Syntheses of two imidazolate-4-amide-5-imidate linker based hexagonal metal-organic frameworks with flexible ethoxy substituent
- A rare example of in situ linker generation with the formation of soft porous Zn- and Co-MOFs (IFP-9 and -10, respectively) is reported. The flexible ethoxy groups of IFP-9 and -10 protrude into the 1D hexagonal channels. The gas- sorption behavior of both materials for H2, CO2 and CH4 showed wide hysteretic isotherms, typical for MOFs having a flexible substituent which can give rise to a gate effect.
| Verfasserangaben: | Suvendu Sekhar MondalORCiDGND, Subarna Dey, Igor A. Baburin, Alexandra Kelling, Uwe SchildeORCiDGND, Christoph Janiak, Hans-Jürgen HoldtORCiD |
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| URL: | http://pubs.rsc.org/en/Content/ArticleLanding/2013/CE/c3ce41632a |
| DOI: | https://doi.org/10.1039/C3CE41632A |
| Publikationstyp: | Wissenschaftlicher Artikel |
| Sprache: | Englisch |
| Jahr der Erstveröffentlichung: | 2008 |
| Erscheinungsjahr: | 2008 |
| Datum der Freischaltung: | 25.03.2017 |
| Quelle: | CrystEngComm. - 45 (2013), 15, S. 9394 - 9399 |
| Organisationseinheiten: | Mathematisch-Naturwissenschaftliche Fakultät / Institut für Chemie |
