@article{Mackert2004, author = {Mackert, J{\"u}rgen}, title = {Reorganiszation and Stabilization}, series = {Journal of classical sociology}, volume = {4}, journal = {Journal of classical sociology}, number = {3}, publisher = {Sage Publ.}, address = {London}, issn = {1468-795X}, pages = {311 -- 336}, year = {2004}, abstract = {The consequences of economic globalization have created a new interest in'EmileDurkheim's conception of an institutional and moral reorganization of modernsociety that he developed in Professional Ethics and Civic Morals. Contrary toexisting attempts to explain these political processes towards democratization, thisarticle argues for a causal analysis of social change and concentrates on the socialmechanisms that trigger the reorganization process of modern society. Two thesesare entertained. The first thesis argues that the programme of an institutional andmoral reorganization of modern society can be reanalysed as a causal process ofdemocratization. This process takes two steps. While social mechanisms of reorgan-izationbring about the institutional and moral reorganization of modern society,social mechanisms of stabilizationguarantee the functioning of the emergingdemocratic system. Further, the second thesis argues that this kind of explanationcan be applied to Durkheim's vision of a European confederation. The analysisreveals that his idea of a 'post-national' constellation refers to crucial problems ofthe recent debate regarding a democratic deficit in the European Union, and itshows that Durkheim's contribution to both political sociology and historical-comparative research has been misconceived and prematurely repudiated.}, language = {en} } @misc{Eckstein2004, author = {Eckstein, Lars}, title = {David Dabydeen}, isbn = {3-520-83804-4}, year = {2004}, language = {en} } @article{Schwarz2004, author = {Schwarz, Anja}, title = {Modes of 'un-Australianness' and 'un-Germanness': Contemporary Debates on Cultural Diversity in Germany and Australia}, year = {2004}, language = {en} } @article{WegenerWirgesGerhardetal.2004, author = {Wegener, Michael and Wirges, Werner and Gerhard, Reimund and Dansachm{\"u}ller, M. and Schw{\"o}diauer, R. and Bauer-Gogonea, Simona and Bauer, Siegfried and Paajanen, Mika and Minkkinen, Hannu and Raukola, J.}, title = {Controlled inflation of voids in cellular polymer ferroelectrets : optimizing electromechanical transducer properties}, year = {2004}, abstract = {When exposed to sufficiently high electric fields, polymer-foam electret materials with closed cells exhibit ferroelectric-like behavior and may therefore be called ferroelectrets. In cellular ferroelectrets, the influence of the cell size and shape distributions on the application-relevant properties is not yet understood. Therefore, controlled inflation experiments were carried out on cellular polypropylene films, and the resulting elastical and electromechanical parameters were determined. The elastic modulus in the thickness direction shows a minimum with a corresponding maximum in the electromechanical transducer coefficient. The resonance frequency shifts as a function of the elastic modulus and the relative density of the inflated cellular films. Therefore, the transducer properties of cellular ferroelectrets can be optimized by means of controlled inflation. (C) 2004 American Institute of Physics}, language = {en} } @article{Sprinz2004, author = {Sprinz, Detlef F.}, title = {Environment meets statistics : Quantitative analysis of international environmental policy}, isbn = {0-472-06861-X}, year = {2004}, language = {en} } @article{SprinzWolinskyNahmias2004, author = {Sprinz, Detlef F. and Wolinsky-Nahmias, Yael}, title = {Introduction : Methodology in international relations research}, isbn = {0-472-06861-X}, year = {2004}, language = {en} } @article{OPUS4-32397, title = {Models, numbers and cases : methods for studying international relations}, editor = {Sprinz, Detlef F. and Wolinsky-Nahmias, Yael}, edition = {4. [print.]}, publisher = {Univ. of Michigan Press}, address = {Ann Arbor, Mich.}, isbn = {0-472-09861-6}, pages = {412 S.}, year = {2004}, language = {en} } @phdthesis{Lederer2004, author = {Lederer, Markus}, title = {Paul, T. V., (Hrsg.), The Nation-State in Question; Princeton, Univ. Press, 2003}, year = {2004}, language = {en} } @article{AsghariBroegCaroneetal.2004, author = {Asghari, N. and Broeg, C. and Carone, L. and Casas-Miranda, R. and Palacio, J. C. C. and Csillik, I. and Dvorak, R. and Freistetter, F. and Hadjivantsides, G. and Hussmann, H. and Khramova, A. and Khristoforova, M. and Khromova, I. and Kitiashivilli, I. and Kozlowski, S. and Laakso, T. and Laczkowski, T. and Lytvinenko, D. and Miloni, O. and Morishima, R. and Moro-Martin, A. and Paksyutov, V. and Pal, A. and Patidar, V. and Pecnik, B. and Peles, O. and Pyo, J. and Quinn, T. and Rodriguez, A. and Romano, C. and Saikia, E. and Stadel, J. and Thiel, M. and Todorovic, N. and Veras, D. and Neto, E. V. and Vilagi, J. and von Bloh, Werner and Zechner, R. and Zhuchkova, E.}, title = {Stability of terrestrial planets in the habitable zone of G1 777 A, HD 72659, G1 614, 47 Uma and HD 4208}, issn = {0004-6361}, doi = {10.1051/0004-6361:20040390}, year = {2004}, abstract = {We have undertaken a thorough dynamical investigation of five extrasolar planetary systems using extensive numerical experiments. The systems Gl 777 A, HD 72659, Gl 614, 47 Uma and HD 4208 were examined concerning the question of whether they could host terrestrial-like planets in their habitable zones (HZ). First we investigated the mean motion resonances between fictitious terrestrial planets and the existing gas giants in these five extrasolar systems. Then a fine grid of initial conditions for a potential terrestrial planet within the HZ was chosen for each system, from which the stability of orbits was then assessed by direct integrations over a time interval of 1 million years. For each of the five systems the 2-dimensional grid of initial conditions contained 80 eccentricity points for the Jovian planet and up to 160 semimajor axis points for the fictitious planet. The computations were carried out using a Lie-series integration method with an adaptive step size control. This integration method achieves machine precision accuracy in a highly efficient and robust way, requiring no special adjustments when the orbits have large eccentricities. The stability of orbits was examined with a determination of the Renyi entropy, estimated from recurrence plots, and with a more straightforward method based on the maximum eccentricity achieved by the planet over the 1 million year integration. Additionally, the eccentricity is an indication of the habitability of a terrestrial planet in the HZ; any value of e > 0.2 produces a significant temperature difference on a planet's surface between apoapse and periapse. The results for possible stable orbits for terrestrial planets in habitable zones for the five systems are: for Gl 777 A nearly the entire HZ is stable, for 47 Uma, HD 72659 and HD 4208 terrestrial planets can survive for a sufficiently long time, while for Gl 614 our results exclude terrestrial planets moving in stable orbits within the HZ. Studies such as this one are of primary interest to future space missions dedicated to finding habitable terrestrial planets in other stellar systems. Assessing the likelihood of other habitable planets, and more generally the possibility of other life, is the central question of astrobiology today. Our investigation indicates that, from the dynamical point of view, habitable terrestrial planets seem to be compatible with many of the currently discovered extrasolar systems}, language = {en} } @article{SprinzWolinskyNahmias2004, author = {Sprinz, Detlef F. and Wolinsky-Nahmias, Yael}, title = {Conclusion : Multimedhod Research}, isbn = {0-472-06861-X}, year = {2004}, language = {en} } @misc{Lederer2004, author = {Lederer, Markus}, title = {Reuter, P., Truman, E. M., Chasing dirty money, the fight agaist money laundering; Washington D.C., Institute for International Economics, 2004}, year = {2004}, language = {en} } @article{RichterWassermannZimmeretal.2004, author = {Richter, Gudrun and Wassermann, J{\"u}rgen and Zimmer, Martin and Ohrnberger, Matthias}, title = {Correlation of seismic activity and fumarole temperature at the Mt. Merapi volcano (Indonesia) in 2000}, issn = {0377-0273}, doi = {10.1016/j.jvolgeores.2004.03.006}, year = {2004}, abstract = {In this paper we present densely sampled fumarole temperature data, recorded continuously at a high-temperature fumarole of Mt. Merapi volcano (Indonesia). These temperature time series are correlated with continuous records of rainfall and seismic waveform data collected at the Indonesian - German multi-parameter monitoring network. The correlation analysis of fumarole temperature and precipitation data shows a clear influence of tropical rain events on fumarole temperature. In addition, there is some evidence that rainfall may influence seismicity rates, indicating interaction of meteoric water with the volcanic system. Knowledge about such interactions is important, as lava dome instabilities caused by heavy-precipitation events may result in pyroclastic flows. Apart from the strong external influences on fumarole temperature and seismicity rate, which may conceal smaller signals caused by volcanic degassing processes, the analysis of fumarole temperature and seismic data indicates a statistically significant correlation between a certain type of seismic activity and an increase in fumarole temperature. This certain type of seismic activity consists of a seismic cluster of several high-frequency transients and an ultra-long-period signal (< 0.002 Hz), which are best observed using a broadband seismometer deployed at a distance of 600 m from the active lava dome. The corresponding change in fumarole temperature starts a few minutes after the ultra-long-period signal and simultaneously with the high-frequency seismic cluster. The change in fumarole temperature, an increase of 5 degreesC on average, resembles a smoothed step. Fifty-four occurrences of simultaneous high-frequency seismic cluster, ultra-long period signal and increase of fumarole temperature have been identified in the data set from August 2000 to January 2001. The observed signals appear to correspond to degassing processes in the summit region of Mt. Merapi. (C) 2004 Elsevier B.V. All rights reserved}, language = {en} } @article{YangVardenyKoehleretal.2004, author = {Yang, C. and Vardeny, Z. V. and K{\"o}hler, Anna and Wohlgenannt, M. and Al-Suti, Mohammed K. and Khan, Muhammad S.}, title = {Spectroscopic study of spin-dependent exciton formation rates in pi-conjugated semiconductors : Comparison with electroluminescence techniques}, year = {2004}, abstract = {It has been found in recent measurements that the singlet-to-triplet exciton ratio in organic light-emitting diodes (OLEDs) is larger than expected from spin degeneracy, and that singlet excitons form at a larger rate than triplets. We employed the technique of optically detected magnetic resonance to measure the spin-dependent exciton formation rates in films of a polymer and corresponding monomer, and explore the relation between the formation rates and the actual singlet-to-triplet ratio measured previously in OLEDs. We found that the spin-dependent exciton formation rates can indeed quantitatively explain the observed exciton yields, and that singlet formation rates and yields are significantly enhanced only in polymer OLEDs, but not in OLEDs made from the corresponding monomer}, language = {en} } @article{ShumyantsevaIvanovBistolasetal.2004, author = {Shumyantseva, V. V. and Ivanov, Y. D. and Bistolas, Nikitas and Scheller, Frieder W. and Archakov, Alexander I. and Wollenberger, Ursula}, title = {Direct electron transfer of cytochrome P450 2B4 at electrodes modified with non-ionic detergent and colloidal clay nanoparticles}, year = {2004}, abstract = {A method for construction of biosensors with membranous cytochrome P450 isoenzymes was developed based on clay/ detergent/protein mixed films. Thin films of sodium montmorillonite colloid with incorporated cytochrome P450 2134 (CYP2B4) with nonionic detergent were prepared on glassy carbon electrodes. The modified electrodes were electrochemically characterized, and bio-electrocatalytic reactions were followed. CYP2B4 can be reduced fast on clay- modified glassy carbon electrodes in the presence of the nonionic detergent Tween 80. In anaerobic solutions, reversible oxidation and reduction is obtained with a formal potential between -0.292 and - 0.305 V vs Ag/AgCl 1 M KCl depending on the preparation of the biosensor. In air-saturated solution, bio-electrocatalytic reduction currents can be obtained with the CYP2B4-modified electrode on addition of typical substrates such as aminopyrine and benzphetamine. This reaction was suppressed when methyrapone, an inhibitor of P450 reactions, was present. Measurement of product formation also indicates the bioelectrocatialysis by CYP2B4}, language = {en} } @article{KhanSreearunothaiHerzetal.2004, author = {Khan, Amena L. T. and Sreearunothai, Paiboon and Herz, Laura M. and Banach, Michael J. and K{\"o}hler, Anna}, title = {Morphology-dependent energy transfer within polyfluorene thin films}, year = {2004}, language = {en} } @article{StrehmelKraudeltWetzeletal.2004, author = {Strehmel, Veronika and Kraudelt, Heide and Wetzel, Hendrik and G{\"o}rnitz, Eckhard and Laschewsky, Andr{\´e}}, title = {Free radical polymerization of methacrylates in ionic liquids}, year = {2004}, language = {en} } @article{Sanner2004, author = {Sanner, Helge}, title = {Economy vs. history : what does actually determine the distribution of firms' locations in cities?}, year = {2004}, language = {en} } @book{MihahnSchnor2004, author = {Mihahn, Michael and Schnor, Bettina}, title = {Fault-Tolerant Grid Peer Services}, series = {Technischer Bericht}, journal = {Technischer Bericht}, publisher = {Universit{\"a}t Potsdam, Institut f{\"u}r Informatik}, address = {Potsdam}, issn = {0946-7580}, year = {2004}, language = {en} } @article{YangJaiserNeheretal.2004, author = {Yang, Xiao Hui and Jaiser, Frank and Neher, Dieter and Lawson, PaDreyia V. and Br{\´e}das, Jean-Luc and Zojer, Egbert and G{\"u}ntner, Roland and Scanduicci de Freitas, Patricia and Forster, Michael and Scherf, Ullrich}, title = {Suppression of the keto-emission in polyfluorene light-emitting diodes : Experiments and models}, issn = {1616-301X}, year = {2004}, abstract = {The spectral characteristics of polyfluorene (PF)-based light-emitting diodes (LEDs) containing a defined low concentration of either keto-defects or of the polymer poly(9.9-octylfuorene-co-benzothiadiazole) (F8BT) are preseneted. Both types of blend layers were tested in different device configurations with respect to the relative and absolute intensities of green blue emission components. It is shown that blending hole-transporting molecules into the emission layer at low concentration or incorporation of a suitable hole-transport layer reduces the green emission contribution in the electroluminescence (EL) spectrum of the PF:F8BT blend, which is similar to what is observed for the keto- containing PF layer. We conclude that the keto-defects in PF homopolymer layers mainly constitute weakly emissive electron traps, in agreement with the results of quantum-mechanical calculations}, language = {en} } @article{ZbilutGiulianiColosimoetal.2004, author = {Zbilut, J. P. and Giuliani, A. and Colosimo, A. and Mitchell, J. C. and Colafranceschi, M. and Marwan, Norbert and Webber, C. L. and Uversky, V. N.}, title = {Charge and hydrophobicity patterning along the sequence predicts the folding mechanism and aggregation of proteins : a computational approach}, issn = {1535-3893}, year = {2004}, abstract = {The presence of partially folded intermediates along the folding funnel of proteins has been suggested to be a signature of potentially aggregating systems. Many studies have concluded that metastable, highly flexible intermediates are the basic elements of the aggregation process. In a previous paper, we demonstrated how the choice between aggregation and folding behavior was influenced by hydrophobicity distribution patterning along the sequence, as quantified by recurrence quantification analysis (RQA) of the Myiazawa-Jernigan coded primary structures. In the present paper, we tried to unify the "partially folded intermediate" and "hydrophobicity/charge" models of protein aggregation verifying the ability of an empirical relation, developed for rationalizing the effect of different mutations on aggregation propensity of acyl-phosphatase and based on the combination of hydrophobicity RQA and charge descriptors, to discriminate in a statistically significant way two different protein populations: (a) proteins that fold by a process passing by partially folded intermediates and (b) proteins that do not present partially folded intermediates}, language = {en} } @article{Wyrwa2004, author = {Wyrwa, Ulrich}, title = {The roots of evil : the foundation years of anti-semitism : from the time of Bismarck to Hitler}, issn = {0044-2828}, year = {2004}, language = {en} } @article{Selting2004, author = {Selting, Margret}, title = {Dresden Fallbogen contours as an example of regionalized German intonation}, year = {2004}, abstract = {Based on data from a Mid-German dialect area of Dresden, this article presents research on the structure and functions of regionalized intonation. The Dresden data comes from informal conversation-like settings and illustrates a contour that is typical of the Dresden city vernacular: a contour previously named and described as the Dresden Fallbogen. An analysis of the phonetic forms and phonological structures of the contour is provided, and its use and function in conversational interactions is described. Additional methods of investigating the perception and identification of these contours by subjects in an experimental setting are also given. The article concludes with remarks about the possible relevance of this contour as a signal of identity}, language = {en} } @article{Wischer2004, author = {Wischer, Ilse}, title = {Old English Prefixed Verbs and the Question of Aspect and Aktionsart}, isbn = {3-88476- 702-X}, year = {2004}, language = {en} } @article{Wischer2004, author = {Wischer, Ilse}, title = {The HAVE-perfect in Old English}, year = {2004}, language = {en} } @article{WebsterThomasFoersteretal.2004, author = {Webster, J. D. and Thomas, R. and F{\"o}rster, Hans-J{\"u}rgen and Seltmann, R. and Tappen, C.}, title = {Geochemical evolution of halogen-enriched granite magmas and mineralizing fluids of the Zinnwald tin-tungsten mining district, Erzgebirge, Germany}, issn = {0026-4598}, year = {2004}, abstract = {We remelted and analyzed crystallized silicate melt inclusions in quartz from a porphyritic albitezinnwaldite microgranite dike to determine the composition of highly evolved, shallowly intruded, Li- and F-rich granitic magma and to investigate the role of crystal fractionation and aqueous fluid exsolution in causing the extreme extent of magma differentiation. This dike is intimately associated with tin- and tungsten-mineralized granites of Zinnwald, Erzgebirge, Germany. Prior research on Zinnwald granite geochemistry was limited by the effects of strong and pervasive greisenization and alkali-feldspar metasomatism of the rocks. These melt inclusions, however, provide important new constraints on magmatic and mineralizing processes in Zinnwald magmas. The mildly peraluminous granitic melt inclusions are strongly depleted in CAFEMIC constituents (e.g., CaO, FeO, MgO, TiO2), highly enriched in lithophile trace elements, and highly but variably enriched in F and Cl. The melt inclusions contain up to several thousand ppm Cl and nearly 3 wt\% F, on average; several inclusions contain more than 5 wt\% F. The melt inclusions are geochemically similar to the corresponding whole-rock sample, except that the former contain much more F and less CaO, FeO, Zr, Nb, Sr, and Ba. The Sr and Ba abundances are very low implying the melt inclusions represent magma that was more evolved than that represented by the bulk rock. Relationships involving melt constituents reflect increasing lithophile-element and halogen abundances in residual melt with progressive magma differentiation. Modeling demonstrates that differentiation was dominated by crystal fractionation involving quartz and feldspar and significant quantities of topaz and F-rich zinnwaldite. The computed abundances of the latter phases greatly exceed their abundances in the rocks, suggesting that the residual melt was separated physically from phenocrysts during magma movement and evolution. Interactions of aqueous fluids with silicate melt were also critical to magma evolution. To better understand the role of halogen-charged, aqueous fluids in magmatic differentiation and in subsequent mineralization and metasomatism of the Zinnwald granites, Cl-partitioning experiments were conducted with a F-enriched silicate melt and aqueous fluids at 2,000 bar (200 MPa). The results of the experimentally determined partition coefficients for Cl and F, the compositions of fluid inclusions in quartz and other phenocrysts, and associated geochemical modeling point to an important role of magmatic-hydrothermal fluids in influencing magma geochemistry and evolution. The exsolution of halogen-charged fluids from the Li- and F- enriched Zinnwald granitic magma modified the Cl, alkali, and F contents of the residual melt, and may have also sequestered Li, Sri, and W from the melt. Many of these fluids contained strongly elevated F concentrations that were equivalent to or greater than their Cl abundances. The exsolution of F-, Cl-, Li-, +/- W- and Sn-bearing hydrothermal fluids from Zinnwald granite magmas was important in effecting the greisenizing and alkali-feldspathizing metasomatism of the granites and the concomitant mineralization}, language = {en} } @article{Simon2004, author = {Simon, Theresia Maria}, title = {Alternatives to strategic positioning of a university library}, issn = {0044-2380}, year = {2004}, abstract = {In the past academic libraries in Germany have been successfully undertaking joint endeavors toward a social and political definition of the knowledge society by cooperatively developing ways to provide information and increasing the digital forms of metadata and media. In doing so, they have unintentionally created the basis for a competitive playing field in which the individual library must establish strategic positions for success if it is to maintain viability and ensure continuous flow of resources. This article develops a framework for discussing such alternative and potentially successful strategies from the point of view of a university library}, language = {en} } @article{WilkePartzschFarges2004, author = {Wilke, Max and Partzsch, G. M. and Farges, Francois}, title = {XAFS of iron in silicate melt at high temperature}, issn = {0024-4937}, year = {2004}, language = {en} } @article{TuvalSchneiderPiroetal.2004, author = {Tuval, I. and Schneider, J. and Piro, O. and Tel, Tomas}, title = {Opening up fractal structures of three-dimensional flows via leaking}, issn = {0295-5075}, year = {2004}, abstract = {We study the behavior of time-periodic three-dimensional incompressible flows modelled by three-dimensional volume-preserving maps in the presence of a leakage. The distribution of residence times, and the chaotic saddle together with its stable and unstable invariant manifolds are described and characterized. They shed light. on typical filamentation of chaotic flows whose local stable and unstable manifolds are always of different, character (plane or line). We point out that leaking is a useful method which sheds light on typical filamentation of chaotic flows. In particular; the topology depends on the number of local expanding directions, and is the same in the leaked system as in the closed flow}, language = {en} } @article{SramaAhrensAltobellietal.2004, author = {Srama, Ralf and Ahrens, Thomas J. and Altobelli, Nicolas and Auer, S. and Bradley, J. G. and Burton, M. and Dikarev, V. V. and Economou, T. and Fechtig, Hugo and G{\"o}rlich, M. and Grande, M. and Graps, Amara and Gr{\"u}n, Eberhard and Havnes, Ove and Helfert, Stefan and Horanyi, Mihaly and Igenbergs, E. and Jessberger, Elmar K. and Johnson, T. V. and Kempf, Sascha and Krivov, Alexander v. and Kr{\"u}ger, Harald and Mocker-Ahlreep, Anna and Moragas-Klostermeyer, Georg and Lamy, Philippe and Landgraf, Markus and Linkert, Dietmar and Linkert, G. and Lura, F. and McDonnell, J. A. M. and Moehlmann, Dirk and Morfill, Gregory E. and Muller, M. and Roy, M. and Schafer, G. and Schlotzhauer, G. and Schwehm, Gerhard H. and Spahn, Frank and St{\"u}big, M. and Svestka, Jiri and Tschernjawski, V}, title = {The Cassini Cosmic Dust Analyzer}, issn = {0038-6308}, year = {2004}, abstract = {The Cassini-Huygens Cosmic Dust Analyzer (CDA) is intended to provide direct observations of dust grains with masses between 10(-19) and 10(-9) kg in interplanetary space and in the jovian and saturnian systems, to investigate their physical, chemical and dynamical properties as functions of the distances to the Sun, to Jupiter and to Saturn and its satellites and rings, to study their interaction with the saturnian rings, satellites and magnetosphere. Chemical composition of interplanetary meteoroids will be compared with asteroidal and cometary dust, as well as with Saturn dust, ejecta from rings and satellites. Ring and satellites phenomena which might be effects of meteoroid impacts will be compared with the interplanetary dust environment. Electrical charges of particulate matter in the magnetosphere and its consequences will be studied, e.g. the effects of the ambient plasma and the magnetic held on the trajectories of dust particles as well as fragmentation of particles due to electrostatic disruption. The investigation will be performed with an instrument that measures the mass, composition, electric charge, speed, and flight direction of individual dust particles. It is a highly reliable and versatile instrument with a mass sensitivity 106 times higher than that of the Pioneer 10 and I I dust detectors which measured dust in the saturnian system. The Cosmic Dust Analyzer has significant inheritance from former space instrumentation developed for the VEGA, Giotto, Galileo, and Ulysses missions. It will reliably measure impacts from as low as I impact per month up to 104 impacts per second. The instrument weighs 17 kg and consumes 12 W, the integrated time-of-flight mass spectrometer has a mass resolution of up to 50. The nominal data transmission rate is 524 bits/s and varies between 50 and 4192 bps}, language = {en} } @article{TahtinenBagnoKochetal.2004, author = {Tahtinen, Petri and Bagno, Alessandro and Koch, Andreas and Pihlaja, Kalevi}, title = {Conformational analysis of saturated trans-fused 1,3,2-benzoxazaphosphinine 2-oxides - DFT calculation of NMR J(PH) coupling constants}, issn = {1434-193X}, year = {2004}, abstract = {The (3)J(P,H) and (4)J(P,H) spin-spin coupling constants of a selected test set of organophosphorus compounds, calculated by density functional theory (DFT) methods, were found to correlate well with the experimentally measured coupling constants. The contribution of the spin-dipole (SD) term to the coupling constants was found to be negligible, and the diamagnetic and paramagnetic spin-orbit (DSO and PSO) terms cancelled each other, as in the case of J(H,H). Calculation solely of the Fermi contact (FC) term was found to be sufficient to provide good estimates of the coupling constants. In the second part of the work, the conformational equilibria and coupling constants in 2-bis(2- chloroethyl)amino-trans-octahydro-2H-1,3,2-benzoxazaphosphinine 2-oxide and its 3-methyl derivative were studied. DFT methods failed in predicting the relative stabilities of the conformations but yielded good geometries and coupling constants. Optimization of the conformations at the Moller-Plesset second-order perturbation theory (MP2) level resulted in energy differences compatible with previous experimental observations. ((C) Wiley-VCH Verlag GmbH \& Co. KGaA, 69451 Weinheim, Germany, 2004)}, language = {en} } @article{Stede2004, author = {Stede, Manfred}, title = {Does discourse processing need discourse topics?}, issn = {0301-4428}, year = {2004}, language = {en} } @article{WilkePartzschBernhardtetal.2004, author = {Wilke, Max and Partzsch, G. M. and Bernhardt, Rita and Lattard, D.}, title = {Determination of the iron oxidation state in basaltic glasses using XANES at the K-edge}, issn = {0009-2541}, year = {2004}, abstract = {Fe K-edge X-ray absorption near edge structure (XANES) and Mossbauer spectra were collected on synthetic glasses of basaltic composition and of glasses on the sodium oxide-silica binary to establish a relation between the pre- edge of the XANES at the K-edge and the Fe oxidation state of depolymerised glasses. Charges of sample material were equilibrated at ambient pressure, superliquidus temperatures and oxygen fugacities that were varied over a range of about 15 orders of magnitude. Most experiments were carried out in gas-flow furnaces, either with pure oxygen, air, or different CO/CO2 mixtures. For the most reduced conditions, the samples charges were enclosed together with a pellet of the IQF oxygen buffer in an evacuated silica glass ampoule. Fe3+/SigmaFe x 100 of the samples determined by Mossbauer spectroscopy range between 0\% and 100\%. Position and intensity of the pre-edge centroid position vary strongly depending on the Fe oxidation state. The pre-edge centroid position and the Fe oxidation state determined by Mossbauer spectroscopy are nonlinearly related and have been fitted by a quadratic polynomial. Alternatively, the ratio of intensities measured at positions sensitive to Fe2+ and Fe3+, respectively, provides an even more sensitive method. Pre- edge intensities of the sample suite indicate average Fe co-ordination between 4 and 6 for all samples regardless of oxidation state. A potential application of the calibration given here opens the possibility of determining Fe oxidation state in glasses of similar compositions with high spatial resolution by use of a Micro-XANES setup (e.g., glass inclusions in natural minerals). (C) 2004 Elsevier B.V. All rights reserved}, language = {en} } @article{SengeRichter2004, author = {Senge, Mathias O. and Richter, J.}, title = {Synthetic, transformations of porphyrins : Advances 2002-2004}, issn = {1088-4246}, year = {2004}, abstract = {Contemporary methods for the modification of porphyrins are presented. In association with the Third International Conference on Porphyrins and Phthalocyanines (ICPP-3) a survey of current method developments and reactivity studies is made. The review focuses on synthetic transformations of porphyrins currently in use for various applications and on functional group transformations. A brief survey of important developments covers selectively the literature from late 2001 to early 2004. Copyright (c) 2004 Society of Porphyrins C Phthalocyanines}, language = {en} } @article{SchraderPenzkoferHolzeretal.2004, author = {Schrader, Sigurd and Penzkofer, Alfons and Holzer, W. and Velagapudi, Ramakrishna and Grimm, Bernhard}, title = {Laser spectroscopic investigation of a new precursor - type polyparaphenylenevinylene}, issn = {0022-2313}, year = {2004}, abstract = {Optical, structural and morphological properties of thin films of polyparaphenylenevinylene (PPV) formed by an alkyl sulfinyl precursor route have been studied. Thin films were fabricated on an optical glass and on quartz glass either by spin-coating of the precursor solution or by layer-by-layer deposition using Langmuir-Blodgett technique. PPV precursor films were also spin-coated on gold-coated glass in order to study thin-film optical parameters by surface plasmon spectroscopy. We have been successful in forming about 40 precursor mono layers on quartz glass by Langmuir- Blodgett technique using optimized surface pressure and dipping conditions. After thermal conversion of the precursor layers good quality fluorescent PPV films of yellow colour have been obtained. Optical characterization of the films was carried out by linear absorption and emission spectroscopy, ellipsometry, and surface plasmon spectroscopy. Structural and morphological studies on the thin films were carried out by using X-ray scattering and atomic force microscopy. Wave- guided travelling-wave laser action has been achieved in a PPV film on quartz glass. The sample was transversally pumped with picosecond laser pulses (wavelength 347.15 nm, duration 35 ps). Laser emission occurred at 550 nm for pump pulse energy densities above 1 x 10(-4) J cm(-2). (C) 2004 Elsevier B.V. All rights reserved}, language = {en} } @article{SegertZierke2004, author = {Segert, Astrid and Zierke, Irene}, title = {Stakeholder networks on sustainable management in rural areas}, issn = {0005-9080}, year = {2004}, abstract = {The situation of the German agricultural economy is currently somewhat problematic and requires transitions to sustainable development. The authors consider the network of different stakeholders in rural areas an important social resource for the transition to sustainable agriculture as the change in European and national agricultural policies requires active target groups at regional level. On the empirical basis of two case examples in East German rural areas, they studied the establishment of rural networks and their social development conditions. The study demonstrates how such regional networks must be organised and what socio-cultural contexts are shaping them. The institutionalisation of guiding principles for collaborative cooperation and the incorporation of regional networks in a framework of social environments are of significance for their formation and their ability to flexibly adapt to changing environmental conditions}, language = {en} } @article{Saalfrank2004, author = {Saalfrank, Peter}, title = {Theory of photon- and STM-induced bond cleavage at surfaces}, issn = {1359-0286}, year = {2004}, abstract = {In this contribution, recent advances in the theory of laser and, to a lesser extent, of scanning tunneling microscope (STM) induced cleavage of bonds between an adsorbate and a solid surface, will be reviewed. Special emphasis will be given to the quantum dynamics of electronically non-adiabatic reactions. (c) 2005 Elsevier Ltd. All rights reserved}, language = {en} } @article{ScherbaumCottonSmit2004, author = {Scherbaum, Frank and Cotton, Fabrice and Smit, P.}, title = {On the use of response spectral-reference data for the selection and ranking of ground-motion models for seismic-hazard analysis in regions of moderate seismicity : the case of rock motion}, issn = {0037-1106}, year = {2004}, abstract = {The use of ground-motion-prediction equations to estimate ground shaking has become a very popular approach for seismic-hazard assessment, especially in the framework of a logic-tree approach. Owing to the large number of existing published ground-motion models, however, the selection and ranking of appropriate models for a particular target area often pose serious practical problems. Here we show how observed around-motion records can help to guide this process in a systematic and comprehensible way. A key element in this context is a new, likelihood based, goodness-of-fit measure that has the property not only to quantify the model fit but also to measure in some degree how well the underlying statistical model assumptions are met. By design, this measure naturally scales between 0 and 1, with a value of 0.5 for a situation in which the model perfectly matches the sample distribution both in terms of mean and standard deviation. We have used it in combination with other goodness-of-fit measures to derive a simple classification scheme to quantify how well a candidate ground-rnotion-prediction equation models a particular set of observed-response spectra. This scheme is demonstrated to perform well in recognizing a number of popular ground-motion models from their rock-site- recording, subsets. This indicates its potential for aiding the assignment of logic-tree weights in a consistent and reproducible way. We have applied our scheme to the border region of France, Germany, and Switzerland where the M-w 4.8 St. Die earthquake of 22 February 2003 in eastern France recently provided a small set of observed-response spectra. These records are best modeled by the ground-motion-prediction equation of Berge-Thierry et al. (2003), which is based on the analysis of predominantly European data. The fact that the Swiss model of Bay et al. (2003) is not able to model the observed records in an acceptable way may indicate general problems arising from the use of weak-motion data for strong-motion prediction}, language = {en} } @article{OPUS4-15433, title = {Preparation of simple and mixed nickel and cobalt molybdates using hybrid precursors made from an ordered polymer matrix and inorganic salts}, year = {2004}, abstract = {The amphiphilic poly(ampholyte) poly(N,N-diallyl-N-hexylamine-alt-maleic acid), bearing simultaneously carboxylic acids, amines and hydrocarbon side chains, was used as a matrix to stabilize inorganic ion species (anionic as well as cationic) generated in aqueous solution from Ni(NO3)(2).6H(2)O, Co(NO3)(2).6H(2)O and (NH4)2MoO(4). Drying produces hybrid organic-inorganic blends which, due to the amphiphilicity of the copolymer, exhibit supramolecular organization in the bulk. Solid state studies show that up to two moles of metal cations (alone or together with metal anions) per repeat unit of the copolymer can be blended without loss of homogeneity in the hybrid material. A systematic screening permitted the determination of the optimal conditions for the preparation of homogeneous blends. Thermal treatment of the hybrid materials produces simple and mixed nickel and/or cobalt molybdates. The alpha- as well as the P- phase were obtained, and the mixed structures are solid solutions of simple NiMoO4 and CoMoO4}, language = {en} } @article{RuehlHamscherGarciaetal.2004, author = {R{\"u}hl, Ralph and Hamscher, Gerd and Garcia, Ada and Nau, Heinz and Schweigert, Florian J.}, title = {Identification of 14-hydroxy-retro-retinol and 4-hydroxy-retinol as endogenous retinoids in rats throughout neonatal development}, issn = {0024-3205}, year = {2004}, abstract = {14-Hydroxy-retro-retinol was previously described as an in vivo and in vitro metabolite of retinol. Furthermore, the retinoid 4-hydroxy-retinol was identified as an endogenous occurring retinoid in the amphibian organism and an in vitro metabolite of retinol. We describe in the present study that 14-hydroxy-retro-retinol and 4-hydroxy- retinol are present in normal neonatal rat serum as endogenous occurring retinoids in normal non-vitamin A supplemented mammals (rats). Both retinoids were detected in serum and liver of neonatal rats at days 3 and 11 after birth. The respective concentrations at day 11 after birth were 41.8 +/- 2.8 ng/ml (serum)/ 104 +/- 6 ng/g (liver) for 4-hydroxy- retinol and 23 +/- 4.6 ng/ml (serum)/ 285 +/- 5 ng/g (liver) for 14-hydroxy-retro-retinol. Both retinoids could not be detected in adult rat serum and liver. From our experiments important physiological functions of these retinoids during postnatal development could be postulated. (C) 2004 Elsevier Inc. All rights reserved}, language = {en} } @article{RoetzlerRomerBudzinskietal.2004, author = {R{\"o}tzler, Jochen and Romer, R. L. and Budzinski, Hubertus and Oberh{\"a}nsli, Roland}, title = {Ultrahigh-temperature high-pressure granulites from Tirschheim, Saxon Granulite Massif, Germany : P-T-t path and geotectonic implications}, issn = {0935-1221}, year = {2004}, abstract = {The Saxon granulites, the type granulite locality, were deeply buried, extremely heated and then rapidly exhumed during the Variscan Orogeny; thus their evolution differs from many granulites elsewhere. The peak-metamorphic assemblages of layered felsic-mafic granulites from a 500 m deep borehole consist of garnet, kyanite, rutile, ternary feldspar and quartz in felsic granulite, and garnet, omphacite, titanite, ternary feldspar and quartz in mafic granulite. A minimum temperature of 1000-1020degreesC, calculated from reintegrated hypersolvus feldspar in felsic and mafic granulites, is consistent with the highest temperature estimates from garnet-clinopyroxene equilibria. Various equilibria in felsic and mafic granulites record a peak pressure of about 23 kbar. Diffusion zoning and local homogenisation of minerals reflect near-isothermal decompression that preceded cooling and partial hydration at medium- to low-pressure. U-Pb dating of titanite yields an age of peak metamorphism at 340.7+/-0.8 Ma (2sigma). However, chemical inheritance from precursor rutile and post-peak Pb loss are also evident, suggesting a protolith age of 499+/-2 Ma (2sigma) and partial resetting down to an age of 333+/-2 Ma (2sigma). Rb-Sr mica ages of 333.2+/-3.3 Ma (2sigma) are interpreted as dating cooling through about 620degreesC. Hence the Saxon granulites were exhumed to the upper crust during the short period of 6-11 Ma, which corresponds to average exhumation and cooling rates of 10 mm/year and 50degreesC/Ma, respectively. Such rapid exhumation is inconsistent with recent numerical models that assume foreland- directed transport of the Saxon granulites in the lower crust followed by extensional unroofing. Instead, high-pressure rocks of the Saxon Granulite Massif and the nearby Erzgebirge experienced a buoyant rise to the middle crust and subsequent juxtaposition with structurally higher units along a series of medium- to low-pressure detachment faults}, language = {en} } @article{RosenblumPikovskij2004, author = {Rosenblum, Michael and Pikovskij, Arkadij}, title = {Delayed feedback control of collective synchrony : an approach to suppression of pathological brain rhythms}, issn = {1063-651X}, year = {2004}, abstract = {We suggest a method for suppression of synchrony in a globally coupled oscillator network, based on the time- delayed feedback via the mean field. Having in mind possible applications for suppression of pathological rhythms in neural ensembles, we present numerical results for different models of coupled bursting neurons. A theory is developed based on the consideration of the synchronization transition as a Hopf bifurcation}, language = {en} } @article{RichterEngbert2004, author = {Richter, Eike M. and Engbert, Ralf}, title = {Parafoveal processing during reading}, issn = {0301-0066}, year = {2004}, language = {en} } @article{Fery2004, author = {F{\´e}ry, Caroline}, title = {German accent revisited}, year = {2004}, language = {en} } @article{PetersPetersRebienetal.2004, author = {Peters, Karl and Peters, E. M. and Rebien, F. and Maurer, M. and Linker, Torsten}, title = {Crystal structure of (3aS,4S,9R,9aS)-4-hydroxy-9-phenyl-3a,4,9,9a-tetra-hydro-3H-naphtho[2,3- c]furan-1- one,C18H16O3}, issn = {1433-7266}, year = {2004}, abstract = {C18H16O3, monoclinic, P12(1)/n1 (no. 14), a = 8.284(l) Angstrom, b = 9.524(l) Angstrom, c = 17.729(1) Angstrom, beta = 93.69(1)degrees, V = 1395.9 Angstrom(3), Z = 4, R-gt(F) = 0.052, wR(ref)(F-2) = 0.146, T = 293 K.}, language = {en} } @article{PetersPetersRebienetal.2004, author = {Peters, Karl and Peters, E. M. and Rebien, F. and Engelhardt, Ulrike and Linker, Torsten}, title = {Crystal structure of methyl (1R,4S)-4-hydroxy-1-phenyl-1,4-dihydronaphthalene-2-carboxylate,C18H16O3}, issn = {1433-7266}, year = {2004}, abstract = {C18H16O3, monoclinic, C12/c1 (no. 15), a = 28.674(4) Angstrom, b = 8.133(1) Angstrom, c = 13.065(2) Angstrom, beta = 108.96(1)degrees, V = 2881.6 Angstrom Z = 8, R-gt(F) = 0.077, wR(ref)(F-2) = 0.245, T = 293 K.}, language = {en} } @article{PacholskyVakeelHimmeletal.2004, author = {Pacholsky, Dirk and Vakeel, Padmanabhan and Himmel, Mirko and Lowe, T. and Stradal, T. and Rottner, K. and F{\"u}rst, Dieter Oswald and vanderVen, Peter F. M.}, title = {Xin repeats define a novel actin-binding motif}, issn = {0021-9533}, year = {2004}, abstract = {Xin is a protein that is expressed during early developmental stages of cardiac and skeletal muscles. Immunolocalization studies indicated a peripheral localization in embryonic mouse heart, where Xin localizes with beta- catenin and N-cadherin. In adult tissues, Xin is found primarily in the intercalated discs of cardiomyocytes and the myotendinous junctions of skeletal muscle cells, both specialized attachment sites of the myofibrillar ends to the sarcolemma. A large part of the Xin protein consists of unique 16 amino acid repeats with unknown function. We have investigated the characteristics of the Xin repeats by transfection experiments and actin-binding assays and ascertained that, upon expression in cultured cells, these repeats bind to and stabilize the actin-based cytoskeleton. In vitro co- sedimentation assays with skeletal muscle actin indicated that they not only directly bind actin filaments, but also have the capability of arranging microfilaments into networks that sediment upon low-speed centrifugation. Very similar repeats were also found in Xin-repeat protein 2' (XIRP2), a novel protein that seems to be expressed mainly in striated muscles. Human XIRP2 contains 28 Xin repeats with properties identical to those of Xin. We conclude that the Xin repeats define a novel, repetitive actin-binding motif present in at least two different muscle proteins. These Xin- repeat proteins therefore constitute the first two members of a novel family of actin-binding proteins}, language = {en} } @article{ZieheKawanabeHarmeling2004, author = {Ziehe, Andreas and Kawanabe, Motoaki and Harmeling, Stefan}, title = {Blind separation of post-nonlinear mixtures using linearizing transformations and temporal decorrelation}, issn = {1532-4435}, year = {2004}, abstract = {We propose two methods that reduce the post-nonlinear blind source separation problem (PNL-BSS) to a linear BSS problem. The first method is based on the concept of maximal correlation: we apply the alternating conditional expectation (ACE) algorithm-a powerful technique from nonparametric statistics-to approximately invert the componentwise nonlinear functions. The second method is a Gaussianizing transformation, which is motivated by the fact that linearly mixed signals before nonlinear transformation are approximately Gaussian distributed. This heuristic, but simple and efficient procedure works as good as the ACE method. Using the framework provided by ACE, convergence can be proven. The optimal transformations obtained by ACE coincide with the sought-after inverse functions of the nonlinearitics. After equalizing the nonlinearities, temporal decorrelation separation (TDSEP) allows us to recover the source signals. Numerical simulations testing "ACE-TD" and "Gauss-TD" on realistic examples are performed with excellent results}, language = {en} } @article{ZhukGunther2004, author = {Zhuk, Alexandre and Gunther, U.}, title = {Massive scalar fields in the early universe}, issn = {0218-2718}, year = {2004}, abstract = {We discuss the role of gravitational excitons/radions in different cosmological scenarios. Gravitational excitons are massive moduli fields which describe conformal excitations of the internal spaces and which, due to their Planck-scale suppressed coupling to matter fields, are WIMPs. It is demonstrated that, depending on the concrete scenario, observational cosmological data set strong restrictions on the allowed masses and initial oscillation amplitudes of these particles}, language = {en} } @article{ZhouKurths2004, author = {Zhou, Changsong and Kurths, J{\"u}rgen}, title = {Resonant patterns in noisy active media}, issn = {1063-651X}, year = {2004}, abstract = {We investigate noise-controlled resonant response of active media to weak periodic forcing, both in excitable and oscillatory regimes. In the excitable regime, we find that noise-induced irregular wave structures can be reorganized into frequency-locked resonant patterns by weak signals with suitable frequencies. The resonance occurs due to a matching condition between the signal frequency and the noise-induced inherent time scale of the media. m:1 resonant regions similar to the Arnold tongues in frequency locking of self-sustained oscillatory media are observed. In the self-sustained oscillatory regime, noise also controls the oscillation frequency and reshapes significantly the Arnold tongues. The combination of noise and weak signal thus could provide an efficient tool to manipulate active extended systems in experiments}, language = {en} } @article{ZbilutMitchellGiulianietal.2004, author = {Zbilut, J. P. and Mitchell, J. C. and Giuliani, A. and Colosimo, A. and Marwan, Norbert and Webber, C. L.}, title = {Singular hydrophobicity patterns and net charge : a mesoscopic principle for protein aggregation/folding}, issn = {0378-4371}, year = {2004}, abstract = {A statistical model describing the propensity for protein aggregation is presented. Only amino-acid hydrophobicity values and calculated net charge are used for the model. The combined effects of hydrophobic patterns as computed by the signal analysis technique, recurrence quantification, plus calculated net charge were included in a function emphasizing the effect of singular hydrophobic patches which were found to be statistically significant for predicting aggregation propensity as quantified by fluorescence studies obtained from the literature. These results suggest preliminary evidence for a mesoscopic principle for protein folding/aggregation. (C) 2004 Elsevier B.V. All rights reserved}, language = {en} }