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Syntheses of two imidazolate-4-amide-5-imidate linker-based hexagonal metal–organic frameworks with flexible ethoxy substituent

  • A rare example of in situ linker generation with the formation of soft porous Zn- and Co-MOFs (IFP-9 and -10, respectively) is reported. The flexible ethoxy groups of IFP-9 and -10 protrude into the 1D hexagonal channels. The gas-sorption behavior of both materials for H2, CO2 and CH4 showed wide hysteretic isotherms, typical for MOFs having a flexible substituent which can give rise to a gate effect.

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Author:Suvendu Sekhar Mondal, Subarna Dey, Igor A. Baburin, Alexandra Kelling, Uwe SchildeORCiDGND, Gotthard Seifert, Christoph Janiak, Hans-Jürgen Holdt
Series (Serial Number):Postprints der Universität Potsdam : Mathematisch-Naturwissenschaftliche Reihe (234)
Document Type:Postprint
Date of first Publication:2013/10/08
Year of Completion:2013
Publishing Institution:Universität Potsdam
Release Date:2016/08/11
Tag:adsorption; behavior; carbon-dioxide; crystals; gases; ligand; pressure; selectivity; temperature; zinc
First Page:9394
Last Page:9399
Source:CrystEngComm (2013) Nr. 15, S. 9394-9399. - DOI: 10.1039/C3CE41632A
Organizational units:Mathematisch-Naturwissenschaftliche Fakultät / Institut für Chemie
Dewey Decimal Classification:5 Naturwissenschaften und Mathematik / 54 Chemie / 540 Chemie und zugeordnete Wissenschaften
Peer Review:Referiert
Publication Way:Open Access
Licence (German):License LogoKeine Nutzungslizenz vergeben - es gilt das deutsche Urheberrecht