Supramolecular assemblies with honeycomb structures by pi-pi stacking of octahedral metal complexes of 1,12- diazaperylene
- Homoleptic Ni-II and Fe-II complexes of the "large-surface" phenanthroline-type ligand 1,12-diazaperylene (dap), [Ni(dap)(3)](BF4)(2) (1) and [Fe(dap)(3)](PF6)(2) (2), respectively, were synthesized. In the crystal structure the complex cation [M(dap)(3)](2+) (M = Ni, Fe) exhibits C-3 symmetry and interacts with three other cations by pi-pi stacking. It forms a new metalla-supramolecular assembly with a honeycomb structure containing nanochannels running parallel to the crystallographic c axis. Aggregation by pi-pi stacking between metal complexes of "large-surface" ligands should give new perspectives for inorganic supramolecular chemistry.
| Author details: | Stefan Kammer, Holger Müller, Nicolas Grunwald, Anja Bellin, Alexandra Kelling, Uwe SchildeORCiDGND, Wulfhard Mickler, Carsten DoscheGND, Hans-Jürgen HoldtORCiD |
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| URL: | http://www3.interscience.wiley.com/cgi-bin/jhome/27721/ |
| DOI: | https://doi.org/10.1002/ejic.200600092 |
| ISSN: | 1343-1948 |
| Publication type: | Article |
| Language: | English |
| Year of first publication: | 2006 |
| Publication year: | 2006 |
| Release date: | 2017/03/24 |
| Source: | European journal of inorganic chemistry. - ISSN 1343-1948. - (2006), 8, S. 1547 - 1551 |
| Organizational units: | Mathematisch-Naturwissenschaftliche Fakultät / Institut für Chemie |
| Peer review: | Referiert |
| Institution name at the time of the publication: | Mathematisch-Naturwissenschaftliche Fakultät / Institut für Organische Chemie und Strukturanalytik |
