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Syntheses of two imidazolate-4-amide-5-imidate linker-based hexagonal metal-organic frameworks with flexible ethoxy substituent

  • A rare example of in situ linker generation with the formation of soft porous Zn- and Co-MOFs (IFP-9 and -10, respectively) is reported. The flexible ethoxy groups of IFP-9 and -10 protrude into the 1D hexagonal channels. The gas-sorption behavior of both materials for H-2, CO2 and CH4 showed wide hysteretic isotherms, typical for MOFs having a flexible substituent which can give rise to a gate effect.

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Author details:Suvendu Sekhar MondalORCiDGND, Subarna Dey, Igor A. Baburin, Alexandra Kelling, Uwe SchildeORCiDGND, Gotthard Seifert, Christoph Janiak, Hans-Jürgen HoldtORCiD
DOI:https://doi.org/10.1039/c3ce41632a
ISSN:1466-8033
Title of parent work (English):CrystEngComm
Publisher:Royal Society of Chemistry
Place of publishing:Cambridge
Publication type:Article
Language:English
Year of first publication:2013
Publication year:2013
Release date:2017/03/26
Volume:15
Issue:45
Number of pages:6
First page:9394
Last Page:9399
Funding institution:German Research Foundation on "Metal-Organic Frameworks" [1362]
Organizational units:Mathematisch-Naturwissenschaftliche Fakultät / Institut für Chemie
Peer review:Referiert
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