Synthesis of a Co(II)-imidazolate framework from an anionic linker precursor: gas-sorption ans magnetic proberties
- A Co(II)-imidazolate-4-amide-5-imidate based MOF, IFP-5, is synthesized by using an imidazolate anion-based novel ionic liquid as a linker precursor under solvothermal conditions. IFP-5 shows significant amounts of gas (N2, CO2, CH4 and H2) uptake capacities. IFP-5 exhibits an independent high spin Co(II) centre and antiferromagnetic coupling.
| Author details: | Suvendu Sekhar MondalORCiDGND, Asamanjoy Bhunia, Serhiy Demeshok, Alexandra Kelling, Uwe SchildeORCiDGND, Christoph Janiak, Hans-Jürgen HoldtORCiD |
|---|---|
| URL: | http://pubs.rsc.org/en/content/articlelanding/2013/ce/c3ce42040j |
| Publication type: | Article |
| Language: | English |
| Year of first publication: | 2008 |
| Publication year: | 2008 |
| Release date: | 2017/03/25 |
| Source: | CrystEngComm. - 1 (2014), 16, S. 39 - 42 |
| Organizational units: | Mathematisch-Naturwissenschaftliche Fakultät / Institut für Chemie |
