TY  - JOUR
A1  - Kammer, Stefan
A1  - Müller, Holger
A1  - Grunwald, Nicolas
A1  - Bellin, Anja
A1  - Kelling, Alexandra
A1  - Schilde, Uwe
A1  - Mickler, Wulfhard
A1  - Dosche, Carsten
A1  - Holdt, Hans-Jürgen
T1  - Supramolecular assemblies with honeycomb structures by pi-pi stacking of octahedral metal complexes of 1,12- diazaperylene
N2  - Homoleptic Ni-II and Fe-II complexes of the "large-surface" phenanthroline-type ligand 1,12-diazaperylene (dap), [Ni(dap)(3)](BF4)(2) (1) and [Fe(dap)(3)](PF6)(2) (2), respectively, were synthesized. In the crystal structure the complex cation [M(dap)(3)](2+) (M = Ni, Fe) exhibits C-3 symmetry and interacts with three other cations by pi-pi stacking. It forms a new metalla-supramolecular assembly with a honeycomb structure containing nanochannels running parallel to the crystallographic c axis. Aggregation by pi-pi stacking between metal complexes of "large-surface" ligands should give new perspectives for inorganic supramolecular chemistry.
Y1  - 2006
UR  - https://publishup.uni-potsdam.de/frontdoor/index/index/docId/12093
UR  - http://www3.interscience.wiley.com/cgi-bin/jhome/27721/
SN  - 1343-1948
ER  -