@article{AlbrechtSchaeferLangeetal.2012, author = {Albrecht, Steve and Schaefer, Sebastian and Lange, Ilja and Yilmaz, Seyfullah and Dumsch, Ines and Allard, Sybille and Scherf, Ullrich and Hertwig, Andreas and Neher, Dieter}, title = {Light management in PCPDTBT:PC70BM solar cells: A comparison of standard and inverted device structures}, series = {Organic electronics : physics, materials and applications}, volume = {13}, journal = {Organic electronics : physics, materials and applications}, number = {4}, publisher = {Elsevier}, address = {Amsterdam}, issn = {1566-1199}, doi = {10.1016/j.orgel.2011.12.019}, pages = {615 -- 622}, year = {2012}, abstract = {We compare standard and inverted bulk heterojunction solar cells composed of PCPDTBT:PC70BM blends. Inverted devices comprising 100 nm thick active layers exhibited short circuit currents of 15 mA/cm(2), 10\% larger than in corresponding standard devices. Modeling of the optical field distribution in the different device stacks proved that this enhancement originates from an increased absorption of incident light in the active layer. Internal quantum efficiencies (IQEs) were obtained from the direct comparison of experimentally derived and modeled currents for different layer thicknesses, yielding IQEs of similar to 70\% for a layer thickness of 100 nm. Simulations predict a significant increase of the light harvesting efficiency upon increasing the layer thickness to 270 nm. However, a continuous deterioration of the photovoltaic properties with layer thickness was measured for both device architectures, attributed to incomplete charge extraction. On the other hand, our optical modeling suggests that inverted devices based on PCPDTBT should be able to deliver high power conversion efficiencies (PCEs) of more than 7\% provided that recombination losses can be reduced.}, language = {en} } @article{AlbrechtSchindlerKurpiersetal.2012, author = {Albrecht, Steve and Schindler, Wolfram and Kurpiers, Jona and Kniepert, Juliane and Blakesley, James C. and Dumsch, Ines and Allard, Sybille and Fostiropoulos, Konstantinos and Scherf, Ullrich and Neher, Dieter}, title = {On the field dependence of free charge carrier generation and recombination in blends of PCPDTBT/PC70BM influence of solvent additives}, series = {The journal of physical chemistry letters}, volume = {3}, journal = {The journal of physical chemistry letters}, number = {5}, publisher = {American Chemical Society}, address = {Washington}, issn = {1948-7185}, doi = {10.1021/jz3000849}, pages = {640 -- 645}, year = {2012}, abstract = {We have applied time-delayed collection field (TDCF) and charge extraction by linearly increasing voltage (CELIV) to investigate the photogeneration, transport, and recombination of charge carriers in blends composed of PCPDTBT/PC70BM processed with and without the solvent additive diiodooctane. The results suggest that the solvent additive has severe impacts on the elementary processes involved in the photon to collected electron conversion in these blends. First, a pronounced field dependence of the free carrier generation is found for both blends, where the field dependence is stronger without the additive. Second, the fate of charge carriers in both blends can be described with a rather high bimolecular recombination coefficients, which increase with decreasing internal field. Third, the mobility is three to four times higher with the additive. Both blends show a negative field dependence of mobility, which we suggest to cause bias-dependent recombination coefficients.}, language = {en} } @article{LangeKniepertPingeletal.2013, author = {Lange, Ilja and Kniepert, Juliane and Pingel, Patrick and Dumsch, Ines and Allard, Sybille and Janietz, Silvia and Scherf, Ullrich and Neher, Dieter}, title = {Correlation between the open circuit voltage and the energetics of organic bulk heterojunction solar cells}, series = {The journal of physical chemistry letters}, volume = {4}, journal = {The journal of physical chemistry letters}, number = {22}, publisher = {American Chemical Society}, address = {Washington}, issn = {1948-7185}, doi = {10.1021/jz401971e}, pages = {3865 -- 3871}, year = {2013}, abstract = {A detailed investigation of the open circuit voltage (V-OC) of organic bulk heterojunction solar cells comprising three different donor polymers and two different fullerene-based acceptors is presented. Bias amplified charge extraction (BACE) is combined with Kelvin Probe measurements to derive information on the relevant energetics in the blend. On the example of P3HT:PC70BM the influence of composition and preparation conditions on the relevant transport levels will be shown. Moderate upward shifts of the P3HT HOMO depending on crystallinity are observed, but contrarily to common believe, the dependence of V-OC on blend composition and thermal history is found to be largely determined by the change in the PCBM LUMO energy. Following this approach, we quantified the energetic contribution to the V-OC in blends with fluorinated polymers or higher adduct fullerenes.}, language = {en} } @article{AlbrechtTumblestonJanietzetal.2014, author = {Albrecht, Steve and Tumbleston, John R. and Janietz, Silvia and Dumsch, Ines and Allard, Sybille and Scherf, Ullrich and Ade, Harald W. and Neher, Dieter}, title = {Quantifying charge extraction in organic solar cells: The case of fluorinated PCPDTBT}, series = {The journal of physical chemistry letters}, volume = {5}, journal = {The journal of physical chemistry letters}, number = {7}, publisher = {American Chemical Society}, address = {Washington}, issn = {1948-7185}, doi = {10.1021/jz500457b}, pages = {1131 -- 1138}, year = {2014}, abstract = {We introduce a new and simple method to quantify the effective extraction mobility in organic solar cells at low electric fields and charge carrier densities comparable to operation conditions under one sun illumination. By comparing steady-state carrier densities at constant illumination intensity and under open-circuit conditions, the gradient of the quasi-Fermi potential driving the current is estimated as a function of external bias and charge density. These properties are then related to the respective steady-state current to determine the effective extraction mobility. The new technique is applied to different derivatives of the well-known low-band-gap polymer PCPDTBT blended with PC70BM. We show that the slower average extraction due to lower mobility accounts for the moderate fill factor when solar cells are fabricated with mono- or difluorinated PCPDTBT. This lower extraction competes with improved generation and reduced nongeminate recombination, rendering the monofluorinated derivative the most efficient donor polymer.}, language = {en} }