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A supramolecular Co(II)(14)- metal-organic cube in a hydrogen-bonded network and a Co(II)-organic framework with a flexible methoxy substituent

  • The reaction of 4,5-dicyano-2-methoxyimidazole (L1) with Co(NO3)(2.) 6H(2)O under solvothermal conditions in DMF, a MOF, IFP-8 and a hydrogen-bonded network consisting of tetradecanuclear Co(II)(14)-metal organic cube (1) are achieved. 1 shows the bcu net with 14 cobalt atoms.

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Author:Suvendu Sekhar Mondal, Asamanjoy Bhunia, Alexandra Kelling, Uwe SchildeORCiDGND, Christoph Janiak, Hans-Jürgen Holdt
ISSN:1359-7345 (print)
ISSN:1364-548X (online)
Pubmed Id:http://www.ncbi.nlm.nih.gov/pubmed?term=24710036
Parent Title (English):Chemical communications
Publisher:Royal Society of Chemistry
Place of publication:Cambridge
Document Type:Article
Year of first Publication:2014
Year of Completion:2014
Release Date:2017/03/27
First Page:5441
Last Page:5443
Funder:Priority Program 1362 of the German Research Foundation on "Metal-Organic Frameworks"
Organizational units:Mathematisch-Naturwissenschaftliche Fakultät / Institut für Chemie
Peer Review:Referiert