@article{OrtmannAhrensMilewskietal.2014,
  author    = {Ortmann, Thomas and Ahrens, Heiko and Milewski, Sven and Lawrenz, Frank and Groening, Andreas and Laschewsky, Andr{\´e} and Garnier, Sebastien and Helm, Christiane A.},
  title     = {Lipid monolayers with adsorbed oppositely charged polyelectrolytes: Influence of reduced charge densities},
  series = {Polymers},
  volume    = {6},
  journal   = {Polymers},
  number    = {7},
  publisher = {MDPI},
  address   = {Basel},
  issn      = {2073-4360},
  doi       = {10.3390/polym6071999},
  pages     = {1999 -- 2017},
  year      = {2014},
  abstract  = {Polyelectrolytes in dilute solutions (0.01 mmol/L) adsorb in a two-dimensional lamellar phase to oppositely charged lipid monolayers at the air/water interface. The interchain separation is monitored by Grazing Incidence X-ray Diffraction. On monolayer compression, the interchain separation decreases to a factor of two. To investigate the influence of the electrostatic interaction, either the line charge density of the polymer is reduced (a statistic copolymer with 90\% and 50\% charged monomers) or mixtures between charged and uncharged lipids are used (dipalmitoylphosphatidylcholine (DPPC)/dioctadecyldimethylammonium bromide (DODAB)) On decrease of the surface charge density, the interchain separation increases, while on decrease of the linear charge density, the interchain separation decreases. The ratio between charged monomers and charged lipid molecules is fairly constant; it decreases up to 30\% when the lipids are in the fluid phase. With decreasing surface charge or linear charge density, the correlation length of the lamellar order decreases.},
  language  = {en}
}
@article{deCarvalhoMetzlerCherstvy2016,
  author    = {de Carvalho, Sidney J. and Metzler, Ralf and Cherstvy, Andrey G.},
  title     = {Critical adsorption of polyelectrolytes onto planar and convex highly charged surfaces},
  series = {New journal of physics : the open-access journal for physics},
  volume    = {18},
  journal   = {New journal of physics : the open-access journal for physics},
  publisher = {IOP Publ.},
  address   = {London},
  issn      = {1367-2630},
  doi       = {10.1088/1367-2630/18/8/083037},
  year      = {2016},
  abstract  = {We study the adsorption-desorption transition of polyelectrolyte chains onto planar, cylindrical and spherical surfaces with arbitrarily high surface charge densities by massive Monte Carlo computer simulations. We examine in detail how the well known scaling relations for the threshold transition—demarcating the adsorbed and desorbed domains of a polyelectrolyte near weakly charged surfaces—are altered for highly charged interfaces. In virtue of high surface potentials and large surface charge densities, the Debye-H{\"u}ckel approximation is often not feasible and the nonlinear Poisson-Boltzmann approach should be implemented. At low salt conditions, for instance, the electrostatic potential from the nonlinear Poisson-Boltzmann equation is smaller than the Debye-H{\"u}ckel result, such that the required critical surface charge density for polyelectrolyte adsorption σc increases. The nonlinear relation between the surface charge density and electrostatic potential leads to a sharply increasing critical surface charge density with growing ionic strength, imposing an additional limit to the critical salt concentration above which no polyelectrolyte adsorption occurs at all. We contrast our simulations findings with the known scaling results for weak critical polyelectrolyte adsorption onto oppositely charged surfaces for the three standard geometries. Finally, we discuss some applications of our results for some physical-chemical and biophysical systems.},
  language  = {en}
}
@misc{deCarvalhoMetzlerCherstvy2016,
  author    = {de Carvalho, Sidney J. and Metzler, Ralf and Cherstvy, Andrey G.},
  title     = {Critical adsorption of polyelectrolytes onto planar and convex highly charged surfaces},
  url       = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-100295},
  pages     = {17},
  year      = {2016},
  abstract  = {We study the adsorption-desorption transition of polyelectrolyte chains onto planar, cylindrical and spherical surfaces with arbitrarily high surface charge densities by massive Monte Carlo computer simulations. We examine in detail how the well known scaling relations for the threshold transition—demarcating the adsorbed and desorbed domains of a polyelectrolyte near weakly charged surfaces—are altered for highly charged interfaces. In virtue of high surface potentials and large surface charge densities, the Debye-H{\"u}ckel approximation is often not feasible and the nonlinear Poisson-Boltzmann approach should be implemented. At low salt conditions, for instance, the electrostatic potential from the nonlinear Poisson-Boltzmann equation is smaller than the Debye-H{\"u}ckel result, such that the required critical surface charge density for polyelectrolyte adsorption σc increases. The nonlinear relation between the surface charge density and electrostatic potential leads to a sharply increasing critical surface charge density with growing ionic strength, imposing an additional limit to the critical salt concentration above which no polyelectrolyte adsorption occurs at all. We contrast our simulations findings with the known scaling results for weak critical polyelectrolyte adsorption onto oppositely charged surfaces for the three standard geometries. Finally, we discuss some applications of our results for some physical-chemical and biophysical systems.},
  language  = {en}
}
@article{deCarvalhoMetzlerCherstvy2016,
  author    = {de Carvalho, Sidney J. and Metzler, Ralf and Cherstvy, Andrey G.},
  title     = {Critical adsorption of polyelectrolytes onto planar and convex highly charged surfaces: the nonlinear Poisson-Boltzmann approach},
  series = {NEW JOURNAL OF PHYSICS},
  volume    = {18},
  journal   = {NEW JOURNAL OF PHYSICS},
  publisher = {IOP Publ. Ltd.},
  address   = {Bristol},
  issn      = {1367-2630},
  doi       = {10.1088/1367-2630/18/8/083037},
  pages     = {17},
  year      = {2016},
  abstract  = {We study the adsorption-desorption transition of polyelectrolyte chains onto planar, cylindrical and spherical surfaces with arbitrarily high surface charge densities by massive Monte Carlo computer simulations. We examine in detail how the well known scaling relations for the threshold transition demarcating the adsorbed and desorbed domains of a polyelectrolyte near weakly charged surfaces-are altered for highly charged interfaces. In virtue of high surface potentials and large surface charge densities, the Debye-Huckel approximation is often not feasible and the nonlinear Poisson-Boltzmann approach should be implemented. At low salt conditions, for instance, the electrostatic potential from the nonlinear Poisson-Boltzmann equation is smaller than the Debye-Huckel result, such that the required critical surface charge density for polyelectrolyte adsorption sigma(c) increases. The nonlinear relation between the surface charge density and electrostatic potential leads to a sharply increasing critical surface charge density with growing ionic strength, imposing an additional limit to the critical salt concentration above which no polyelectrolyte adsorption occurs at all. We contrast our simulations findings with the known scaling results for weak critical polyelectrolyte adsorption onto oppositely charged surfaces for the three standard geometries. Finally, we discuss some applications of our results for some physical-chemical and biophysical systems.},
  language  = {en}
}