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A supramolecular Co(II)₁₄-metal–organic cube in a hydrogen-bonded network and a Co(II)–organic framework with a flexible methoxy substituent

  • The reaction of 4,5-dicyano-2-methoxyimidazole (L1) with Co(NO3)2·6H2O under solvothermal conditions in DMF, a MOF, IFP-8 and a hydrogen-bonded network consisting of tetradecanuclear Co(II)14-metal organic cube (1) are achieved. 1 shows the bcu net with 14 cobalt atoms.

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Author details:Suvendu Sekhar MondalORCiDGND, Asamanjoy Bhunia, Alexandra Kelling, Uwe SchildeORCiDGND, Christoph Janiak, Hans-Jürgen HoldtORCiD
DOI:https://doi.org/10.1039/c3cc49698h
ISSN:2046-2069
Title of parent work (English):Chemical communications : ChemComm
Publisher:Royal Society of Chemistry
Publication type:Article
Language:English
Date of first publication:2014/03/26
Publication year:2014
Release date:2015/03/20
Tag:zinc
Volume:2014
Issue:41
Number of pages:3
First page:5441
Last Page:5443
Organizational units:Mathematisch-Naturwissenschaftliche Fakultät
DDC classification:5 Naturwissenschaften und Mathematik / 54 Chemie / 540 Chemie und zugeordnete Wissenschaften
Peer review:Referiert
Publishing method:Open Access
Grantor:RSC
License (English):License LogoCreative Commons - Namensnennung 3.0 Unported
External remark:Zweitveröffentlichung als Postprints der Universität Potsdam : Mathematisch-Naturwissenschaftliche Reihe ; 169
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