@phdthesis{Weikl2007,
  author    = {Weikl, Thomas R.},
  title     = {Transition states and loop-closure principles in protein folding},
  url       = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus-26975},
  school      = {Universit{\"a}t Potsdam},
  year      = {2007},
  abstract  = {Proteins are chain molecules built from amino acids. The precise sequence of the 20 different types of amino acids in a protein chain defines into which structure a protein folds, and the three-dimensional structure in turn specifies the biological function of the protein. The reliable folding of proteins is a prerequisite for their robust function. Misfolding can lead to protein aggregates that cause severe diseases, such as Alzheimer's, Parkinson's, or the variant Creutzfeldt-Jakob disease. Small single-domain proteins often fold without experimentally detectable metastable intermediate states. The folding dynamics of these proteins is thought to be governed by a single transition-state barrier between the unfolded and the folded state. The transition state is highly instable and cannot be observed directly. However, mutations in which a single amino acid of the protein is substituted by another one can provide indirect access. The mutations slightly change the transition-state barrier and, thus, the folding and unfolding times of the protein. The central question is how to reconstruct the transition state from the observed changes in folding times. In this habilitation thesis, a novel method to extract structural information on transition states from mutational data is presented. The method is based on (i) the cooperativity of structural elements such as alpha-helices and beta-hairpins, and (ii) on splitting up mutation-induced free-energy changes into components for these elements. By fitting few parameters, the method reveals the degree of structure formation of alpha-helices and beta-hairpins in the transition state. In addition, it is shown in this thesis that the folding routes of small single-domain proteins are dominated by loop-closure dependencies between the structural elements.},
  language  = {en}
}
@techreport{PetersenKirchner2008,
  type      = {Working Paper},
  author    = {Petersen, Hans-Georg and Kirchner, Markus},
  title     = {Education return and financing},
  issn      = {1864-1431},
  url       = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus-26969},
  year      = {2008},
  abstract  = {The paper sheds some light on the education returns in Germany in the post war period. After describing higher education in Germany the current stand of higher education financing within the single states is presented. In six states tuition fees will be introduced in 2007/08 and discussions are going on in even some more. In the second part of the paper an empirical analysis is done using longitudinal data from the German social pension system. The analysis over the whole lifecycle renders results which proof that the higher education advantages are quite remarkable and might be a justification for more intensified financing by tuition fees. But all this has to be embedded into an encompassing strategy of tax and social policy, especially to prevent a strengthened process of social selection, which would be counterproductive for an increased and highly qualified human capital in Germany.},
  language  = {en}
}
@phdthesis{Tirok2008,
  author    = {Tirok, Katrin},
  title     = {Predator-prey dynamics under the influence of exogenous and endogenous regulation : a data-based modeling study on spring plankton with respect to climate change},
  url       = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus-24528},
  school      = {Universit{\"a}t Potsdam},
  year      = {2008},
  abstract  = {Understanding the interactions of predators and their prey and their responses to environmental changes is one of the striking features of ecological research. In this thesis, spring dynamics of phytoplankton and its consumers, zooplankton, were considered in dependence on the environmental conditions in a deep lake (Lake Constance) and a shallow marine water (mesocosms from Kiel Bight), using descriptive statistics, multiple regression models, and process-oriented dynamic simulation models. The development of the spring phytoplankton bloom, representing a dominant feature in the plankton dynamics in temperate and cold oceans and lakes, may depend on temperature, light, and mixing intensity, and the success of over-wintering phyto- and zooplankton. These factors are often correlated in the field. Unexpectedly, irradiance often dominated algal net growth rather than vertical mixing even in deep Lake Constance. Algal net losses from the euphotic layer to larger depth were induced by vertical mixing, but were compensated by the input from larger depth when algae were uniformly distributed over the water column. Dynamics of small, fast-growing algae were well predicted by abiotic variables, such as surface irradiance, vertical mixing intensity, and temperature. A simulation model additionally revealed that even in late winter, grazing may represent an important loss factor of phytoplankton during calm periods when losses due to mixing are small. The importance of losses by mixing and grazing changed rapidly as it depended on the variable mixing intensity. Higher temperature, lower global irradiance and enhanced mixing generated lower algal biomass and primary production in the dynamic simulation model. This suggests that potential consequences of climate change may partly counteract each other. The negative effect of higher temperatures on phytoplankton biomass was due to enhanced temperature-sensitive grazing losses. Comparing the results from deep Lake Constance to those of the shallow mesocosm experiments and simulations, confirmed the strong direct effect of light in contrast to temperature, and the importance of grazing already in early spring as soon as moderate algal biomasses developed. In Lake Constance, ciliates dominated the herbivorous zooplankton in spring. The start of ciliate net growth in spring was closely linked to that of edible algae, chlorophyll a and the vertical mixing intensity but independent of water temperature. The duration of ciliate dominance in spring was largely controlled by the highly variable onset of the phytoplankton bloom, and little by the less variable termination of the ciliate bloom by grazing of meta-zooplankton. During years with an extended spring bloom of algae and ciliates, they coexisted at relatively high biomasses over 15-30 generations, and internally forced species shifts were observed in both communities. Interception feeders alternated with filter feeders, and cryptomonads with non-cryptomonads in their relative importance. These dynamics were not captured by classical 1-predator-1-prey models which consistently predict pronounced predator-prey cycles or equilibria with either the predator or the prey dominating or suppressed. A multi-species predator-prey model with predator species differing in their food selectivity, and prey species in their edibility reproduced the observed patterns. Food-selectivity and edibility were related to the feeding and growth characteristics of the species, which represented ecological trade-offs. For example, the prey species with the highest edibility also had the highest maximum growth rate. Data and model revealed endogenous driven ongoing species alternations, which yielded a higher variability in species-specific biomasses than in total predator and prey biomass. This holds for a broad parameter space as long as the species differ functionally. A more sophisticated model approach enabled the simulation of a continuum of different functional types and adaptability of predator and prey communities to altered environmental conditions, and the maintenance of a rather low model complexity, i.e., low number of equations and free parameters. The community compositions were described by mean functional traits --- prey edibility and predator food-selectivity --- and their variances. The latter represent the functional diversity of the communities and thus, the potential for adaptation. Oscillations in the mean community trait values indicated species shifts. The community traits were related to growth and grazing characteristics representing similar trade-offs as in the multi-species model. The model reproduced the observed patterns, when nonlinear relationships between edibility and capacity, and edibility and food availability for the predator were chosen. A constant minimum amount of variance represented ongoing species invasions and thus, preserved a diversity which allows adaptation on a realistic time-span.},
  language  = {en}
}
@phdthesis{Lisec2008,
  author    = {Lisec, Jan},
  title     = {Identification and characterization of metabolic Quantitative Trait Loci (QTL) in Arabidopsis thaliana},
  url       = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus-25903},
  school      = {Universit{\"a}t Potsdam},
  year      = {2008},
  abstract  = {Plants are the primary producers of biomass and thereby the basis of all life. Many varieties are cultivated, mainly to produce food, but to an increasing amount as a source of renewable energy. Because of the limited acreage available, further improvements of cultivated species both with respect to yield and composition are inevitable. One approach to further progress in developing improved plant cultivars is a systems biology oriented approach. This work aimed to investigate the primary metabolism of the model plant A.thaliana and its relation to plant growth using quantitative genetics methods. A special focus was set on the characterization of heterosis, the deviation of hybrids from their parental means for certain traits, on a metabolic level. More than 2000 samples of recombinant inbred lines (RILs) and introgression lines (ILs) developed from the two accessions Col-0 and C24 were analyzed for 181 metabolic traces using gas-chromatography/ mass-spectrometry (GC-MS). The observed variance allowed the detection of 157 metabolic quantitative trait loci (mQTL), genetic regions carrying genes, which are relevant for metabolite abundance. By analyzing several hundred test crosses of RILs and ILs it was further possible to identify 385 heterotic metabolic QTL (hmQTL). Within the scope of this work a robust method for large scale GC-MS analyses was developed. A highly significant canonical correlation between biomass and metabolic profiles (r = 0.73) was found. A comparable analysis of the results of the two independent experiments using RILs and ILs showed a large agreement. The confirmation rate for RIL QTL in ILs was 56 \% and 23 \% for mQTL and hmQTL respectively. Candidate genes from available databases could be identified for 67 \% of the mQTL. To validate some of these candidates, eight genes were re-sequenced and in total 23 polymorphisms could be found. In the hybrids, heterosis is small for most metabolites (< 20\%). Heterotic QTL gave rise to less candidate genes and a lower overlap between both populations than was determined for mQTL. This hints that regulatory loci and epistatic effects contribute to metabolite heterosis. The data described in this thesis present a rich source for further investigation and annotation of relevant genes and may pave the way towards a better understanding of plant biology on a system level.},
  language  = {en}
}
@phdthesis{Beyvers2008,
  author    = {Beyvers, Stephanie},
  title     = {Selective excitation of adsorbate vibrations on dissipative surfaces},
  url       = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus-25516},
  school      = {Universit{\"a}t Potsdam},
  year      = {2008},
  abstract  = {The selective infrared (IR) excitation of molecular vibrations is a powerful tool to control the photoreactivity prior to electronic excitation in the ultraviolet / visible (UV/Vis) light regime ("vibrationally mediated chemistry"). For adsorbates on surfaces it has been theoretically predicted that IR preexcitation will lead to higher UV/Vis photodesorption yields and larger cross sections for other photoreactions. In a recent experiment, IR-mediated desorption of molecular hydrogen from a Si(111) surface on which atomic hydrogen and deuterium were co-adsorbed was achieved, following a vibrational mechanism as indicated by the isotope-selectivity. In the present work, selective vibrational IR excitation of adsorbate molecules, treated as multi-dimensional oscillators on dissipative surfaces, has been simulated within the framework of open-system density matrix theory. Not only potential-mediated, inter-mode coupling poses an obstacle to selective excitation but also the coupling of the adsorbate ("system") modes to the electronic and phononic degrees of freedom of the surface ("bath") does. Vibrational relaxation thereby takes place, depending on the availabilty of energetically fitting electron-hole (e/h) pairs and/or phonons (lattice vibrations) in the surface, on time-scales ranging from milliseconds to several hundreds of femtoseconds. On metal surfaces, where the relaxation process of the adsorbate via the e/h pair mechanism dominates, vibrational lifetimes are usually shorter than on insulator or semiconductor surfaces, in the range of picoseconds, being also the timescale of the IR pulses used here. Further inhibiting factors for selectivity can be the harmonicity of a mode and weak dipole activities ("dark modes") rendering vibrational excitation with moderate field intensities difficult. In addition to simple analytical pulses, optimal control theory (OCT) has been employed here to generate a suitable electric field to populate the target state/mode maximally. The complex OCT fields were analyzed by Husimi transformation, resolving the control field in time and energy. The adsorbate/surface systems investigated were CO/Cu(100), H/Si(100) and 2H/Ru(0001). These systems proved to be suitable models to study the above mentioned effects. Further, effects of temperature, pure dephasing (elastic scattering processes), pulse duration and dimensionality (up to four degrees of freedom) were studied. It was possible to selectively excite single vibrational modes, often even state-selective. Special processes like hot-band excitation, vibrationally mediated desorption and the excitation of "dark modes" were simulated. Finally, a novel OCT algorithm in density matrix representation has been developed which allows for time-dependent target operators and thus enables to control the excitation mechanism instead of only the final state. The algorithm is based on a combination of global (iterative) and local (non-iterative) OCT schemes, such that short, globally controlled time-intervals are coupled locally in time. Its numerical performance and accuracy were tested and verified and it was successfully applied to stabilize a two-state linear-combination and to enforce a successive "ladder climbing" in a rather harmonic system, where monochromatic, analytical pulses simultaneously excited several states, leading to a population loss in the target state.},
  language  = {en}
}
@phdthesis{HernandezGarcia2008,
  author    = {Hernandez Garcia, Hugo Fernando},
  title     = {Multiscale simulation of heterophase polymerization : application to the synthesis of multicomponent colloidal polymer particles},
  url       = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus-25036},
  school      = {Universit{\"a}t Potsdam},
  year      = {2008},
  abstract  = {Heterophase polymerization is a technique widely used for the synthesis of high performance polymeric materials with applications including paints, inks, adhesives, synthetic rubber, biomedical applications and many others. Due to the heterogeneous nature of the process, many different relevant length and time scales can be identified. Each of these scales has a direct influence on the kinetics of polymerization and on the physicochemical and performance properties of the final product. Therefore, from the point of view of product and process design and optimization, the understanding of each of these relevant scales and their integration into one single model is a very promising route for reducing the time-to-market in the development of new products, for increasing the productivity and profitability of existing processes, and for designing products with improved performance or cost/performance ratio. The process considered is the synthesis of structured or composite polymer particles by multi-stage seeded emulsion polymerization. This type of process is used for the preparation of high performance materials where a synergistic behavior of two or more different types of polymers is obtained. Some examples include the synthesis of core-shell or multilayered particles for improved impact strength materials and for high resistance coatings and adhesives. The kinetics of the most relevant events taking place in an emulsion polymerization process has been investigated using suitable numerical simulation techniques at their corresponding time and length scales. These methods, which include Molecular Dynamics (MD) simulation, Brownian Dynamics (BD) simulation and kinetic Monte Carlo (kMC) simulation, have been found to be very powerful and highly useful for gaining a deeper insight and achieving a better understanding and a more accurate description of all phenomena involved in emulsion polymerization processes, and can be potentially extended to investigate any type of heterogeneous process. The novel approach of using these kinetic-based numerical simulation methods can be regarded as a complement to the traditional thermodynamic-based macroscopic description of emulsion polymerization. The particular events investigated include molecular diffusion, diffusion-controlled polymerization reactions, particle formation, absorption/desorption of radicals and monomer, and the colloidal aggregation of polymer particles. Using BD simulation it was possible to precisely determine the kinetics of absorption/desorption of molecular species by polymer particles, and to simulate the colloidal aggregation of polymer particles. For diluted systems, a very good agreement between BD simulation and the classical theory developed by Smoluchowski was obtained. However, for concentrated systems, significant deviations from the ideal behavior predicted by Smoluchowski were evidenced. BD simulation was found to be a very valuable tool for the investigation of emulsion polymerization processes especially when the spatial and geometrical complexity of the system cannot be neglected, as is the case of concentrated dispersions, non-spherical particles, structured polymer particles, particles with non-uniform monomer concentration, and so on. In addition, BD simulation was used to describe non-equilibrium monomer swelling kinetics, which is not possible using the traditional thermodynamic approach because it is only valid for systems at equilibrium. The description of diffusion-controlled polymerization reactions was successfully achieved using a new stochastic algorithm for the kMC simulation of imperfectly mixed systems (SSA-IM). In contrast to the traditional stochastic simulation algorithm (SSA) and the deterministic rate of reaction equations, instead of assuming perfect mixing in the whole reactor, the new SSA-IM determines the volume perfectly mixed between two consecutive reactions as a function of the diffusion coefficient of the reacting species. Using this approach it was possible to describe, using a single set of kinetic parameters, typical mass transfer limitations effects during a free radical batch polymerization such as the cage effect, the gel effect and the glass effect. Using multiscale integration it was possible to investigate the formation of secondary particles during the seeded emulsion polymerization of vinyl acetate over a polystyrene seed. Three different cases of radical generation were considered: generation of radicals by thermal decomposition of water-soluble initiating compounds, generation of radicals by a redox reaction at the surface of the particles, and generation of radicals by thermal decomposition of surface-active initiators "inisurfs" attached to the surface of the particles. The simulation results demonstrated the satisfactory reduction in secondary particles formation achieved when the locus of radical generation is controlled close to the particles surface.},
  language  = {en}
}
@phdthesis{Doyle2007,
  author    = {Doyle, Timothy F.},
  title     = {The role of context in meaning and understanding},
  url       = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus-20691},
  school      = {Universit{\"a}t Potsdam},
  year      = {2007},
  abstract  = {In this work the concept of 'context' is considered in five main points. First, context is seen as always necessary for an adequate explication of the concepts of meaning and understanding. Context always plays a role and is not merely brought into consideration when handling a special class of statements or terms, or when there is doubt and clarification is necessary. Second, context cannot be completely reduced to some system of representation. The reason for this is the presence of humans, which is always an important component of a context. Humans experience situations in ways that are not always reducible to symbolic representation. Third, contexts are in principle open. In normal cases they cannot be determined or described in advance. A context is not to be equated with a set of information. Fourth, we understand the parameters of a context pragmatically, which is why we are not led into doubt or even to meaning skepticism by the open nature of a context. This pragmatic knowledge belongs to the category of an ability. Fifth, contexts are, in principle, accessible. This denies the idea that some contexts are incommensurable. There are a number of pragmatic ways of accessing unfamiliar contexts. Some of these are here examined in light of the so-called 'culture wars' in the U.S.A.},
  language  = {en}
}
@phdthesis{Ide2008,
  author    = {Ide, Andreas Hans Peter},
  title     = {Self-Structuring of functionalized micro- and mesoporous organosilicas using boron-silane-precursors},
  url       = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus-23717},
  school      = {Universit{\"a}t Potsdam},
  year      = {2008},
  abstract  = {The structuring of porous silica materials at the nanometer scale and their surface functionalization are important issues of current materials research. Many innovations in chromatography, catalysis and electronic devices benefit from this knowledge. The work at hand is dedicated to the targeted design of functional organosilica materials. In this context a new precursor concept based on boron-silanes is presented. These precursors combine the properties of a structure directing group and a silica source by covalent borane linkage. Formation of the precursor is easily realized by a sequential two-step hydroboration, firstly on bis(triethoxysilyl)ethene, and secondly on an unsaturated structure directing moiety such as alkenes or polymers. The so prepared precursors self-organize when hydrolysis of their inorganic moiety takes place via an aggregation of their organic side chains into hydrophobic domains. In this way, the additional use of a surfactant as a template is not necessary. Chemical cleavage of these moieties (e.g. by ammonolysis or oxidative saponification) yields an organosilica where all functionalities are exclusively located at the pore wall and therefore accessible. The accessibility of the functionalities is a vital point for applications and is not necessarily granted for common silica functionalization approaches. Further advantages of the boron-silane concept are the possibility to introduce a variety of surface functionalities by heterolytic cleavage of the boron linker and the control of the pore morphology. For that purpose the covalent linkage of different alkyl groups and polymers was studied. Another aspect is the access to chiral boron silane precursors yielding functionalized mesoporous organosilica with chiral functionalities exclusively located at the pore walls after condensation and removal of the structure directing moiety. These materials possess great potential for applications documented by preliminary investigations on chiral resolution of a racemic mixture by HPLC and asymmetric catalysis. In the course of this work valuable insights into the targeted structuring and surface functionalization of organosilicas were gained. A promising outlook for further investigations is the extension of this concept by altering the structure directing moieties of the precursor. That way the morphology of the final organosilica might be controlled by for example mesogens. Furthermore, the use of the boron linker enables the introduction of multiple functionalities into organosilicas, making the obtained material unique in its performance.},
  language  = {en}
}
@phdthesis{Bahrke2008,
  author    = {Bahrke, Sven},
  title     = {Mass spectrometric analysis of chitooligosaccharides and their interaction with proteins},
  url       = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus-20179},
  school      = {Universit{\"a}t Potsdam},
  year      = {2008},
  abstract  = {Chitooligosaccharides are composed of glycosamin and N-acetylglycisamin residues. Gel permeations chromatography is employed for the separation of oligomers, cation exchange chromatography is used for the separation of homologes and isomers. Trideuterioacetylation of the chitooligosaccharides followed by MALDI-TOF mass spectrometry allowes for the quantitation of mixtures of homologes. vMALDI LTQ multiple-stage MS is employed for quantitative sequencing of complex mixtures of heterochitooligosaccharides. Pure homologes and isomers are applied to biological assays. Chitooligosaccahrides form high-affinity non-covalent complexes with HC gp-39 (human cartilage glycoprotein of 39 kDa). The affinity of the chitooligosaccharides depends on DP, FA and the sequence of glycosamin and N-acetylglycosamin moieties. (+)nanoESI Q TOF MS/MS is used for identification of a high-affinity binding chitooligosaccharide of a non-covalent chitinase B - chitooligosaccharide complex. DADAA is identified as the heterochitoisomer binding with highest affinity and biostability to HC gp-39. Fluorescence based enzyme assays confirm the results.},
  language  = {en}
}
@phdthesis{Wrzus2008,
  author    = {Wrzus, Cornelia},
  title     = {Similarity in personal relationships : associations with relationship regulation between and within individuals},
  url       = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus-20158},
  school      = {Universit{\"a}t Potsdam},
  year      = {2008},
  abstract  = {People engage in a multitude of different relationships. Relatives, spouses, and friends are modestly to moderately similar in various characteristics, e.g., personality characteristics, interests, appearance. The role of psychological (e.g., skills, global appraisal) and social (e.g., gender, familial status) similarities in personal relationships and the association with relationship quality (emotional closeness and reciprocity of support) were examined in four independent studies. Young adults (N = 456; M = 27 years) and middle-aged couples from four different family types (N = 171 couples, M = 38 years) gave answer to a computer-aided questionnaire regarding their ego-centered networks. A subsample of 175 middle-aged adults (77 couples and 21 individuals) participated in a one-year follow-up questioning. Two experimental studies (N = 470; N = 802), both including two assessments with an interval of five weeks, were conducted to examine causal relationships among similarity, closeness, and reciprocity expectations. Results underline the role of psychological and social similarities as covariates of emotional closeness and reciprocity of support on the between-relationship level, but indicate a relatively weak effect within established relationships. In specific relationships, such as parent-child relationships and friendships, psychological similarity partly alleviates the effects of missing genetic relatedness. Individual differences moderate these between-relationship effects. In all, results combine evolutionary and social psychological perspectives on similarity in personal relationships and extend previous findings by means of a network approach and an experimental manipulation of existing relationships. The findings further show that psychological and social similarity have different implications for the study of personal relationships depending on the phase in the developmental process of relationships.},
  language  = {en}
}
@misc{Meyer2007,
  type      = {Master Thesis},
  author    = {Meyer, Eike},
  title     = {Democracy promotion by the European Union in Morocco within the framework of the European Neighbourhood Policy},
  url       = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus-19591},
  school      = {Universit{\"a}t Potsdam},
  year      = {2007},
  abstract  = {The intention of this master-thesis is a critical assessment of the European Union´s (EU) approach to external democracy promotion in Morocco. The study follows a comparative approach and compares the approach pursued by the EU within the framework of the European Neighbourhood Policy (ENP), incepted in 2004, with the approach that it had developed up until then under the framework of the Euro-Mediterranean Partnership (EMP). The comparison is done with the intention to analyse, to what degree it is justified to speak of a new impetus for democratisation through the ENP in partner countries. The analysis takes into consideration the range of possible instruments for external democracy promotion in the categories „diplomacy", „conditionality" and „positive instruments". For the comparison of democracy promotion under the EMP and the ENP it is suggested to compare the implemented measures in respect to three distinct dimensions: As a first dimension, instruments of democracy promotion are analysed with respect to the focus on indirect vs. direct instruments, e.g. those which aim at establishing socio-economic preconditions favourable to successful democratisation, vs. those which immediately intervene in the processes of political reform. As a second dimension, it is asked whether there has been a shift in the democracy promotion approach on a continuum between consensual cooptation and coercive intervention. As a third dimension, finally, it is analysed whether the approach has undergone a general intensification of efforts, e.g. whether the approach to democracy promotion has become a more active one. The analysis in this master-thesis comes to the conclusion that since the inception of the ENP the EU is indeed pursuing a slightly more direct and certainly a more active approach to democracy promotion in Morocco, while no significant change can be observed in comparison to the strictly partnership-oriented and consensual approach of the EMP. It can be argued that, under the ENP, relations to Morocco have indeed become somewhat more "political", although at the same time they are still not pro-actively oriented at a political liberalisation of the political regime. Reforms promoted by the EU in Morocco are modest and largely in line with the reform agenda of the Morrocan government itself - e.g. a still largely authoritarian monarchy. Concrete reform steps directed at an opening of the political space, which is largely reserved to the king and its administration, are neither demanded nor supported by democracy promotion instruments, also under the ENP.},
  language  = {en}
}
@phdthesis{Muschalla2008,
  author    = {Muschalla, Beate},
  title     = {Workplace-related anxieties and workplace phobia : a concept of domain-specific mental disorders},
  url       = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus-20048},
  school      = {Universit{\"a}t Potsdam},
  year      = {2008},
  abstract  = {Background: Anxiety in the workplace is a special problem as workplaces are especially prone to provoke anxiety: There are social hierarchies, rivalries between colleagues, sanctioning through superiors, danger of accidents, failure, and worries of job security. Workplace phobia is a phobic anxiety reaction with symptoms of panic occurring when thinking of or approaching the workplace, and with clear tendency of avoidance. Objectives: What characterizes workplace-related anxieties and workplace phobia as domain-specific mental disorders in contrast to conventional anxiety disorders? Method: 230 patients from an inpatient psychosomatic rehabilitation center were interviewed with the (semi-)structured Mini-Work-Anxiety-Interview and the Mini International Neuropsychiatric Interview, concerning workplace-related anxieties and conventional mental disorders. Additionally, the patients filled in the self-rating questionnaires Job-Anxiety-Scale (JAS) and the Symptom Checklist (SCL-90-R)measuring job-related and general psychosomatic symptom load. Results: Workplace-related anxieties occurred together with conventional anxiety disorders in 35\% of the patients, but also alone in others (23\%). Workplace phobia could be found in 17\% of the interviewed, any diagnosis of workplace-related anxiety was stated in 58\%. Workplace phobic patients had significantly higher scores in job-anxiety than patients without workplace phobia. Patients with workplace phobia were significantly longer on sick leave in the past 12 months (23,5 weeks) than patients without workplace phobia (13,4 weeks). Different qualities of workplace-related anxieties lead with different frequencies to work participation disorders. Conclusion: Workplace phobia cannot be described by only assessing the general level of psychosomatic symptom load and conventional mental disorders. Workplace-related anxieties and workplace phobia have an own clinical value which is mainly defined by specific workplace-related symptom load and work-participation disorders. They require special therapeutic attention and treatment instead of a "sick leave" certification by the general health physician. Workplace phobia should be named with a proper diagnosis according to ICD-10 chapter V, F 40.8: "workplace phobia".},
  language  = {en}
}
@misc{Trapp2007,
  type      = {Master Thesis},
  author    = {Trapp, Matthias},
  title     = {Analysis and exploration of virtual 3D city models using 3D information lenses},
  url       = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus-13930},
  school      = {Universit{\"a}t Potsdam},
  year      = {2007},
  abstract  = {This thesis addresses real-time rendering techniques for 3D information lenses based on the focus \& context metaphor. It analyzes, conceives, implements, and reviews its applicability to objects and structures of virtual 3D city models. In contrast to digital terrain models, the application of focus \& context visualization to virtual 3D city models is barely researched. However, the purposeful visualization of contextual data of is extreme importance for the interactive exploration and analysis of this field. Programmable hardware enables the implementation of new lens techniques, that allow the augmentation of the perceptive and cognitive quality of the visualization compared to classical perspective projections. A set of 3D information lenses is integrated into a 3D scene-graph system: • Occlusion lenses modify the appearance of virtual 3D city model objects to resolve their occlusion and consequently facilitate the navigation. • Best-view lenses display city model objects in a priority-based manner and mediate their meta information. Thus, they support exploration and navigation of virtual 3D city models. • Color and deformation lenses modify the appearance and geometry of 3D city models to facilitate their perception. The presented techniques for 3D information lenses and their application to virtual 3D city models clarify their potential for interactive visualization and form a base for further development.},
  language  = {en}
}
@phdthesis{Gebauer2008,
  author    = {Gebauer, Denis},
  title     = {A novel view on the early stage of crystallization},
  url       = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus-19818},
  school      = {Universit{\"a}t Potsdam},
  year      = {2008},
  abstract  = {This thesis provides a novel view on the early stage of crystallization utilizing calcium carbonate as a model system. Calcium carbonate is of great economical, scientific and ecological importance, because it is a major part of water hardness, the most abundant Biomineral and forms huge amounts of geological sediments thus binding large amounts of carbon dioxide. The primary experiments base on the evolution of supersaturation via slow addition of dilute calcium chloride solution into dilute carbonate buffer. The time-dependent measurement of the Ca2+ potential and concurrent pH = constant titration facilitate the calculation of the amount of calcium and carbonate ions bound in pre-nucleation stage clusters, which have never been detected experimentally so far, and in the new phase after nucleation, respectively. Analytical Ultracentrifugation independently proves the existence of pre-nucleation stage clusters, and shows that the clusters forming at pH = 9.00 have a proximately time-averaged size of altogether 70 calcium and carbonate ions. Both experiments show that pre-nucleation stage cluster formation can be described by means of equilibrium thermodynamics. Effectively, the cluster formation equilibrium is physico-chemically characterized by means of a multiple-binding equilibrium of calcium ions to a 'lattice' of carbonate ions. The evaluation gives GIBBS standard energy for the formation of calcium/carbonate ion pairs in clusters, which exhibits a maximal value of approximately 17.2 kJ mol^-1 at pH = 9.75 and relates to a minimal binding strength in clusters at this pH-value. Nucleated calcium carbonate particles are amorphous at first and subsequently become crystalline. At high binding strength in clusters, only calcite (the thermodynamically stable polymorph) is finally obtained, while with decreasing binding strength in clusters, vaterite (the thermodynamically least stable polymorph) and presumably aragonite (the thermodynamically intermediate stable polymorph) are obtained additionally. Concurrently, two different solubility products of nucleated amorphous calcium carbonate (ACC) are detected at low binding strength and high binding strength in clusters (ACC I 3.1EE-8 M^2, ACC II 3.8EE-8 M^2), respectively, indicating the precipitation of at least two different ACC species, while the clusters provide the precursor species of ACC. It is proximate that ACC I may relate to calcitic ACC -i.e. ACC exhibiting short range order similar to the long range order of calcite and that ACC II may relate to vateritic ACC, which will subsequently transform into the particular crystalline polymorph as discussed in the literature, respectively. Detailed analysis of nucleated particles forming at minimal binding strength in clusters (pH = 9.75) by means of SEM, TEM, WAXS and light microscopy shows that predominantly vaterite with traces of calcite forms. The crystalline particles of early stages are composed of nano-crystallites of approximately 5 to 10 nm size, respectively, which are aligned in high mutual order as in mesocrystals. The analyses of precipitation at pH = 9.75 in presence of additives -polyacrylic acid (pAA) as a model compound for scale inhibitors and peptides exhibiting calcium carbonate binding affinity as model compounds for crystal modifiers- shows that ACC I and ACC II are precipitated in parallel: pAA stabilizes ACC II particles against crystallization leading to their dissolution for the benefit of crystals that form from ACC I and exclusively calcite is finally obtained. Concurrently, the peptide additives analogously inhibit the formation of calcite and exclusively vaterite is finally obtained in case of one of the peptide additives. These findings show that classical nucleation theory is hardly applicable for the nucleation of calcium carbonate. The metastable system is stabilized remarkably due to cluster formation, while clusters forming by means of equilibrium thermodynamics are the nucleation relevant species and not ions. Most likely, the concept of cluster formation is a common phenomenon occurring during the precipitation of hardly soluble compounds as qualitatively shown for calcium oxalate and calcium phosphate. This finding is important for the fundamental understanding of crystallization and nucleation-inhibition and modification by additives with impact on materials of huge scientific and industrial importance as well as for better understanding of the mass transport in crystallization. It can provide a novel basis for simulation and modelling approaches. New mechanisms of scale formation in Bio- and Geomineralization and also in scale inhibition on the basis of the newly reported reaction channel need to be considered.},
  language  = {en}
}
@phdthesis{Fischer2008,
  author    = {Fischer, Anna},
  title     = {"Reactive hard templating" : from carbon nitrides to metal nitrides},
  url       = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus-19777},
  school      = {Universit{\"a}t Potsdam},
  year      = {2008},
  abstract  = {Nanostructured inorganic materials are routinely synthesized by the use of templates. Depending on the synthesis conditions of the product material, either "soft" or "hard" templates can be applied. For sol-gel processes, usually "soft" templating techniques are employed, while "hard" templates are used for high temperature synthesis pathways. In classical templating approaches, the template has the unique role of structure directing agent, in the sense that it is not participating to the chemical formation of the resulting material. This work investigates a new templating pathway to nanostructured materials, where the template is also a reagent in the formation of the final material. This concept is described as "reactive templating" and opens a synthetic path toward materials which cannot be synthesised on a nanometre scale by classical templating approaches. Metal nitrides are such kind of materials. They are usually produced by the conversion of metals or metal oxides in ammonia flow at high temperature (T > 1000°C), which make the application of classical templating techniques difficult. Graphitic carbon nitride, g-C3N4, despite its fundamental and theoretical importance, is probably one of the most promising materials to complement carbon in material science and many efforts are put in the synthesis of this material. A simple polyaddition/elimination reaction path at high temperature (T = 550°C) allows the polymerisation of cyanamide toward graphitic carbon nitride solids. By hard templating, using nanostructured silica or aluminium oxide as nanotemplates, a variety of nanostructured graphitic carbon nitrides such as nanorods, nanotubes, meso- and macroporous powders could be obtained by nanocasting or nanocoating. Due to the special semi-conducting properties of the graphitic carbon nitride matrix, the nanostructured graphitic carbon nitrides show unexpected catalytic activity for the activation of benzene in Friedel-Crafts type reactions, making this material an interesting metal free catalyst. Furthermore, due to the chemical composition of g-C3N4 and the fact that it is totally decomposed at temperatures between 600°C and 800°C even under inert atmosphere, g-C3N4 was shown to be a good nitrogen donor for the synthesis of early transition metal nitrides at high temperatures. Thus using the nanostructured carbon nitrides as "reactive templates" or "nanoreactors", various metal nitride nanostructures, such as nanoparticles and porous frameworks could be obtained at high temperature. In this approach the carbon nitride nanostructure played both the role of the nitrogen source and of the exotemplate, imprinting its size and shape to the resulting metal nitride nanostructure.},
  language  = {en}
}
@phdthesis{Imranulhaq2008,
  author    = {Imran ul-haq, Muhammad},
  title     = {Synthesis of fluorinated polymers in supercritical carbon dioxide (scCO₂)},
  url       = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus-19868},
  school      = {Universit{\"a}t Potsdam},
  year      = {2008},
  abstract  = {For the first time stabilizer-free vinylidene fluoride (VDF) polymerizations were carried out in homogeneous phase with supercritical CO₂. Polymerizations were carried out at 140°C, 1500 bar and were initiated with di-tert-butyl peroxide (DTBP). In-line FT-NIR (Fourier Transform- Near Infrared) spectroscopy showed that complete monomer conversion may be obtained. Molecular weights were determined via size-exclusion chromatography (SEC) and polymer end group analysis by 1H-NMR spectroscopy. The number average molecular weights were below 104 g∙mol-1 and polydispersities ranged from 3.1 to 5.7 depending on DTBP and VDF concentration. To allow for isothermal reactions high CO₂ contents ranging from 61 to 83 wt.\% were used. The high-temperature, high-pressure conditions were required for homogeneous phase polymerization. These conditions did not alter the amount of defects in VDF chaining. Scanning electron microscopy (SEM) indicated that regular stack-type particles were obtained upon expansion of the homogeneous polymerization mixture. To reduce the required amount of initiator, further VDF polymerizations using chain transfer agents (CTAs) to control molecular weights were carried out in homogeneous phase with supercritical carbon dioxide (scCO₂) at 120 °C and 1500 bar. Using perfluorinated hexyl iodide as CTA, polymers of low polydispersity ranging from 1.5 to 1.2 at the highest iodide concentration of 0.25 mol·L-1 were obtained. Electrospray ionization- mass spectroscopy (ESI-MS) indicates the absence of initiator derived end groups, supporting livingness of the system. The "livingness" is based on the labile C-I bond. However, due to the weakness of the C-I bond perfluorinated hexyl iodide also contributes to initiation. To allow for kinetic analyses of VDF polymerizations the CTA should not contribute to initiation. Therefore, additional CTAs were applied: BrCCl3, C6F13Br and C6F13H. It was found that C6F13H does not contribute to initiation. At 120°C and 1500 bar kp/kt0.5~ 0.64 (L·mol-1·s-1)0.5 was derived. The chain transfer constant (CT) at 120°C has been determined to be 8·10-1, 9·10-2 and 2·10-4 for C6F13I, C6F13Br and C6F13H, respectively. These CT values are associated with the bond energy of the C-X bond. Moreover, the labile C-I bond allows for functionalization of the polymer to triazole end groups applying click reactions. After substitution of the iodide end group by an azide group 1,3 dipolar cycloadditions with alkynes yield polymers with 1,2,3 triazole end groups. Using symmetrical alkynes the reactions may be carried out in the absence of any catalyst. This end-functionalized poly (vinylidene fluoride) (PVDF) has higher thermal stability as compared to the normal PVDF. PVDF samples from homogeneous phase polymerizations in supercritical CO₂ and subsequent expansion to ambient conditions were analyzed with respect to polymer end groups, crystallinity, type of polymorphs and morphology. Upon expansion the polymer was obtained as white powder. Scanning electron microscopy (SEM) showed that DTBP derived polymer end groups led to stack-type particles whereas sponge- or rose-type particles were obtained in case of CTA fragments as end groups. Fourier-Transform Infrared spectroscopy and wide angle X-ray diffraction indicated that the type of polymorph, α or β crystal phase was significantly affected by the type of end group. The content of β-phase material, which is responsible for piezoelectricity of PVDF, is the highest for polymer with DTBP-derived end groups. In addition, the crystallinity of the material, as determined via differential scanning calorimetry is affected by the end groups and polymer molecular weights. For example, crystallinity ranges from around 26 \% for DTBP-derived end groups to a maximum of 62 \% for end groups originating from perfluorinated hexyl iodide for polymers with Mn ~2200 g·mol-1. Expansion of the homogeneous polymerization mixture results in particle formation by a non-optimized RESS (Rapid Expansion from Supercritical Solution) process. Thus, it was tested how polymer end groups affect the particles size distribution obtained from RESS process under controlled conditions (T = 50°C and P = 200 bar). In all RESS experiments, small primary PVDF with diameters less than 100 nm without the use of liquid solvents, surfactants, or other additives were produced. A strong correlation between particle size and particle size distribution with polymer end groups and molecular weight of the original material was observed. The smallest particles were found for RESS of PVDF with Mn~ 4000 g·mol-1 and PFHI (C6F13I) - derived end groups.},
  language  = {en}
}
@phdthesis{Rehak2008,
  author    = {Rehak, Katrin},
  title     = {Pliocene-Pleistocene landscape evolution in south-central Chile : interactions between tectonic, geomorphic, and climatic processes},
  url       = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus-19793},
  school      = {Universit{\"a}t Potsdam},
  year      = {2008},
  abstract  = {Landscapes evolve in a complex interplay between climate and tectonics. Thus, the geomorphic characteristics of a landscape can only be understood if both, climatic and tectonic signals of past and ongoing processes can be identified. In order to evaluate the impact of both forcing factors it is crucial to quantify the evolution of geomorphic markers in natural environments. The Cenozoic Andes are an ideal setting to evaluate tectonic and climatic aspects of landscape evolution at different time and length scales in different natural compartments. The Andean Cordillera constitutes the type subduction orogen and is associated with the subduction of the oceanic Nazca Plate beneath the South American continent since at least 200 million years. In Chile and the adjacent regions this convergent margin is characterized by active tectonics, volcanism, and mountain building. Importantly, along the coast of Chile megathrust earthquakes occur frequently and influence landscape evolution. In fact, the largest earthquake ever recorded occurred in south-central Chile in 1960 and comprised a rupture zone of ~ 1000 km length. However, on longer time scales beyond historic documentation of seismicity it is not well known, how such seismotectonic segments have behaved and how they influence the geomorphic evolution of the coastal realms. With several semi-independent morphotectonic segments, recurrent megathrust earthquakes, and a plethora of geomorphic features indicating sustained tectonism, the margin of Chile is thus a key area to study relationships between surface processes and tectonics. In this study, I combined geomorphology, geochronology, sedimentology, and morphometry to quantify the Pliocene-Pleistocene landscape evolution of the tectonically active south-central Chile forearc. Thereby, I provide (1) new results about the influence of seismotectonic forearc segmentation on the geomorphic evolution and (2) new insights in the interaction between climate and tectonics with respect to the morphology of the Chilean forearc region. In particular, I show that the forearc is characterized by three long-term segments that are not correlated with short-lived earthquake-rupture zones that may. These segments are the Nahuelbuta, Tolt{\´e}n, and Bueno segments, each recording a distinct geomorphic and tectonic evolution. The Nahuelbuta and Bueno segments are undergoing active tectonic uplift. The long-term behavior of these two segments is manifested in form of two doubly plunging, growing antiforms that constitute an integral part of the Coastal Cordillera and record the uplift of marine and river terraces. In addition, these uplifting areas have caused major changes in flow directions or rivers. In contrast, the Tolt{\´e}n segment, situated between the two other segments, appears to be quasi-stable. In order to further quantify uplift and incision in the actively deforming Nahuelbuta segment, I dated an erosion surface and fluvial terraces in the Coastal Cordillera with cosmogenic 10Be and 26Al and optically stimulated luminescence, respectively. According to my results, late Pleistocene uplift rates corresponding to 0.88 mm a-1 are faster than surface-uplift rates averaging over the last 5 Ma, which are in the range of 0.21 mm a-1. This discrepancy suggests that surface uplift is highly variable in time and space and might preferably concentrate along reverse faults as indicated by a late Pleistocene flow reversal. In addition, the results of exposure dating with cosmogenic 10Be and 26Al indicate that the morphotectonic segmentation of this region of the forearc has been established in Pliocene time, coeval with the initiation of uplift of the Coastal Cordillera about 5 Ma ago, inferred to be related to a shift in subduction mode from erosion to accretion. Finally, I dated volcanic clasts obtained from alluvial surfaces in the Central Depression, a low-relief sector separating the Coastal from the Main Cordillera, with stable cosmogenic 3He and 21Ne, in order to reveal the controls of sediment accumulation in the forearc. My results document that these gently sloping surfaces have been deposited 150 to 300 ka ago. This deposition may be related to changes in the erosional regime during glacial episodes. Taken together, the data indicates that the overall geomorphic expression of the forearc is of post-Miocene age and may be intimately related to a climatic overprint of the tectonic system. This climatic forcing is also reflected in the topography and local relief of the Central and Southern Andes that vary considerably along the margin, determined by the dominant surface process that in turn is eventually controlled by climate. However, relief also partly reflects surface processes that have taken place under past climatic conditions. This emphasizes that due care has to be exercised when interpreting landscapes as mirrors of modern climates.},
  language  = {en}
}
@misc{Paun2007,
  type      = {Master Thesis},
  author    = {Paun, Christopher},
  title     = {Democratization and police reform},
  url       = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus-19487},
  school      = {Universit{\"a}t Potsdam},
  year      = {2007},
  abstract  = {This paper compares police reforms during democratization in Poland, Hungary, and Bosnia-Herzegovina. It analyses the changes to the structure of the democratic control of the police in each reform, paying special attention to the decentralization versus centralization aspect of it. The research question of this paper is: Why are some states decentralizing the democratic control of the police, while others are centralizing it, both with the aim of democratization? The theoretical background of this study are theories about policy diffusion and policy transfer. Therefore this study can be categorized as part of two different research areas. On the one hand, it is a paper from the discipline of International Relations. On the other hand, it is a paper from the discipline of Comparative Politics. The combined attention to international and national factors influencing police reform is reflected by the structure of this paper. Chapter 3 examines police structures and police reforms in established democracies as possible role models for new democracies. Chapter 4 looks at international and transnational actors that actively try to influence police reform. After having examined these external factors, three cases of police reform in new democracies are examined in chapter 5.},
  language  = {en}
}
@phdthesis{Lantuit2008,
  author    = {Lantuit, Hugues},
  title     = {The modification of arctic permafrost coastlines},
  url       = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus-19732},
  school      = {Universit{\"a}t Potsdam},
  year      = {2008},
  abstract  = {The arctic region is undergoing the most rapid environmental change experienced on Earth, and the rate of change is expected to increase over the coming decades. Arctic coasts are particularly vulnerable because they lie at the interface between terrestrial systems dominated by permafrost and marine systems dominated by sea ice. An increased rise in sea level and degradation of sea-ice as predicted by the Intergovernmental Panel on Climate Change in its most recent report and as observed recently in the Arctic will likely result in greater rates of coastal retreat. An increase in coastal erosion would result in dramatic increases in the volume of sediment, organic carbon and contaminants to the Arctic Ocean. These in turn have the potential to create dramatic changes in the geochemistry and biodiversity of the nearshore zone and affect the Arctic Ocean carbon cycle. To calculate estimates of organic carbon input from coastal erosion to the Arctic Ocean, current methods rely on the length of the coastline in the form of non self-similar line datasets. This thesis however emphasizes that using shorelines drawn at different scales can induce changes in the amount of sediment released by 30\% in some cases. It proposes a substitute method of computations of erosion based on areas instead of lengths (i.e. buffers instead of shoreline lengths) which can be easily implemented at the circum-Arctic scale. Using this method, variations in quantities of eroded sediment are, on average, 70\% less affected by scale changes and are therefore a more reliable method of calculation. Current estimates of coastal erosion rates in the Arctic are scarce and long-term datasets are a handful, which complicates assessment and prognosis of coastal processes, in particular the occurrence of coastal hazards. This thesis aims at filling the gap by providing the first long-term dataset (1951-2006) of coastal erosion on the Bykovsky Peninsula, North-East Siberia. This study shows that the coastline, which is made of ice-rich permafrost, retreated at a mean annual rate of 0.59 m/yr between 1951and 2006. Rates were highly variable: 97.0 \% of the rates observed were less than 2 m/yr and 81.6\% were less than 1m/yr. However, no significant trend in erosion could be recorded despite the study of five temporal subperiods within 1951-2006. The juxtaposition of wind records could not help to explain erosion records either and this thesis emphasizes the local controls on erosion, in particular the cryostratigraphy, the proximity of the Peninsula to the Lena River Delta freshwater plume and the local topographical constraints on swell development. On ice-rich coastal stretches of the Artic, the interaction of coastal dynamics and permafrost leads to the occurrence of spectacular "C-shaped" depressions termed retrogressive thaw slumps which can reach lengths of up to 650 m. On Herschel Island and at King Point (Yukon Coastal Plain, northern Canada), topographical, sedimentological and biogeochemical surveys were conducted to investigate the present and past activity of these landforms. In particular, undisturbed tundra areas were compared with zones of former slump activity, now stabilized and re-vegetated. This thesis shows that stabilized areas are drier and less prone to plant growth than undisturbed areas and feature fundamentally different geotechnical properties. Radiocarbon dating and topographical surveys indicated until up to 300 BP a likely period of dramatic slump activity on Herschel Island, similar to the one currently observed, which led to the creation of these surfaces. This thesis hypothesizes the occurrence of a ~250 years cycle of slump activity on the Herschel Island shoreline based on the surveyed topography and cryostratigraphy and anticipates higher frequency of slump activity in the future. The variety of processes described in this thesis highlights the changing nature of the intensity and frequency of physical processes acting upon the arctic coast. It also challenges current perceptions of the threats to existing industry and community infrastructure in the Arctic. The increasing presence of humans on Artic coasts coupled with the expected development of shipping will drive an increase in economical and industrial activity on these coasts which remains to be addressed scientifically.},
  language  = {en}
}
@article{Fanselow2007,
  author    = {Fanselow, Gisbert},
  title     = {The restricted access of information structure to syntax},
  url       = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus-19713},
  year      = {2007},
  abstract  = {This paper sketches the view that syntax does not directly interact with information structure. Therefore, syntactic data are of little help when one wants to narrow down the interpretation of terms such as "focus", "topic", etc.},
  language  = {en}
}
@article{Fery2007,
  author    = {F{\´e}ry, Caroline},
  title     = {Information structural notions and the fallacy of invariant correlates},
  url       = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus-19692},
  year      = {2007},
  abstract  = {In a first step, definitions of the irreducible information structural categories are given, and in a second step, it is shown that there are no invariant phonological or otherwise grammatical correlates of these categories. In other words, the phonology, syntax or morphology are unable to define information structure. It is a common mistake that information structural categories are expressed by invariant grammatical correlates, be they syntactic, morphological or phonological. It is rather the case that grammatical cues help speaker and hearer to sort out which element carries which information structural role, and only in this sense are the grammatical correlates of information structure important. Languages display variation as to the role of grammar in enhancing categories of information structure, and this variation reflects the variation found in the 'normal' syntax and phonology of languages.},
  language  = {en}
}
@article{EndrissHinterwimmer2007,
  author    = {Endriss, Cornelia and Hinterwimmer, Stefan},
  title     = {Direct and indirect aboutness topics},
  url       = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus-19640},
  year      = {2007},
  abstract  = {We propose a definition of aboutness topicality that not only encompasses individual denoting DPs, but also indefinites. We concentrate on the interpretative effects of marking indefinites as topics: they either receive widest scope in their clause, or they are interpreted in the restrictor of an overt or covert Q-adverb. We show that in the first case they are direct aboutness topics insofar as they are the subject of a predication expressed by the comment, while in the second case they are indirect aboutness topics: they define the subject of a higher-order predication - namely the set of situations that the respective Q-adverb quantifies over.},
  language  = {en}
}
@article{Kasimir2006,
  author    = {Kasimir, Elke},
  title     = {On 'nicht...sondern...' (contrastive 'not...but...')},
  url       = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus-19537},
  year      = {2006},
  abstract  = {This article presents an analysis of German nicht...sondern... (contrastive not...but...) which departs from the commonly held view that this construction should be explained by appeal to its alleged corrective function. It will be demonstrated that in nicht A sondern B (not A but B), A and B just behave like stand-alone unmarked answers to a common question Q, and that this property of sondern is presuppositional in character. It is shown that from this general observation many interesting properties of nicht...sondern... follow, among them distributional differences between German 'sondern' and German 'aber' (contrastive but, concessive but), intonational requirements and exhaustivity effects. sondern's presupposition is furthermore argued to be the result of the conventionalization of conversational implicatures.},
  language  = {en}
}
@article{vandeVijverSennemaZimmer–Stahl2006,
  author    = {van de Vijver, Ruben and Sennema, Anke and Zimmer-Stahl, Anne},
  title     = {An analysis of pitch and duration in material used to test L2 processing of words},
  url       = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus-19583},
  year      = {2006},
  abstract  = {The material reported on in this paper is part of a set of experiments in which the role of Information Structure on L2 processing of words is tested. Pitch and duration of 4 sets of experimental material in German and English are measured and analyzed in this paper. The well-known finding that accent boosts duration and pitch is confirmed. Syntactic and lexical means of marking focus, however, do not give the duration and the pitch of a word an extra boost.},
  language  = {en}
}
@article{SchmitzHoehleMuelleretal.2006,
  author    = {Schmitz, Michaela and H{\"o}hle, Barbara and M{\"u}ller, Anja and Weissenborn, J{\"u}rgen},
  title     = {The recognition of the prosodic focus position in German-learning infants from 4 to 14 months},
  url       = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus-19566},
  year      = {2006},
  abstract  = {The aim of the present study was to elucidate in a study with 4-, 6-, 8-, and 14-month-old German-learning children, when and how they may acquire the regularities which underlie Focus-to-Stress Alignment (FSA) in the target language, that is, how prosody is associated with specific communicative functions. Our findings suggest, that 14-month-olds have already found out that German allows for variable focus positions, after having gone through a development which goes from a predominantly prosodically driven processing of the input to a processing where prosody interacts more and more with the growing lexical and syntactic knowledge of the child.},
  language  = {en}
}
@article{EndrissHinterwimmer2006,
  author    = {Endriss, Cornelia and Hinterwimmer, Stefan},
  title     = {Quantificational Variability Effects with plural definites},
  url       = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus-19512},
  year      = {2006},
  abstract  = {In this paper we compare the behaviour of adverbs of frequency (de Swart 1993) like usually with the behaviour of adverbs of quantity like for the most part in sentences that contain plural definites. We show that sentences containing the former type of Q-adverb evidence that Quantificational Variability Effects (Berman 1991) come about as an indirect effect of quantification over situations: in order for quantificational variability readings to arise, these sentences have to obey two newly observed constraints that clearly set them apart from sentences containing corresponding quantificational DPs, and that can plausibly be explained under the assumption that quantification over (the atomic parts of) complex situations is involved. Concerning sentences with the latter type of Q-adverb, on the other hand, such evidence is lacking: with respect to the constraints just mentioned, they behave like sentences that contain corresponding quantificational DPs. We take this as evidence that Q-adverbs like for the most part do not quantify over the atomic parts of sum eventualities in the cases under discussion (as claimed by Nakanishi and Romero (2004)), but rather over the atomic parts of the respective sum individuals.},
  language  = {en}
}
@article{HellmuthSkopeteas2007,
  author    = {Hellmuth, Sam and Skopeteas, Stavros},
  title     = {Information structure in linguistic theory and in speech production : validation of a Cross-Linguistic data set},
  publisher = {Universit{\"a}tsverlag Potsdam},
  address   = {Potsdam},
  isbn      = {978-3-939469-72-8},
  issn      = {1866-4725},
  url       = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus-19450},
  pages     = {141 -- 186},
  year      = {2007},
  abstract  = {The aim of this paper is to validate a dataset collected by means of production experiments which are part of the Questionnaire on Information Structure. The experiments generate a range of information structure contexts that have been observed in the literature to induce specific constructions. This paper compares the speech production results from a subset of these experiments with specific claims about the reflexes of information structure in four different languages. The results allow us to evaluate and in most cases validate the efficacy of our elicitation paradigms, to identify potentially fruitful avenues of future research, and to highlight issues involved in interpreting speech production data of this kind.},
  language  = {en}
}
@article{KueglerSkopeteasVerhoeven2007,
  author    = {K{\"u}gler, Frank and Skopeteas, Stavros and Verhoeven, Elisabeth},
  title     = {Encoding information structure in Yucatec Maya},
  url       = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus-19469},
  year      = {2007},
  abstract  = {The aim of this paper is to outline the means for encoding information structure in Yucatec Maya. Yucatec Maya is a tone language, displaying a three-fold opposition in the tonal realization of syllables. From the morpho-syntactic point of view, the grammar of Yucatec Maya contains morphological (topic affixes, morphological marking of out-of-focus predicates) and syntactic (designated positions) means to uniquely specify syntactic constructions for their information structure. After a descriptive overview of these phenomena, we present experimental evidence which reveals the impact of the nonavailability of prosodic alternatives on the choice of syntactic constructions in language production.},
  language  = {en}
}
@phdthesis{Lange2008,
  author    = {Lange, Dietrich},
  title     = {The South Chilean subduction zone between 41° and 43.5°S : seismicity, structure and state of stress},
  url       = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus-18948},
  school      = {Universit{\"a}t Potsdam},
  year      = {2008},
  abstract  = {Die st{\"a}rksten Erdbeben treten an Subduktionszonen auf, so z.B. das st{\"a}rkste instrumentell jemals gemessene Erdbeben vom 22. Mai 1960 mit einer Magnitude von 9,5 Mw in S{\"u}d Chile. In dieser Arbeit werden lokal gewonnene seismologische Daten aus dem zentralen Bereich des 1960er-Bebens vorgestellt. Das seismologische Netzwerk umfasste den chilenischen Forearc zwischen Tiefseegraben und den vulkanischen Bogen zwischen 41,5°-43,5°S und {\"u}berdeckte sowohl die Insel Chilo{\´e} als auch die Nord-S{\"u}d-streichende Liqui{\~n}e-Ofqui St{\"o}rungszone (LOFZ). Zwischen November 2004 und Oktober 2005 konnten 364 lokale Ereignisse registriert werden. Die gewonnen Aufzeichnungen erlauben Aussagen sowohl {\"u}ber das aktuelle Spannungsfeld im Forearc als auch {\"u}ber das lokale Geschwindigkeitsmodell und die Geometrie der subduzierten Benioff-Zone. Mit einer Auswahl von P- und S-Laufzeiten von gut lokalisierbaren Erdbeben wurden ein Minimum 1-D Geschwindigkeitsmodell, Stationsresiduen und die Hypozentralparameter invertiert. Dieses Geschwindigkeitsmodell diente als Startmodell f{\"u}r die 2-D Tomographie. Das 2-D vp-Modell zeigt eine Zone erh{\"o}hter Geschwindigkeiten unterhalb des L{\"a}ngstals und des {\"o}stlichen Bereiches der Insel Chilo{\´e}, die als Mantelaufw{\"o}lbung interpretiert werden kann. Die Benioff-Zone wird als eine mit ca. 30° ostw{\"a}rts einfallende Struktur abgebildet. Die seismische Hauptaktivit{\"a}t findet parallel zur K{\"u}ste der Insel Chilo{\´e} in Tiefen zwischen 12 und 30 km statt; es handelt sich um Beben, die wahrscheinlich auf der Plattengrenzfl{\"a}che stattfinden. In Tiefen {\"u}ber 70 km l{\"a}sst die Seismizit{\"a}t bereits stark nach, die tiefsten Beben wurden in 120 km Tiefe registriert. Die Abwesenheit tieferer Seismizit{\"a}t wird auf das junge Alter (und eine damit verbundene hohe Temperatur) der ozeanischen Platte zur{\"u}ckgef{\"u}hrt. Neben der Seismizit{\"a}t in der Benioff-Zone treten flache, krustale Beben in verschiedenen H{\"a}ufungen entlang des magmatischen Bogens auf. Diese Bereiche erh{\"o}hter Seismizit{\"a}t sind r{\"a}umlich mit der LOFZ und den Vulkanen Chait{\´e}n, Michinmahuida und Corcovado verkn{\"u}pft. Beben bis zu einer Magnitude von 3,8 Mw zeigen die gegenw{\"a}rtige Aktivit{\"a}t der LOFZ. Herdfl{\"a}chen entlang der LOFZ wurden aus Momententensor-Inversion anhand von Amplitudenspektren von Raumwellen gewonnen. Ergebnisse einer Spannungsfeldinversion zeigen ein Blattverschiebungsregime f{\"u}r den magmatischen Bogen und ein {\"U}berschiebungsregime f{\"u}r Beben in der Benioff-Zone auf. Die hier gemachten seismologischen Beobachtungen, zusammen mit teleseismischen Erdbeben und geologischen Befunden, unterst{\"u}tzen die Modellvorstellung eines sich nordw{\"a}rts bewegenden kontinentalen Forearc-Blocks f{\"u}r S{\"u}d Chile.},
  language  = {en}
}
@phdthesis{Kwiecien2008,
  author    = {Kwiecien, Olga},
  title     = {Paleoenvironmental changes in the Black Sea region during the last 26,000 years : a multi-proxy study of lacustrine sediments from the western Black Sea},
  url       = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus-19180},
  school      = {Universit{\"a}t Potsdam},
  year      = {2008},
  abstract  = {Paleoenvironmental records provide ample information on the Late Quaternary climatic evolution. Due to the great diversity of continental mid-latitude environments the synthetic picture of the past mid-latitudinal climate changes is, however, far from being complete. Owing to its significant size and landlocked setting the Black Sea constitutes a perfect location to study patterns and mechanisms of climate change along the continental interior of Central and Eastern Europe and Asia Minor. Presently, the southern drainage area of the Black Sea is characterized by a Mediterranean-type climate while the northern drainage is under the influence of Central and Northern European climate. During the Last Glacial a decrease in the global sea level disconnected the Black Sea from the Mediterranean Sea transforming it into a giant closed lake. At that time atmospheric precipitation and related with it river run-off were the most important factors driving sediment supply and water chemistry of the Black 'Lake'. Therefore studying properties of the Black Sea sediments provides important information on the interactions and development of the Mediterranean and Central and North European climate in the past. One significant outcome of my thesis is an improved chronostraphigraphical framework for the glacial lacustrine unit of the Black Sea sediment cores, which allowed to refine the environmental history of the Black Sea region and enabled a reliable correlation with data from other marine and terrestrial archives. Data gathered along a N-S transect presented on a common time scale revealed coherent changes in the basin and its surrounding. During the glacial, the southward-shifted Polar Front reduced moisture transport to the northern drainage of the Black Sea and let the southern drainage become dominant in freshwater and sediment supply into the basin. Changes in NW Anatolian precipitation reconstructed from the variability of the terrigenous input imply that during the glacial the regional rainfall variability was strongly influenced by Mediterranean sea surface temperatures and decreased in response to the cooling associated with the North Atlantic Heinrich Events H1 and H2. In contrast to regional precipitation changes, the hydrological properties of the Black Sea remained relatively stable under full glacial conditions. First significant modification in the freshwater/sediment sources reconstructed from changes in the sediment composition, lithology, and 18O of ostracods took place at around 16.4 cal ka BP, simultaneous to the early deglacial northward retreat of the oceanic and atmospheric polar fronts. Meltwater pulses, most probably derived from the disintegrating European ice sheets, changed the isotopic composition of the Black Sea and increased the supply from northern sediment sources. While these changes signalized a mitigation of the Northern European and Mediterranean climate, a decisive increase in local temperature was indicated only later at the transition from the Oldest Dryas to the B{\o}lling around 14.6 cal ka BP. At that time the warming of the Black Sea surface initiated massive phytoplankton blooms, which in turn, induced the precipitation of inorganic carbonates. This biologically triggered process significantly changed the water chemistry and was recorded by simultaneous shifts in the elemental composition of ostracod shells and in the isotopic composition of the inorganically-precipitated carbonates. Starting with the B/A warming and continuing through the YD cold interval and the Early Holocene warming, the Black Sea temperature signal corresponds to the precipitation and temperature changes recorded in the wider Mediterranean region. Early Holocene conditions, similar to those of the B{\o}lling/Aller{\o}d, were punctured by the marine inflow from the Mediterranean at ~ 9.3 cal ka BP, which terminated the lacustrine phase of the Black Sea and had a substantial impact on the chemical and physical properties of its water.},
  language  = {en}
}
@phdthesis{Vazhappilly2008,
  author    = {Vazhappilly, Tijo Joseph},
  title     = {Vibrationally enhanced associative photodesorption of H2 (D2) from Ru(0001) : quantum and classical approaches},
  url       = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus-19056},
  school      = {Universit{\"a}t Potsdam},
  year      = {2008},
  abstract  = {Nowadays, reactions on surfaces are attaining great scientific interest because of their diverse applications. Some well known examples are production of ammonia on metal surfaces for fertilizers and reduction of poisonous gases from automobiles using catalytic converters. More recently, also photoinduced reactions at surfaces, useful, \textit{e.g.}, for photocatalysis, were studied in detail. Often, very short laser pulses are used for this purpose. Some of these reactions are occurring on femtosecond (1 fs=\$10^{-15}\$ s) time scales since the motion of atoms (which leads to bond breaking and new bond formation) belongs to this time range. This thesis investigates the femtosecond laser induced associative photodesorption of hydrogen, H\$_2\$, and deuterium, D\$_2\$, from a ruthenium metal surface. Many interesting features of this reaction were explored by experimentalists: (i) a huge isotope effect in the desorption probability of H\$_2\$ and D\$_2\$, (ii) the desorption yield increases non-linearly with the applied visible (vis) laser fluence, and (iii) unequal energy partitioning to different degrees of freedom. These peculiarities are due to the fact that an ultrashort vis pulse creates hot electrons in the metal. These hot electrons then transfer energy to adsorbate vibrations which leads to desorption. In fact, adsorbate vibrations are strongly coupled to metal electrons, \textit{i.e.}, through non-adiabatic couplings. This means that, surfaces introduce additional channels for energy exchange which makes the control of surface reactions more difficult than the control of reactions in the gas phase. In fact, the quantum yield of surface photochemical reactions is often notoriously small. One of the goals of the present thesis is to suggest, on the basis of theoretical simulations, strategies to control/enhance the photodesorption yield of H\$_2\$ and D\$_2\$ from Ru(0001). For this purpose, we suggest a \textit{hybrid scheme} to control the reaction, where the adsorbate vibrations are initially excited by an infrared (IR) pulse, prior to the vis pulse. Both \textit{adiabatic} and \textit{non-adiabatic} representations for photoinduced desorption problems are employed here. The \textit{adiabatic} representation is realized within the classical picture using Molecular Dynamics (MD) with electronic frictions. In a quantum mechanical description, \textit{non-adiabatic} representations are employed within open-system density matrix theory. The time evolution of the desorption process is studied using a two-mode reduced dimensionality model with one vibrational coordinate and one translational coordinate of the adsorbate. The ground and excited electronic state potentials, and dipole function for the IR excitation are taken from first principles. The IR driven vibrational excitation of adsorbate modes with moderate efficiency is achieved by (modified) \$\pi\$-pulses or/and optimal control theory. The fluence dependence of the desorption reaction is computed by including the electronic temperature of the metal calculated from the two-temperature model. Here, our theoretical results show a good agreement with experimental and previous theoretical findings. We then employed the IR+vis strategy in both models. Here, we found that vibrational excitation indeed promotes the desorption of hydrogen and deuterium. To summarize, we conclude that photocontrol of this surface reaction can be achieved by our IR+vis scheme.},
  language  = {en}
}
@phdthesis{Germer2008,
  author    = {Germer, Sonja},
  title     = {Near-surface hydrology and hydrochemistry under contrasting land-cover},
  url       = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus-19049},
  school      = {Universit{\"a}t Potsdam},
  year      = {2008},
  abstract  = {Human transformation of the Earth's land surface has far-reaching and important consequences for the functioning of hydrological and hydrochemical processes in watersheds. In nowadays land-use change from forest to pasture is a major issue in particular in the tropics. A sustainable management of deforested areas requires an in-depth understanding of the water and nutrient cycle. On this basis we compared the involved hydrological pathways for rainfall to reach streams and the nutrient budgets of a tropical rainforest and a pasture. In addition we studied the links of hydrochemical differences to differences of the relative importance of flowpaths. This study was conducted in the southwestern part of the Brazilian Amazon basin. An intensive hydrological and hydrochemical sampling and monitoring network was set up. The results indicate that the hydrology was modified in many ways due to land-use change. The most important alteration was the increased importance of the fast flowpath overland flow. Solute exports were in particular linked to the increased volume of overland flow that resulted from the land-use change. An additional reason for the increased nutrient exports from the pasture are the high concentrations of these nutrients in pasture overland flow probably as a due to cattle excrements. Tight nutrient cycles with minimal nutrient losses could not be maintained after the land-use change. This study provides the first attempt to quantify the respective nutrient losses.},
  language  = {en}
}
@phdthesis{CastroMarin2007,
  author    = {Castro Marin, Inmaculada},
  title     = {Nitrate: metabolism and development},
  url       = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus-18827},
  school      = {Universit{\"a}t Potsdam},
  year      = {2007},
  abstract  = {The major aim of this thesis was to study the effect of nitrate on primary metabolism and in development of the model plant Arabidopsis thaliana. The present work has two separate topics. First, to investigate the GDH family, a small gene family at the interface between nitrogen and carbon metabolisms. Second, to investigate the mechanisms whereby nitrogen is regulating the transition to flowering time in Arabidopsis thaliana. To gain more insights into the regulation of primary metabolism by the functional characterization of the glutamate dehydrogenase (GDH) family, an enzyme putatively involved in the metabolism of amino acids and thus suggested to play different and essential roles in carbon and nitrogen metabolism in plants, knock out mutants and transgenic plants carrying RNA interference construct were generated and characterized. The effect of silencing GDH on carbon and nitrogen metabolisms was investigated, especially the level of carbohydrates and the amino acid pool were further analysed. It has been shown that GDH expression is regulated by light and/or sugar status therefore, phenotypic and metabolic analysis were developed in plants grown at different points of the diurnal rhythm and in response to an extended night period. In addition, we are interested in the effect of nutrient availability in the transition from vegetative growth to flowering and especially in nitrate as a metabolite that triggers widespread and coordinated changes in metabolism and development. Nutrient availability has a dramatic effect on flowering time, with a marked delay of flowering when nitrate is supplied (Stitt, 1999). The use of different mutants and transgenic plants impaired in flowering signalling pathways was crucial to evaluate the impact of different nitrate concentrations on flowering time and to better understand the interaction of nitrate-dependent signals with other main flowering signalling pathways. Plants were grown on glutamine as a constitutive source of nitrogen, and the nitrate supply varied. Low nitrate led to earlier flowering. The response to nitrate is accentuated in short days and in the CONSTANS deficient co2 mutant, whereas long days or overexpression of CONSTANS overrides the nitrate response. These results indicate that nitrates acts downstream of the known flowering signalling pathways for photoperiod, autonomy, vernalization and gibberellic acid. Global analyses of gene expression of two independent flowering systems, a light impaired mutant (co2tt4) and a constitutive over-expresser of the potent repressor of flowering (35S::FLC), were to be investigated under two different concentrations of nitrate in order to identify candidate genes that may be involved in the regulation of flowering time by nitrate.},
  language  = {en}
}
@phdthesis{Vijayakrishnan2008,
  author    = {Vijayakrishnan, Balakumar},
  title     = {Solution and solid phase synthesis of N,N'-diacetyl chitotetraoses},
  url       = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus-18830},
  school      = {Universit{\"a}t Potsdam},
  year      = {2008},
  abstract  = {The three major biopolymers, proteins, nucleic acids and glycoconjugates are mainly responsible for the information transfer, which is a fundamental process of life. The biological importance of proteins and nucleic acids are well explored and oligosaccharides in the form of glycoconjugates have gained importance recently. The β-(1→4) linked N-acetylglucosamine (GlcNAc) moiety is a frequently occurring structural unit in various naturally and biologically important oligosaccharides and related conjugates. Chitin which is the most abundant polymer of GlcNAc is widely distributed in nature whereas the related polysaccharide chitosan (polymer of GlcN and GlcNAc) occurs in certain fungi. Chitooligosaccharides of mixed acetylation patterns are of interest for the determination of the substrate specificities and mechanism of chitinases. In this report, we describe the chemical synthesis of three chitotetraoses namely GlcNAc-GlcN-GlcNAc-GlcN, GlcN-GlcNAc-GlcNAc-GlcN and GlcN-GlcN-GlcNAc-GlcNAc. Benzyloxycarbonyl (Z) and p-nitrobenzyloxycarbonyl (PNZ) were used for the amino functionality due to their ability to form the β-linkage during the glycosylation reactions through neighboring group participation and the trichloroacetimidate approach was utilized for the donor. Monomeric, dimeric acceptors and donors have been prepared by utilizing the Z and PNZ groups and coupling between the appropriate donor and acceptors in the presence of Lewis acid yielded the protected tetrasaccharides. Finally cleavage of PNZ followed by reacetylation and the deblocking of other protecting groups afforded the N,N'-diacetyl chitotetraoses in good yield. Successful syntheses for the protected diacetyl chitotetraoses by solid phase synthesis have also been described.},
  language  = {en}
}
@phdthesis{GholamiGhadikolaei2007,
  author    = {Gholami Ghadikolaei, Iraj},
  title     = {Data analysis of continuous gravitational waves},
  url       = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus-18800},
  school      = {Universit{\"a}t Potsdam},
  year      = {2007},
  abstract  = {This thesis describes two main projects; the first one is the optimization of a hierarchical search strategy to search for unknown pulsars. This project is divided into two parts; the first part (and the main part) is the semi-coherent hierarchical optimization strategy. The second part is a coherent hierarchical optimization strategy which can be used in a project like Einstein@Home. In both strategies we have found that the 3-stages search is the optimum strategy to search for unknown pulsars. For the second project we have developed a computer software for a coherent Multi-IFO (Interferometer Observatory) search. To validate our software, we have worked on simulated data as well as hardware injected signals of pulsars in the fourth LIGO science run (S4). While with the current sensitivity of our detectors we do not expect to detect any true Gravitational Wave signals in our data, we can still set upper limits on the strength of the gravitational waves signals. These upper limits, in fact, tell us how weak a signal strength we would detect. We have also used our software to set upper limits on the signal strength of known isolated pulsars using LIGO fifth science run (S5) data.},
  language  = {en}
}
@phdthesis{Worseck2007,
  author    = {Worseck, G{\´a}bor},
  title     = {The transverse proximity effect in quasar spectra},
  url       = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus-18738},
  school      = {Universit{\"a}t Potsdam},
  year      = {2007},
  abstract  = {The intergalactic medium is kept highly photoionised by the intergalactic UV background radiation field generated by the overall population of quasars and galaxies. In the vicinity of sources of UV photons, such as luminous high-redshift quasars, the UV radiation field is enhanced due to the local source contribution. The higher degree of ionisation is visible as a reduced line density or generally as a decreased level of absorption in the Lyman alpha forest of neutral hydrogen. This so-called proximity effect has been detected with high statistical significance towards luminous quasars. If quasars radiate rather isotropically, background quasar sightlines located near foreground quasars should show a region of decreased Lyman alpha absorption close to the foreground quasar. Despite considerable effort, such a transverse proximity effect has only been detected in a few cases. So far, studies of the transverse proximity effect were mostly limited by the small number of suitable projected pairs or groups of high-redshift quasars. With the aim to substantially increase the number of quasar groups in the vicinity of bright quasars we conduct a targeted survey for faint quasars around 18 well-studied quasars at employing slitless spectroscopy. Among the reduced and calibrated slitless spectra of 29000 objects on a total area of 4.39 square degrees we discover in total 169 previously unknown quasar candidates based on their prominent emission lines. 81 potential z>1.7 quasars are selected for confirmation by slit spectroscopy at the Very Large Telescope (VLT). We are able to confirm 80 of these. 64 of the newly discovered quasars reside at z>1.7. The high success rate of the follow-up observations implies that the majority of the remaining candidates are quasars as well. In 16 of these groups we search for a transverse proximity effect as a systematic underdensity in the HI Lyman alpha absorption. We employ a novel technique to characterise the random absorption fluctuations in the forest in order to estimate the significance of the transverse proximity effect. Neither low-resolution spectra nor high-resolution spectra of background quasars of our groups present evidence for a transverse proximity effect. However, via Monte Carlo simulations the effect should be detectable only at the 1-2sigma level near three of the foreground quasars. Thus, we cannot distinguish between the presence or absence of a weak signature of the transverse proximity effect. The systematic effects of quasar variability, quasar anisotopy and intrinsic overdensities near quasars likely explain the apparent lack of the transverse proximity effect. Even in absence of the systematic effects, we show that a statistically significant detection of the transverse proximity effect requires at least 5 medium-resolution quasar spectra of background quasars near foreground quasars whose UV flux exceeds the UV background by a factor 3. Therefore, statistical studies of the transverse proximity effect require large numbers of suitable pairs. Two sightlines towards the central quasars of our survey fields show intergalactic HeII Lyman alpha absorption. A comparison of the HeII absorption to the corresponding HI absorption yields an estimate of the spectral shape of the intergalactic UV radiation field, typically parameterised by the HeII/HI column density ratio eta. We analyse the fluctuating UV spectral shape on both lines of sight and correlate it with seven foreground quasars. On the line of sight towards Q0302-003 we find a harder radiation field near 4 foreground quasars. In the direct vicinity of the quasars eta is consistent with values of 25-100, whereas at large distances from the quasars eta>200 is required. The second line of sight towards HE2347-4342 probes lower redshifts where eta is directly measurable in the resolved HeII forest. Again we find that the radiation field near the 3 foreground quasars is significantly harder than in general. While eta still shows large fluctuations near the quasars, probably due to radiative transfer, the radiation field is on average harder near the quasars than far away from them. We interpret these discoveries as the first detections of the transverse proximity effect as a local hardness fluctuation in the UV spectral shape. No significant HI proximity effect is predicted for the 7 foreground quasars. In fact, the HI absorption near the quasars is close to or slightly above the average, suggesting that the weak signature of the transverse proximity effect is masked by intrinsic overdensities. However, we show that the UV spectral shape traces the transverse proximity effect even in overdense regions or at large distances. Therefore, the spectral hardness is a sensitive physical measure of the transverse proximity effect that is able to break the density degeneracy affecting the traditional searches.},
  language  = {en}
}
@phdthesis{Mueller2008,
  author    = {M{\"u}ller, Melanie J. I.},
  title     = {Bidirectional transport by molecular motors},
  url       = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus-18715},
  school      = {Universit{\"a}t Potsdam},
  year      = {2008},
  abstract  = {In biological cells, the long-range intracellular traffic is powered by molecular motors which transport various cargos along microtubule filaments. The microtubules possess an intrinsic direction, having a 'plus' and a 'minus' end. Some molecular motors such as cytoplasmic dynein walk to the minus end, while others such as conventional kinesin walk to the plus end. Cells typically have an isopolar microtubule network. This is most pronounced in neuronal axons or fungal hyphae. In these long and thin tubular protrusions, the microtubules are arranged parallel to the tube axis with the minus ends pointing to the cell body and the plus ends pointing to the tip. In such a tubular compartment, transport by only one motor type leads to 'motor traffic jams'. Kinesin-driven cargos accumulate at the tip, while dynein-driven cargos accumulate near the cell body. We identify the relevant length scales and characterize the jamming behaviour in these tube geometries by using both Monte Carlo simulations and analytical calculations. A possible solution to this jamming problem is to transport cargos with a team of plus and a team of minus motors simultaneously, so that they can travel bidirectionally, as observed in cells. The presumably simplest mechanism for such bidirectional transport is provided by a 'tug-of-war' between the two motor teams which is governed by mechanical motor interactions only. We develop a stochastic tug-of-war model and study it with numerical and analytical calculations. We find a surprisingly complex cooperative motility behaviour. We compare our results to the available experimental data, which we reproduce qualitatively and quantitatively.},
  language  = {en}
}
@book{Narmania2007,
  author    = {Narmania, David},
  title     = {Rights of local jurisdictions and tax revenue distribution in Georgia},
  url       = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus-18766},
  publisher      = {Universit{\"a}t Potsdam},
  year      = {2007},
  abstract  = {This paper describes the administrative powers of local jurisdictions in Georgia, emphasizing on the tax competences and the abilities to mobilize other sources of income. Having listed and explained the types of revenues and incomes, the articles continues to show their distribution among administrative levels according to the current tax code. Following a brief overview of the main laws underlying tax regulation, the existing problems of the status quo before 2007 and some perspectives for the immediate future are outlined.},
  language  = {en}
}
@phdthesis{Tukhlina2008,
  author    = {Tukhlina, Natalia},
  title     = {Feedback control of complex oscillatory systems},
  url       = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus-18546},
  school      = {Universit{\"a}t Potsdam},
  year      = {2008},
  abstract  = {In the present dissertation paper an approach which ensures an efficient control of such diverse systems as noisy or chaotic oscillators and neural ensembles is developed. This approach is implemented by a simple linear feedback loop. The dissertation paper consists of two main parts. One part of the work is dedicated to the application of the suggested technique to a population of neurons with a goal to suppress their synchronous collective dynamics. The other part is aimed at investigating linear feedback control of coherence of a noisy or chaotic self-sustained oscillator. First we start with a problem of suppressing synchronization in a large population of interacting neurons. The importance of this task is based on the hypothesis that emergence of pathological brain activity in the case of Parkinson's disease and other neurological disorders is caused by synchrony of many thousands of neurons. The established therapy for the patients with such disorders is a permanent high-frequency electrical stimulation via the depth microelectrodes, called Deep Brain Stimulation (DBS). In spite of efficiency of such stimulation, it has several side effects and mechanisms underlying DBS remain unclear. In the present work an efficient and simple control technique is suggested. It is designed to ensure suppression of synchrony in a neural ensemble by a minimized stimulation that vanishes as soon as the tremor is suppressed. This vanishing-stimulation technique would be a useful tool of experimental neuroscience; on the other hand, control of collective dynamics in a large population of units represents an interesting physical problem. The main idea of suggested approach is related to the classical problem of oscillation theory, namely the interaction between a self-sustained (active) oscillator and a passive load (resonator). It is known that under certain conditions the passive oscillator can suppress the oscillations of an active one. In this thesis a much more complicated case of active medium, which itself consists of thousands of oscillators is considered. Coupling this medium to a specially designed passive oscillator, one can control the collective motion of the ensemble, specifically can enhance or suppress it. Having in mind a possible application in neuroscience, the problem of suppression is concentrated upon. Second, the efficiency of suggested suppression scheme is illustrated by considering more complex case, i.e. when the population of neurons generating the undesired rhythm consists of two non-overlapping subpopulations: the first one is affected by the stimulation, while the collective activity is registered from the second one. Generally speaking, the second population can be by itself both active and passive; both cases are considered here. The possible applications of suggested technique are discussed. Third, the influence of the external linear feedback on coherence of a noisy or chaotic self-sustained oscillator is considered. Coherence is one of the main properties of self-oscillating systems and plays a key role in the construction of clocks, electronic generators, lasers, etc. The coherence of a noisy limit cycle oscillator in the context of phase dynamics is evaluated by the phase diffusion constant, which is in its turn proportional to the width of the spectral peak of oscillations. Many chaotic oscillators can be described within the framework of phase dynamics, and, therefore, their coherence can be also quantified by the way of the phase diffusion constant. The analytical theory for a general linear feedback, considering noisy systems in the linear and Gaussian approximation is developed and validated by numerical results.},
  language  = {en}
}
@phdthesis{Zemanova2007,
  author    = {Zemanov{\´a}, Lucia},
  title     = {Structure-function relationship in hierarchical model of brain networks},
  url       = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus-18400},
  school      = {Universit{\"a}t Potsdam},
  year      = {2007},
  abstract  = {The mammalian brain is, with its numerous neural elements and structured complex connectivity, one of the most complex systems in nature. Recently, large-scale corticocortical connectivities, both structural and functional, have received a great deal of research attention, especially using the approach of complex networks. Here, we try to shed some light on the relationship between structural and functional connectivities by studying synchronization dynamics in a realistic anatomical network of cat cortical connectivity. We model the cortical areas by a subnetwork of interacting excitable neurons (multilevel model) and by a neural mass model (population model). With weak couplings, the multilevel model displays biologically plausible dynamics and the synchronization patterns reveal a hierarchical cluster organization in the network structure. We can identify a group of brain areas involved in multifunctional tasks by comparing the dynamical clusters to the topological communities of the network. With strong couplings of multilevel model and by using neural mass model, the dynamics are characterized by well-defined oscillations. The synchronization patterns are mainly determined by the node intensity (total input strengths of a node); the detailed network topology is of secondary importance. The biologically improved multilevel model exhibits similar dynamical patterns in the two regimes. Thus, the study of synchronization in a multilevel complex network model of cortex can provide insights into the relationship between network topology and functional organization of complex brain networks.},
  language  = {en}
}
@phdthesis{Buha2008,
  author    = {Buha, Jelena},
  title     = {Nonaqueous syntheses of metal oxide and metal nitride nanoparticles},
  url       = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus-18368},
  school      = {Universit{\"a}t Potsdam},
  year      = {2008},
  abstract  = {Nanostructured materials are materials consisting of nanoparticulate building blocks on the scale of nanometers (i.e. 10-9 m). Composition, crystallinity and morphology can enhance or even induce new properties of the materials, which are desirable for todays and future technological applications. In this work, we have shown new strategies to synthesise metal oxide and metal nitride nanomaterials. The first part of the work deals with the study of nonaqueous synthesis of metal oxide nanoparticles. We succeeded in the synthesis of In2O3 nanopartcles where we could clearly influence the morphology by varying the type of the precursors and the solvents; of ZnO mesocrystals by using acetonitrile as a solvent; of transition metal oxides (Nb2O5, Ta2O5 and HfO2) that are particularly hard to obtain on the nanoscale and other technologically important materials. Solvothermal synthesis however is not restricted to formation of oxide materials only. In the second part we show examples of nonaqueous, solvothermal reactions of metal nitrides, but the main focus lies on the investigation of the influence of different morphologies of metal oxide precursors on the formation of the metal nitride nanoparticles. In spite of various reports, the number and variety of nanocrystalline metal nitrides is marginally small by comparison to metal oxides; hence preformed metal oxides as precursors for the preparation of metal nitrides are a logical choice. By reacting oxide nanoparticles with cyanamide, urea or melamine, at temperatures of 800 to 900 °C under nitrogen flow metal nitrides could be obtained. We studied in detail the influence of the starting material and realized that size, crystallinity, type of nitrogen source and temperature play the most important role. We have managed to propose and verify a dissolution-recrystallisation model as the formation mechanism. Furthermore we could show that the initial morphology of the oxides could be retained when ammonia flow was used instead.},
  language  = {en}
}
@phdthesis{Schroeder2007,
  author    = {Schr{\"o}der, Birgit Eva},
  title     = {Spatial and temporal dynamics of the terrestrial carbon cycle : assimilation of two decades of optical satellite data into a process-based global vegetation model},
  url       = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus-17596},
  school      = {Universit{\"a}t Potsdam},
  year      = {2007},
  abstract  = {This PhD thesis presents the spatio-temporal distribution of terrestrial carbon fluxes for the time period of 1982 to 2002 simulated by a combination of the process-based dynamic global vegetation model LPJ and a 21-year time series of global AVHRR-fPAR data (fPAR - fraction of photosynthetically active radiation). Assimilation of the satellite data into the model allows improved simulations of carbon fluxes on global as well as on regional scales. As it is based on observed data and includes agricultural regions, the model combined with satellite data produces more realistic carbon fluxes of net primary production (NPP), soil respiration, carbon released by fire and the net land-atmosphere flux than the potential vegetation model. It also produces a good fit to the interannual variability of the CO2 growth rate. Compared to the original model, the model with satellite data constraint produces generally smaller carbon fluxes than the purely climate-based stand-alone simulation of potential natural vegetation, now comparing better to literature estimates. The lower net fluxes are a result of a combination of several effects: reduction in vegetation cover, consideration of human influence and agricultural areas, an improved seasonality, changes in vegetation distribution and species composition. This study presents a way to assess terrestrial carbon fluxes and elucidates the processes contributing to interannual variability of the terrestrial carbon exchange. Process-based terrestrial modelling and satellite-observed vegetation data are successfully combined to improve estimates of vegetation carbon fluxes and stocks. As net ecosystem exchange is the most interesting and most sensitive factor in carbon cycle modelling and highly uncertain, the presented results complementary contribute to the current knowledge, supporting the understanding of the terrestrial carbon budget.},
  language  = {en}
}
@phdthesis{Kryvych2007,
  author    = {Kryvych, Sergiy},
  title     = {Gene expression profiling in different stages of development of Arabidopsis thaliana leaftrichomes at the single cell level},
  url       = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus-17474},
  school      = {Universit{\"a}t Potsdam},
  year      = {2007},
  abstract  = {Each organ of a multicellular organism is unique at the level of its tissues and cells. Furthermore, responses to environmental stimuli or developmental signals occur differentially at the single cell or tissue level. This underlines the necessity of precise investigation of the "building block of life" -the individual cell. Although recently large amount of data concerning different aspects of single cell performance was accumulated, our knowledge about development and differentiation of individual cell within specialized tissue are still far from being complete. To get more insight into processes that occur in certain individual cell during its development and differentiation changes in gene expression during life cycle of A. thaliana leaf hair cell (trichome) were explored in this work. After onset of trichome development this cell changes its cell cycle: it starts endoreduplication (a modified cell cycle in which DNA replication continues in the absence of mitosis and cytokinesis). This makes trichomes a suitable model for studying cell cycle regulation, regulation of cell development and differentiation. Cells of interest were sampled by puncturing them with glass microcapillaries. Each sample contained as few as ten single cells. At first time trichomes in initial stage of trichome development were investigated. To allow their sampling they were specifically labelled by green fluorescent protein (GFP). In total three cell types were explored: pavement cells, trichome initials and mature trichomes. Comparison of gene expression profiles of these cells allowed identification of the genes differentially expressed in subsequent stages of trichome development. Bioinformatic analysis of genes preferentially expressed in trichome initials showed their involvement in hormonal, metal, sulphur response and cell-cycle regulation. Expression pattern of three selected candidate genes, involved in hormonal response and early developmental processes was confirmed by independent method. Effects of mutations in these genes on both trichome and plant development as well as on plant metabolism were analysed. As an outcome of this work novel components in the sophisticated machinery of trichome development and cell cycle progression were identified. These factors could integrate hormone stimuli and network interactions between characterized and as yet unknown members of this machinery. I expect findings presented in this work to enhance and complement our current knowledge about cell cycle progression and trichome development, as well as about performance of the individual cell in general.},
  language  = {en}
}
@phdthesis{Nazaran2008,
  author    = {Nazaran, Pantea},
  title     = {Nucleation in emulsion polymerization : steps towards a non-micellar nucleation theory},
  url       = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus-17521},
  school      = {Universit{\"a}t Potsdam},
  year      = {2008},
  abstract  = {For more than 70 years, understanding of the mechanism of particle nucleation in emulsion polymerization has been one of the most challenging issues in heterophase polymerization research. Within this work a comprehensive experimental study of particle nucleation in emulsion polymerization of styrene at 70 °C and variety of conditions has been performed. To follow the onset of nucleation, on-line conductivity measurements were applied. This technique is highly sensitive to the mobility of conducting species and hence, it can be employed to follow aggregation processes leading to particle formation. On the other hand, by recording the optical transmission (turbidity) of the reaction mixture particle growth was followed. Complementary to the on-line investigations, off-line characterizations of the particle morphology and the molecular weight have been performed. The aim was to achieve a better insight in the processes taking place after starting the reaction via particle nucleation until formation of colloidally stable latex particles. With this experimental protocol the initial period of styrene emulsion polymerization in the absence as well as in the presence of various surfactants (concentrations above and below the critical micellization concentration) and also in the presence of seed particles has been investigated. Ionic and non-ionic initiators (hydrophilic and hydrophobic types) have been applied to start the polymerizations. Following the above algorithm, experimental evidence has been obtained showing the possibility of performing surfactant-free emulsion polymerization of styrene with oil-soluble initiators. The duration of the pre-nucleation period (that is the time between starting the polymerization and nucleation) can be precisely adjusted with the initiator hydrophobicity, the equilibration time of styrene in water, and the surfactant concentration. Spontaneous emulsification of monomer in water, as soon as both phases are brought into contact, is a key factor to explain the experimental results. The equilibration time of monomer in water as well as the type and concentration of other materials in water (surfactants, seed particles, etc.) control the formation rate and the size of the emulsified droplets and thus, have a strong influence on the particle nucleation and the particle morphology. One of the main tasks was to investigate the effect of surfactant molecules and especially micelles on the nucleation mechanism. Experimental results revealed that in the presence of emulsifier micelles the conductivity pattern does not change essentially. This means that the presence of emulsifiers does not change the mechanism of particle formation qualitatively. However, surfactants assist in the nucleation process as they lower the activation free energy of particle formation. Contrary, seed particles influence particle nucleation, substantially. In the presence of seed particles above a critical volume fraction the formation of new particles can be suppressed. However, micelles and seed particles as absorbers exhibit a common behavior under conditions where monomer equilibration is not allowed. Results prove that the nucleation mechanism comprises the initiation of water soluble oligomers in the aqueous phase followed by their aggregation. The process is heterogeneous in nature due to the presence of monomer droplets.},
  language  = {en}
}
@phdthesis{Pazienti2007,
  author    = {Pazienti, Antonio},
  title     = {Manipulations of spike trains and their impact on synchrony analysis},
  url       = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus-17447},
  school      = {Universit{\"a}t Potsdam},
  year      = {2007},
  abstract  = {The interaction between neuronal cells can be identified as the computing mechanism of the brain. Neurons are complex cells that do not operate in isolation, but they are organized in a highly connected network structure. There is experimental evidence that groups of neurons dynamically synchronize their activity and process brain functions at all levels of complexity. A fundamental step to prove this hypothesis is to analyze large sets of single neurons recorded in parallel. Techniques to obtain these data are meanwhile available, but advancements are needed in the pre-processing of the large volumes of acquired data and in data analysis techniques. Major issues include extracting the signal of single neurons from the noisy recordings (referred to as spike sorting) and assessing the significance of the synchrony. This dissertation addresses these issues with two complementary strategies, both founded on the manipulation of point processes under rigorous analytical control. On the one hand I modeled the effect of spike sorting errors on correlated spike trains by corrupting them with realistic failures, and studied the corresponding impact on correlation analysis. The results show that correlations between multiple parallel spike trains are severely affected by spike sorting, especially by erroneously missing spikes. When this happens sorting strategies characterized by classifying only good'' spikes (conservative strategies) lead to less accurate results than tolerant'' strategies. On the other hand, I investigated the effectiveness of methods for assessing significance that create surrogate data by displacing spikes around their original position (referred to as dithering). I provide analytical expressions of the probability of coincidence detection after dithering. The effectiveness of spike dithering in creating surrogate data strongly depends on the dithering method and on the method of counting coincidences. Closed-form expressions and bounds are derived for the case where the dither equals the allowed coincidence interval. This work provides new insights into the methodologies of identifying synchrony in large-scale neuronal recordings, and of assessing its significance.},
  language  = {en}
}
@phdthesis{Glushak2007,
  author    = {Glushak, Ksenia},
  title     = {Atmospheric circulation and the surface mass balance in a regional climate model of Antarctica},
  url       = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus-17296},
  school      = {Universit{\"a}t Potsdam},
  year      = {2007},
  abstract  = {Understanding the Earth's climate system and particularly climate variability presents one of the most difficult and urgent challenges in science. The Antarctic plays a crucial role in the global climate system, since it is the principal region of radiative energy deficit and atmospheric cooling. An assessment of regional climate model HIRHAM is presented. The simulations are generated with the HIRHAM model, which is modified for Antarctic applications. With a horizontal resolution of 55km, the model has been run for the period 1958-1998 creating long-term simulations from initial and boundary conditions provided by the European Centre for Medium-Range Weather Forecasts (ECMWF) ERA40 re-analysis. The model output is compared with observations from observation stations, upper air data, global atmospheric analyses and satellite data. In comparison with the observations, the evaluation shows that the simulations with the HIRHAM model capture both the large and regional scale circulation features with generally small bias in the modeled variables. On the annual time scale the largest errors in the model simulations are the overestimation total cloud cover and the colder near-surface temperature over the interior of the Antarctic plateau. The low-level temperature inversion as well as low-level wind jet is well captured by the model. The decadal scale processes were studied based on trend calculations. The long-term run was divided into two 20 years parts. The 2m temperature, 500 hPa temperature, MSLP, precipitation and net mass balance trends were calculated for both periods and over 1958 - 1998. During the last two decades the strong surface cooling was observed over the Eastern Antarctica, this result is in good agreement with the result of Chapman and Walsh (2005) who calculated the temperature trend based on the observational data. The MSLP trend reveals a big disparity between the first and second parts of the 40 year run. The overall trend shows the strengthening of the circumpolar vortex and continental anticyclone. The net mass balance as well as precipitation show a positive trend over the Antarctic Peninsula region, along Wilkes Land and in Dronning Maud Land. The Antarctic ice sheet grows over the Eastern part of Antarctica with small exceptions in Dronning Maud Land and Wilkes Land and sinks in the Antarctic Peninsula; this result is in good agreement with the satellite-measured altitude presented in Davis (2005) . To better understand the horizontal structure of MSLP, temperature and net mass balance trends the influence of the Southern Annual Mode (SAM) on the Antarctic climate was investigated. The main meteorological parameters during the positive and negative Antarctic Oscillation (AAO) phases were compared to each other. A positive/negative AAO index means strengthening/weakening of the circumpolar vortex, poleward/northward storm tracks and prevailing/weakening westerly winds. For detailed investigation of global teleconnection, two positive and one negative periods of AAO phase were chosen. The differences in MSLP and 2m temperature between positive and negative AAO years during the winter months partly explain the surface cooling during the last decades.},
  language  = {en}
}
@phdthesis{Linckels2008,
  author    = {Linckels, Serge},
  title     = {An e-librarian service : supporting explorative learning by a description logics based semantic retrieval tool},
  url       = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus-17452},
  school      = {Universit{\"a}t Potsdam},
  year      = {2008},
  abstract  = {Although educational content in electronic form is increasing dramatically, its usage in an educational environment is poor, mainly due to the fact that there is too much of (unreliable) redundant, and not relevant information. Finding appropriate answers is a rather difficult task being reliant on the user filtering of the pertinent information from the noise. Turning knowledge bases like the online tele-TASK archive into useful educational resources requires identifying correct, reliable, and "machine-understandable" information, as well as developing simple but efficient search tools with the ability to reason over this information. Our vision is to create an E-Librarian Service, which is able to retrieve multimedia resources from a knowledge base in a more efficient way than by browsing through an index, or by using a simple keyword search. In our E-Librarian Service, the user can enter his question in a very simple and human way; in natural language (NL). Our premise is that more pertinent results would be retrieved if the search engine understood the sense of the user's query. The returned results are then logical consequences of an inference rather than of keyword matchings. Our E-Librarian Service does not return the answer to the user's question, but it retrieves the most pertinent document(s), in which the user finds the answer to his/her question. Among all the documents that have some common information with the user query, our E-Librarian Service identifies the most pertinent match(es), keeping in mind that the user expects an exhaustive answer while preferring a concise answer with only little or no information overhead. Also, our E-Librarian Service always proposes a solution to the user, even if the system concludes that there is no exhaustive answer. Our E-Librarian Service was implemented prototypically in three different educational tools. A first prototype is CHESt (Computer History Expert System); it has a knowledge base with 300 multimedia clips that cover the main events in computer history. A second prototype is MatES (Mathematics Expert System); it has a knowledge base with 115 clips that cover the topic of fractions in mathematics for secondary school w.r.t. the official school programme. All clips were recorded mainly by pupils. The third and most advanced prototype is the "Lecture Butler's E-Librarain Service"; it has a Web service interface to respect a service oriented architecture (SOA), and was developed in the context of the Web-University project at the Hasso-Plattner-Institute (HPI). Two major experiments in an educational environment - at the Lyc{\´e}e Technique Esch/Alzette in Luxembourg - were made to test the pertinence and reliability of our E-Librarian Service as a complement to traditional courses. The first experiment (in 2005) was made with CHESt in different classes, and covered a single lesson. The second experiment (in 2006) covered a period of 6 weeks of intensive use of MatES in one class. There was no classical mathematics lesson where the teacher gave explanations, but the students had to learn in an autonomous and exploratory way. They had to ask questions to the E-Librarian Service just the way they would if there was a human teacher.},
  subject      = {Terminologische Logik},
  language  = {en}
}
@inproceedings{OPUS4-1574,
  title     = {Clumping in hot-star winds : proceedings of an international workshop held in Potsdam, Germany, 18. - 22. June 2007},
  editor    = {Hamann, Wolf-Rainer and Feldmeier, Achim and Oskinova, Lidia M.},
  publisher = {Universit{\"a}tsverlag Potsdam},
  address   = {Potsdam},
  isbn      = {978-3-940793-33-1},
  url       = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus-13981},
  pages     = {254},
  year      = {2007},
  abstract  = {Stellar winds play an important role for the evolution of massive stars and their cosmic environment. Multiple lines of evidence, coming from spectroscopy, polarimetry, variability, stellar ejecta, and hydrodynamic modeling, suggest that stellar winds are non-stationary and inhomogeneous. This is referred to as 'wind clumping'. The urgent need to understand this phenomenon is boosted by its far-reaching implications. Most importantly, all techniques to derive empirical mass-loss rates are more or less corrupted by wind clumping. Consequently, mass-loss rates are extremely uncertain. Within their range of uncertainty, completely different scenarios for the evolution of massive stars are obtained. Settling these questions for Galactic OB, LBV and Wolf-Rayet stars is prerequisite to understanding stellar clusters and galaxies, or predicting the properties of first-generation stars. In order to develop a consistent picture and understanding of clumped stellar winds, an international workshop on 'Clumping in Hot Star Winds' was held in Potsdam, Germany, from 18. - 22. June 2007. About 60 participants, comprising almost all leading experts in the field, gathered for one week of extensive exchange and discussion. The Scientific Organizing Committee (SOC) included John Brown (Glasgow), Joseph Cassinelli (Madison), Paul Crowther (Sheffield), Alex Fullerton (Baltimore), Wolf-Rainer Hamann (Potsdam, chair), Anthony Moffat (Montreal), Stan Owocki (Newark), and Joachim Puls (Munich). These proceedings contain the invited and contributed talks presented at the workshop, and document the extensive discussions.},
  language  = {en}
}
@phdthesis{Dronov2007,
  author    = {Dronov, Roman},
  title     = {Multi-component protein films by layer-by-layer : assembly and electron transfer},
  url       = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus-17281},
  school      = {Universit{\"a}t Potsdam},
  year      = {2007},
  abstract  = {Electron transfer phenomena in proteins represent one of the most common types of biochemical reactions. They play a central role in energy conversion pathways in living cells, and are crucial components in respiration and photosynthesis. These complex biochemical reaction cascades consist of a series of proteins and protein complexes that couple a charge transfer to different forms of chemical energy. The efficiency and sophisticated optimisation of signal transfer in these natural redox chains has inspired engineering of artificial architectures mimicking essential properties of their natural analogues. Implementation of direct electron transfer (DET) in protein assemblies was a breakthrough in bioelectronics, providing a simple and efficient way for coupling biological recognition events to a signal transducer. DET avoids the use of redox mediators, reducing potential interferences and side reactions, as well as being more compatible with in vivo conditions. However, only a few haem proteins, including the redox protein cytochrome c (cyt.c), and blue copper enzymes show efficient DET on different kinds of electrodes. Previous investigations with cyt.c have mainly focused on heterogeneous electron transfer of monolayers of this protein on gold. An important advance was the fabrication of cyt.c multilayers by electrostatic layer-by-layer self-assembly. The ease of fabrication, the stability, and the controllable permeability of polyelectrolyte multilayers have made them particularly attractive for electroanalytical applications. With cyt.c and sulfonated polyaniline it was for the first time possible that fully electro-active multilayers of the redox protein could be prepared. This approach was extended to design an analytical signal chain based on multilayers of cyt.c and xanthine oxidase (XOD). The system does not need an external mediator but relies on an in situ generation of a mediating radical and thus allows a signal transfer from hypoxanthine via the substrate converting enzyme and cyt.c to the electrode. Another kind of a signal chain is based on assembling proteins in complexes on electrodes in such a way that a direct protein-protein electron transfer becomes feasible. This design does not need a redox mediator in analogy to natural protein communication. For this purpose, cyt.c and the enzyme bilirubin oxidase (BOD, EC 1.3.3.5) are co-immobilized in a self-assembled polyelectrolyte multilayer on gold electrodes. Although these two proteins are not natural reaction partners, the protein architecture facilitates an electron transfer from the electrode via multiple protein layers to molecular oxygen resulting in a significant catalytic reduction current. Finally, we describe a novel strategy for multi-protein layer-by-layer self-assembly combining cyt.c with an enzyme sulfite oxidase (SOx) without use of any additional polymer. Electrostatic interactions between these two proteins with rather separated pI values during the assembly process from a low ionic strength buffer were found sufficient for the layer-by-layer deposition of the both biomolecules. It is anticipated that the concepts described in this work will stimulate further progress in multilayer design of even more complex biomimetic signal cascades taking advantage of direct communication between proteins.},
  language  = {en}
}
@phdthesis{Lindenmaier2007,
  author    = {Lindenmaier, Falk},
  title     = {Hydrology of a large unstable hillslope at Ebnit, Vorarlberg : identifying dominating processes and structures},
  url       = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus-17424},
  school      = {Universit{\"a}t Potsdam},
  year      = {2007},
  abstract  = {The objective of this thesis is to improve the knowledge of control mechanisms of hydrological induced mass movements. To this end, detailed hydrological process studies and physically-based hydrological modelling were applied. The study site is a hillslope in the Dornbirn Ache valley near Bregenz, Austria. This so called Heum{\"o}s slope features a deep-seated translational shear zone and surface near creep movements of up to 10 cm a year. The Cretaceous marlstones of the Austrian Helveticum have a high susceptibility for weathering and might form clay-rich cohesive sediments. In addition, glacial and post-glacial processes formed an unstable hillslope. High yearly precipitation depths of about 2100 mm and rainstorms with both high intensities and precipitation depths govern surface and subsurface hydrological processes. Pressure propagation induced in hydrological active areas influences laterally the groundwater reactions of the moving mass. A complex three-dimensional subsurface pressure system is the cause for fast groundwater reactions despite low hydraulic conductivities. To understand hillslope scale variability, hydrotopes representing specific dominating processes were mapped using vegetation association distribution and soil core analysis. Detailed small-scale soil investigations followed to refine the understanding of these hydrotopes. A perceptional model was developed from the hydrotope distribution and was corroborated by these detailed investigations. The moving hillslope is dominated by surface-runoff generation. Infiltration and deep percolation of water is inhibited through clay-rich gleysols; the yearly average soil moisture is close to saturation. Steep slopes adjacent to the moving hillslope are far more active concerning infiltration, preferential flow and groundwater fluctuations. Spring discharge observations at the toe of the steep slopes are in close relation to groundwater table observations on the moving hillslope body. Evidence of pressure propagation from the steep slopes towards the hillslope body is gathered by comparison of dominating structures and processes. The application of the physically-based hydrological model CATFLOW substantiates the idea of pressure propagation as a key process for groundwater reactions and as a possible trigger for movement in the hillslope.},
  language  = {en}
}