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Microwave synthesis and inherent stabilization of metal nanoparticles in 1-methyl-3-(3-carboxyethyl)-imidazolium tetrafluoroborate

  • The synthesis of Co-NPs and Mn-NPs by microwave-induced decomposition of the metal carbonyls Co-2(CO)(8) and Mn-2(CO)(10), respectively, yields smaller and better separated particles in the functionalized IL 1-methyl-3-(3-carboxyethyl)-imidazolium tetrafluoroborate [EmimCO(2)H][BF4] (1.6 +/- 0.3 nm and 4.3 +/- 1.0 nm, respectively) than in the non-functionalized IL 1-n-butyl-3-methylimidazolium tetrafluoroborate [Bmim][BF4]. The particles are stable in the absence of capping ligands (surfactants) for more than six months although some variation in particle size could be observed by TEM.

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Metadaten
Author:Dorothea Marquardt, Zailai Xie, Andreas TaubertORCiDGND, Ralf Thomann, Christoph Janiak
DOI:https://doi.org/10.1039/c1dt10795j
ISSN:1477-9226 (print)
Parent Title (English):Dalton transactions : a journal of inorganic chemistry, including bioinorganic, organometallic, and solid-state chemistry
Publisher:Royal Society of Chemistry
Place of publication:Cambridge
Document Type:Article
Language:English
Year of first Publication:2011
Year of Completion:2011
Release Date:2017/03/26
Volume:40
Issue:33
Pagenumber:4
First Page:8290
Last Page:8293
Funder:University of Potsdam, through DFG [Ja466/17-1]; Fonds der Chemischen Industrie; MPI of Colloids and Interfaces (Colloid Chemistry Department); Chinese Science Council
Organizational units:Mathematisch-Naturwissenschaftliche Fakultät / Institut für Chemie
Peer Review:Referiert