Anisotropic effect of the nitrate anion-manifestation of diamagnetic proton chemical shifts in the 1H NMR spectra of NO3-coordinated complexes
- The anisotropic effect of the planar nitrate anion NO3- has been ab initio calculated employing the Nucleus- Independent Chemical Shift (NICS) concept of von Ragué Schleyer and visualized as Iso-Chemical-Shielding Surfaces (ICSSs) of various (de)shieldings. Complexation-induced shifts in the 1H NMR spectra of nitrate/metal complexes or nitrate/receptor supramolecules can be separated now into anisotropic influences of the suitably coordinated nitrate anions and effects originating from differential sources.
| Verfasserangaben: | Erich KleinpeterORCiDGND, Andreas KochORCiDGND, Himansu S. Sahoo, Dillip Kumar Chand |
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| URL: | http://www.sciencedirect.com/science/article/pii/S0040402008005814 |
| DOI: | https://doi.org/10.1016/j.tet.2008.03.063 |
| Publikationstyp: | Wissenschaftlicher Artikel |
| Sprache: | Englisch |
| Jahr der Erstveröffentlichung: | 2008 |
| Erscheinungsjahr: | 2008 |
| Datum der Freischaltung: | 25.03.2017 |
| Quelle: | Tetrahedron. - 64 (2008), 22, S. 5044 - 5050 |
| Organisationseinheiten: | Mathematisch-Naturwissenschaftliche Fakultät / Institut für Chemie |
