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Giant Zn-14 molecular building block in hydrogen-bonded network with permanent porosity for gas uptake

  • In situ imidazolate-4,5-diamide-2-olate linker generation leads to the formation of a [Zn-14(L2)(12)(O)-(OH)(2)(H2O)(4)] molecular building block (MBB) with a Zn-6 octahedron inscribed in a Zn-8 cube. The MBBs connect by amide-amide hydrogen bonds to a 3D robust supramolecular network which can be activated for N-2, CO2, CH4, and H-2 gas sorption.

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Author:Suvendu Sekhar Mondal, Asamanjoy Bhunia, Alexandra Kelling, Uwe SchildeORCiDGND, Christoph Janiak, Hans-Jürgen Holdt
ISSN:0002-7863 (print)
Pubmed Id:http://www.ncbi.nlm.nih.gov/pubmed?term=24313724
Parent Title (English):Journal of the American Chemical Society
Publisher:American Chemical Society
Place of publication:Washington
Document Type:Article
Year of first Publication:2014
Year of Completion:2014
Release Date:2017/03/27
First Page:44
Last Page:47
Funder:German Research Foundation on "Metal-Organic Frameworks" [1362]
Organizational units:Mathematisch-Naturwissenschaftliche Fakultät / Institut für Chemie
Peer Review:Referiert