@article{ThomasWebsterRhedeetal.2006, author = {Thomas, Rainer and Webster, J. D. and Rhede, Dieter and Seifert, W. and Rickers, Karen and F{\"o}rster, Hans-J{\"u}rgen and Heinrich, Wilhelm and Davidson, P.}, title = {The transition from peraluminous to peralkaline granitic melts: Evidence from melt inclusions and accessory minerals}, series = {Lithos : an international journal of mineralogy, petrology, and geochemistry}, volume = {91}, journal = {Lithos : an international journal of mineralogy, petrology, and geochemistry}, number = {1-4}, publisher = {Elsevier}, address = {Amsterdam}, issn = {0024-4937}, doi = {10.1016/j.lithos.2006.03.013}, pages = {137 -- 149}, year = {2006}, abstract = {Fractional crystallization of peraluminous F- and H(2)O-rich granite magmas progressively enriches the remaining melt with volatiles. We show that, at saturation, the melt may separate into two immiscible conjugate melt fractions, one of the fractions shows increasing peraluminosity and the other increasing peralkalinity. These melt fractions also fractionate the incompatible elements to significantly different degrees. Coexisting melt fractions have differing chemical and physical properties and, due to their high density and viscosity contrasts, they will tend to separate readily from each other. Once separated, each melt fraction evolves independently in response to changing T/P/X conditions and further immiscibility events may occur, each generating its own conjugate pair of melt fractions. The strongly peralkaline melt fractions in particular are very reactive and commonly react until equilibrium is attained. Consequently, the peralkaline melt fraction is commonly preserved only in the isolated melt and mineral inclusions. We demonstrate that the differences between melt fractions that can be seen most clearly in differing melt inclusion compositions are also visible in the composition of the resulting ore-forming and accessory minerals, and are visible on scales from a few micrometers to hundreds of meters.}, language = {en} } @article{FerreroBragaBerkesietal.2014, author = {Ferrero, Silvio and Braga, R. and Berkesi, M. and Cesare, Bernardo and Ouazaa, N. Laridhi}, title = {Production of metaluminous melt during fluid-present anatexis: an example from the Maghrebian basement, La Galite Archipelago, central Mediterranean}, series = {Journal of metamorphic geology}, volume = {32}, journal = {Journal of metamorphic geology}, number = {2}, publisher = {Wiley-Blackwell}, address = {Hoboken}, issn = {0263-4929}, doi = {10.1111/jmg.12068}, pages = {209 -- 225}, year = {2014}, abstract = {Garnet brought to the surface by late Miocene granitoids at La Galite Archipelago (Central Mediterranean, Tunisia) contains abundant primary melt and fluid inclusions. Microstructural observations and mineral chemistry define the host garnet as a peritectic phase produced by biotite incongruent melting at ~800 degrees C and 0.5GPa, under fluid-present conditions. The trapped melt is leucogranitic with an unexpected metaluminous and almost peralkaline character. Fluid inclusions are one phase at room temperature, and contain a CO2-dominated fluid, with minor H2O, N-2 and CH4. Siderite and an OH-bearing phase were identified by Raman and IR spectroscopy within every analysed inclusion, and are interpreted as products of a post-entrapment carbonation/hydration reaction between the fluid and the host during cooling. The fluid present during anatexis is therefore inferred to have been originally richer in both H2O and CO2. The production of anatectic melt with a metaluminous signature can be explained as the result of partial melting of relatively Al-poor protoliths assisted by CO2-rich fluids.}, language = {en} } @article{CarvalhoBartoliFerrietal.2019, author = {Carvalho, Bruna B. and Bartoli, Omar and Ferri, Fabio and Cesare, Bernardo and Ferrero, Silvio and Remusat, Laurent and Capizzi, Luca Samuele and Poli, Stefano}, title = {Anatexis and fluid regime of the deep continental crust: New clues from melt and fluid inclusions in metapelitic migmatites from Ivrea Zone (NW Italy)}, series = {Journal of metamorphic geology}, volume = {37}, journal = {Journal of metamorphic geology}, number = {7}, publisher = {Wiley}, address = {Hoboken}, issn = {0263-4929}, doi = {10.1111/jmg.12463}, pages = {951 -- 975}, year = {2019}, abstract = {We investigate the inclusions hosted in peritectic garnet from metapelitic migmatites of the Kinzigite Formation (Ivrea Zone, NW Italy) to evaluate the starting composition of the anatectic melt and fluid regime during anatexis throughout the upper amphibolite facies, transition, and granulite facies zones. Inclusions have negative crystal shapes, sizes from 2 to 10 mu m and are regularly distributed in the core of the garnet. Microstructural and micro-Raman investigations indicate the presence of two types of inclusions: crystallized silicate melt inclusions (i.e., nanogranitoids, NI), and fluid inclusions (FI). Microstructural evidence suggests that FI and NI coexist in the same cluster and are primary (i.e., were trapped simultaneously during garnet growth). FI have similar compositions in the three zones and comprise variable proportions of CO2, CH4, and N-2, commonly with siderite, pyrophyllite, and kaolinite, suggesting a COHN composition of the trapped fluid. The mineral assemblage in the NI contains K-feldspar, plagioclase, quartz, biotite, muscovite, chlorite, graphite and, rarely, calcite. Polymorphs such as kumdykolite, cristobalite, tridymite, and less commonly kokchetavite, were also found. Rehomogenized NI from the different zones show that all the melts are leucogranitic but have slightly different compositions. In samples from the upper amphibolite facies, melts are less mafic (FeO + MgO = 2.0-3.4 wt\%), contain 860-1700 ppm CO2 and reach the highest H2O contents (6.5-10 wt\%). In the transition zone melts have intermediate H2O (4.8-8.5 wt\%), CO2 (457-1534 ppm) and maficity (FeO + MgO = 2.3-3.9 wt\%). In contrast, melts at granulite facies reach highest CaO, FeO + MgO (3.2-4.7 wt\%), and CO2 (up to 2,400 ppm), with H2O contents comparable (5.4-8.3 wt\%) to the other two zones. Our results represent the first clear evidence for carbonic fluid-present melting in the Ivrea Zone. Anatexis of metapelites occurred through muscovite and biotite breakdown melting in the presence of a COH fluid, in a situation of fluid-melt immiscibility. The fluid is assumed to have been internally derived, produced initially by devolatilization of hydrous silicates in the graphitic protolith, then as a result of oxidation of carbon by consumption of Fe3+-bearing biotite during melting. Variations in the compositions of the melts are interpreted to result from higher T of melting. The H2O contents of the melts throughout the three zones are higher than usually assumed for initial H2O contents of anatectic melts. The CO2 contents are highest at granulite facies, and show that carbon-contents of crustal magmas are not negligible at high T. The activity of H2O of the fluid dissolved in granitic melts decreases with increasing metamorphic grade. Carbonic fluid-present melting of the deep continental crust represents, together with hydrate-breakdown melting reactions, an important process in the origin of crustal anatectic granitoids.}, language = {en} } @article{BorghiniFerreroO’Brienetal.2019, author = {Borghini, Alessia and Ferrero, Silvio and O'Brien, Patrick J. and Laurent, Oscar and G{\"u}nter, Christina and Ziemann, Martin Andreas}, title = {Cryptic metasomatic agent measured in situ in Variscan mantle rocks}, volume = {38}, publisher = {Wiley-Blackwell}, address = {Oxford [u.a.]}, issn = {1525-1314}, doi = {10.1111/jmg.12519}, pages = {207 -- 234}, year = {2019}, abstract = {Garnet of eclogite (formerly termed garnet clinopyroxenite) hosted in lenses of orogenic garnet peridotite from the Granulitgebirge, NW Bohemian Massif, contains unique inclusions of granitic melt, now either glassy or crystallized. Analysed glasses and re-homogenized inclusions are hydrous, peraluminous, and enriched in highly incompatible elements characteristic of the continental crust such as Cs, Li, B, Pb, Rb, Th, and U. The original melt thus represents a pristine, chemically evolved metasomatic agent, which infiltrated the mantle via deep continental subduction during the Variscan orogeny. The bulk chemical composition of the studied eclogites is similar to that of Fe-rich basalt and the enrichment in LILE and U suggest a subduction-related component. All these geochemical features confirm metasomatism. In comparison with many other garnet+clinopyroxene-bearing lenses in peridotites of the Bohemian Massif, the studied samples from Rubinberg and Klatschm{\"u}hle are more akin to eclogite than pyroxenites, as reflected in high jadeite content in clinopyroxene, relatively low Mg, Cr, and Ni but relatively high Ti. However, trace elements of both bulk rock and individual mineral phases show also important differences making these samples rather unique. Metasomatism involving a melt requiring a trace element pattern very similar to the composition reported here has been suggested for the source region of rocks of the so-called durbachite suite, that is, ultrapotassic melanosyenites, which are found throughout the high-grade Variscan basement. Moreover, the Th, U, Pb, Nb, Ta, and Ti patterns of these newly studied melt inclusions (MI) strongly resemble those observed for peridotite and its enclosed pyroxenite from the T-7 borehole (Star{\´e}, Česk{\´e} Středhoři Mountains) in N Bohemia. This suggests that a similar kind of crustal-derived melt also occurred here. This study of granitic MI in eclogites from peridotites has provided the first direct characterization of a preserved metasomatic melt, possibly responsible for the metasomatism of several parts of the mantle in the Variscides.}, language = {en} } @article{BartoliAcostaVigilFerreroetal.2016, author = {Bartoli, Omar and Acosta-Vigil, Antonio and Ferrero, Silvio and Cesare, Bernardo}, title = {Granitoid magmas preserved as melt inclusions in high-grade metamorphic rocks}, series = {American mineralogist : an international journal of earth and planetary materials}, volume = {101}, journal = {American mineralogist : an international journal of earth and planetary materials}, publisher = {Mineralogical Society of America}, address = {Chantilly}, issn = {0003-004X}, doi = {10.2138/am-2016-5541CCBYNCND}, pages = {1543 -- 1559}, year = {2016}, abstract = {This review presents a compositional database of primary anatectic granitoid magmas, entirely based on melt inclusions (MI) in high-grade metamorphic rocks. Although MI are well known to igneous petrologists and have been extensively studied in intrusive and extrusive rocks, MI in crustal rocks that have undergone anatexis (migmatites and granulites) are a novel subject of research. They are generally trapped along the heating path by peritectic phases produced by incongruent melting reactions. Primary MI in high-grade metamorphic rocks are small, commonly 5-10 pm in diameter, and their most common mineral host is peritectic garnet. In most cases inclusions have crystallized into a cryptocrystalline aggregate and contain a granitoid phase assemblage (nanogranitoid inclusions) with quartz, K-feldspar, plagioclase, and one or two mica depending on the particular circumstances. After their experimental remelting under high-confining pressure, nanogranitoid MI can be analyzed combining several techniques (EMP, LA-ICP-MS, NanoSIMS, Raman). The trapped melt is granitic and metaluminous to peraluminous, and sometimes granodioritic, tonalitic, and trondhjemitic in composition, in agreement with the different P-T-a(H2o) conditions of melting and protolith composition, and overlap the composition of experimental glasses produced at similar conditions. Being trapped along the up-temperature trajectory as opposed to classic MI in igneous rocks formed during down-temperature magma crystallization fundamental information provided by nanogranitoid MI is the pristine composition of the natural primary anatectic melt for the specific rock under investigation. So far similar to 600 nanogranitoid MI, coming from several occurrences from different geologic and geodynamic settings and ages, have been characterized. Although the compiled MI database should be expanded to other potential sources of crustal magmas, MI data collected so far can be already used as natural "starting-point" compositions to track the processes involved in formation and evolution of granitoid magmas.}, language = {en} }