Probing the Hofmeister effect with ultrafast core-hole spectroscopy

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In the current work, X-ray emission spectra of aqueous solutions of different inorganic salts within the Hofmeister series are presented. The results reflect the direct interaction of the ions with the water molecules and therefore, reveal general properties of the salt-water interactions. Within the experimental precision a significant effect of the ions on the water structure has been observed but no ordering according to the structure maker/structure breaker concept could be mirrored in the results indicating that the Hofmeister effect if existent may be caused by more complex interactions.

Metadaten
Author details:	Zhong Yin, Ivan Rajkovic, Katharina Kubicek, Wilson Quevedo, Annette Pietzsch ORCiD, Philippe Wernet, Alexander Föhlisch ORCiD GND, Simone Techert
DOI:	https://doi.org/10.1021/jp504577a
ISSN:	1520-6106
Pubmed ID:	https://pubmed.ncbi.nlm.nih.gov/25029209
Title of parent work (English):	The journal of physical chemistry : B, Condensed matter, materials, surfaces, interfaces & biophysical chemistry
Publisher:	American Chemical Society
Place of publishing:	Washington
Publication type:	Article
Language:	English
Year of first publication:	2014
Publication year:	2014
Release date:	2017/03/27
Volume:	118
Issue:	31
Number of pages:	6
First page:	9398
Last Page:	9403
Funding institution:	German Science Foundation (DFG) [SFB755, SFB 1073]; Advanced Study Group of the Max Planck Society; Deutsches Elektronen-Synchrotron; Helmholtz Zentrum Berlin; Volkswagen foundation under the Peter Paul Ewald fellowship program [I/85832]; European Community [290605 (PSI- FELLOW/COFUND)]
Organizational units:	Mathematisch-Naturwissenschaftliche Fakultät / Institut für Physik und Astronomie
Peer review:	Referiert