovskite solar cells. We demonstrate via absolute and transient photoluminescence (PL) experiments how the incorporation of Sr significantly reduces the non-radiative recombination losses in the neat perovskite layer. We show that Sr segregates at the perovskite surface, where it induces important changes of morphology and energetics. Notably, the Sr-enriched surface exhibits a wider band gap and a more n-type character, accompanied with significantly stronger surface band bending. As a result, we observe a significant increase of the quasi-Fermi level splitting in the neat perovskite by reduced surface recombination and more importantly, a strong reduction of losses attributed to non-radiative recombination at the interface to the C-60 electron-transporting layer. The resulting solar cells exhibited a V-oc of 1.18 V, which could be further improved to nearly 1.23 V through addition of a thin polymer interlayer, reducing the non-radiative voltage loss to only 110 meV. Our work shows that simply adding a small amount of Sr to the precursor solutions induces a beneficial surface modification in the perovskite, without requiring any post treatment, resulting in high efficiency solar cells with power conversion efficiency (PCE) up to 20.3\%. Our results demonstrate very high V-oc values and efficiencies in Sr-containing quadruple cation perovskite pin-type solar cells and highlight the imperative importance of addressing and minimizing the recombination losses at the interface between perovskite and charge transporting layer.}, language = {en} } @misc{WolffCanilRehermannetal.2020, author = {Wolff, Christian Michael and Canil, Laura and Rehermann, Carolin and Nguyen, Ngoc Linh and Zu, Fengshuo and Ralaiarisoa, Maryline and Caprioglio, Pietro and Fiedler, Lukas and Stolterfoht, Martin and Kogikoski, Junior, Sergio and Bald, Ilko and Koch, Norbert and Unger, Eva L. and Dittrich, Thomas and Abate, Antonio and Neher, Dieter}, title = {Correction to 'Perfluorinated self-assembled monolayers enhance the stability and efficiency of inverted perovskite solar cells' (2020, 14 (2), 1445-1456)}, series = {ACS nano}, volume = {14}, journal = {ACS nano}, number = {11}, publisher = {American Chemical Society}, address = {Washington, DC}, issn = {1936-0851}, doi = {10.1021/acsnano.0c08081}, pages = {16156 -- 16156}, year = {2020}, language = {en} } @article{RaoufiHoermannLigorioetal.2020, author = {Raoufi, Meysam and H{\"o}rmann, Ulrich and Ligorio, Giovanni and Hildebrandt, Jana and P{\"a}tzel, Michael and Schultz, Thorsten and Perdig{\´o}n-Toro, Lorena and Koch, Norbert and List-Kratochvil, Emil and Hecht, Stefan and Neher, Dieter}, title = {Simultaneous effect of ultraviolet radiation and surface modification on the work function and hole injection properties of ZnO thin films}, series = {Physica Status Solidi. A , Applications and materials science}, volume = {217}, journal = {Physica Status Solidi. A , Applications and materials science}, number = {5}, publisher = {Wiley-VCH}, address = {Weinheim}, issn = {1862-6300}, doi = {10.1002/pssa.201900876}, pages = {1 -- 6}, year = {2020}, abstract = {The combined effect of ultraviolet (UV) light soaking and self-assembled monolayer deposition on the work function (WF) of thin ZnO layers and on the efficiency of hole injection into the prototypical conjugated polymer poly(3-hexylthiophen-2,5-diyl) (P3HT) is systematically investigated. It is shown that the WF and injection efficiency depend strongly on the history of UV light exposure. Proper treatment of the ZnO layer enables ohmic hole injection into P3HT, demonstrating ZnO as a potential anode material for organic optoelectronic devices. The results also suggest that valid conclusions on the energy-level alignment at the ZnO/organic interfaces may only be drawn if the illumination history is precisely known and controlled. This is inherently problematic when comparing electronic data from ultraviolet photoelectron spectroscopy (UPS) measurements carried out under different or ill-defined illumination conditions.}, language = {en} }