@article{ZinsmeisterSmolka2012, author = {Zinsmeister, Heike and Smolka, Eva}, title = {Corpus-based evidence for approximating semantic transparency of complex verbs}, series = {Potsdam cognitive science series}, journal = {Potsdam cognitive science series}, number = {3}, publisher = {Universit{\"a}tsverlag Potsdam}, address = {Potsdam}, issn = {2190-4545}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus-62353}, pages = {45 -- 59}, year = {2012}, language = {en} } @phdthesis{Zenichowski2012, author = {Zenichowski, Karl}, title = {Quantum dynamical study of Si(100) surface-mounted, STM-driven switches at the atomic and molecular scale}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus-62156}, school = {Universit{\"a}t Potsdam}, year = {2012}, abstract = {The aim of this thesis is the quantum dynamical study of two examples of scanning tunneling microscope (STM)-controllable, Si(100)(2x1) surface-mounted switches of atomic and molecular scale. The first example considers the switching of single H-atoms between two dangling-bond chemisorption sites on a Si-dimer of the Si(100) surface (Grey et al., 1996). The second system examines the conformational switching of single 1,5-cyclooctadiene molecules chemisorbed on the Si(100) surface (Nacci et al., 2008). The temporal dynamics are provided by the propagation of the density matrix in time via an according set of equations of motion (EQM). The latter are based on the open-system density matrix theory in Lindblad form. First order perturbation theory is used to evaluate those transition rates between vibrational levels of the system part. In order to account for interactions with the surface phonons, two different dissipative models are used, namely the bilinear, harmonic and the Ohmic bath model. IET-induced vibrational transitions in the system are due to the dipole- and the resonance-mechanism. A single surface approach is used to study the influence of dipole scattering and resonance scattering in the below-threshold regime. Further, a second electronic surface was included to study the resonance-induced switching in the above-threshold regime. Static properties of the adsorbate, e.g., potentials and dipole function and potentials, are obtained from quantum chemistry and used within the established quantum dynamical models.}, language = {en} } @phdthesis{Zarafshani2012, author = {Zarafshani, Zoya}, title = {Chain-end functionalization and modification of polymers using modular chemical reactions}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus-59723}, school = {Universit{\"a}t Potsdam}, year = {2012}, abstract = {Taking advantage of ATRP and using functionalized initiators, different functionalities were introduced in both α and ω chain-ends of synthetic polymers. These functionalized polymers could then go through modular synthetic pathways such as click cycloaddition (copper-catalyzed or copper-free) or amidation to couple synthetic polymers to other synthetic polymers, biomolecules or silica monoliths. Using this general strategy and designing these co/polymers so that they are thermoresponsive, yet bioinert and biocompatible with adjustable cloud point values (as it is the case in the present thesis), the whole generated system becomes "smart" and potentially applicable in different branches. The applications which were considered in the present thesis were in polymer post-functionalization (in situ functionalization of micellar aggregates with low and high molecular weight molecules), hydrophilic/hydrophobic tuning, chromatography and bioconjugation (enzyme thermoprecipitation and recovery, improvement of enzyme activity). Different α-functionalized co/polymers containing cholesterol moiety, aldehyde, t-Boc protected amine, TMS-protected alkyne and NHS-activated ester were designed and synthesized in this work.}, language = {en} } @article{Wynn2012, author = {Wynn, Natalie}, title = {Jews, antisemitism and Irish politics}, series = {PaRDeS : Zeitschrift der Vereinigung f{\"u}r J{\"u}dische Studien e.V.}, journal = {PaRDeS : Zeitschrift der Vereinigung f{\"u}r J{\"u}dische Studien e.V.}, number = {18}, publisher = {Universit{\"a}tsverlag Potsdam}, address = {Potsdam}, issn = {1614-6492}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus-61514}, pages = {51 -- 66}, year = {2012}, abstract = {Im Artikel wird eine der gr{\"o}ßten Schw{\"a}chen der Historiographie der irischen Judenheiten betrachtet: die fehlende Bestimmung des wahren Ausmaßes des Antisemitismus und dessen Auswirkungen auf die j{\"u}dische Gemeinschaft in Irland. Hierf{\"u}r wird ein kurzer {\"U}berblick {\"u}ber einen Ausschnitt des irisch-j{\"u}dischen Narrativs gegeben: das j{\"u}dische Verh{\"a}ltnis zur nationalistischen Politik in Irland. Der Fokus liegt dabei auf der Notwendigkeit f{\"u}r einen neuartigen Umgang mit den Quellen und den vorliegenden Sachverhalten, um eine ganzheitliche, objektivere und inklusive Geschichte der irischen Judenheiten zu schreiben.}, language = {en} } @misc{WojcinskiDupontSchmidtetal.2012, author = {Wojcinski, Sebastian and Dupont, Jennifer and Schmidt, Werner and Cassel, Michael and Hillemanns, Peter}, title = {Real-time ultrasound elastography in 180 axillary lymph nodes}, series = {Postprints der Universit{\"a}t Potsdam : Humanwissenschaftliche Reihe}, journal = {Postprints der Universit{\"a}t Potsdam : Humanwissenschaftliche Reihe}, number = {626}, issn = {1866-8364}, doi = {10.25932/publishup-43158}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-431584}, pages = {12}, year = {2012}, abstract = {Background To determine the general appearance of normal axillary lymph nodes (LNs) in real-time tissue sonoelastography and to explore the method′s potential value in the prediction of LN metastases. Methods Axillary LNs in healthy probands (n=165) and metastatic LNs in breast cancer patients (n=15) were examined with palpation, B-mode ultrasound, Doppler and sonoelastography (assessment of the elasticity of the cortex and the medulla). The elasticity distributions were compared and sensitivity (SE) and specificity (SP) were calculated. In an exploratory analysis, positive and negative predictive values (PPV, NPV) were calculated based upon the estimated prevalence of LN metastases in different risk groups. Results In the elastogram, the LN cortex was significantly harder than the medulla in both healthy (p=0.004) and metastatic LNs (p=0.005). Comparing healthy and metastatic LNs, there was no difference in the elasticity distribution of the medulla (p=0.281), but we found a significantly harder cortex in metastatic LNs (p=0.006). The SE of clinical examination, B-mode ultrasound, Doppler ultrasound and sonoelastography was revealed to be 13.3\%, 40.0\%, 14.3\% and 60.0\%, respectively, and SP was 88.4\%, 96.8\%, 95.6\% and 79.6\%, respectively. The highest SE was achieved by the disjunctive combination of B-mode and elastographic features (cortex >3mm in B-mode or blue cortex in the elastogram, SE=73.3\%). The highest SP was achieved by the conjunctive combination of B-mode ultrasound and elastography (cortex >3mm in B-mode and blue cortex in the elastogram, SP=99.3\%). Conclusions Sonoelastography is a feasible method to visualize the elasticity distribution of LNs. Moreover, sonoelastography is capable of detecting elasticity differences between the cortex and medulla, and between metastatic and healthy LNs. Therefore, sonoelastography yields additional information about axillary LN status and can improve the PPV, although this method is still experimental.}, language = {en} } @phdthesis{Wohlgemuth2012, author = {Wohlgemuth, Stephanie-Angelika}, title = {Functional nanostructured hydrothermal carbons for sustainable technologies : heteroatom doping and superheated vapor}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus-60120}, school = {Universit{\"a}t Potsdam}, year = {2012}, abstract = {The underlying motivation for the work carried out for this thesis was the growing need for more sustainable technologies. The aim was to synthesize a "palette" of functional nanomaterials using the established technique of hydrothermal carbonization (HTC). The incredible diversity of HTC was demonstrated together with small but steady advances in how HTC can be manipulated to tailor material properties for specific applications. Two main strategies were used to modify the materials obtained by HTC of glucose, a model precursor representing biomass. The first approach was the introduction of heteroatoms, or "doping" of the carbon framework. Sulfur was for the first time introduced as a dopant in hydrothermal carbon. The synthesis of sulfur and sulfur/nitrogen doped microspheres was presented whereby it was shown that the binding state of sulfur could be influenced by varying the type of sulfur source. Pyrolysis may additionally be used to tune the heteroatom binding states which move to more stable motifs with increasing pyrolysis temperature. Importantly, the presence of aromatic binding states in the as synthesized hydrothermal carbon allows for higher heteroatom retention levels after pyrolysis and hence more efficient use of dopant sources. In this regard, HTC may be considered as an "intermediate" step in the formation of conductive heteroatom doped carbon. To assess the novel hydrothermal carbons in terms of their potential for electrochemical applications, materials with defined nano-architectures and high surface areas were synthesized via templated, as well as template-free routes. Sulfur and/or nitrogen doped carbon hollow spheres (CHS) were synthesized using a polystyrene hard templating approach and doped carbon aerogels (CA) were synthesized using either the albumin directed or borax-mediated hydrothermal carbonization of glucose. Electrochemical testing showed that S/N dual doped CHS and aerogels derived via the albumin approach exhibited superior catalytic performance compared to solely nitrogen or sulfur doped counterparts in the oxygen reduction reaction (ORR) relevant to fuel cells. Using the borax mediated aerogel formation, nitrogen content and surface area could be tuned and a carbon aerogel was engineered to maximize electrochemical performance. The obtained sample exhibited drastically improved current densities compared to a platinum catalyst (but lower onset potential), as well as excellent long term stability. In the second approach HTC was carried out at elevated temperatures (550 °C) and pressure (50 bar), corresponding to the superheated vapor regime (htHTC). It was demonstrated that the carbon materials obtained via htHTC are distinct from those obtained via ltHTC and subsequent pyrolysis at 550 °C. No difference in htHTC-derived material properties could be observed between pentoses and hexoses. The material obtained from a polysaccharide exhibited a slightly lower degree of carbonization but was otherwise similar to the monosaccharide derived samples. It was shown that in addition to thermally induced carbonization at 550 °C, the SHV environment exhibits a catalytic effect on the carbonization process. The resulting materials are chemically inert (i.e. they contain a negligible amount of reactive functional groups) and possess low surface area and electronic conductivity which distinguishes them from carbon obtained from pyrolysis. Compared to the materials presented in the previous chapters on chemical modifications of hydrothermal carbon, this makes them ill-suited candidates for electronic applications like lithium ion batteries or electrocatalysts. However, htHTC derived materials could be interesting for applications that require chemical inertness but do not require specific electronic properties. The final section of this thesis therefore revisited the latex hard templating approach to synthesize carbon hollow spheres using htHTC. However, by using htHTC it was possible to carry out template removal in situ because the second heating step at 550 °C was above the polystyrene latex decomposition temperature. Preliminary tests showed that the CHS could be dispersed in an aqueous polystyrene latex without monomer penetrating into the hollow sphere voids. This leaves the stagnant air inside the CHS intact which in turn is promising for their application in heat and sound insulating coatings. Overall the work carried out in this thesis represents a noteworthy development in demonstrating the great potential of sustainable carbon materials.}, language = {en} } @misc{WillnerMassonneRingetal.2012, author = {Willner, Arne P. and Massonne, Hans-Joachim and Ring, Uwe and Sudo, Masafumi and Thomson, Stuart N.}, title = {P-T evolution and timing of a late Palaeozoic fore-arc system and its heterogeneous Mesozoic overprint in north-central Chile (latitudes 31-32° S)}, series = {Postprints der Universit{\"a}t Potsdam : Mathematisch-Naturwissenschaftliche Reihe}, journal = {Postprints der Universit{\"a}t Potsdam : Mathematisch-Naturwissenschaftliche Reihe}, number = {597}, issn = {1866-8372}, doi = {10.25932/publishup-41490}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-414909}, pages = {31}, year = {2012}, abstract = {In the late Palaeozoic fore-arc system of north-central Chile at latitudes 31-32 degrees S (from the west to the east) three lithotectonic units are telescoped within a short distance by a Mesozoic strikeslip event (derived peak P-T conditions in brackets): (1) the basally accreted Choapa Metamorphic Complex (CMC; 350-430 degrees C, 6-9 kbar), (2) the frontally accreted Arrayan Formation (AF; 280-320 degrees C, 4-6 kbar) and (3) the retrowedge basin of the Huentelauquen Formation (HF; 280-320 degrees C, 3-4 kbar). In the CMC, Ar-Ar spot ages locally date white-mica formation at peak P-T conditions and during early exhumation at 279-242 Ma. In a local garnet mica-schist intercalation (570-585 degrees C, 11-13 kbar) Ar-Ar spot ages refer to the ascent from the subduction channel at 307-274 Ma. Portions of the CMC were isobarically heated to 510-580 degrees C at 6.6-8.5 kbar. The age of peak P-T conditions in the AF can only vaguely be approximated at >= 310 Ma by relict fission-track ages consistent with the observation that frontal accretion occurred prior to basal accretion. Zircon fission-track dating indicates cooling below similar to 280 degrees C at similar to 248 Ma in the CMC and the AF, when a regional unconformity also formed. Ar-Ar white-mica spot ages in parts of the CMC and within the entire AF and HF point to heterogeneous resetting during Mesozoic extensional and shortening events at similar to 245-240 Ma, similar to 210-200 Ma, similar to 174-159 Ma and similar to 142-127 Ma. The zircon fission-track ages are locally reset at 109-96 Ma. All resetting of Ar-Ar white-mica ages is proposed to have occurred by in situ dissolution/precipitation at low temperature in the presence of locally penetrating hydrous fluids. Hence syn-and postaccretionary events in the fore-arc system can still be distinguished and dated in spite of its complex heterogeneous postaccretional overprint.}, language = {en} } @article{WillemseCornelissenTurgut2012, author = {Willemse, Marloes and Cornelissen, Sebastiaan and Turgut, Pelin}, title = {Relating the attitudes represented in the maps of the atlas of European values to the students}, series = {Potsdamer geographische Praxis}, journal = {Potsdamer geographische Praxis}, number = {1}, publisher = {Universit{\"a}tsverlag Potsdam}, address = {Potsdam}, issn = {2194-1599}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus-65834}, pages = {69 -- 74}, year = {2012}, abstract = {1. The meaning of religious (sacred) places 2. Why be religious? 3. Secularism in Europe 4. Youth and religion ('No creo en el jamas' (Juanes)) 5. Football \& religion 6. Religion and politics 7. Penguins in heaven 8. Lucky Charms 9. Unity in Diversity 10. Religion and active citizenship}, language = {en} } @misc{WattendorfFestmanWestermannetal.2012, author = {Wattendorf, Elise and Festman, Julia and Westermann, Birgit and Keil, Ursula and Zappatore, Daniela and Franceschini, Rita and Luedi, Georges and Radue, Ernst-Wilhelm and M{\"u}nte, Thomas F. and Rager, G{\"u}nter and Nitsch, Cordula}, title = {Early bilingualism influences early and subsequently later acquired languages in cortical regions representing control functions}, series = {Postprints der Universit{\"a}t Potsdam : Humanwissenschaftliche Reihe}, journal = {Postprints der Universit{\"a}t Potsdam : Humanwissenschaftliche Reihe}, number = {384}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-404092}, pages = {19}, year = {2012}, abstract = {Early acquisition of a second language influences the development of language abilities and cognitive functions. In the present study, we used functional Magnetic Resonance Imaging (fMRI) to investigate the impact of early bilingualism on the organization of the cortical language network during sentence production. Two groups of adult multilinguals, proficient in three languages, were tested on a narrative task; early multilinguals acquired the second language before the age of three years, late multilinguals after the age of nine. All participants learned a third language after nine years of age. Comparison of the two groups revealed substantial differences in language-related brain activity for early as well as late acquired languages. Most importantly, early multilinguals preferentially activated a fronto-striatal network in the left hemisphere, whereas the left posterior superior temporal gyrus (pSTG) was activated to a lesser degree than in late multilinguals. The same brain regions were highlighted in previous studies when a non-target language had to be controlled. Hence the engagement of language control in adult early multilinguals appears to be influenced by the specific learning and acquisition conditions during early childhood. Remarkably, our results reveal that the functional control of early and subsequently later acquired languages is similarly affected, suggesting that language experience has a pervasive influence into adulthood. As such, our findings extend the current understanding of control functions in multilinguals.}, language = {en} } @phdthesis{Waha2012, author = {Waha, Katharina}, title = {Climate change impacts on agricultural vegetation in sub-Saharan Africa}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus-64717}, school = {Universit{\"a}t Potsdam}, year = {2012}, abstract = {Agriculture is one of the most important human activities providing food and more agricultural goods for seven billion people around the world and is of special importance in sub-Saharan Africa. The majority of people depends on the agricultural sector for their livelihoods and will suffer from negative climate change impacts on agriculture until the middle and end of the 21st century, even more if weak governments, economic crises or violent conflicts endanger the countries' food security. The impact of temperature increases and changing precipitation patterns on agricultural vegetation motivated this thesis in the first place. Analyzing the potentials of reducing negative climate change impacts by adapting crop management to changing climate is a second objective of the thesis. As a precondition for simulating climate change impacts on agricultural crops with a global crop model first the timing of sowing in the tropics was improved and validated as this is an important factor determining the length and timing of the crops´ development phases, the occurrence of water stress and final crop yield. Crop yields are projected to decline in most regions which is evident from the results of this thesis, but the uncertainties that exist in climate projections and in the efficiency of adaptation options because of political, economical or institutional obstacles have to be considered. The effect of temperature increases and changing precipitation patterns on crop yields can be analyzed separately and varies in space across the continent. Southern Africa is clearly the region most susceptible to climate change, especially to precipitation changes. The Sahel north of 13° N and parts of Eastern Africa with short growing seasons below 120 days and limited wet season precipitation of less than 500 mm are also vulnerable to precipitation changes while in most other part of East and Central Africa, in contrast, the effect of temperature increase on crops overbalances the precipitation effect and is most pronounced in a band stretching from Angola to Ethiopia in the 2060s. The results of this thesis confirm the findings from previous studies on the magnitude of climate change impact on crops in sub-Saharan Africa but beyond that helps to understand the drivers of these changes and the potential of certain management strategies for adaptation in more detail. Crop yield changes depend on the initial growing conditions, on the magnitude of climate change, and on the crop, cropping system and adaptive capacity of African farmers which is only now evident from this comprehensive study for sub-Saharan Africa. Furthermore this study improves the representation of tropical cropping systems in a global crop model and considers the major food crops cultivated in sub-Saharan Africa and climate change impacts throughout the continent.}, language = {en} }