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Polar substituent effect of the ester group on conformational equilibria of O-mono-substituted cyclohexanesùthe para-substituent effect in cyclohexyl benzoates

  • Together with the nonsubstituted reference compound, para-methoxy- and para-nitro cyclohexyl benzoates have been synthesized and their conformational equilibria studied by low temperature NMR spectroscopy and theoretical DFT calculations. The free energy differences ;G° between axial and equatorial conformers were examined with respect to polar substituent influences on the conformational equilibrium of O-mono-substituted cyclohexane.

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Author:Erich Kleinpeter, Ute Bölke, Andrea Frank
Document Type:Article
Year of first Publication:2008
Year of Completion:2008
Release Date:2017/03/24
Source:Tetrahedron. - 64 (2008), 42, S. 10014 - 10017
Organizational units:Mathematisch-Naturwissenschaftliche Fakultät / Institut für Chemie
Peer Review:Referiert