@article{DelahayeGoebelLoebbickeetal.2012,
  author    = {Delahaye, Emilie and Goebel, Ronald and Loebbicke, Ruben and Guillot, Regis and Sieber, Christoph and Taubert, Andreas},
  title     = {Silica ionogels for proton transport},
  series = {Journal of materials chemistry},
  volume    = {22},
  journal   = {Journal of materials chemistry},
  number    = {33},
  publisher = {Royal Society of Chemistry},
  address   = {Cambridge},
  issn      = {0959-9428},
  doi       = {10.1039/c2jm00037g},
  pages     = {17140 -- 17146},
  year      = {2012},
  abstract  = {A number of ionogels - silica-ionic liquid (IL) hybrid materials - were synthesized and studied for their ionic conductivity. The materials are based on a sulfonated IL, 1-methyl-3-(3-sulfopropyl-)-imidazolium p-toluenesulfonate, [PmimSO(3)H][PTS], which contains a sulfonic acid/sulfonate group both in the IL anion and in the side chain of the IL cation. By way of the sulfonate-sulfonic acid proton transfer, the IL imparts the ionogel with a high ionic conductivity of ca. 10(-2) S cm(-1) in the as-synthesized state at 120 degrees C and 10(-3) S cm(-1) in the dry state at 120 degrees C. The ionogels are stable up to ca. 150 degrees C in dynamic thermogravimetric analysis. This suggests that these materials, which are relatively cheap and easily fabricated, could find application in fuel cells in intermediate temperature ranges where many other membrane materials are not suitable.},
  language  = {en}
}
@article{GoebelXieNeumannetal.2012,
  author    = {Goebel, Ronald and Xie, Zai-Lai and Neumann, Mike and G{\"u}nter, Christina and Loebbicke, Ruben and Kubo, Shiori and Titirici, Maria-Magdalena and Giordano, Cristina and Taubert, Andreas},
  title     = {Synthesis of mesoporous carbon/iron carbide hybrids with unusually high surface areas from the ionic liquid precursor [Bmim][FeCl4]},
  series = {CrystEngComm},
  volume    = {14},
  journal   = {CrystEngComm},
  number    = {15},
  publisher = {Royal Society of Chemistry},
  address   = {Cambridge},
  issn      = {1466-8033},
  doi       = {10.1039/c2ce25064k},
  pages     = {4946 -- 4951},
  year      = {2012},
  abstract  = {Mesoporous carbon/iron carbide hybrid materials with surface areas reaching 800 m(2) g(-1) were synthesized via an exotemplating route using monolithic mesoporous silica as template and the ionic liquid 1-butyl-3-methylimidazolium tetrachloridoferrate(III) [Bmim][FeCl4] as carbon and iron source. After heat treatment (750 degrees C under argon) of the [Bmim][FeCl4] precursor confined within the silica matrix, the silica exotemplate was removed with HF leaving the mesoporous C/Fe3C hybrid behind. The surface areas and the pore sizes depend on the exotemplate and the surface areas a significantly larger than any other surface area reported for C/Fe3C hybrid materials so far. The approach is thus a prototype for the synthesis of high-surface area iron carbide-based hybrid materials with potential application in catalysis.},
  language  = {en}
}