@article{ZhongCausaMooreetal.2020, author = {Zhong, Yufei and Causa, Martina and Moore, Gareth John and Krauspe, Philipp and Xiao, Bo and G{\"u}nther, Florian and Kublitski, Jonas and BarOr, Eyal and Zhou, Erjun and Banerji, Natalie}, title = {Sub-picosecond charge-transfer at near-zero driving force in polymer:non-fullerene acceptor blends and bilayers}, series = {Nature Communications}, volume = {11}, journal = {Nature Communications}, number = {1}, publisher = {Nature Publishing Group UK}, address = {London}, issn = {2041-1723}, doi = {10.1038/s41467-020-14549-w}, pages = {1 -- 10}, year = {2020}, abstract = {Organic photovoltaics based on non-fullerene acceptors (NFAs) show record efficiency of 16 to 17\% and increased photovoltage owing to the low driving force for interfacial charge-transfer. However, the low driving force potentially slows down charge generation, leading to a tradeoff between voltage and current. Here, we disentangle the intrinsic charge-transfer rates from morphology-dependent exciton diffusion for a series of polymer:NFA systems. Moreover, we establish the influence of the interfacial energetics on the electron and hole transfer rates separately. We demonstrate that charge-transfer timescales remain at a few hundred femtoseconds even at near-zero driving force, which is consistent with the rates predicted by Marcus theory in the normal region, at moderate electronic coupling and at low re-organization energy. Thus, in the design of highly efficient devices, the energy offset at the donor:acceptor interface can be minimized without jeopardizing the charge-transfer rate and without concerns about a current-voltage tradeoff.}, language = {en} } @article{Fuhr2021, author = {Fuhr, Harald}, title = {The rise of the Global South and the rise in carbon emissions}, series = {Third world quarterly}, volume = {42}, journal = {Third world quarterly}, number = {11}, publisher = {Routledge, Taylor \& Francis Group}, address = {Abingdon}, issn = {0143-6597}, doi = {10.1080/01436597.2021.1954901}, pages = {2724 -- 2746}, year = {2021}, abstract = {Jointly with the Global North, the rise of the Global South has come at a high cost to the environment. Driven by its high energy intensity and the use of fossil fuels, the South has contributed a significant portion of global emissions during the last 30 years, and is now contributing some 63\% of today's total GHG emissions (including land-use change and forestry). Similar to the Global North, the Global South's emissions are heavily concentrated: India and China alone account for some 60\% and the top 10 countries for some 78\% of the group's emissions, while some 120 countries account for only 22\%. Without highlighting such differences, it makes little sense to use the term 'Global South'. Its members are affected differently, and contribute differently to global climate change. They neither share a common view, nor do they pursue joint interests when it comes to international climate negotiations. Instead, they are organised into more than a dozen subgroups of the global climate regime. There is no single climate strategy for the Global South, and climate action will differ enormously from country to country. Furthermore, just and equitable transitions may be particularly challenging for some countries.}, language = {en} }