The photo-dehydro-Diels-Alder (PDDA) reaction
- The photo-dehydro-Diels-Alder (PDDA) reaction is a valuable extension of the classical Diels-Alder (DA) reaction. The PDDA reaction differs from the DA reaction by the replacement of one of the C-C-double bonds of the diene moiety by a C-C triple bond and by the photochemical triggering of the reaction. This entails that, in contrast to the DA reaction, the PDDA reaction proceeds according to a multistage mechanism with biradicals and cycloallenes as intermediates. The PDDA reaction provides access to a considerable variety of compound classes. For example, 1-phenylnaphthlenes, 1,1'-binaphthyls, N-heterocyclic biaryls, and naphthalenophanes could be obtained by this reaction.
| Author details: | Pablo WessigORCiDGND, Annika Matthes, Charlotte Pick |
|---|---|
| DOI: | https://doi.org/10.1039/c1ob06066j |
| ISSN: | 1477-0520 |
| Title of parent work (English): | Organic & biomolecular chemistry : an international journal of synthetic, physical and biomolecular organic chemistry |
| Publisher: | Royal Society of Chemistry |
| Place of publishing: | Cambridge |
| Publication type: | Article |
| Language: | English |
| Year of first publication: | 2011 |
| Publication year: | 2011 |
| Release date: | 2017/03/26 |
| Volume: | 9 |
| Issue: | 22 |
| Number of pages: | 7 |
| First page: | 7599 |
| Last Page: | 7605 |
| Organizational units: | Mathematisch-Naturwissenschaftliche Fakultät / Institut für Chemie |
| Peer review: | Referiert |
