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From π-expanded coumarins to π-expanded pentacenes

  • The synthesis of two novel types of π-expanded coumarins has been developed. Modified Knoevenagel bis-condensation afforded 3,9-dioxa-perylene-2,8-diones. Subsequent oxidative aromatic coupling or light driven electrocyclization reaction led to dibenzo-1,7-dioxacoronene-2,8-dione. Unparalleled synthetic simplicity, straightforward purification and superb optical properties have the potential to bring these perylene and coronene analogs towards various applications.

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Metadaten
Author details:Marek K. Węcławski, Mariusz Tasior, Tommy Hammann, Piotr J. Cywiński, Daniel T. Gryko
URN:urn:nbn:de:kobv:517-opus4-98822
Publication series (Volume number):Zweitveröffentlichungen der Universität Potsdam : Mathematisch-Naturwissenschaftliche Reihe (280)
Publication type:Postprint
Language:English
Date of first publication:2014/06/16
Publication year:2014
Publishing institution:Universität Potsdam
Release date:2016/11/17
Number of pages:4
Source:Chem. Commun. (2014), Nr. 50, S. 9105-9108. - DOI: 10.1039/C4CC03078H
Organizational units:Mathematisch-Naturwissenschaftliche Fakultät / Institut für Chemie
DDC classification:5 Naturwissenschaften und Mathematik / 54 Chemie / 540 Chemie und zugeordnete Wissenschaften
Peer review:Referiert
Publishing method:Open Access
License (German):License LogoKeine öffentliche Lizenz: Unter Urheberrechtsschutz
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