@article{ArchambaultArcherBenbowetal.2017, author = {Archambault, S. and Archer, A. and Benbow, Wystan and Bird, Ralph and Bourbeau, E. and Buchovecky, M. and Buckley, J. H. and Bugaev, V. and Cerruti, M. and Connolly, M. P. and Cui, W. and Dwarkadas, Vikram V. and Errando, M. and Falcone, A. and Feng, Q. and Finley, J. P. and Fleischhack, H. and Fortson, L. and Furniss, A. and Griffin, S. and Huetten, M. and Hanna, D. and Holder, J. and Johnson, C. A. and Kaaret, P. and Kar, P. and Kelley-Hoskins, N. and Kertzman, M. and Kieda, D. and Krause, M. and Kumar, S. and Lang, M. J. and Maier, G. and McArthur, S. and McCann, A. and Moriarty, P. and Mukherjee, R. and Nieto, D. and Ong, R. A. and Otte, A. N. and Park, Nahee and Pohl, Martin and Popkow, A. and Pueschel, Elisa and Quinn, J. and Ragan, K. and Reynolds, P. T. and Richards, G. T. and Roache, E. and Sadeh, I. and Santander, M. and Sembroski, G. H. and Shahinyan, K. and Slane, P. and Staszak, D. and Telezhinsky, Igor O. and Trepanier, S. and Tyler, J. and Wakely, S. P. and Weinstein, A. and Weisgarber, T. and Wilcox, P. and Wilhelm, Alina and Williams, D. A. and Zitzer, B.}, title = {Gamma-ray Observations of Tycho's Supernova Remnant with VERITAS and Fermi}, series = {The astrophysical journal : an international review of spectroscopy and astronomical physics}, volume = {836}, journal = {The astrophysical journal : an international review of spectroscopy and astronomical physics}, number = {1}, publisher = {IOP Publ. Ltd.}, address = {Bristol}, issn = {0004-637X}, doi = {10.3847/1538-4357/836/1/23}, pages = {8}, year = {2017}, language = {en} } @article{AliuArchambaultAuneetal.2014, author = {Aliu, E. and Archambault, S. and Aune, T. and Behera, B. and Beilicke, M. and Benbow, W. and Berger, K. and Bird, R. and Buckley, J. H. and Bugaev, V. and Cardenzana, J. V. and Cerruti, M. and Chen, Xuhui and Ciupik, L. and Collins-Hughes, E. and Connolly, M. P. and Cui, W. and Dumm, J. and Dwarkadas, Vikram V. and Errando, M. and Falcone, A. and Federici, Simone and Feng, Q. and Finley, J. P. and Fleischhack, H. and Fortin, P. and Fortson, L. and Furniss, A. and Galante, N. and Gall, D. and Gillanders, G. H. and Griffin, S. and Griffiths, S. T. and Grube, J. and Gyuk, G. and Hanna, D. and Holder, J. and Hughes, G. and Humensky, T. B. and Kaaret, P. and Kertzman, M. and Khassen, Y. and Kieda, D. and Krennrich, F. and Kumar, S. and Lang, M. J. and Madhavan, A. S. and Maier, G. and McCann, A. J. and Meagher, K. and Millis, J. and Moriarty, P. and Mukherjee, R. and Nieto, D. and Ong, R. A. and Otte, A. N. and Pandel, D. and Park, N. and Pohl, Martin and Popkow, A. and Prokoph, H. and Quinn, J. and Ragan, K. and Rajotte, J. and Ratliff, G. and Reyes, L. C. and Reynolds, P. T. and Richards, G. T. and Roache, E. and Rousselle, J. and Sembroski, G. H. and Shahinyan, K. and Sheidaei, F. and Smith, A. W. and Staszak, D. and Telezhinsky, Igor O. and Tsurusaki, K. and Tucci, J. V. and Tyler, J. and Varlotta, A. and Vassiliev, V. V. and Vincent, S. and Wakely, S. P. and Ward, J. E. and Weinstein, A. and Welsing, R. and Wilhelm, Alina}, title = {Investigating the TeV morpholoy of MGRO J1908+06 with veritas}, series = {The astrophysical journal : an international review of spectroscopy and astronomical physics}, volume = {787}, journal = {The astrophysical journal : an international review of spectroscopy and astronomical physics}, number = {2}, publisher = {IOP Publ. Ltd.}, address = {Bristol}, issn = {0004-637X}, doi = {10.1088/0004-637X/787/2/166}, pages = {7}, year = {2014}, abstract = {We report on deep observations of the extended TeV gamma-ray source MGRO J1908+06 made with the VERITAS very high energy gamma-ray observatory. Previously, the TeV emission has been attributed to the pulsar wind nebula (PWN) of the Fermi-LAT pulsar PSR J1907+0602. We detect MGRO J1908+06 at a significance level of 14 standard deviations (14 sigma) and measure a photon index of 2.20 +/- 0.10(stat) +/- 0.20(sys). The TeV emission is extended, covering the region near PSR J1907+0602 and also extending toward SNR G40.5-0.5. When fitted with a two-dimensional Gaussian, the intrinsic extension has a standard deviation of sigma(src) = 0 degrees.44 +/- 0 degrees.02. In contrast to other TeV PWNe of similar age in which the TeV spectrum softens with distance from the pulsar, the TeV spectrum measured near the pulsar location is consistent with that measured at a position near the rim of G40.5-0.5, 0 degrees.33 away.}, language = {en} } @article{ArchambaultArcherBenbowetal.2017, author = {Archambault, S. and Archer, A. and Benbow, W. and Bird, Ralph and Bourbeau, E. and Bouvier, A. and Buchovecky, M. and Bugaev, V. and Cardenzana, J. V. and Cerruti, M. and Ciupik, L. and Connolly, M. P. and Cui, W. and Daniel, M. K. and Errando, M. and Falcone, A. and Feng, Q. and Finley, J. P. and Fleischhack, H. and Fortson, L. and Furniss, A. and Gillanders, G. H. and Griffin, S. and Hanna, D. and Hervet, O. and Holder, J. and Hughes, G. and Humensky, T. B. and Hutten, M. and Johnson, C. A. and Kaaret, P. and Kar, P. and Kertzman, M. and Kieda, D. and Krause, M. and Lang, M. J. and Lin, T. T. Y. and Maier, G. and McArthur, S. and Moriarty, P. and Mukherjee, R. and Nieto, D. and Ong, R. A. and Otte, A. N. and Park, N. and Pohl, Martin and Popkow, A. and Pueschel, Elisa and Quinn, J. and Ragan, K. and Reynolds, P. T. and Richards, G. T. and Roache, E. and Rulten, C. and Sadeh, I. and Sembroski, G. H. and Shahinyan, K. and Staszak, D. and Telezhinsky, Igor O. and Trepanier, S. and Wakely, S. P. and Weinstein, A. and Wilcox, P. and Williams, D. A. and Zitzer, B.}, title = {Gamma-ray observations under bright moonlight with VERITAS}, series = {Astroparticle physics}, volume = {91}, journal = {Astroparticle physics}, publisher = {Elsevier}, address = {Amsterdam}, issn = {0927-6505}, doi = {10.1016/j.astropartphys.2017.03.001}, pages = {34 -- 43}, year = {2017}, abstract = {Imaging atmospheric Cherenkov telescopes (IACTs) are equipped with sensitive photomultiplier tube (PMT) cameras. Exposure to high levels of background illumination degrades the efficiency of and potentially destroys these photo-detectors over time, so IACTs cannot be operated in the same configuration in the presence of bright moonlight as under dark skies. Since September 2012, observations have been carried out with the VERITAS IACTs under bright moonlight (defined as about three times the night-sky-background (NSB) of a dark extragalactic field, typically occurring when Moon illumination > 35\%) in two observing modes, firstly by reducing the voltage applied to the PMTs and, secondly, with the addition of ultra-violet (UV) bandpass filters to the cameras. This has allowed observations at up to about 30 times previous NSB levels (around 80\% Moon illumination), resulting in 30\% more observing time between the two modes over the course of a year. These additional observations have already allowed for the detection of a flare from the 1ES 1727 + 502 and for an observing program targeting a measurement of the cosmic-ray positron fraction. We provide details of these new observing modes and their performance relative to the standard VERITAS observations. (C) 2017 Elsevier B.V. All rights reserved.}, language = {en} } @article{ArcherBenbowBirdetal.2018, author = {Archer, A. and Benbow, Wystan and Bird, Ralph and Brose, Robert and Buchovecky, M. and Bugaev, V and Cui, Wei and Danie, M. K. and Falcone, A. and Feng, Qi and Finley, John P. and Flinders, A. and Fortson, L. and Furniss, Amy and Gillanders, Gerard H. and Huttens, M. and Hanna, David and Hervet, O. and Holder, J. and Hughes, G. and Humensky, T. B. and Johnson, Caitlin A. and Kaaret, Philip and Kar, P. and Kelley-Hoskins, N. and Kieda, David and Krause, Maria and Krennrich, F. and Kumar, S. and Lang, M. J. and Lin, T. T. Y. and McArthur, S. and Moriarty, P. and Mukherjee, Reshmi and Nieto, Daniel and Ong, R. A. and Otte, A. N. and Park, Nahee and Petrashyk, A. and Pohl, Martin and Popkow, Alexis and Pueschel, Elisa and Quinn, J. and Ragan, K. and Reynold, P. T. and Richards, Gregory T. and Roache, E. and Rulten, C. and Sadeh, I and Sembroski, G. H. and Shahinyan, Karlen and Tyler, J. and Wakely, S. P. and Weiner, O. M. and Weinstein, A. and Wells, R. M. and Wilcox, P. and Wilhelm, Alina and Williams, David A. and Brisken, W. F. and Pontrelli, P.}, title = {HESS J1943+213}, series = {The astrophysical journal : an international review of spectroscopy and astronomical physics}, volume = {862}, journal = {The astrophysical journal : an international review of spectroscopy and astronomical physics}, number = {1}, publisher = {IOP Publ. Ltd.}, address = {Bristol}, organization = {VERITAS Collaboration}, issn = {0004-637X}, doi = {10.3847/1538-4357/aacbd0}, pages = {15}, year = {2018}, abstract = {HESS J1943+213 is a very high energy (VHE; > 100 GeV) gamma-ray source in the direction of the Galactic plane. Studies exploring the classification of the source are converging toward its identification as an extreme synchrotron BL Lac object. Here we present 38 hr of VERITAS observations of HESS J1943+213 taken over 2 yr. The source is detected with a significance of similar to 20 standard deviations, showing a remarkably stable flux and spectrum in VHE gamma-rays. Multifrequency Very Long Baseline Array (VLBA) observations of the source confirm the extended, jet-like structure previously found in the 1.6 GHz band with the European VLBI Network and detect this component in the 4.6 and 7.3 GHz bands. The radio spectral indices of the core and the jet and the level of polarization derived from the VLBA observations are in a range typical for blazars. Data from VERITAS, Fermi-LAT, Swift-XRT, the FLWO 48 ' telescope, and archival infrared and hard X-ray observations are used to construct and model the spectral energy distribution (SED) of the source with a synchrotron self-Compton model. The well-measured gamma-ray peak of the SED with VERITAS and Fermi-LAT provides constraining upper limits on the source redshift. Possible contribution of secondary gamma-rays from ultra-high-energy cosmic-ray-initiated electromagnetic cascades to the gamma-ray emission is explored, finding that only a segment of the VHE spectrum can be accommodated with this process. A variability search is performed across X-ray and gamma-ray bands. No statistically significant flux or spectral variability is detected.}, language = {en} } @article{AbeysekaraArcherAuneetal.2018, author = {Abeysekara, A. U. and Archer, A. and Aune, Taylor and Benbow, Wystan and Bird, Ralph and Brose, Robert and Buchovecky, M. and Bugaev, V. and Cui, Wei and Daniel, M. K. and Falcone, A. and Feng, Qi and Finley, John P. and Fleischhack, H. and Flinders, A. and Fortson, L. and Furniss, Amy and Gotthelf, Eric V. and Grube, J. and Hanna, David and Hervet, O. and Holder, J. and Huang, K. and Hughes, G. and Humensky, T. B. and Huetten, M. and Johnson, Caitlin A. and Kaaret, Philip and Kar, P. and Kelley-Hoskins, N. and Kertzman, M. and Kieda, David and Krause, Maria and Kumar, S. and Lang, M. J. and Lin, T. T. Y. and Maier, Gernot and McArthur, S. and Moriarty, P. and Mukherjee, Reshmi and Ong, R. A. and Otte, Adam Nepomuk and Pandel, Dirk and Park, Nahee and Petrashyk, A. and Pohl, Martin and Popkow, Alexis and Pueschel, Elisa and Quinn, J. and Ragan, K. and Reynolds, P. T. and Richards, Gregory T. and Roache, E. and Rousselle, J. and Rulten, C. and Sadeh, I. and Santander, M. and Sembroski, G. H. and Shahinyan, Karlen and Tyler, J. and Vassiliev, V. V. and Wakely, S. P. and Ward, J. E. and Weinstein, A. and Wells, R. M. and Wilcox, P. and Wilhelm, Alina and Williams, David A. and Zitzer, B.}, title = {A Very High Energy gamma-Ray Survey toward the Cygnus Region of the Galaxy}, series = {The astrophysical journal : an international review of spectroscopy and astronomical physics}, volume = {861}, journal = {The astrophysical journal : an international review of spectroscopy and astronomical physics}, number = {2}, publisher = {IOP Publ. Ltd.}, address = {Bristol}, issn = {0004-637X}, doi = {10.3847/1538-4357/aac4a2}, pages = {33}, year = {2018}, abstract = {We present results from deep observations toward the Cygnus region using 300 hr of very high energy (VHE)gamma-ray data taken with the VERITAS Cerenkov telescope array and over 7 yr of high-energy.-ray data taken with the Fermi satellite at an energy above 1 GeV. As the brightest region of diffuse gamma-ray emission in the northern sky, the Cygnus region provides a promising area to probe the origins of cosmic rays. We report the identification of a potential Fermi-LAT counterpart to VER J2031+415 (TeV J2032+4130) and resolve the extended VHE source VER J2019+368 into two source candidates (VER J2018+367* and VER J2020+368*) and characterize their energy spectra. The Fermi-LAT morphology of 3FGL J2021.0+4031e (the Gamma Cygni supernova remnant) was examined, and a region of enhanced emission coincident with VER J2019+407 was identified and jointly fit with the VERITAS data. By modeling 3FGL J2015.6+3709 as two sources, one located at the location of the pulsar wind nebula CTB 87 and one at the quasar QSO J2015+371, a continuous spectrum from 1 GeV to 10 TeV was extracted for VER J2016+371 (CTB 87). An additional 71 locations coincident with Fermi-LAT sources and other potential objects of interest were tested for VHE gamma-ray emission, with no emission detected and upper limits on the differential flux placed at an average of 2.3\% of the Crab Nebula flux. We interpret these observations in a multiwavelength context and present the most detailed gamma-ray view of the region to date.}, language = {en} } @article{AbeysekaraArcherBenbowetal.2018, author = {Abeysekara, A. U. and Archer, A. and Benbow, Wystan and Bird, Ralph and Brose, Robert and Buchovecky, M. and Bugaev, V. and Connolly, M. P. and Cui, Wei and Errando, Manel and Falcone, A. and Feng, Qi and Finley, John P. and Flinders, A. and Fortson, L. and Furniss, Amy and Gillanders, Gerard H. and Huetten, M. and Hanna, David and Hervet, O. and Holder, J. and Hughes, G. and Humensky, T. B. and Johnson, Caitlin A. and Kaaret, Philip and Kar, P. and Kelley-Hoskins, N. and Kertzman, M. and Kieda, David and Krause, Maria and Krennrich, F. and Lang, M. J. and Lin, T. T. Y. and Maier, Gernot and McArthur, S. and Moriarty, P. and Mukherjee, Reshmi and Ong, R. A. and Park, N. and Perkins, Jeremy S. and Petrashyk, A. and Pohl, Martin and Popkow, Alexis and Pueschel, Elisa and Quinn, J. and Ragan, K. and Reynolds, P. T. and Richards, Gregory T. and Roache, E. and Rulten, C. and Sadeh, I. and Santander, M. and Sembroski, G. H. and Shahinyan, Karlen and Tyler, J. and Wakely, S. P. and Weiner, O. M. and Weinstein, A. and Wells, R. M. and Wilcox, P. and Wilhelm, Alina and Williams, David A. and Zitzer, B. and Vurm, Indrek and Beloborodov, Andrei}, title = {A Strong Limit on the Very-high-energy Emission from GRB 150323A}, series = {The astrophysical journal : an international review of spectroscopy and astronomical physics}, volume = {857}, journal = {The astrophysical journal : an international review of spectroscopy and astronomical physics}, number = {1}, publisher = {IOP Publ. Ltd.}, address = {Bristol}, organization = {VERITAS Collaboration}, issn = {0004-637X}, doi = {10.3847/1538-4357/aab371}, pages = {6}, year = {2018}, abstract = {On 2015 March 23, the Very Energetic Radiation Imaging Telescope Array System (VERITAS) responded to a Swift-Burst Alert Telescope (BAT) detection of a gamma-ray burst, with observations beginning 270 s after the onset of BAT emission, and only 135 s after the main BAT emission peak. No statistically significant signal is detected above 140 GeV. The VERITAS upper limit on the fluence in a 40-minute integration corresponds to about 1\% of the prompt fluence. Our limit is particularly significant because the very-high-energy (VHE) observation started only similar to 2 minutes after the prompt emission peaked, and Fermi-Large Area Telescope observations of numerous other bursts have revealed that the high-energy emission is typically delayed relative to the prompt radiation and lasts significantly longer. Also, the proximity of GRB 150323A (z = 0.593) limits the attenuation by the extragalactic background light to similar to 50\% at 100-200 GeV. We conclude that GRB 150323A had an intrinsically very weak high-energy afterglow, or that the GeV spectrum had a turnover below similar to 100 GeV. If the GRB exploded into the stellar wind of a massive progenitor, the VHE non-detection constrains the wind density parameter to be A greater than or similar to 3 x 10(11) g . cm(-1), consistent with a standard Wolf-Rayet progenitor. Alternatively, the VHE emission from the blast wave would be weak in a very tenuous medium such as the interstellar medium, which therefore cannot be ruled out as the environment of GRB 150323A.}, language = {en} } @article{AbeysekaraArcherBenbowetal.2019, author = {Abeysekara, A. U. and Archer, A. and Benbow, Wystan and Bird, Ralph and Brill, A. and Brose, Robert and Buchovecky, M. and Calderon-Madera, D. and Christiansen, J. L. and Cui, W. and Daniel, M. K. and Falcone, A. and Feng, Q. and Fernandez-Alonso, M. and Finley, J. P. and Fortson, Lucy and Furniss, Amy and Gent, A. and Giuri, C. and Gueta, O. and Hanna, David and Hassan, T. and Hervet, Oliver and Holder, J. and Hughes, G. and Humensky, T. B. and Johnson, Caitlin A. and Kaaret, P. and Kertzman, M. and Kieda, David and Krause, Maria and Krennrich, F. and Kumar, S. and Lang, M. J. and Maier, Gernot and Moriarty, P. and Mukherjee, Reshmi and Nievas-Rosillo, M. and Ong, R. A. and Pfrang, Konstantin Johannes and Pohl, Martin and Prado, R. R. and Pueschel, Elisa and Quinn, J. and Ragan, K. and Reynolds, P. T. and Ribeiro, D. and Richards, G. T. and Roache, E. and Rovero, A. C. and Sadeh, Iftach and Santander, M. and Sembroski, G. H. and Shahinyan, Karlen and Sushch, Iurii and Svraka, T. and Weinstein, A. and Wells, R. M. and Wilcox, Patrick and Wilhelm, Alina and Williams, David Arnold and Williamson, T. J. and Zitzer, B.}, title = {Measurement of the Extragalactic Background Light Spectral Energy Distribution with VERITAS}, series = {The astrophysical journal : an international review of spectroscopy and astronomical physics}, volume = {885}, journal = {The astrophysical journal : an international review of spectroscopy and astronomical physics}, number = {2}, publisher = {IOP Publ. Ltd.}, address = {Bristol}, issn = {0004-637X}, doi = {10.3847/1538-4357/ab4817}, pages = {8}, year = {2019}, abstract = {The extragalactic background light (EBL), a diffuse photon field in the optical and infrared range, is a record of radiative processes over the universe?s history. Spectral measurements of blazars at very high energies (>100 GeV) enable the reconstruction of the spectral energy distribution (SED) of the EBL, as the blazar spectra are modified by redshift- and energy-dependent interactions of the gamma-ray photons with the EBL. The spectra of 14 VERITAS-detected blazars are included in a new measurement of the EBL SED that is independent of EBL SED models. The resulting SED covers an EBL wavelength range of 0.56?56 ?m, and is in good agreement with lower limits obtained by assuming that the EBL is entirely due to radiation from cataloged galaxies.}, language = {en} } @article{BenbowBirdBrilletal.2019, author = {Benbow, W. and Bird, R. and Brill, A. and Brose, Robert and Chromey, A. J. and Daniel, M. K. and Feng, Q. and Finley, J. P. and Fortson, L. and Furniss, A. and Gillanders, G. H. and Giuri, C. and Gueta, O. and Hanna, D. and Halpern, J. P. and Hassan, Tarek and Holder, J. and Hughes, G. and Humensky, T. B. and Joyce, Amy M. and Kaaret, P. and Kar, P. and Kelley-Hoskins, N. and Kertzman, M. and Kieda, D. and Krause, M. and Lang, M. J. and Lin, T. T. Y. and Maier, Gernot and Matthews, N. and Moriarty, P. and Mukherjee, R. and Nieto, D. and Nievas-Rosillos, M. and Ong, R. A. and Park, N. and Petrashyk, A. and Pohl, Martin and Pueschel, Elisa and Quinn, John and Ragan, K. and Reynolds, P. T. and Richards, G. T. and Roache, E. and Rulten, C. and Sadeh, Iftach and Santander, M. and Sembroski, G. H. and Shahinyan, K. and Sushch, Iurii and Wakely, S. P. and Wells, R. M. and Wilcox, P. and Wilhelm, Alina and Williams, David A. and Williamson, T. J.}, title = {Direct measurement of stellar angular diameters by the VERITAS Cherenkov telescopes}, series = {Nature astronomy}, volume = {3}, journal = {Nature astronomy}, number = {6}, publisher = {Nature Publ. Group}, address = {London}, issn = {2397-3366}, doi = {10.1038/s41550-019-0741-z}, pages = {511 -- 516}, year = {2019}, abstract = {The angular size of a star is a critical factor in determining its basic properties1. Direct measurement of stellar angular diameters is difficult: at interstellar distances stars are generally too small to resolve by any individual imaging telescope. This fundamental limitation can be overcome by studying the diffraction pattern in the shadow cast when an asteroid occults a star2, but only when the photometric uncertainty is smaller than the noise added by atmospheric scintillation3. Atmospheric Cherenkov telescopes used for particle astrophysics observations have not generally been exploited for optical astronomy due to the modest optical quality of the mirror surface. However, their large mirror area makes them well suited for such high-time-resolution precision photometry measurements4. Here we report two occultations of stars observed by the Very Energetic Radiation Imaging Telescope Array System (VERITAS)5 Cherenkov telescopes with millisecond sampling, from which we are able to provide a direct measurement of the occulted stars' angular diameter at the ≤0.1 mas scale. This is a resolution never achieved before with optical measurements and represents an order of magnitude improvement over the equivalent lunar occultation method6. We compare the resulting stellar radius with empirically derived estimates from temperature and brightness measurements, confirming the latter can be biased for stars with ambiguous stellar classifications.}, language = {en} } @article{PoghosyanShahinyanKoetz2018, author = {Poghosyan, Armen H. and Shahinyan, A. A. and Koetz, Joachim}, title = {Self-assembled monolayer formation of distorted cylindrical AOT micelles on gold surfaces}, series = {Colloids and surfaces : an international journal devoted to the principles and applications of colloid and interface science ; A, Physicochemical and engineering aspects}, volume = {546}, journal = {Colloids and surfaces : an international journal devoted to the principles and applications of colloid and interface science ; A, Physicochemical and engineering aspects}, publisher = {Elsevier}, address = {Amsterdam}, issn = {0927-7757}, doi = {10.1016/j.colsurfa.2018.02.067}, pages = {20 -- 27}, year = {2018}, abstract = {Self-assembling features of sodium dioctyl sulfosuccinate (AOT) molecules and micelle adsorption on gold Au (111) surfaces have been examined using molecular dynamics simulation. We argue that AOT micelles display a strong adsorption on gold surfaces resulting in distorted cylindrical micelles attached to the (111) facets. The well protected Au(111) facets decorated by a dense packed elongated ellipsoidal AOT layer hinder the diffusion of the reactant to the (111) facets and could result in the preferential growth of ultra-thin gold nanoplatelets.}, language = {en} } @article{PoghosyanShahinyanKoetz2018, author = {Poghosyan, Armen H. and Shahinyan, A. A. and Koetz, Joachim}, title = {Catanionic AOT/BDAC micelles on gold {111} surfaces}, series = {Colloid and polymer science : official journal of the Kolloid-Gesellschaft}, volume = {296}, journal = {Colloid and polymer science : official journal of the Kolloid-Gesellschaft}, number = {8}, publisher = {Springer}, address = {New York}, issn = {0303-402X}, doi = {10.1007/s00396-018-4348-1}, pages = {1301 -- 1306}, year = {2018}, abstract = {A sodium dioctyl sulfosuccinate (AOT)/benzyl hexadecyl dimethyl ammonium chloride (BDAC) mixed micelle self-organization and adsorption on gold Au(111) surfaces have been investigated using a molecular dynamics approach. The spherical AOT/BDAC mixed micelle is strongly adsorbed on the gold surface and is disoriented to a cylinder-like shape.}, language = {en} } @article{PoghosyanArsenyanAntonyanetal.2015, author = {Poghosyan, Armen H. and Arsenyan, Levon H. and Antonyan, Lilit A. and Shahinyan, Aram A. and Koetz, Joachim}, title = {Molecular dynamics simulations of branched polyethyleneimine in water-in-heptanol micelles stabilized by zwitterionic surfactants}, series = {Colloids and surfaces : an international journal devoted to the principles and applications of colloid and interface science ; A, Physicochemical and engineering aspects}, volume = {479}, journal = {Colloids and surfaces : an international journal devoted to the principles and applications of colloid and interface science ; A, Physicochemical and engineering aspects}, publisher = {Elsevier}, address = {Amsterdam}, issn = {0927-7757}, doi = {10.1016/j.colsurfa.2015.03.053}, pages = {18 -- 24}, year = {2015}, abstract = {We have performed a 50 ns molecular dynamics simulation of a hyperbranched polymer, i.e. polyethyleneimine (PEI), inside inverse micelles formed with zwitterionic surfactants 3-(N, N-dimethyldodecylammoniio)-propansulfonate (SB) in heptanol. The runs were performed using the GROMACS simulation package. During simulation time the PEI molecule undergoes a conformational deformation and compaction. The radius of gyration of the PEI molecule finally located in the center of the water droplet is decreased from 3 nm to 1.7 nm. The unusual shrinking of the PEI molecule inside the micelle explains the extraordinary template effect of these microemulsions by making cadmium sulfide or gold clusters. (C) 2015 Elsevier B.V. All rights reserved.}, language = {en} } @article{PoghosyanAdamyanShahinyanetal.2019, author = {Poghosyan, Armen H. and Adamyan, Maksim P. and Shahinyan, Aram A. and Koetz, Joachim}, title = {AOT Bilayer Adsorption on Gold Surfaces}, series = {The journal of physical chemistry : B, Condensed matter, materials, surfaces, interfaces \& biophysical chemistry}, volume = {123}, journal = {The journal of physical chemistry : B, Condensed matter, materials, surfaces, interfaces \& biophysical chemistry}, number = {4}, publisher = {American Chemical Society}, address = {Washington}, issn = {1520-6106}, doi = {10.1021/acs.jpcb.8b11471}, pages = {948 -- 953}, year = {2019}, abstract = {A molecular dynamics study was done to reveal the adsorption properties of sodium dioctyl sulfosuccinate (AOT) bilayers on gold Au(111) surfaces. Examining the rotational mobility of AOT molecules, we track that the correlation time of AOT molecules on the adsorbed layer is much higher. The data estimating the diffusive motion of AOT molecule show a substantially lower rate of diffusion (similar to 10(-10) cm(2)/s) in the adsorbed layers in comparison to other ones. The results show that an adsorbed layer is more rigid, whereas the outer layers undergo considerable lateral and vertical fluctuations.}, language = {en} } @article{PoghosyanArsenyanGharabekyanetal.2009, author = {Poghosyan, Armen H. and Arsenyan, Levon H. and Gharabekyan, Hrant H. and Koetz, Joachim and Shahinyan, Aram A.}, title = {Molecular dynamics study of poly(diallyldimethylammonium chloride) (PDADMAC)/sodium dodecyl sulfate (SDS)/ decanol/water systems}, issn = {1520-6106}, doi = {10.1021/Jp806289c}, year = {2009}, abstract = {We have performed a 50 ns of molecular dynamics study of poly(diallyldimethylammonium chloride) (PDADMAC)/ sodium dodecyl sulfate (SDS)/decanol/water systems. The influence of the cationic polyelectrolyte on the anionic SDS- based lamellar liquid crystalline system was investigated. The main structural parameters have been calculated and compared with experimental data. We obtain two types of PDADMAC conformation, a more folded structure A and a structure B where the PDADMAC molecule is adsorbed at the anionic head groups of the surfactant molecules. The polyelectrolyte- induced coexistence of two lamellar phases at a concentration of 2-3\% of PDADMAC is observed, which is in agreement with experimental findings.}, language = {en} } @article{PoghosyanArsenyanGharabekyanetal.2011, author = {Poghosyan, Armen H. and Arsenyan, Levon H. and Gharabekyan, Hrant H. and Falkenhagen, Sandra and Koetz, Joachim and Shahinyan, Aram A.}, title = {Molecular dynamics simulations of inverse sodium dodecyl sulfate (SDS) micelles in a mixed toluene/pentanol solvent in the absence and presence of poly(diallyldimethylammonium chloride) (PDADMAC)}, series = {Journal of colloid and interface science}, volume = {358}, journal = {Journal of colloid and interface science}, number = {1}, publisher = {Elsevier}, address = {San Diego}, issn = {0021-9797}, doi = {10.1016/j.jcis.2011.01.091}, pages = {175 -- 181}, year = {2011}, abstract = {We have performed a 15 ns molecular dynamics simulation of inverse sodium dodecyl sulfate (SDS) micelles in a mixed toluene/pentanol solvent in the absence and presence of a cationic polyelectrolyte, i.e. poly(diallyldimethylammonium chloride) (PDADMAC). The NAMD code and CHARMM force field were used. During the simulation time, the radii of SOS inverse micelles changed and the radii of the water droplets have been calculated. The behavior of SDS hydrocarbon chains has been characterized by calculating the orientation order parameter and the chain average length. The water droplet properties (water flow, water molecules displacement) have been examined. In summary the MD simulations indicate a more rigid and ordered surfactant film due to the formation of a polyelectrolyte palisade layer in full agreement with the experimental findings, e.g. the viscosity increase and shift of the percolation boundary.}, language = {en} } @article{PoghosyanArsenyanShahinyanetal.2016, author = {Poghosyan, Armen H. and Arsenyan, Levon H. and Shahinyan, Aram A. and Koetz, Joachim}, title = {Polyethyleneimine loaded inverse SDS micelle in pentanol/toluene media}, series = {Colloids and surfaces : an international journal devoted to the principles and applications of colloid and interface science ; A, Physicochemical and engineering aspects}, volume = {506}, journal = {Colloids and surfaces : an international journal devoted to the principles and applications of colloid and interface science ; A, Physicochemical and engineering aspects}, publisher = {Elsevier}, address = {Amsterdam}, issn = {0927-7757}, doi = {10.1016/j.colsurfa.2016.07.018}, pages = {402 -- 408}, year = {2016}, abstract = {An atomic scale molecular dynamics simulation (100 ns) was carried out to reveal the conformational features of a cationic polyelectrolyte, i.e., hyperbranched polyethyleneimine (PEI), inside of water-in-oil microemulsion droplets stabilized by the anionic sodium dodecyl sulfate surfactant (SDS) layer. Simulations show that the polymer reorients very quickly and is localized at the headgroup region, i.e., the polymer nitrogens are close to SDS sulfur atoms. In spite of the availability of surface roughness caused by the polymer, we track a stable inverse micelle during the production run. In overall, the obtained parameters are well compared with experimental findings. (C) 2016 Elsevier B.V. All rights reserved.}, language = {en} }