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Gate effects in a hexagonal zinc-imidazolate-4-amide-5-imidate framework with flexible methoxy substituents and CO2 selectivity

  • A new imidazolate-4-amide-5-imidate based MOF, IFP-7, is generated, having flexible methoxy groups, which act as molecular gates for guest molecules. This allows highly selective CO2 sorption over N-2 and CH4 gases.

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Author:Suvendu Sekhar Mondal, Asamanjoy Bhunia, Igor A. Baburin, Christian Jäger, Alexandra Kelling, Uwe SchildeORCiDGND, Gotthard Seifert, Christoph Janiak, Hans-Jürgen Holdt
ISSN:1359-7345 (print)
Parent Title (English):Chemical communications
Publisher:Royal Society of Chemistry
Place of publication:Cambridge
Document Type:Article
Year of first Publication:2013
Year of Completion:2013
Release Date:2017/03/26
First Page:7599
Last Page:7601
Funder:German Research Foundation on "Metal-Organic Frameworks"
Organizational units:Mathematisch-Naturwissenschaftliche Fakultät / Institut für Chemie
Peer Review:Referiert