TY  - JOUR
A1  - Krause, Pascal
A1  - Klamroth, Tillmann
A1  - Saalfrank, Peter
T1  - Time-dependent configuration-interaction calculations of laser-pulse-driven many-electron dynamics : Controlled dipole switching in lithium cyanide
N2  - We report simulations of laser-driven many-electron dynamics by means of the time-dependent configuration interaction singles (doubles) approach. The method accounts for the correlation of ground and excited states, is capable of describing explicitly time-dependent, nonlinear phenomena, and is systematically improvable. Lithium cyanide serves as a molecular test system in which the charge distribution and hence the dipole moment are shown to be switchable, in a controlled fashion, by (a series of) laser pulses which induce selective, state-to-state electronic transitions. One focus of our time-dependent calculations is the question of how fast the transition from the ionic ground state to a specific excited state that is embedded in a multitude of other states can be made, without creating an electronic wave packet. (c) 2005 American Institute of Physics
Y1  - 2005
UR  - https://publishup.uni-potsdam.de/frontdoor/index/index/docId/13725
SN  - 0021-9606
ER  -