@phdthesis{KaramzadehToularoud2020, author = {Karamzadeh Toularoud, Nasim}, title = {Earthquake source and receiver array optimal configuration}, doi = {10.25932/publishup-45982}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-459828}, school = {Universit{\"a}t Potsdam}, pages = {viii, 94}, year = {2020}, abstract = {Seismic receiver arrays have variety of applications in seismology, particularly when the signal enhancement is a prerequisite to detect seismic events, and in situations where installing and maintaining sparse networks are impractical. This thesis has mainly focused on the development of a new approach for seismological source and receiver array design.The proposed approach deals with the array design task as an optimization problem. The criteria and prerequisite constraints in array design task are integrated in objective function definition and evaluation of a optimization process. Three cases are covered in this thesis: (1) a 2-D receiver array geometry optimization, (2) a 3-D source array optimization, and (3) an array application to monitor microseismic data, where the effect of different types of noise are evaluated. A flexible receiver array design framework implements a customizable scenario modelling and optimization scheme by making use of synthetic seismograms. Using synthetic seismograms to evaluate array performance makes it possible to consider additional constraints, e.g. land ownership, site-specific noise levels or characteristics of the seismic sources under investigation. The use of synthetic array beamforming as an array design criteria is suggested. The framework is customized by designing a 2-D small scale receiver array to monitor earthquake swarm activity in northwest Bohemia/ Vogtland in central Europe. Two sub-functions are defined to verify the accuracy of horizontal slowness estimation; one to suppress aliasing effects due to possible secondary lobes of synthetic array beamforming calculated in horizontal slowness space, and the other to reduce the event's mislocation caused by miscalculation of the horizontal slowness vector. Subsequently, a weighting technique is applied to combine the sub-functions into one single scalar objective function to use in the optimization process. The idea of optimal array is employed to design a 3-D source array, given a well-located catalog of events. The conditions to make source arrays are formulated in four objective functions and a weighted sum technique is used to combine them in one single scalar function. The criteria are: (1) accurate slowness vector estimation, (2) high waveform coherency, (3) low location error and (4) high energy of coda phases. The method is evaluated by two experiments, (1) a synthetic test using realistic synthetic seismograms, (2) using real seismograms, and for each case optimized SA elements are configured using the data from the Vogtland area. The location of a possible scatterer in the velocity model, that makes the converted/reflected phases, e.g. sp-phases, is retrieved by a grid search method using the optimized SA. The accuracy of the approach and the obtained results demonstrated that the method is applicable to study the crustal structure and the location of crustal scatterers when the strong converted phases are observed in the data and a well-located catalog is available. Small aperture arrays are employed in seismology for a variety of applications, ranging from pure event detection to monitor and study of microcosmic activities. The monitoring of microseismicity during temporary human activities is often difficult, as the signal-to-noise ratio is very low and noise is strongly increased during the operation. The combination of small aperture seismic arrays with shallow borehole sensors offers a solution. We tested this monitoring approach at two different sites, (1) accompanying a fracking experiment in sedimentary shale at 4~km depth, and (2) above a gas field under depletion. Arrays recordings are compared with recordings available from shallow borehole sensors and examples of detection and location performance of the array are given. The effect of different types of noise at array and borehole stations are compared and discussed.}, language = {en} } @phdthesis{Nooshiri2020, author = {Nooshiri, Nima}, title = {Improvement of routine seismic source parameter estimation based on regional and teleseismic recordings}, doi = {10.25932/publishup-45946}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-459462}, school = {Universit{\"a}t Potsdam}, pages = {ix, 118}, year = {2020}, abstract = {Seismological agencies play an important role in seismological research and seismic hazard mitigation by providing source parameters of seismic events (location, magnitude, mechanism), and keeping these data accessible in the long term. The availability of catalogues of seismic source parameters is an important requirement for the evaluation and mitigation of seismic hazards, and the catalogues are particularly valuable to the research community as they provide fundamental long-term data in the geophysical sciences. This work is well motivated by the rising demand for developing more robust and efficient methods for routine source parameter estimation, and ultimately generation of reliable catalogues of seismic source parameters. Specifically, the aim of this work is to develop some methods to determine hypocentre location and temporal evolution of seismic sources based on regional and teleseismic observations more accurately, and investigate the potential of these methods to be integrated in near real-time processing. To achieve this, a location method that considers several events simultaneously and improves the relative location accuracy among nearby events has been provided. This method tries to reduce the biasing effects of the lateral velocity heterogeneities (or equivalently to compensate for limitations and inaccuracies in the assumed velocity model) by calculating a set of timing corrections for each seismic station. The systematic errors introduced into the locations by the inaccuracies in the assumed velocity structure can be corrected without explicitly solving for a velocity model. Application to sets of multiple earthquakes in complex tectonic environments with strongly heterogeneous structure such as subduction zones and plate boundary region demonstrate that this relocation process significantly improves the hypocentre locations compared to standard locations. To meet the computational demands of this location process, a new open-source software package has been developed that allows for efficient relocation of large-scale multiple seismic events using arrival time data. Upon that, a flexible location framework is provided which can be tailored to various application cases on local, regional, and global scales. The latest version of the software distribution including source codes, a user guide, an example data set, and a change history, is freely available to the community. The developed relocation algorithm has been modified slightly and then its performance in a simulated near real-time processing has been evaluated. It has been demonstrated that applying the proposed technique significantly reduces the bias in routine locations and enhance the ability to locate the lower magnitude events using only regional arrival data. Finally, to return to emphasis on global seismic monitoring, an inversion framework has been developed to determine the seismic source time function through direct waveform fitting of teleseismic recordings. The inversion technique can be systematically applied to moderate- size seismic events and has the potential to be performed in near real-time applications. It is exemplified by application to an abnormal seismic event; the 2017 North Korean nuclear explosion. The presented work and application case studies in this dissertation represent the first step in an effort to establish a framework for automatic, routine generation of reliable catalogues of seismic event locations and source time functions.}, language = {en} } @phdthesis{Holm2020, author = {Holm, Stine}, title = {Methanogenic communities and metaplasmidome-encoded functions in permafrost environments exposed to thaw}, school = {Universit{\"a}t Potsdam}, pages = {VI, 243}, year = {2020}, abstract = {This thesis investigates how the permafrost microbiota responds to global warming. In detail, the constraints behind methane production in thawing permafrost were linked to methanogenic activity, abundance and composition. Furthermore, this thesis offers new insights into microbial adaptions to the changing environmental conditions during global warming. This was assesed by investigating the potential ecological relevant functions encoded by plasmid DNA within the permafrost microbiota. Permafrost of both interglacial and glacial origin spanning the Holocene to the late Pleistocene, including Eemian, were studied during long-term thaw incubations. Furthermore, several permafrost cores of different stratigraphy, soil type and vegetation cover were used to target the main constraints behind methane production during short-term thaw simulations. Short- and long-term incubations simulating thaw with and without the addition of substrate were combined with activity measurements, amplicon and metagenomic sequencing of permanently frozen and seasonally thawed active layer. Combined, it allowed to address the following questions. i) What constraints methane production when permafrost thaws and how is this linked to methanogenic activity, abundance and composition? ii) How does the methanogenic community composition change during long-term thawing conditions? iii) Which potential ecological relevant functions are encoded by plasmid DNA in active layer soils? The major outcomes of this thesis are as follows. i) Methane production from permafrost after long-term thaw simulation was found to be constrained mainly by the abundance of methanogens and the archaeal community composition. Deposits formed during periods of warmer temperatures and increased precipitation, (here represented by deposits from the Late Pleistocene of both interstadial and interglacial periods) were found to respond strongest to thawing conditions and to contain an archaeal community dominated by methanogenic archaea (40\% and 100\% of all detected archaea). Methanogenic population size and carbon density were identified as main predictors for potential methane production in thawing permafrost in short-term incubations when substrate was sufficiently available. ii) Besides determining the methanogenic activity after long-term thaw, the paleoenvironmental conditions were also found to influence the response of the methanogenic community composition. Substantial shifts within methanogenic community structure and a drop in diversity were observed in deposits formed during warmer periods, but not in deposits from stadials, when colder and drier conditions occurred. Overall, a shift towards a dominance of hydrogenotrophic methanogens was observed in all samples, except for the oldest interglacial deposits from the Eemian, which displayed a potential dominance of acetoclastic methanogens. The Eemian, which is discussed to serve as an analogue to current climate conditions, contained highly active methanogenic communities. However, all potential limitation of methane production after permafrost thaw, it means methanogenic community structure, methanogenic population size, and substrate pool might be overcome after permafrost had thawed on the long-term. iii) Enrichments with soil from the seasonally thawed active layer revealed that its plasmid DNA ('metaplasmidome') carries stress-response genes. In particular it encoded antibiotic resistance genes, heavy metal resistance genes, cold shock proteins and genes encoding UV-protection. Those are functions that are directly involved in the adaptation of microbial communities to stresses in polar environments. It was further found that metaplasmidomes from the Siberian active layer originate mainly from Gammaproteobacteria. By applying enrichment cultures followed by plasmid DNA extraction it was possible to obtain a higher average contigs length and significantly higher recovery of plasmid sequences than from extracting plasmid sequences from metagenomes. The approach of analyzing 'metaplasmidomes' established in this thesis is therefore suitable for studying the ecological role of plasmids in polar environments in general. This thesis emphasizes that including microbial community dynamics have the potential to improve permafrost-carbon projections. Microbially mediated methane release from permafrost environments may significantly impact future climate change. This thesis identified drivers of methanogenic composition, abundance and activity in thawing permafrost landscapes. Finally, this thesis underlines the importance to study how the current warming Arctic affects microbial communities in order to gain more insight into microbial response and adaptation strategies.}, language = {en} } @phdthesis{Menges2020, author = {Menges, Johanna}, title = {Organic Carbon Storage, Transfer and Transformation in the Himalaya}, school = {Universit{\"a}t Potsdam}, pages = {179}, year = {2020}, abstract = {The transfer of particulate organic carbon from continents to the ocean is an important component of the global carbon cycle. Transfer to and burial of photosynthetically fixed biospheric organic carbon in marine sediments can effectively sequester atmospheric carbon dioxide over geological timescales. The exhumation and erosion of fossil organic carbon contained in sedimentary rocks, i.e. petrogenic carbon, can result in remineralization, releasing carbon to the atmosphere. In contrast, eroded petrogenic organic carbon that gets transferred back to the ocean and reburied does not affect atmospheric carbon content. Mountain ranges play a key role in this transfer since they can source vast amounts of sediment including particulate organic carbon. Globally, the export of both, biospheric and petrogenic organic carbon has been linked to sediment export. Additionally, short transfer times from mountains to the ocean and high sediment concentrations have been shown to increase the likelihood of organic carbon burial. While the importance of mountain ranges in the organic carbon cycle is now widely recognized, the processes acting within mountain ranges to influence the storage, cycling and mobilization of organic carbon, as well as carbon fluxes from mountain ranges remain poorly constrained. In this thesis, I employ different methods to assess the nature and fate of particulate organic carbon in mountain belts, ranging from the molecular to regional landscape scale. These studies are located along the Trans-Himalayan Kali Gandaki River in Central Nepal. This river traverses all major geological and climatic zones of the Himalaya, from the dry northern Tibetan plateau to the high-relief, monsoon dominated steep High Himalaya and the lower relief and abundant vegetation of the Lesser Himalayan region. First, I document how biospheric organic matter has accumulated during the Holocene in the headwaters of the Kali Gandaki River valley, by combining compound specific isotope measurements with different dating methods and grain size data, and investigate the stability of this organic carbon reservoir on millennial timescales. I show, that around 1.6 ka an eco-geomorphic tipping point occurred leading to a destabilization of the landscape resulting in today's high erosion rates and the excavation of the aged organic carbon reservoir. This study highlights the climatic and geomorphic controls on biospheric organic carbon storage and release from mountain ranges. Second, I systematically investigate the spatial variation of particulate organic carbon fluxes across the Himalaya along the Kali Gandaki River, using bulk stable and radioactive isotopes combined with a new Bayesian modeling approach. The detailed dataset allows the distinction of aged and modern biospheric organic carbon as well as petrogenic organic carbon across the Himalayan mountain range and the investigation of the role of climatic and geomorphic factors in their riverine export. The data suggest a decoupling of the particulate organic carbon from the sediment yield along the Kali Gandaki River, partially driven by climatic and geomorphic processes. In contrast to the suspended sediment, a large part of the particulate organic carbon exported by the river originates from the Tibetan part of the catchment and is dominated by petrogenic organic carbon derived from Jurassic shales with only minor contributions of modern and aged biospheric organic carbon. These findings emphasize the importance of organic carbon source distribution and erosion mechanisms in determining the organic carbon export from mountain ranges. In a third step, I explore the potential of ultra-high resolution mass spectrometry for particulate organic carbon transport studies. I have generated a novel and unprecedented high-resolution molecular dataset, which contains up to 103 molecular formulas of the lipid fraction of particulate organic matter for modern and aged biospheric carbon, petrogenic organic carbon and river sediments. First, I test if this dataset can be used to better resolve different organic carbon sources and to identify new geochemical tracers. Using multivariate statistics, I identify up to 10² characteristic molecular formulas for the major organic carbon sources in the upper part of the Kali Gandaki catchment, and trace their transfer from the surrounding landscape into the river sediment. Second, I test the potential of the molecular dataset to trace molecular transformations along source-to-sink pathways. I identify changes in molecular metrics derived from the dataset, which are characteristic of transformation processes during incorporation of litter into soil, the aging of soil material, and the mobilization of the organic carbon into the river. These two studies demonstrate that high-resolution molecular datasets open a promising analytical window on particulate organic carbon and can provide novel insights into the composition, sourcing and transformation of riverine particulate organic carbon. Collectively, these studies advance our understanding of the processes contributing to the storage and mobilization of organic carbon in the Central Himalaya, the mountain belt that dominates global erosional fluxes. They do so by identifying the major sources of particulate organic carbon to the Trans-Himalayan Kali Gandaki River, by elucidating their sensitivity to climate and geomorphic processes, and by identifying some of the transformations of this material on the molecular scale. As a result, the thesis demonstrates that the amount and composition of organic carbon routed from mountain belts is a function of the dynamic interactions of geologic, biologic, geomorphic and climatic processes within the mountain belt. This understanding will ultimately help in answering whether the build-up and erosion of mountain ranges over geological time represents a net carbon source or sink to the atmosphere. Beyond this, the thesis contributes to our technical ability to characterize organic matter and attribute it to sources by scoping the potential of high-end molecular analysis.}, language = {en} } @phdthesis{RodriguezZuluaga2020, author = {Rodriguez Zuluaga, Juan}, title = {Electric and magnetic characteristics of equatorial plasma depletions}, doi = {10.25932/publishup-44587}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-445873}, school = {Universit{\"a}t Potsdam}, pages = {xvi, 87}, year = {2020}, abstract = {Near-Earth space represents a significant scientific and technological challenge. Particularly at magnetic low-latitudes, the horizontal magnetic field geometry at the dip equator and its closed field-lines support the existence of a distinct electric current system, abrupt electric field variations and the development of plasma irregularities. Of particular interest are small-scale irregularities associated with equatorial plasma depletions (EPDs). They are responsible for the disruption of trans-ionospheric radio waves used for navigation, communication, and Earth observation. The fast increase of satellite missions makes it imperative to study the near-Earth space, especially the phenomena known to harm space technology or disrupt their signals. EPDs correspond to the large-scale structure (i.e., tens to hundreds of kilometers) of topside F region irregularities commonly known as Spread F. They are observed as depleted-plasma density channels aligned with the ambient magnetic field in the post-sunset low-latitude ionosphere. Although the climatological variability of their occurrence in terms of season, longitude, local time and solar flux is well-known, their day to day variability is not. The sparse observations from ground-based instruments like radars and the few simultaneous measurements of ionospheric parameters by space-based instruments have left gaps in the knowledge of EPDs essential to comprehend their variability. In this dissertation, I profited from the unique observations of the ESA's Swarm constellation mission launched in November 2013 to tackle three issues that revealed novel and significant results on the current knowledge of EPDs. I used Swarm's measurements of the electron density, magnetic, and electric fields to answer, (1.) what is the direction of propagation of the electromagnetic energy associated with EPDs?, (2.) what are the spatial and temporal characteristics of the electric currents (field-aligned and diamagnetic currents) related to EPDs, i.e., seasonal/geographical, and local time dependencies?, and (3.) under what conditions does the balance between magnetic and plasma pressure across EPDs occur? The results indicate that: (1.) The electromagnetic energy associated with EPDs presents a preference for interhemispheric flows; that is, the related Poynting flux directs from one magnetic hemisphere to the other and varies with longitude and season. (2.) The field-aligned currents at the edges of EPDs are interhemispheric. They generally close in the hemisphere with the highest Pedersen conductance. Such hemispherical preference presents a seasonal/longitudinal dependence. The diamagnetic currents increase or decrease the magnetic pressure inside EPDs. These two effects rely on variations of the plasma temperature inside the EPDs that depend on longitude and local time. (3.) EPDs present lower or higher plasma pressure than the ambient. For low-pressure EPDs the plasma pressure gradients are mostly dominated by variations of the plasma density so that variations of the temperature are negligible. High-pressure EPDs suggest significant temperature variations with magnitudes of approximately twice the ambient. Since their occurrence is more frequent in the vicinity of the South Atlantic magnetic anomaly, such high temperatures are suggested to be due to particle precipitation. In a broader context, this dissertation shows how dedicated satellite missions with high-resolution capabilities improve the specification of the low-latitude ionospheric electrodynamics and expand knowledge on EPDs which is valuable for current and future communication, navigation, and Earth-observing missions. The contributions of this investigation represent several 'firsts' in the study of EPDs: (1.) The first observational evidence of interhemispheric electromagnetic energy flux and field-aligned currents. (2.) The first spatial and temporal characterization of EPDs based on their associated field-aligned and diamagnetic currents. (3.) The first evidence of high plasma pressure in regions of depleted plasma density in the ionosphere. These findings provide new insights that promise to advance our current knowledge of not only EPDs but the low-latitude post-sunset ionosphere environment.}, language = {en} } @phdthesis{Kaya2020, author = {Kaya, Mustafa}, title = {Cretaceous-Paleogene evolution of the proto-Paratethys Sea in Central Asia}, doi = {10.25932/publishup-48329}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-483295}, school = {Universit{\"a}t Potsdam}, pages = {iv, 237}, year = {2020}, abstract = {Unlike today's prevailing terrestrial features, the geologic past of Central Asia witnessed marine environments and conditions as well. A vast, shallow sea, known as proto-Paratethys, extended across Eurasia from the Mediterranean Tethys to the Tarim Basin in western China during Cretaceous to Paleogene times. This sea formed about 160 million years ago (during Jurassic times) when the waters of the Tethys Ocean flooded into Eurasia. It drastically retreated to the west and became isolated as the Paratethys during the Late Eocene-Oligocene (ca. 34 Ma). Having well-constrained timing and paleogeography for the Cretaceous-Paleogene proto-Paratethys sea incursions in Central Asia is essential to properly understand and distinguish the controlling mechanisms and their link to Asian paleoenvironmental and paleoclimatic change. The Cretaceous-Paleogene tectonic evolution of the Pamir and Tibet and their far-field effects play a significant role on the sedimentological and structural evolution of the Central Asian basins and on the evolution of the proto-Paratethys sea fluctuations as well. Comparing the records of the sea incursions to the tectonic and eustatic events has paramount importance to reveal the controlling mechanisms behind the sea incursions. However, due to inaccuracies in the dating of rocks (mostly continental rocks and marine rocks with benthic microfossils providing low-resolution biostratigraphic constraints) and conflicting results, there has been no consensus on the timing of the sea incursions and interpretation of their records has been in question. Here, we present a new chronostratigraphic framework based on biostratigraphy and magnetostratigraphy as well as a detailed paleoenvironmental analysis for the Cretaceous and Paleogene proto-Paratethys Sea incursions in the Tajik and Tarim basins, in Central Asia. This enables us to identify the major drivers of marine fluctuations and their potential consequences on regional and global climate, particularly Asian aridification and the global carbon cycle perturbations such as the Paleocene-Eocene Thermal Maximum (PETM). To estimate the paleogeographic evolution of the proto-Paratethys Sea, the refined age constraints and detailed paleoenvironmental interpretations are combined with successive paleogeographic maps. Regional coastlines and depositional environments during the Cretaceous-Paleogene sea advances and retreats were drawn based on the results of this thesis and integrated with existing literature to generate new paleogeographic maps. Before its final westward retreat in the Eocene, a total of six Cretaceous and Paleogene major sea incursions have been distinguished from the sedimentary records of the Tajik and Tarim basins in Central Asia. All have been studied and documented here. We identify the presence of marine conditions already in the Early Cretaceous in the western Tajik Basin, followed by the Cenomanian (ca. 100 Ma) and Santonian (ca. 86 Ma) major marine incursions far into the eastern Tajik and Tarim basins separated by a Turonian-Coniacian (ca. 92-86 Ma) regression. Basin-wide tectonic subsidence analyses imply that the Early Cretaceous invasion of the sea into the Tajik Basin is related to increased Pamir tectonism (at ca. 130 - 90 Ma) in a retro-arc basin setting inferred to be linked to collision and subduction. This tectonic event mainly governed the Cenomanian (ca. 100 Ma) sea incursion in conjunction with a coeval global eustatic high resulting in the maximum geographic extent of the sea. The following Turonian-Coniacian (ca. 92-86 Ma) major regression, driven by eustasy, coincides with a sharp slowdown in tectonic subsidence related to a regime change in Pamir tectonism from compression to extension. The Santonian (ca. 86 Ma) major sea incursion was more likely controlled dominantly by eustasy as also evidenced by the coeval fluctuations in the west Siberian Basin. During the early Maastrichtian, the global Late Cretaceous cooling is inferred from the disappearance of mollusk-rich limestones and the dominance of bryozoan-rich and echinoderm-rich limestones in the Tajik Basin documenting the first evidence for the Late Cretaceous cooling event in Central Asia. Following the last Cretaceous sea incursion, a major regional restriction event, marked by the exceptionally thick (≤ 400 m) shelf evaporites is assigned a Danian-Selandian age (ca. 63-59 Ma). This is followed by the largest recorded proto-Paratethys sea incursion with a transgression estimated as early Thanetian (ca. 59-57 Ma) and a regression within the Ypresian (ca. 53-52 Ma). The transgression of the next incursion is now constrained as early Lutetian (ca. 47-46 Ma), whereas its regression is constrained as late Lutetian (ca. 41 Ma) and is associated with a drastic increase in both tectonic subsidence and basin infilling. The age of the final and least pronounced sea incursion restricted to the westernmost margin of the Tarim Basin is assigned as Bartonian-Priabonian (ca. 39.7-36.7 Ma). We interpret the long-term westward retreat of the proto-Paratethys Sea starting at ca. 41 Ma to be associated with far-field tectonic effects of the Indo-Asia collision and Pamir/Tibetan plateau uplift. Short-term eustatic sea level transgressions are superimposed on this long-term regression and seem coeval with the transgression events in the other northern Peri-Tethyan sedimentary provinces for the 1st and 2nd Paleogene sea incursions. However, the last Paleogene sea incursion is interpreted as related to tectonism. The transgressive and regressive intervals of the proto-Paratethys Sea correlate well with the reported humid and arid phases, respectively in the Qaidam and Xining basins, thus demonstrating the role of the proto-Paratethys Sea as an important moisture source for the Asian interior and its regression as a contributor to Asian aridification. We lastly study the mechanics, relative contribution and preservation efficiency of ancient epicontinental seas as carbon sinks with new and existing data, using organic rich (sapropel) deposits dated to the PETM from the extensive epicontinental proto-Paratethys and West Siberian seas. We estimate ca. 1390±230 Gt organic C burial, a substantial amount compared to previously estimated global total excess organic C burial (ca. 1700-2900 Gt) is focused in the proto-Paratethys and West Siberian seas alone. We also speculate that enhanced organic carbon burial later over much of the proto-Paratethys (and later Paratethys) basin (during the deposition of the Kuma Formation and Maikop series, repectively) may have majorly contributed to drawdown of atmospheric carbon dioxide before and during the EOT cooling and glaciation of Antarctica. For past periods with smaller epicontinental seas, the effectiveness of this negative carbon cycle feedback was arguably diminished, and the same likely applies to the present-day.}, language = {en} } @phdthesis{Meijer2020, author = {Meijer, Niels}, title = {Asian dust, monsoons and westerlies during the Eocene}, doi = {10.25932/publishup-48868}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-488687}, school = {Universit{\"a}t Potsdam}, pages = {ix, 155}, year = {2020}, abstract = {The East Asian monsoons characterize the modern-day Asian climate, yet their geological history and driving mechanisms remain controversial. The southeasterly summer monsoon provides moisture, whereas the northwesterly winter monsoon sweeps up dust from the arid Asian interior to form the Chinese Loess Plateau. The onset of this loess accumulation, and therefore of the monsoons, was thought to be 8 million years ago (Ma). However, in recent years these loess records have been extended further back in time to the Eocene (56-34 Ma), a period characterized by significant changes in both the regional geography and global climate. Yet the extent to which these reconfigurations drive atmospheric circulation and whether the loess-like deposits are monsoonal remains debated. In this thesis, I study the terrestrial deposits of the Xining Basin previously identified as Eocene loess, to derive the paleoenvironmental evolution of the region and identify the geological processes that have shaped the Asian climate. I review dust deposits in the geological record and conclude that these are commonly represented by a mix of both windblown and water-laid sediments, in contrast to the pure windblown material known as loess. Yet by using a combination of quartz surface morphologies, provenance characteristics and distinguishing grain-size distributions, windblown dust can be identified and quantified in a variety of settings. This has important implications for tracking aridification and dust-fluxes throughout the geological record. Past reversals of Earth's magnetic field are recorded in the deposits of the Xining Basin and I use these together with a dated volcanic ash layer to accurately constrain the age to the Eocene period. A combination of pollen assemblages, low dust abundances and other geochemical data indicates that the early Eocene was relatively humid suggesting an intensified summer monsoon due to the warmer greenhouse climate at this time. A subsequent shift from predominantly freshwater to salt lakes reflects a long-term aridification trend possibly driven by global cooling and the continuous uplift of the Tibetan Plateau. Superimposed on this aridification are wetter intervals reflected in more abundant lake deposits which correlate with highstands of the inland proto-Paratethys Sea. This sea covered the Eurasian continent and thereby provided additional moisture to the winter-time westerlies during the middle to late Eocene. The long-term aridification culminated in an abrupt shift at 40 Ma reflected by the onset of windblown dust, an increase in steppe-desert pollen, the occurrence of high-latitude orbital cycles and northwesterly winds identified in deflated salt deposits. Together, these indicate the onset of a Siberian high atmospheric pressure system driving the East Asian winter monsoon as well as dust storms and was triggered by a major sea retreat from the Asian interior. These results therefore show that the proto-Paratethys Sea, though less well recognized than the Tibetan Plateau and global climate, has been a major driver in setting up the modern-day climate in Asia.}, language = {en} } @phdthesis{Desanois2019, author = {Desanois, Louis}, title = {On the origin of epithermal Sn-Ag-Zn mineralization at the Pirquitas mine, NW Argentina}, doi = {10.25932/publishup-43082}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-430822}, school = {Universit{\"a}t Potsdam}, pages = {104}, year = {2019}, abstract = {The Central Andes host large reserves of base and precious metals. The region represented, in 2017, an important part of the worldwide mining activity. Three principal types of deposits have been identified and studied: 1) porphyry type deposits extending from central Chile and Argentina to Bolivia, and Northern Peru, 2) iron oxide-copper-gold (IOCG) deposits, extending from central Peru to central Chile, and 3) epithermal tin polymetallic deposits extending from Southern Peru to Northern Argentina, which compose a large part of the deposits of the Bolivian Tin Belt (BTB). Deposits in the BTB can be divided into two major types: (1) tin-tungsten-zinc pluton-related polymetallic deposits, and (2) tin-silver-lead-zinc epithermal polymetallic vein deposits. Mina Pirquitas is a tin-silver-lead-zinc epithermal polymetallic vein deposit, located in north-west Argentina, that used to be one of the most important tin-silver producing mine of the country. It was interpreted to be part of the BTB and it shares similar mineral associations with southern pluton related BTB epithermal deposits. Two major mineralization events related to three pulses of magmatic fluids mixed with meteoric water have been identified. The first event can be divided in two stages: 1) stage I-1 with quartz, pyrite, and cassiterite precipitating from fluids between 233 and 370 °C and salinity between 0 and 7.5 wt\%, corresponding to a first pulse of fluids, and 2) stage I-2 with sphalerite and tin-silver-lead-antimony sulfosalts precipitating from fluids between 213 and 274 °C with salinity up to 10.6 wt\%, corresponding to a new pulse of magmatic fluids in the hydrothermal system. The mineralization event II deposited the richest silver ores at Pirquitas. Event II fluids temperatures and salinities range between 190 and 252 °C and between 0.9 and 4.3 wt\% respectively. This corresponds to the waning supply of magmatic fluids. Noble gas isotopic compositions and concentrations in ore-hosted fluid inclusions demonstrate a significant contribution of magmatic fluids to the Pirquitas mineralization although no intrusive rocks are exposed in the mine area. Lead and sulfur isotopic measurements on ore minerals show that Pirquitas shares a similar signature with southern pluton related polymetallic deposits in the BTB. Furthermore, the major part of the sulfur isotopic values of sulfide and sulfosalt minerals from Pirquitas ranges in the field for sulfur derived from igneous rocks. This suggests that the main contribution of sulfur to the hydrothermal system at Pirquitas is likely to be magma-derived. The precise age of the deposit is still unknown but the results of wolframite dating of 2.9 ± 9.1 Ma and local structural observations suggest that the late mineralization event is younger than 12 Ma.}, language = {en} } @phdthesis{Beamish2019, author = {Beamish, Alison Leslie}, title = {Hyperspectral remote sensing of the spatial and temporal heterogeneity of low Arctic vegetation}, doi = {10.25932/publishup-42592}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-425922}, school = {Universit{\"a}t Potsdam}, pages = {v, 102}, year = {2019}, abstract = {Arctic tundra ecosystems are experiencing warming twice the global average and Arctic vegetation is responding in complex and heterogeneous ways. Shifting productivity, growth, species composition, and phenology at local and regional scales have implications for ecosystem functioning as well as the global carbon and energy balance. Optical remote sensing is an effective tool for monitoring ecosystem functioning in this remote biome. However, limited field-based spectral characterization of the spatial and temporal heterogeneity limits the accuracy of quantitative optical remote sensing at landscape scales. To address this research gap and support current and future satellite missions, three central research questions were posed: • Does canopy-level spectral variability differ between dominant low Arctic vegetation communities and does this variability change between major phenological phases? • How does canopy-level vegetation colour images recorded with high and low spectral resolution devices relate to phenological changes in leaf-level photosynthetic pigment concentrations? • How does spatial aggregation of high spectral resolution data from the ground to satellite scale influence low Arctic tundra vegetation signatures and thereby what is the potential of upcoming hyperspectral spaceborne systems for low Arctic vegetation characterization? To answer these questions a unique and detailed database was assembled. Field-based canopy-level spectral reflectance measurements, nadir digital photographs, and photosynthetic pigment concentrations of dominant low Arctic vegetation communities were acquired at three major phenological phases representing early, peak and late season. Data were collected in 2015 and 2016 in the Toolik Lake Research Natural Area located in north central Alaska on the North Slope of the Brooks Range. In addition to field data an aerial AISA hyperspectral image was acquired in the late season of 2016. Simulations of broadband Sentinel-2 and hyperspectral Environmental and Mapping Analysis Program (EnMAP) satellite reflectance spectra from ground-based reflectance spectra as well as simulations of EnMAP imagery from aerial hyperspectral imagery were also obtained. Results showed that canopy-level spectral variability within and between vegetation communities differed by phenological phase. The late season was identified as the most discriminative for identifying many dominant vegetation communities using both ground-based and simulated hyperspectral reflectance spectra. This was due to an overall reduction in spectral variability and comparable or greater differences in spectral reflectance between vegetation communities in the visible near infrared spectrum. Red, green, and blue (RGB) indices extracted from nadir digital photographs and pigment-driven vegetation indices extracted from ground-based spectral measurements showed strong significant relationships. RGB indices also showed moderate relationships with chlorophyll and carotenoid pigment concentrations. The observed relationships with the broadband RGB channels of the digital camera indicate that vegetation colour strongly influences the response of pigment-driven spectral indices and digital cameras can track the seasonal development and degradation of photosynthetic pigments. Spatial aggregation of hyperspectral data from the ground to airborne, to simulated satel-lite scale was influenced by non-photosynthetic components as demonstrated by the distinct shift of the red edge to shorter wavelengths. Correspondence between spectral reflectance at the three scales was highest in the red spectrum and lowest in the near infra-red. By artificially mixing litter spectra at different proportions to ground-based spectra, correspondence with aerial and satellite spectra increased. Greater proportions of litter were required to achieve correspondence at the satellite scale. Overall this thesis found that integrating multiple temporal, spectral, and spatial data is necessary to monitor the complexity and heterogeneity of Arctic tundra ecosystems. The identification of spectrally similar vegetation communities can be optimized using non-peak season hyperspectral data leading to more detailed identification of vegetation communities. The results also highlight the power of vegetation colour to link ground-based and satellite data. Finally, a detailed characterization non-photosynthetic ecosystem components is crucial for accurate interpretation of vegetation signals at landscape scales.}, language = {en} } @phdthesis{Scheffler2019, author = {Scheffler, Franziska}, title = {Selenite pseudomorphs}, school = {Universit{\"a}t Potsdam}, pages = {154}, year = {2019}, language = {en} }