TY  - JOUR
A1  - Goebel, Ronald
A1  - White, Robin J.
A1  - Titirici, Maria-Magdalena
A1  - Taubert, Andreas
T1  - Carbon-based ionogels tuning the properties of the ionic liquid via carbon-ionic liquid interaction
T2  - Physical chemistry, chemical physics : a journal of European Chemical Societies
N2  - The behavior of two ionic liquids (ILs), 1-ethyl-3-methylimidazolium dicyanamide [Emim][DCA] and 1-ethyl-3-methylimidazolium triflate [Emim][TfO], in (meso) porous carbonaceous hosts was investigated. Prior to IL incorporation into the host, the carbon matrix was thermally annealed between 180 and 900 degrees C to control carbon condensation and surface chemistry. The resulting materials have an increasing "graphitic'' carbon character with increasing treatment temperature, reflected in a modified behavior of the ILs when impregnated into the carbon host. The two ILs show significant changes in the thermal behavior as measured from differential scanning calorimetry; these changes can be assigned to anion-pi interaction between the IL anions and the pore wall surfaces of these flexible carbonaceous support materials.
Y1  - 2012
UR  - https://publishup.uni-potsdam.de/frontdoor/index/index/docId/36332
SN  - 1463-9076
VL  - 14
IS  - 17
SP  - 5992
EP  - 5997
PB  - Royal Society of Chemistry
CY  - Cambridge
ER  -