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Current versus temperature-induced switching in a single-molecule tunnel junction : 1,5 cyclooctadiene on Si(001)

  • The biconformational switching of single cyclooctadiene molecules chemisorbed on a Si(001) surface was explored by quantum chemical and quantum dynamical calculations and low-temperature scanning tunneling microscopy experiments. The calculations rationalize the experimentally observed switching driven by inelastic electron tunneling (IET) at 5 K. At higher temperatures, they predict a controllable crossover behavior between IET-driven and thermally activated switching, which is fully confirmed by experiment.

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Metadaten
Author:Christophe Nacci, Stefan Foelsch, Karl Zenichowski, Jadranka Dokic, Tillmann KlamrothORCiDGND, Peter SaalfrankORCiDGND
URL:http://pubs.acs.org/journal/nalefd
DOI:https://doi.org/10.1021/Nl901419g
ISSN:1530-6984
Document Type:Article
Language:English
Year of first Publication:2009
Year of Completion:2009
Release Date:2017/03/25
Source:Nano letters. - ISSN 1530-6984. - 9 (2009), 8, S. 2996 - 3000
Organizational units:Mathematisch-Naturwissenschaftliche Fakultät / Institut für Chemie
Peer Review:Referiert